Status and research of highly efficient hydrogen production through high temperature steam electrolysis at INET

Hydrogen generation through high temperature steam electrolysis (HTSE) using solid oxide electrolysis cells (SOEC) has recently received increasingly international interest in the large-scale, highly efficient nuclear hydrogen production field. The research and development of HTSE technology was initiated in INET of Tsinghua University from 2005 as one of the approaches in National Key Special Projects for HTGR which aims at promoting highly efficient and sustainable application of nuclear process heat in the future. In the past three years, the research team mainly focused on preliminary investigation, feasibility study, equipment development and fundamental research. Currently, two bench-scale equipments for the study of HTSE process and SOEC components have been designed and constructed. In addition, the research group made rapid progress in the development of novel anode materials, effective microstructure control of cathodes and theoretically quantitative analysis of hydrogen production efficiency through HTSE coupled with HTGR.     

Efficient utilization of waste heat from molten carbonate fuel cell in parabolic trough power plant for electricity and hydrogen coproduction

Direct steam generating parabolic trough power plant is an important technology to match future electric energy demand. One of the problems related to its emergence is energy storage. Solar-to-hydrogen is a promising technology for solar energy storage. Electrolysis is among the most processes of hydrogen production recently investigated. High temperature steam electrolysis is a clean process to efficiently produce hydrogen. In this paper, steam electrolysis process using solar energy is used to produce hydrogen. A heat recovery steam generator generates high temperature steam thanks to the molten carbonate fuel cell's waste heat. The analytical study investigates the energy efficiency of solar power plant, molten carbonate fuel cell and electrolyser. The impact of waste heat utilization on electricity and hydrogen generation is analysed. The results of calculations done with MATLAB software show that fuel cell produces 7.73 MWth of thermal energy at design conditions. 73.37 tonnes of hydrogen and 14.26 GWh of electricity are yearly produced. The annual energy efficiency of electrolyser is 70% while the annual mean electric efficiency of solar power plant is 18.30%.The proposed configuration based on the yearly electricity production and hydrogen generation has presented a good performance.     

Efficiency evaluation of high-temperature steam electrolytic systems coupled with different nuclear reactors

High efficiency is one of the remarkable advantages for the technology of high temperature steam electrolysis (HTSE). But when HTSE is coupled with different types of nuclear reactors, the coupled modes and materials selection of SOEC must be considered in order to achieve high overall thermal-to-hydrogen conversion efficiency. In this paper, we proposed two possible coupled modes between HTSE systems and the nuclear reactors. As for the nuclear reactor with high outlet temperature, the direct-coupled mode is a suitable choice while for the nuclear reactor with the outlet temperature of reactor lower than 650 °C an assistant electricity-heating mode could be adopted. To compare the overall thermal-to-hydrogen conversion efficiencies of two coupled modes, the simple energy flow charts for the water splitting cycle were presented and discussed. Also, the η_overall of HTSE coupled with different nuclear reactors were calculated. The results showed that HTSE should be a competitive way for large-scale hydrogen production no matter coupled with nuclear reactors with high outlet temperature or low outlet temperature.     

Efficiency of hydrogen production systems using alternative nuclear energy technologies

Nuclear energy can be used as the primary energy source in centralized hydrogen production through high-temperature thermochemical processes, water electrolysis, or high-temperature steam electrolysis. Energy efficiency is important in providing hydrogen economically and in a climate friendly manner. High operating temperatures are needed for more efficient thermochemical and electrochemical hydrogen production using nuclear energy. Therefore, high-temperature reactors, such as the gas-cooled, molten-salt-cooled and liquid-metal-cooled reactor technologies, are the candidates for use in hydrogen production. Several candidate technologies that span the range from well developed to conceptual are compared in our analysis. Among these alternatives, high-temperature steam electrolysis (HTSE) coupled to an advanced gas reactor cooled by supercritical CO₂ (S-CO₂) and equipped with a supercritical CO₂ power conversion cycle has the potential to provide higher energy efficiency at a lower temperature range than the other alternatives.     

