共查询到20条相似文献,搜索用时 296 毫秒
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为了研制碳化硅吸波纤维, 首次采用聚二甲基硅烷(PDMS)和二茂铁合成聚铁碳硅烷(PFCS), PFCS经多孔熔融纺丝、 空气不熔化和在N2中1320℃连续烧成, 可制得连续含铁碳化硅(SiC(Fe))吸波纤维; 用SiC(Fe)纤维与环氧树脂制备的结构材料具有良好的吸波性能。XPS剖面分析、 Raman光谱表明: 纤维表面有一层厚约100nm的富碳层, 由表及里铁的含量逐渐增加; 随着温度的升高游离碳的排列逐渐规整化。研究了碳对纤维性能的影响, 结果表明: 游离碳的存在有利于纤维电阻率的降低, 复介电常数和介电损耗的增大。 相似文献
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以聚硅碳硅烷和乙酰丙酮铝为原料,在反应装置的裂解柱中加入填料,在常压下合成了聚铝碳硅烷.结果表明:添加填料使合成聚铝碳硅烷的时间缩短46%,聚铝碳硅烷的从1008增大到2436,分子量的分布变窄,—Si—Si—键的含量低;在N_2气氛中,在400℃以下失重减少,在1200℃陶瓷的产率从65%提高到69%;加入填料可促进—Si—Si—链转化为—Si—C—Si—链,制备出的聚铝碳硅烷纤维在预氧化过程中氧的增重少,预氧化烧成后得到的Si—Al—C—O连续纤维强度为2.1 GPa,在Ar中1800℃烧结可得到致密的SiC(Al)纤维.纤维的结晶行为与不加填料时的类似. 相似文献
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连续Si-Fe-C-O功能陶瓷纤维的制备及其表面分析 总被引:1,自引:0,他引:1
采用聚二甲基硅烷(PDMS)?和二茂铁合成出聚铁碳硅烷(PFCS), 后者经熔融纺丝、预氧化、烧成, 可制得?电阻率低至10-2Ω·cm、拉伸强度 2.0GPa、长度>500m的连续Si-Fe-C-O纤维. 探索了连续Si-Fe-C-O纤维的制备工艺. 研究了铁对纤维电?阻率和β-SiC结晶的影响: 铁含量的增 加有利于β-SiC晶粒的增长和电阻率的降低. XPS剖面分析表明: 陶瓷纤维的表面富含碳, 随着径向深度增大铁含量增加. 相似文献
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Si-C-Fe-O功能陶瓷纤维的制备 总被引:1,自引:0,他引:1
本文采用低分子量的聚硅烷(LPS)和二茂铁合成出聚铁碳硅烷(PFCS),后者经熔融纺丝、预氧化、烧成,可制得电阻率低至10-2Ω·cm的Si-C-Fe-O纤维.在预氧化过程中,Si-H反应程度增加的同时纤维的重量增加.研究了二茂铁对纤维电阻率和β-SiC结晶的影响:二茂铁用量的增加有利于β-SiC晶粒的增长和电阻率的降低. 相似文献
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含铍碳化硅陶瓷先驱体聚铍碳硅烷的合成 总被引:2,自引:0,他引:2
以氢氧化铍、硫酸和乙酰丙酮为原料合成了乙酰丙酮铍(Be(acac)2).用乙酰丙酮铍和聚碳硅烷在加热的条件下反应一定时间,生成了树脂状的产物.反应中乙酰丙酮铍被消耗,生成产物熔点相对起始聚碳硅烷熔点升高.元素分析表明产物中含有铍元素,凝胶渗透色谱分析表明产物分子量相对起始聚碳硅烷向增大的方向发生变化.傅立叶红外光谱分析表明产物中主要存在如下结构:Si(CH3)2—CH2—,—Si(CH3)·(H)—CH2—.核磁共振1H-NMR分析表明反应物中Si—H键被消耗.根据分析结果推测了反应机理,Si—H键的消耗在产物的形成中起了重要作用.实验与理论分析表明先驱体产物是一种含铍聚碳硅烷,可以命名为聚铍碳硅烷(PBeCS).在1200℃的高温处理下产物作为先驱体可以转化为碳化硅陶瓷,元素分析表明碳化硅陶瓷中含有铍,是含铍碳化硅陶瓷. 相似文献
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《International journal for numerical methods in engineering》2018,113(9):1488-1506
In this paper, we present a new method for inserting several triangulated surfaces into an existing tetrahedral mesh generated by the meccano method. The result is a conformal mesh where each inserted surface is approximated by a set of faces of the final tetrahedral mesh. First, the tetrahedral mesh is refined around the inserted surfaces to capture their geometric features. Second, each immersed surface is approximated by a set of faces from the tetrahedral mesh. Third, following a novel approach, the nodes of the approximated surfaces are mapped to the corresponding immersed surface. Fourth, we untangle and smooth the mesh by optimizing a regularized shape distortion measure for tetrahedral elements in which we move all the nodes of the mesh, restricting the movement of the edge and surface nodes along the corresponding entity they belong to. The refining process allows approximating the immersed surface for any initial meccano tetrahedral mesh. Moreover, the proposed projection method avoids computational expensive geometric projections. Finally, the applied simultaneous untangling and smoothing process delivers a high‐quality mesh and ensures that the immersed surfaces are interpolated. Several examples are presented to assess the properties of the proposed method. 相似文献
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Standards are the basis for production enterprises to organize production ex-factory inspection trade 《中国标准化(英文版)》2008,25(1):24-25
Standards are the basis for production enterprises to organize production, ex-factory inspection, trade (delivery) and technical exchanges, product certification, quality arbitration and supervision.…… 相似文献
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A flow calorimeter for enthalpy increment measurements on condensed gases is presented. A better knowledge of the properties of the liquefied natural gas is needed, and therefore a liquid loop has been designed for our flow calorimeter. The fluid loop in the calorimeter is designed in order to avoid the two-phase region, since two phases would give compositional disturbances in the measurements. The avoidance of the two-phase region is made possible by increasing the pressure of the test fluid after the measurement section, then heating the fluid at super-critical pressure past the critical point. Finally, the fluid is throttled to the low-pressure gas state at the inlet condition of the compressor that circulates the fluid. To perform the pressure increase, a new cryogenic pump has been designed. To evaluate the new equipment, measurements were taken on liquid ethane over the temperature range 146–256 K at pressure between 0.9 and 5.1 MPa. 相似文献
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Steffen Müller-Probandt 《材料科学与工程:中英文B版...》2018,(4):161-177
