添加剂对水基乳化液极压性能的影响

采用MS 800A四球摩擦试验机,考察了7种新型添加剂在乳化液中的极压性能.并通过扫描电子显微镜(SEM)和能量色散谱(EDS)对摩擦表面进行微观分析.实验结果表明:氯化脂肪酸DA8527能在金属表面形成承载能力很强的保护膜,具有很好的极压性能;加入少量的酯类添加剂GY25和油酸异辛酯IPO时乳化液就能达到较高的p值;多硫化物RC2540对提高乳化液极压性有一定的作用,硫化脂肪RC2526和氯化石蜡P51NR的极压效果一般,水溶性磷酸酯L P 700极压性能较差.     

ESM122润滑添加剂的磨损自补偿效应研究

研制出了在不同载荷和不同行程内对45~#钢-45~#钢摩擦副及45~#钢-锡青铜摩擦副均形成负磨损,具有优异的磨损自补偿效应和摩擦学效应的磨损自补偿润滑添加剂FSAM122。红外光谱分析证实,润滑添加剂在钢和铜摩擦表面形成了由聚合酯组成的自补偿膜。     

ESMl22润滑添加剂的磨损自补偿效应研究

研制出了在不同载荷和不同行程内对45^#钢—45^#钢摩擦副及45^#钢—锡青铜摩擦副均形成负磨损，具有优异的磨损自补偿效应和摩擦学效应的磨损自补偿润滑添加剂ESMl22。红外光谱分析证实，润滑添加剂在钢和铜摩擦表面形成了由聚合酯组成的自补偿膜。     

润滑添加剂三乙醇胺硼酸酯的摩擦学特性研究

三乙醇胺硼酸酯是一种新的绿色水基全合成切削液防锈添加剂,但其在切削加工过程中的摩擦学特性尚未有报道。以钛合金与硬质合金为摩擦副,通过摩擦磨损试验比较三乙醇胺硼酸酯并与传统润滑添加剂丙三醇和聚乙二醇的摩擦学性能,同时考察不同含量的三乙醇胺硼酸酯水溶液的摩擦学性能。结果表明:三乙醇胺硼酸酯具有与丙三醇和聚乙二醇相似的减摩抗磨性能,在相对较高的载荷下,三乙醇胺硼酸酯的润滑性能更优;三乙醇胺硼酸酯水溶液的减摩抗磨性能随着其含量的增加逐渐增强,当三乙醇胺硼酸酯的体积分数达到40%以上时,溶液的润滑性能更为显著。研究表明,三乙醇胺硼酸酯有可能成为一种新型切削液润滑添加剂。     

碳酸酯对Ti6Al4V/钢摩擦副摩擦磨损性能的影响

采用SRV型微动摩擦磨损实验机分别考察了Ti6Al4V-钢摩擦副在2种碳酸酯润滑下的摩擦磨损性能,并利用扫描电子显微镜和X射线光电子能谱仪分析了Ti6Al4V磨斑表面形貌和典型元素的化学状态。结果表明,2种碳酸酯作为Ti6Al4V/钢摩擦副的润滑剂所表现出的减摩抗磨和承载能力优于其相对应的脂肪醇;载荷和频率明显影响Ti6Al4V/钢摩擦副在碳酸酯润滑下的摩擦磨损行为;碳酸二-2-乙基己酯所表现出的减摩抗磨和承载能力明显优于碳酸二辛酯;2种碳酸酯对Ti6Al4V/钢摩擦副的润滑机制为在Ti6Al4V磨损表面形成吸附膜,从而起到减摩抗磨的作用。     

时效强化2024铝合金的摩擦学性能

采用X射线衍射仪(XRD)对时效强化的2024铝合金进行分析;在MFT-R4000高速往复摩擦磨损试验机上考察强化与未强化铝合金在含二烷基二硫代氨基甲酸钼(Mo DTC)、二烷基硫代磷酸锌(ZDDP)和磷酸复酯铵盐(T391)添加剂的润滑油润滑下的摩擦磨损性能;采用扫描电镜(SEM)观察分析磨痕表面形貌;采用EDS分析磨斑表明元素含量。结果表明:时效强化2024铝不但提高了铝的表面硬度,也提高了2024铝合金的摩擦学性能。时效强化的2024铝合金润滑性能的改善归因于铝合金的时效强化及润滑剂的摩擦化学作用。     

羟基硅酸铝润滑油添加剂对钢/铸铁摩擦副磨损性能的影响

采用球盘试验和销盘试验相结合的方法,研究了钢/铸铁摩擦副在不同油润滑条件下磨损性能的变化,考察了不同含量羟基硅酸铝添加剂的作用效果,采用扫描电镜、X射线衍射仪以及纳米压痕仪对试验样品进行了分析测试。结果表明,该金属陶瓷添加剂表现出显著的抗磨性能,提高了钢/铸铁摩擦副承载能力和使用寿命;随着添加剂含量的增加,抗磨作用更加明显,负磨损现象开始出现;该添加剂可以抑制凹坑和裂纹的扩展,从而使摩擦表面形貌得到改善,并通过改变摩擦表面层的结构使摩擦副的磨损性能得到显著提高。     