Configuration design and performance optimum analysis of a solar-driven high temperature steam electrolysis system for hydrogen production

A new solar-driven high temperature steam electrolysis system for hydrogen production is presented, in which the main energy consumption processes such as steam electrolysis processes, heat transfer processes, and product compression processes are included. The detailed thermodynamic-electrochemical modeling of the solid oxide steam electrolysis (SOSE) is carried out, and consequently, the electrical and thermal energy required by every energy consumption process are determined. The efficiency of the system is derived, from which the effects of some of the important parameters such as the operating temperature, component thickness of the SOSE, leakage resistance, effectiveness of heat exchangers, and inlet rate of water on the performance of the system are discussed. It is found that the efficiency attains its maximum when a proper current density is chosen. The ratio of the required electric energy to the total energy input of the system is calculated, and consequently, the problem how to rationally operate the solar concentrating beam splitting device is investigated. The results obtained will be helpful for further understanding the optimal design and performance improvement of a practical solar-driven high temperature steam electrolysis system for hydrogen production.     

Investigation of solar energy utilization for production of hydrogen and sustainable chemical fertilizer: A case study

Renewable energies play a vital role in the economic and social development and progress of many countries. As one of the most significant sources of renewable energy, solar energy has been used due to its availability in many regions. Generating electricity for hydrogen production is one of the applications of solar energy. In petrochemical complexes, hydrogen is often used for producing fertilizers, especially urea fertilizers. The present study aims at investigating five major Iranian petrochemical complexes in terms of their suitability for the construction of a solar plant to produce electrolysis‐based green chemical fertilizers. To this end, a multicriteria decision‐making model is proposed, which includes the fuzzy analytic hierarchy process (AHP) and extended TODIM method of multicriteria decision making (including crisp, interval, and fuzzy numbers). The present research investigates 10 criteria for prioritizing petrochemical complexes, classified into four general categories, namely, climatic, geographic, environmental, and probability of natural disaster occurrence categories. Having calculated the weight of the criteria using the fuzzy AHP method, the alternatives are prioritized using the extended TODIM method. The methods of simple additive weighting (SAW), Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS), and VIKOR were then used for validation of the results. Results showed that the Shiraz Petrochemical Complex has the highest priority and Khorasan Petrochemical Complex has the lowest priority for producing green fertilizer via solar energy–assisted water electrolysis. By using the solar system, Shiraz Petrochemical Complex can emit over 1900 tons less pollutants in the environment per day and provides up to 8% of its annual total production through clean energy.     

Development and performance analysis of a new solar tower and high temperature steam electrolyzer hybrid integrated plant

In this article, an extensive thermodynamic performance assessment for the useful products from the solar tower and high-temperature steam electrolyzer assisted multigeneration system is performed, and also its sustainability index is also investigated. The system under study is considered for multi-purposes such as power, heating, cooling, drying productions, and also hydrogen generation and liquefaction. In this combined plant occurs of seven sub-systems; the solar tower, gas turbine cycle, high temperature steam electrolyzer, dryer process, heat pump, and absorption cooling system with single effect. In addition, the energy and exergy performance, irreversibility and sustainability index of multigeneration system are examined according to several factors, such as environment temperature, gas turbine input pressure, solar radiation and pinch point temperature of HRSG. Results of thermodynamic and sustainability assessments show that the total energetic and exergetic efficiency of suggested paper are calculated as 60.14%, 58.37%, respectively. The solar tower sub-system has the highest irreversibility with 18775 kW among the multigeneration system constituents. Solar radiation and pinch point temperature of HRSG are the most critical determinants affecting the system energetic and exergetic performances, and also hydrogen production rate. In addition, it has been concluded that, the sustainability index of multigeneration suggested study has changed between 2.2 and 3.05.     