We associate a variety of innovations with the term "Industry 4.0". The pioneer of many 4.0 modifications forms the basisfor the trend towards the integrated di... 相似文献
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On November 30, 2007, the China Association for Standardization (CAS) held a press conference at Beijing Diaoyutai State Guest House. Leaders from the China Household Electric Appliance Research Institute, the China Household Electric Appliance Association, and the China Consumers' Association attended and made speeches.…… 相似文献
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Zusammenfassung Bei der Gestaltung von Ernteprozessen — beispielsweise des Prozesses Mähdrusch, Körnertransport und -abnahme — als transportverbundene Fließarbeitsverfahren mit mindestens zwei verschiedenen Arbeitsmitteln gibt es einen großen Optimierungsspielraum. Solche Prozesse sind mehrstufige Bedienungsprozesse mit gemischter Anordnung der Bedienungseinrichtungen. Außerdem besitzen sie stark ausgeprägte räumliche Aspekte. Es wird vor allem gezeigt, welche Merkmale solcher Prozesse in Simulationsmodellen abgebildet sein müssen, welche Zielgrößen in Abhängigkeit von welchen Einflußgrößen unter Berücksichtigung welcher Prozeßbedingungen ermittelt werden sollten und wie der Bewertungsprozeß zur Ermittlung der gewünschten Informationen gestaltet werden muß. 相似文献
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Janet Lang 《Materials and Manufacturing Processes》2017,32(7-8):857-866
ABSTRACTThe production of ferrous metal increased during the Roman Late Republican period, Principate and Empire. The direct bloomery process was used to extract the metal from its ores using slag-tapping and slag-pit furnaces. The fuel was charcoal and an air blast was introduced by bellows-operated tuyères. Iron formed as a bloom, often as a spongy mass of metal, which contained impurities from the smelting process, including unreacted ore, fuel, slag and fragments from the furnace walls, while the metal was often inhomogeneous with varied carbon contents. Blooms were either smithed directly into bars or ingots or they were broken up, which also allowed the removal of gross impurities and a selection of pieces with similar properties to be made. These could then be forge-welded together and formed into characteristically shaped ingots. Making steel in the furnace seems to have been achieved: it depended on the ore and the furnace and conditions within it. Surface carburization was also carried out. Iron and steel were used extensively in construction and for tools and weapons. Fire welding was often used to add pieces of steel to make the edges of tools and weapons, which could be heat-treated by quenching to harden them. 相似文献
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C. Qihong W. Zhan‐Wen J. Yi J. Yehua L. Fei F. Hanguang 《Materialwissenschaft und Werkstofftechnik》2014,45(7):582-590
In the present study a high‐boron high speed steel (HSS) roll material was designed. Many expensive alloy elements have been substituted by cheap boron alloy, and high‐boron high speed steel roll has been manufactured by centrifugal casting method. The microstructures, mechanical properties and wear resistance of centrifugal casting high‐boron high speed steel roll have been investigated by optical microscopy (OM), scanning electron microscopy (SEM), and X‐ray diffraction (XRD) analysis, hardness test, impact test and wear test. The results indicated that the solidification microstructures of high‐boron high speed steel roll consisted of M2(B,C), (W,Mo)2(B,C), M3(B,C), M23(B,C)6 type borocarbides and martensite, a small amount of retained austenite. Borocarbides were continuously distributed over the grain boundary. After quenching from 1050 °C, local broken network appeared in partial borocarbides, and fine secondary borocarbide precipitated from the matrix. After tempering from 525 °C, the amount of precipitated borocarbide increased significantly. After heat treatment, the hardness of high‐boron high speed steel roll excelled 60 HRC, and its impact toughness excelled 8.0 J/cm2. The single groove steel rolling amount of high‐boron high speed steel rolls increases by 500% than that of bainite cast iron roll, when the rolls are used in K1 mill housing of bar mill. 相似文献
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Dimiter Hadjistamov 《材料科学与工程:中英文B版...》2019,(2):56-65
The definition of the thixotropy is a decrease in viscosity with time in shear and a subsequent recovery of viscosity after the shear deformation is removed.We ... 相似文献