铝合金加工用水基切削液润滑性能的影响因素

使用攻丝扭矩实验方法研究铝合金加工用水基切削液润滑性能的影响因素。实验结果表明,稀释液pH值、乳液粒径对润滑性能的影响最为显著,基础油含量、润滑添加剂种类及含量等亦有明显影响;稀释液pH值越低、乳液粒径越大、基础油和合成酯含量越高,润滑性能越好;三羟甲基丙烷油酸酯、乙氧基化聚合酯、氯化石蜡、硫化脂肪酸酯等均为有效的铝合金加工润滑添加剂,但硫化烯烃润滑性能较差。     

离子液体对石墨烯润滑油分散及润滑性能的影响

研究离子液体作为添加剂对石墨烯润滑油分散和润滑性能的影响。通过改变离子液体质量分数、超声功率以及时间等条件,考察离子液体/石墨烯润滑油的分散稳定性;采用Rtec多功能摩擦磨损试验机,以Si3N4/钢为摩擦副,考察不同条件下离子液体/石墨烯润滑油的摩擦学行为;采用扫描电镜和超景深显微镜对磨损表面进行分析,探究离子液体作为添加剂的润滑机制。结果表明:离子液体质量分数为0.002 5%、超声时间为60 min,超声功率为600 W时石墨烯润滑油的分散性和稳定性均显著提高;加入离子液体后,石墨烯润滑油的润滑性能提高,其摩擦因数随离子液体质量分数的增加而下降,随超声功率的增加而降低,随超声时间的增加而增加。研究发现,由于离子液体阳离子的长链结构和自身黏度较大,离子液体构成的润滑膜较厚且易于吸附在摩擦副表面,并与石墨烯发生协同作用形成了混合润滑膜,从而避免了摩擦副之间的直接接触,改善了摩擦磨损性能。     

钻杆转速对铝合金隔水管摩擦学性能的影响

以G105钻杆材料和7075铝合金隔水管材料为对摩副,通过销盘摩擦实验研究了钻杆转速对7075铝合金隔水管摩擦学性能的影响。研究结果表明:随着钻杆转速的增大,7075铝合金隔水管的磨损率先减小后增大,平均摩擦系数逐渐减小。在低钻杆转速下(50 r/min),由于大量磨粒滞留在摩擦面,主要磨损机理是磨粒磨损;在中等转速下(100 r/min),由于接触面温度升高,隔水管表面形成一层致密的摩擦层,有效地保护了铝合金隔水管基体,此时磨损机理作为氧化磨损;在高钻杆转速下,摩擦接触面温度急剧升高,此时主要磨损机理转变为粘着分层磨损。研究成果可以为钻井工程师安全使用7075铝合金隔水管提供一定的参考。     

An experiment study of hard coating and cutting fluid effect in milling aluminum alloy

This paper investigates the cutting performance of a tungsten carbide end mill with hard coating and a sulfurous boric acid ester cutting fluid in milling A6061P-T651 aluminum alloy. The experiments were conducted to compare the milling force responses and flank wear under various cutting conditions. The results indicate that adding sulfurous boric acid ester cutting fluid decreases tool wear by 12.5% for hard coating tungsten carbide end mills and decreases the milling force by 10%. Besides, the average values of side and end flank wear of TiAlN-surface multilayer end mills can be decreased 38.7% and 68.7% respectively compared with uncoated and dry end mills.     

Friction and wear characteristics of ZDDP in the sliding of steel against aluminum alloy

The tribological properties of zinc dialkyldithiophosphate (ZDDP) antiwear additives in the sliding of steel against aluminum alloy were investigated by an oscillating friction and wear apparatus, an Optimol SRV tester. It was found that ZDDP produced larger wear of aluminum alloy than base stock, especially at high concentration. The acting mechanism of ZDDP in the lubricated aluminum-on-steel system was proposed.     

Effect of ECAE on Microstructure and Tribological Properties of Cu–10%Al–4%Fe Alloy

Equal channel angular extrusion (ECAE) process was carried out for a commercial aluminum bronze alloy (Cu–10%Al–4%Fe) produced by hotrolling at high temperature. The effect of ECAE on microstructure, mechanical, and tribological properties of the alloy was investigated. Experimental results showed that the grain size of the alloy decreased with the increase of the pass number of ECAE. After applying ECAE with six passes, the hardness and yield strength of the alloy increased from 118 kgf/mm² and 356 MPa to 165 kgf/mm² and 588 MPa, respectively. The friction coefficient and wear rate of the aluminum bronze alloy were largely reduced due to the improvement of mechanical properties after ECAE. The adhesive wear was the primary wear mechanism for the specimen without ECAE, while abrasive wear was dominant for the specimen with ECAE after six passes.     