Influence of pore formers on physical properties and microstructures of supporting cathodes of solid oxide electrolysis cells

High-temperature steam electrolysis (HTSE) systems using solid oxide electrolysis cells (SOECs) provided a promising method for highly efficient large-scale hydrogen production, which was one of the most potential hydrogen production technologies to meet the hydrogen economy demand in the future.     

Solar UT-3 thermochemical cycle for hydrogen production

The UT-3 thermochemical hydrogen producing cycle is a four step process developed at the University of Tokyo. In the process, only solid and gas reactants/products are used and the maximum temperature is 1033 K. The process has been developed to be coupled with gas cooled nuclear reactors (HTGR). In this article, a new UT-3 process is conceived to be coupled with a solar heat source. In the new process, all four reactions are carried out in a adiabatic equipment where steam (or steam + nitrogen) can be used as a vector. The operation of the process is done continuously. During sunshine hours, the energy to the process is supplied directly from the solar receiver. During cloudy periods and nights, it is supplied from a thermal storage system where the necessary high temperature heat is stored during sunshine hours. The solar UT-3 process has been evaluated using the ASPEN-PLUS code. It is found that the overall thermal efficiency is 49.5%, the exergetic efficiency is 52.9% and the process can be realized using conventional materials. Sizing of a solar hydrogen plant producing 2000 Nm³ per hour hydrogen has been carried out and operation of various equipment has been discussed.     

Life cycle assessment of high temperature electrolysis for hydrogen production via nuclear energy

A life cycle assessment (LCA) of one proposed method of hydrogen production—the high temperature electrolysis of water vapor—is presented in this paper. High temperature electrolysis offers an advantage of higher energy efficiency over the conventional low-temperature alkaline electrolysis due to reduced cell potential and consequent electrical energy requirements. The primary energy source for the electrolysis will be advanced nuclear reactors operating at temperatures corresponding to those required for the high temperature electrolysis. The LCA examines the environmental impact of the combined advanced nuclear-high temperature electrolysis plant, focusing upon quantifying the emissions of carbon dioxide, sulfur dioxide, and nitrogen oxides per kilogram of hydrogen produced. The results are presented in terms of the global warming potential (GWP) and the acidification potential (AP) of the system. The GWP for the system is 2000 g carbon dioxide equivalent and the AP, 0.15 g equivalents of hydrogen ion equivalent per kilogram of hydrogen produced. The GWP and AP of this process are one-sixth and one-third, respectively, of those for the hydrogen production by steam reforming of natural gas, and are comparable to producing hydrogen from wind- or hydro-electricity powered conventional electrolysis.     

Performance evaluation of a solarized gas turbine system integrated to a high temperature electrolyzer for hydrogen production

In this paper, the performance of a solar gas turbine (SGT) system integrated to a high temperature electrolyzer (HTE) to generate hybrid electrical power and hydrogen fuel is analyzed. The idea behind this design is to mitigate the losses in the electrical power transmission and use the enthalpy of exhaust gases released from the gas turbine (GT) to make steam for the HTE. In this context, a GT system is coupled with a solar tower including heliostat solar field and central receiver to generate electrical power. To make steam for the HTE, a flameless boiler is integrated to the SGT system applying the SGT extremely high temperature exhaust gases as the oxidizer. The results indicate that by increasing the solar receiver outlet temperature from 800 K to 1300 K, the solar share increases from 22.1% to 42.38% and the overall fuel consumption of the plant reduces from 7 kg/s to 2.7 kg/s. Furthermore, flameless mode is achievable in the boiler while the turbine inlet temperature (TIT) is maintained at the temperatures higher than 1314 K. Using constant amounts of the SGT electrical power, the HTE voltage decreases by enhancing the HTE steam temperature which result in the augmentation of the overall hydrogen production. To increase the HTE steam temperature from 950 K to 1350 K, the rate of fuel consumption in the flameless boiler increases from 0.1 m/s to 0.8 m/s; however, since the HTE hydrogen production increases from 4.24 mol/s to 16 mol/s it can be interpreted that the higher steam temperatures would be affordable. The presented hybrid system in this paper can be employed to perform more thermochemical analyses to achieve insightful understanding of the hybrid electrical power-hydrogen production systems.     

