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采用动态硫化方法制备高聚合度聚氯乙烯(HPVC)/SBR共混型热塑性弹性体,考察了单一组分相容剂「相容剂分别为NBR270、NBR P65、CPE和氢化苯乙烯-丁二烯、苯乙烯嵌段共聚物(SEBS)」、复合相容剂(SEBS/NBR和CPE/NBR)及交联程度对HPVC/SBR共混体系相容性的影响。结果表明,使用复合相容剂可明显改善HPVC/SBR共混物的性能;动态硫化在改善共混物力学性能方面起主要作 相似文献
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PVC/SBR热塑性弹性体的研制 总被引:1,自引:0,他引:1
以ABS、氯丁橡胶(CR)、马来酸酐(MA)接枝SBR(SBR-MA)作增容剂对PVC/SBR的共混比、增容剂、增塑剂用量做了优化选择。同时对动态硫化PVC/SBR的硫化体系、硫化工艺条件进行了探讨,并比较了动态硫化对共混体性能的影响。结果表明:PVC/SBR为80/20,增容剂ABS/SBR-MA为5/5时,选用半有效硫化体系,165℃下动态硫化6min,共混物综合性能最佳 相似文献
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从硫化特性、热变形值、凝胶质量分数和物理性能等方面考察了四亚乙基五胺(TEPA)对PVC和PVC/NBR共混物的交联作用以及PVC和NBR同时交联对共混物性能的影响。结果表明,PVC/NBR共混物中的PVC组分交联后,共混物的物理性能和热变形性能都有所改善;PVC和NBR两组分同时交联可改善共混物的物理性能和热变形性能,在NBR用量较大(60份以上)时效果更为明显,若NBR用量太低,则共混物热变形性能反而有所下降;交联剂TEPA对硫黄硫化NBR有一定抑制作用,对共混物的物理性能影响不大,但在一定用量范围内有较小的劣化作用 相似文献
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研究了橡胶型乙烯醋酸乙烯酯共聚物(EVM)/NBR共混比、硫黄和叔丁基酚醛树脂(2402树脂)硫化体系对共混物性能的影响,并对比了动态硫化和静态硫化共混物在性能上的差异。试验结果表明,EVM/NBR共混比显著影响共混物的力学性能,而采用NBR预先动态硫化的方法后,共混物胶料的挤出口型膨胀率明显减小,老化性能得到改善,同时减弱了硫黄和2402树脂等硫化体系对EVM硫化的影响,使多种硫化体系可以共存于共混物中。DSC分析表明EVM/NBR动态硫化共混物只有一个玻璃化温度,且介于EVM和NBR之间,说明EVM和NBR具有良好的相容性。 相似文献
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PVC/ENR/XNBR(NBR)动态硫化共混物 总被引:1,自引:0,他引:1
能干不氧化天然橡胶(ENR)、聚氯乙烯(PVC)和羧基丁腈橡胶(XNBR)之间的自硫化反应,实现了PVC/ENR/XNBR三元共混物的动态友化,由此得到了具有热塑性弹性体的一些典型特征的PVC/ENR/XNBR动态自硫化共混物。该人混物与自硫化反应不明显的PVC/ENR/NBR共混物进行了比较,发现动态自硫化反应显著提高了共混物的综合性能。结果表明,当橡塑比为70/30时,前者的拉伸强度为11.8 相似文献
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M. S. J. Simmonds W. M. Blaney F. Delle Monache M. Marquina Mac-Quhae G. B. Marini Bettolo 《Journal of chemical ecology》1985,11(12):1593-1599
Vismiones and ferruginins, representatives of a new class of lypophilic anthranoids from the genusVismia were found to inhibit feeding in larvae of species ofSpodoptera, Heliothis, and inLocusta migratoria. 相似文献
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Cheng-Le Zhao Shane Porzio Alan Smith Haiyan Ge H. T. Davis L. E. Scriven 《Journal of Coatings Technology and Research》2006,3(2):109-115
Despite its industrial importance, the subject of freeze-thaw (F/T) stability of latex coatings has not been studied extensively.
There is also a lack of fundamental understanding about the process and the mechanisms through which a coating becomes destabilized.
High pressure (2100 bar) freezing fixes the state of water-suspended particles of polymer binder and inorganic pigments without
the growth of ice crystals during freezing that produce artifacts in direct imaging scanning electron microscopy (SEM) of
fracture surfaces of frozen coatings. We show that by incorporating copolymerizable functional monomers, it is possible to
achieve F/T stability in polymer latexes and in low-VOC paints, as judged by the microstructures revealed by the cryogenic
SEM technique. Particle coalescence as well as pigment segregation in F/T unstable systems are visualized. In order to achieve
F/T stability in paints, latex particles must not flocculate and should provide protection to inorganic pigment and extender
particles. Because of the unique capabilities of the cryogenic SEM, we are able to separate the effects of freezing and thawing,
and study the influence of the rate of freezing and thawing on F/T stability. Destabilization can be caused by either freezing
or thawing. A slow freezing process is more detrimental to F/T stability than a fast freezing process; the latter actually
preserves suspension stability during freezing.
Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004 in Chicago,
IL. Tied for first place in The John A. Gordon Best Paper Competition. 相似文献
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Ethanol and (−)-α-Pinene: Attractant Kairomones for Bark and Ambrosia Beetles in the Southeastern US
In 2002–2004, we examined the flight responses of 49 species of native and exotic bark and ambrosia beetles (Coleoptera: Scolytidae
and Platypodidae) to traps baited with ethanol and/or (−)-α-pinene in the southeastern US. Eight field trials were conducted
in mature pine stands in Alabama, Florida, Georgia, North Carolina, and South Carolina. Funnel traps baited with ethanol lures
(release rate, about 0.6 g/day at 25–28°C) were attractive to ten species of ambrosia beetles (Ambrosiodmus tachygraphus, Anisandrus sayi, Dryoxylon onoharaensum, Monarthrum mali, Xyleborinus saxesenii, Xyleborus affinis, Xyleborus ferrugineus, Xylosandrus compactus, Xylosandrus crassiusculus, and Xylosandrus germanus) and two species of bark beetles (Cryptocarenus heveae and Hypothenemus sp.). Traps baited with (−)-α-pinene lures (release rate, 2–6 g/day at 25–28°C) were attractive to five bark beetle species
(Dendroctonus terebrans, Hylastes porculus, Hylastes salebrosus, Hylastes tenuis, and Ips grandicollis) and one platypodid ambrosia beetle species (Myoplatypus flavicornis). Ethanol enhanced responses of some species (Xyleborus pubescens, H. porculus, H. salebrosus, H. tenuis, and Pityophthorus cariniceps) to traps baited with (−)-α-pinene in some locations. (−)-α-Pinene interrupted the response of some ambrosia beetle species
to traps baited with ethanol, but only the response of D. onoharaensum was interrupted consistently at most locations. Of 23 species of ambrosia beetles captured in our field trials, nine were
exotic and accounted for 70–97% of total catches of ambrosia beetles. Our results provide support for the continued use of
separate traps baited with ethanol alone and ethanol with (−)-α-pinene to detect and monitor common bark and ambrosia beetles
from the southeastern region of the US. 相似文献
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Halyomorpha halys (Stål) (Pentatomidae), called the brown marmorated stink bug (BMSB), is a newly invasive species in the eastern USA that is rapidly spreading from the original point of establishment in Allentown, PA. In its native range, the BMSB is reportedly attracted to methyl (E,E,Z)-2,4,6-decatrienoate, the male-produced pheromone of another pentatomid common in eastern Asia, Plautia stali Scott. In North America, Thyanta spp. are the only pentatomids known to produce methyl 2,4,6-decatrienoate [the (E,Z,Z)-isomer] as part of their pheromones. Methyl 2,4,6-decatrienoates were field-tested in Maryland to monitor the spread of the BMSB and to explore the possibility that Thyanta spp. are an alternate host for parasitic tachinid flies that use stink bug pheromones as host-finding kairomones. Here we report the first captures of adult and nymph BMSBs in traps baited with methyl (E,E,Z)-2,4,6-decatrienoate in central Maryland and present data verifying that the tachinid, Euclytia flava (Townsend), exploits methyl (E,Z,Z)-2,4,6-decatrienoate as a kairomone. We also report the unexpected finding that various isomers of methyl 2,4,6-decatrienoate attract Acrosternum hilare (Say), although this bug apparently does not produce methyl decatrienoates. Other stink bugs and tachinids native to North America were also attracted to methyl 2,4,6-decatrienoates. These data indicate there are Heteroptera in North America in addition to Thyanta spp. that probably use methyl 2,4,6-decatrienoates as pheromones. The evidence that some pentatomids exploit the pheromones of other true bugs as kairomones to find food or to congregate as a passive defense against tachinid parasitism is discussed. 相似文献
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中蓝晨光化工研究院有限公司《塑料工业》编辑部 《塑料工业》2009,37(3)
收集了2007年7月~2008年6月世界塑料工业的相关资料,介绍了2007~2008年国外塑料工业的发展情况,提供了世界塑料产量、消费量及全球各类树脂的需求量及产能情况.按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(尼龙、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、特种工程塑料(聚苯·硫醚、液晶聚合物、聚醚醚酮)、通用热固性树脂(酚醛、聚氨酯、不饱和聚酯树脂、环氧树脂)不同品种的顺序,对树脂的产量、消费量、供需状况及合成工艺、产品应用开发、树脂品种的延伸及应用的进一步扩展等技术作了详细介绍. 相似文献
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中蓝晨光化工研究院《塑料工业》编辑部 《塑料工业》2007,35(3):1-25,67
收集了2005年7月~2006年6月国外塑料工业的相关资料,介绍了2005—2006年国外塑料工业的发展情况。提供了世界塑料产量、消费量及全球各类树脂生产量以及各国塑料制品的进出口情况。作为对比,介绍了中国塑料的生产情况。按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(聚酰胺、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、通用热固性树脂(酚醛、聚氨酯、不饱和树脂、环氧树脂)、特种工程塑料(聚苯硫醚、液晶聚合物、聚醚醚酮)的品种顺序,对树脂的产量、消费量、供需状况及合成工艺、产品开发、树脂品种的延伸及应用的扩展作了详细的介绍。 相似文献