Dry Sliding Wear Behavior of Palmyra Shell Ash–Reinforced Aluminum Matrix (AlSi10Mg) Composites

High strength, light weight, ease of fabrication, excellent castability, and good wear resistance make aluminum alloy composites suitable for commercial applications. In this work, a silica-rich ash particle (palmyra shell ash) was reinforced with aluminum alloy (AlSi10Mg) composites and its mechanical and tribological properties were studied. The aluminum alloy was reinforced with 3, 6, and 9 wt% of palmyra shell ash particles, and its dry sliding wear behavior was studied using a pin-on-disc machine under different loading conditions. The result shows that the dry sliding wear resistance of Al–palmyra shell ash composites was almost similar to that of fly ash– and rice husk ash–reinforced Al-alloy composites and these composites exhibit better wear resistance compared to unreinforced alloy. The palmyra shell ash particle weight fraction significantly affects the wear and friction properties of the composites. Scanning electron microscopic examination of the worn surface reveals that at various loads palmyra shell ash particles act as load-bearing constituents and the wear resistance of the reinforced palmyra shell ash with a size range of 1–50 µm was superior to that of unreinforced alloy. Mechanical properties (hardness and tensile strength) were also studied and it was observed that the reinforced Al-alloy showed a significant increase in mechanical properties.     

The relationship between crack propagation rates and wear rates

In order to check qualitatively the validity of the analysis of crack propagation in delamination wear, wear experiments were performed with 7075-T6 and 2024-T3 aluminum alloys. The former alloy has a higher hardness (by 25%) and a faster crack propagation rate (3–10 times) in normal fatigue tests than the latter. The preliminary test results show that the wear rate of 7075-T6 aluminum is also greater than that for 2024-T3 aluminum, indicating that the wear rate correlates with the crack propagation rate.     

基于车铣技术的刀具磨损和破损分析

在车铣加工中心上，分别采用硬质合金和TiN涂层硬质合金刀片，对铝合金和不锈钢工件进行了车铣加工的刀具磨损试验，研究分析了车铣刀具的磨损和破损特征。研究表明，车铣铝合金的刀具磨损机理主要以刀具表层材料的黏结磨损为主，而车铣不锈钢的刀具磨损机理主要以刀具表层材料的疲劳-剥落磨损为主。车铣不锈钢时，刀具的损坏形式常常以微崩刃、前刀面的剥落和碎断等破损形态为主。     

2Al2铝合金微弧氧化膜性能研究

采用Na2 WO4和Na2SO3电解液对2Al2铝合金进行微弧氧化,研究了微弧氧化陶瓷膜表面形貌、截面组织、显微硬度及耐磨性等性能.结果表明,微弧氧化表面处理可以在2Al2铝合金表面形成致密并与基体结合良好的陶瓷膜,Na2WO4溶液浓度对陶瓷膜颜色、表面形貌、致密度和显微硬度都有影响,但对于陶瓷膜成膜厚度没有显著影响....     

Corrosion and wear of 6082 aluminum alloy

The corrosion and corrosive wear resistance of 6082 wrought aluminum alloy against 410 stainless steel counterface in 0.01 M NaCl solution with different concentrations of sodium molybdate dihydrate solution (0, 0.01, 0.1 and 0.5 M), were studied. The experimental results indicated that the increase in sodium molybdate dihydrate acted as an inhibitor in the 0.01 M NaCl solution resulting in a significant decrease in the corrosion current, meaning improved corrosion resistance. During the corrosive wear under free corrosion conditions of 6082 aluminum alloy specimens against 410 stainless steel counterface, the addition of sodium molybdate dihydrate inhibitor, leads to a decrease in friction coefficient of the examined pair of materials. The dominant wear mechanisms of the aluminum alloy were mainly observed to be plastic deformation and abrasion. These wear mechanisms coexisted with pitting corrosion phenomena, on the surface of this alloy.     

The role of microstructure in the impact wear of two aluminum alloys

The impact wear resistance of two aluminum alloys was investigated using flat-ended aluminum specimens impacted upon a stainless steel counterface. The counterface itself was held stationary in some tests (pure normal impact) and moved transverse to the normal impact direction in other tests (compound impact).The alloys investigated were aluminum-copper: 2011-T3 which was formulated for free-machining applications and 2124 which possessed very high fracture toughness. Thus, one alloy favors crack nucleation and growth, while the other suppresses these. A variety of tests were conducted with both alloys in compound impact loading. The peak impulsive stress was found to influence wear rates significantly; the relative sliding velocity is also an important parameter.Surface and subsurface microscopy were used to define operative wear mechanisms. With the 2011-T3 alloy, the characteristic subsurface features support the delamination theory of wear. With the 2124 alloys, subsurface features differ significantly. These features are discussed in the light of microstructural variations in the alloys.     

压渗法制备陶瓷网络复合材料摩擦行为研究

提出了三维陶瓷网络(骨架)增强金属基复合材料的新构思,设计和制备了一种新型的三维陶瓷网络(骨架)增强铝合金复合材料,研究了其在干摩擦状态下的滑动摩擦磨损行为。结果表明,基体铝合金在重载时产生严重粘着磨损,磨损层发生软化和塑性流动,而复合材料中的陶瓷颗粒暴露于磨损表面并起承载作用,从而保护基体小发生严重磨损。与基体合金相比,复合材料摩擦因数平稳而较低,且耐磨性提高6倍左右。