Hydrogen production by coupling pressurized high temperature electrolyser with solar tower technology

Solar hydrogen production by coupling of pressurized high temperature electrolyser with concentrated solar tower technology is studied. As the high temperature electrolyser requires constant temperature conditions, the focus is made on a molten salt solar tower due to its high storage capacity. A flowsheet was developed and simulations were carried out with Aspen Plus 8.4 software for MW-scale hydrogen production plants. The solar part was laid out with HFLCAL software. Two different scenarios were considered: the first concerns the production of 400 kg/d hydrogen corresponding to mobility use (fuel station). The second scenario deals with the production of 4000 kg/d hydrogen for industrial use. The process was analyzed from a thermodynamic point of view by calculating the overall process efficiency and determining the annual production. It was assumed that a fixed hydrogen demand exists in the two cases and it was assessed to which extent this can be supplied by the solar high temperature electrolysis process including thermal storage as well as hydrogen storage. For time periods with a potential over supply of hydrogen, it was considered that the excess energy is sold as electricity to the grid. For time periods where the hydrogen demand cannot be fully supplied, electricity consumption from the grid was considered. It was assessed which solar multiple is appropriate to achieve low consumption of grid electricity and low excess energy. It is shown that the consumption of grid electricity is reduced for increasing solar multiple but the efficiency is also reduced. At a solar multiple of 3.0 an annual solar-to-H₂ efficiency greater than 14% is achieved at grid electricity production below 5% for the industrial case (4000 kg/d). In a sensitivity study the paramount importance of electrolyser performance, i.e. efficiency and conversion, is shown.     

Geothermal‐based hydrogen production using thermochemical and hybrid cycles: A review and analysis

Geothermal‐based hydrogen production, which basically uses geothermal energy for hydrogen production, appears to be an environmentally conscious and sustainable option for the countries with abundant geothermal energy resources. In this study, four potential methods are identified and proposed for geothermal‐based hydrogen production, namely: (i) direct production of hydrogen from the geothermal steam, (ii) through conventional water electrolysis using the electricity generated through geothermal power plant, (iii) by using both geothermal heat and electricity for high temperature steam electrolysis and/or hybrid processes, and (iv) by using the heat available from geothermal resource in thermochemical processes. Nowadays, most researches are focused on high‐temperature electrolysis and thermochemical processes. Here we essentially discuss some potential low‐temperature thermochemical and hybrid cycles for geothermal‐based hydrogen production, due to their wider practicality, and examine them as a sustainable option for hydrogen production using geothermal heat. We also assess their thermodynamic performance through energy and exergy efficiencies. The results show that these cycles have good potential and attractive overall system efficiencies over 50% based on a complete reaction approach. The copper‐chlorine cycle is identified as a highly promising cycle for geothermal‐hydrogen production. Copyright © 2009 John Wiley & Sons, Ltd.     

太阳能驱动的固体氧化物电解池制氢系统性能研究

采用太阳能驱动电解水制氢是实现将太阳能转换为氢能来存储的最佳方式。该文提出一种采用光伏、光热协同驱动固体氧化物电解池（SOEC）进行高温蒸汽电解的制氢系统。建立各子系统数学模型,选取北京地区夏至日气象参数,分析太阳辐照度对制氢系统的性能影响,最后对整个系统进行能量及火用分析。结果表明,电流密度和温度是影响SOEC工作的重要因素。在电流密度较大的情况下升高温度,将有利于提高电解效率。耦合太阳能后系统最大能量及火用效率分别达到19.1%和20.3%。火用分析结果表明系统最大有用功损失发生在光电转换过程,火用损比例为87%。提升光电效率,将成为提高太阳能-氢能转换效率的关键。     

Efficient STEP (solar thermal electrochemical photo) production of hydrogen – an economic assessment

