共查询到19条相似文献,搜索用时 93 毫秒
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碳二加氢反应器的切换是乙烯装置运行过程中的重大操作工序,而离线切换会造成乙烯产品的大量损失。文中介绍的是天津乙烯在不干扰其它设备的运行和不影响产品质量的前提下,在线无扰动切换碳二加把反应器的方法。 相似文献
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从理论推导得出碳二加氢催化剂选择性快速评价法,并用此方法对三种碳二加氢催化剂选择性进行评价,并指出此快速评价法的独特应用。 相似文献
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经过多年来对碳二加氢反应器切换方式的摸索实践认为,单段床加氢反应流程中在线切换可行。双段床加氢反应流程,采用全加氢负荷在线切换,完全可保证乙炔加氢反应合格。 相似文献
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碳四组分对碳二加氢系统的影响 总被引:1,自引:0,他引:1
论述了碳二加氢进料C4组分含量较高的原因及其对反应器的影响,提出了避免反应器飞温和出口漏炔的方法,减少乙烯损失,提高经济效益,节能降耗。 相似文献
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Amornchai Arpornwichanop Paisan Kittisupakorn Yaneeporn Patcharavorachot Iqbal M. Mujtaba 《Journal of Industrial and Engineering Chemistry》2008,14(2):175-181
This study focuses on the implementation of a nonlinear model predictive control (MPC) algorithm for controlling an industrial fixed-bed reactor where hydrogenations of raw pyrolysis gasoline occur. An orthogonal collocation method is employed to approximate the original reactor model consisting of a set of partial differential equations. The approximate model obtained is used in the synthesis of a MPC controller to control the temperature rising across a catalyst bed within the reactor. In the MPC algorithm, a sequential optimization approach is used to solve an open-loop optimal control problem. Feedback information is incorporated in the MPC to compensate for modeling error and unmeasured disturbances. The control studies are demonstrated in cases of set point tracking and disturbance rejection. 相似文献
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A novel combination of catalyst carrier and reactor design was developed for intensified production of vitamin intermediates. The so called Design Porous Structured Reactor (DPSR) is a laser sintered porous 3D-structure that can be tailored to the desired reaction properties such as fluid conditions or heat removal and can also act simultaneously as catalyst support.The selective hydrogenation of 2-methyl-3-butyn-2-ol (MBY) to 2-methyl-3-buten-2-ol (MBE) under solvent-free conditions was chosen as the reaction to evaluate the potential of DPSRs in comparison to conventional batch reactors. DPSR experiments were performed at varying temperatures and liquid flow rates.DPSRs exceeded batch performance in terms of selectivity, yield and turnover frequency in the analyzed process parameter range. However, DPSRs showed some mass transfer effects. Selectivities and yields increased with higher liquid flow rate due to reduced system pressures and sharper residence time distributions.Overall mass transfer coefficients for DPSRs were determined based on an isothermal non-ideal plug flow model applying heterogeneous Langmuir–Hinshelwood kinetics to account for the chemical conversion. The model showed sufficient accuracy to describe the occurring mass transfer processes.DPSRs were found to be viable alternative for batch reactors, demonstrating the potential for process intensification with an inherent potential for further improvement. 相似文献
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Katsuki Kusakabe Shigeharu Morooka Hideaki Maeda 《Korean Journal of Chemical Engineering》2001,18(3):271-276
The purpose of this article is to demonstrate the applicability of microreactors for use in catalytic reactions at elevated
temperatures. Microchannels were fabricated on both sides of a silicon wafer by wet chemical etching after pattern transfer
using a negative photoresist. The walls of the reactor channel were coated with a platinum layer, for use as a sample catalyst,
by sputtering. A heating element was installed in the channel on the opposite surface of the reactor channel. The reactor
channel was sealed gas-tight with a glass plate by using an anodic bonding technique. A small-scale palladium membrane was
also prepared on the surface of a 50-Μm thick copper film. In the membrane preparation, a negative photoresist was spin-coated
and solidified to serve as a protective film. A palladium layer was then electrodeposited on the other uncovered surface.