A consideration of the economic viability of hydrogen fuel production is important in the STEP (Solar Thermal Electrochemical Photo) production of hydrogen fuel. STEP is an innovative way to decrease costs and increase the efficiency of hydrogen fuel production, which is a synergistic process that can use concentrating photovoltaics (CPV) and solar thermal energy to drive a high temperature, low voltage, electrolysis (water-splitting), resulting in H₂ at decreased energy and higher solar efficiency. This study provides evidence that the STEP system is an economically viable solution for the production of hydrogen. STEP occurs at both higher electrolysis and solar conversion efficiencies than conventional room temperature photovoltaic (PV) generation of hydrogen. This paper probes the economic viability of this process, by comparing four different systems: (1) 10% or (2) 14% flat plate PV driven aqueous alkaline electrolysis H₂ production, (3) 25% CPV driven molten electrolysis H₂ production, and (4) 35% CPV driven solid oxide electrolysis H₂ production. The molten and solid oxide electrolysers are high temperature systems that can make use of light, normally discarded, for heating. This significantly increases system efficiency. Using levelized cost analysis, this study shows significant cost reduction using the STEP system. The total price per kg of hydrogen is shown to decrease from $5.74 to $4.96 to $3.01 to $2.61 with the four alternative systems. The advanced STEP plant requires less than one seventh of the land area of the 10% flat cell plant. To generate the 216 million kg H₂/year required by 1 million fuel cell vehicles, the 35% CPV driven solid oxide electrolysis requires a plant only 9.6 mi² in area. While PV and electrolysis components dominate the cost of conventional PV generated hydrogen, they do not dominate the cost of the STEP-generated hydrogen. The lower cost of STEP hydrogen is driven by residual distribution and gate costs.     

Comparative assessment of hydrogen production methods from renewable and non-renewable sources

In this study, we present a comparative environmental impact assessment of possible hydrogen production methods from renewable and non-renewable sources with a special emphasis on their application in Turkey. It is aimed to study and compare the performances of hydrogen production methods and assess their economic, social and environmental impacts, The methods considered in this study are natural gas steam reforming, coal gasification, water electrolysis via wind and solar energies, biomass gasification, thermochemical water splitting with a Cu–Cl and S–I cycles, and high temperature electrolysis. Environmental impacts (global warming potential, GWP and acidification potential, AP), production costs, energy and exergy efficiencies of these eight methods are compared. Furthermore, the relationship between plant capacity and hydrogen production capital cost is studied. The social cost of carbon concept is used to present the relations between environmental impacts and economic factors. The results indicate that thermochemical water splitting with the Cu–Cl and S–I cycles become more environmentally benign than the other traditional methods in terms of emissions. The options with wind, solar and high temperature electrolysis also provide environmentally attractive results. Electrolysis methods are found to be least attractive when production costs are considered. Therefore, increasing the efficiencies and hence decreasing the costs of hydrogen production from solar and wind electrolysis bring them forefront as potential options. The energy and exergy efficiency comparison study indicates the advantages of biomass gasification over other methods. Overall rankings show that thermochemical Cu–Cl and S–I cycles are primarily promising candidates to produce hydrogen in an environmentally benign and cost-effective way.     

Design,modelling and optimal power and hydrogen management strategy of an off grid PV system for hydrogen production using methanol electrolysis

Hydrogen used as an energy carrier and chemical element can be produced by several processes such as gasification of coal and biomass, steam reforming of fossil fuel and electrolysis of water. Each of these methods has its own advantage and disadvantage. Electrolysis process is seen as the best option for quick hydrogen production. Hydrogen generation by methanol electrolysis process (MEP) gained much attention since it guarantees high purity gas and can be compatible with renewable energies. Furthermore, due to its very low theoretical potential (0.02 V), MEP can save more than 65% of electrical energy required to produce 1 kg of hydrogen compared to water electrolysis process (WEP). Electrolytic hydrogen production using solar photovoltaic (PV) energy is positioned to become as one of the preferred options due to the harmful environmental impacts of widely used methane steam reforming process and also since the prices of PV modules are more competitive.In this paper, hydrogen production by MEP using PV energy is investigated. A design of an off grid PV/battery/MethElec system is proposed. Mathematical models of each component of the system are presented. Semi-empirical relationship between hydrogen production rate and power consumption at 80 °C and 4 M concentration is developed. Optimal power and hydrogen management strategy (PHMS) is designed to achieve high system efficiency and safe operation. Case studies are carried out on two tilts of PV array: horizontal and tilted at 36° using measured meteorological data of solar irradiation and ambient temperature of Algiers site. Simulation results reveal great opportunities of hydrogen production using MEP compared to the WEP with 22.36 g/m² d and 24.38 g/m² d of hydrogen when using system with horizontal and tilted PV array position, respectively.     

Energetic and exergetic assessments of a novel solar power tower based multigeneration system with hydrogen production and liquefaction

In this article, a thermodynamic investigation of solar power tower assisted multigeneration system with hydrogen production and liquefaction is presented for more environmentally-benign multigenerational outputs. The proposed multigeneration system is consisted of mainly eight sub-systems, such as a solar power tower, a high temperature solid oxide steam electrolyzer, a steam Rankine cycle with two turbines, a hydrogen generation and liquefaction cycle, a quadruple effect absorption cooling process, a drying process, a membrane distillation unit and a domestic hot water tank to supply hydrogen, electrical power, heating, cooling, dry products, fresh and hot water generation for a community. The energetic and exergetic efficiencies for the performance of the present multigeneration system are found as 65.17% and 62.35%, respectively. Also, numerous operating conditions and parameters of the systems and their effects on the respective energy and exergy efficiencies are investigated, evaluated and discussed in this study. A parametric study is carried out to analyze the impact of various system design indicators on the sub-systems, exergy destruction rates and exergetic efficiencies and COPs. In addition, the impacts of varying the ambient temperature and solar radiation intensity on the irreversibility and exergetic performance for the present multigeneration system and its components are investigated and evaluated comparatively. According to the modeling results, the solar irradiation intensity is found to be the most influential parameter among other conditions and factors on system performance.     

Valuation and development of the solar hydrogen production

This article considers Algeria as a case study for the evaluation of the solar hydrogen production potential. The study relates to the design of a hydrogen generating station by water electrolysis whose energy resources are solar. The electricity supply is done by a solar tower power plant. The numerical simulation of the hydrogen production for the installation proposed is made while being based on the characteristic equations governing the electrolysis of water, hydraulic pumping system and the solar tower. The hydrogen production rate is given for various values of the solar radiation and several sites of Algeria. The results obtained by the established computer code, and of which the required goal is the determination of the most favorable conditions for a better production of hydrogen, are presented and discussed.     

Green hydrogen as feedstock: Financial analysis of a photovoltaic-powered electrolysis plant

The weather-dependent electricity generation from Renewable Energy Sources (RES), such as solar and wind power, entails that systems for energy storage are becoming progressively more important. Among the different solutions that are being explored, hydrogen is currently considered as a key technology allowing future long-term and large-scale storage of renewable power.Today, hydrogen is mainly produced from fossil fuels, and steam methane reforming (SMR) is the most common route for producing it from natural gas. None of the conventional methods used is GHG-free. The Power-to-Gas concept, based on water electrolysis using electricity coming from renewable sources is the most environmentally clean approach. Given its multiple uses, hydrogen is sold both as a fuel, which can produce electricity through fuel cells, and as a feedstock in several industrial processes. Just the feedstock could be, in the short term, the main market of RES-based hydrogen.In this paper, we present the results obtained from a techno-economic-financial evaluation of a system to produce green hydrogen to be sold as a feedstock for industries and research centres. A system which includes a 200 kW photovoltaic plant and a 180 kW electrolyser, to be located in Messina (Italy), is proposed as a case study. According to the analyses carried out, and taking into account the current development of technologies, it has been found that investment to realise a small-scale PV-based hydrogen production plant can be remunerative.