After the protective film was removed, the resist was again spin-coated on the copper surface, and a pattern of microslits
was transferred by photolithography. After development, the microslits were electrolitically etched away, resulting in the
formation of a palladium membrane as an assemblage of thin layers formed in the microslits. The integration of the microreactor
and the membrane is currently under way. 相似文献
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通过对大庆石化碳二加氢反应器运行状态进行分析,研究了反应温度、空速、一氧化碳、碳四含量对碳二加氢反应器的影响,并提出优化操作方法,保证反应器长周期运行。 相似文献
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Paisan Kittisupakorn Mohamed Azlan Hussain 《Korean Journal of Chemical Engineering》2000,17(3):368-372
The reactant concentration control of a reactor using Model Predictive Control (MPC) is presented in this paper. Two major
difficulties in the control of reactant concentration are that the measurement of concentration is not available for the control
point of view and it is not possible to control the concentration without considering the reactor temperature. Therefore,
MIMO control techniques and state and parameter estimation are needed. One of the MIMO control techniques widely studied recently
is MPC. The basic concept of MPC is that it computes a control trajectory for a whole horizon time minimising a cost function
of a plant subject to a dynamic plant model and an end point constraint. However, only the initial value of controls is then
applied. Feedback is incorporated by using the measurements/estimates to reconstruct the calculation for the next time step.
Since MPC is a model based controller, it requires the measurement of the states of an appropriate process model. However,
in most industrial processes, the state variables are not all measurable. Therefore, an extended Kalman filter (EKF), one
of estimation techniques, is also utilised to estimate unknown/uncertain parameters of the system. Simulation results have
demonstrated that without the reactor temperature constraint, the MPC with EKF can control the reactant concentration at a
desired set point but the reactor temperator is raised over a maximum allowable value. On the other hand, when the maximun
allowable value is added as a constraint, the MPC with EKF can control the reactant concentration at the desired set point
with less drastic control action and within the reactor temperature constraint. This shows that the MPC with EKF is applicable
to control the reactant concentration of chemical reactors. 相似文献
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Woo Jae Kim Chang Hun Choi Sang Heup Moon 《Korean Journal of Chemical Engineering》2002,19(4):617-621
Variation in the selectivity of ethylene produced by acetylene hydrogenation in an integral reactor was analyzed as a function
of the hydrogen/acetylene ratio in the reaction stream at the reactor inlet. The analyses were made for two sample catalysts,
which showed different dependence of the ethylene selectivity on the reactant composition. Even a small mismatch between the
hydrogen/acetylene ratio at the reactor inlet and the ratio for converted reactants caused a large change in the ethylene
selectivity along the reactor position, particularly when the conversion was high. The results of this study indicate two
important factors to be considered in the design and operation of acetylene hydrogenation process: the hydrogen/acetylene
ratio in the reactor inlet should be controlled close to the ratio for converted reactants; and catalysts showing high ethylene
selectivity over a wide range of the hydrogen/ acetylene ratio are required for the design of a highly selective hydrogenation
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This paper is dedicated to Professor Wha Young Lee on the occasion 相似文献
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A generic model predictive control framework has been proposed for a fixed-bed reactor with exothermic reaction. The proposed
framework can conduct nonlinear inferential control of a product concentration together with linear multivariable control
of bed temperatures. In addition, the framework can accommodate the multi-rate sampling and analysis delay caused by the product
measurement. Performance of the proposed technique has been demonstrated with a non-adiabatic fixed bed reactor model producing
maleic anhydride under various operating scenarios. 相似文献
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本文主要讨论分析了轻烃分馏分公司戊烷精分车间装置先进性系统建立的原因,以及建立过程中出现的问题,投用后取得的成效。这次采用先进控制技术对原有的DCS集散系统进行了进一步的优化。该技术是在国内同类装置上首次应用,使我国乃至亚洲戊烷精分装置的综合自动化水平实现了重大突破。它的最大作用是可以克服各种干扰因素,实现对戊烷精分装置的稳定、快速和准确的控制,同时通过优化调整工艺参数实现产品质量和产量的"卡边"控制。 相似文献