镍在自纳米化纯铁表面的扩散系数研究

采用高能喷丸对工业纯铁棒材端面进行了表面自纳米化处理,在处理表面以下一定厚度内形成了纳米晶组织.采用自纳米化纯铁和未自纳米化纯铁端面对接中间夹Ni箔的方法,利用脉冲加压的方式在850℃实现了Ni向纯铁的扩散,用能谱仪(EDS)测试出扩散界面两侧一定范围内Ni原子的扩散浓度,计算了Ni原子在两侧纯铁表面扩散层中的扩散系数.结果表明.工业纯铁经表面自纳米化处理后,在短时间内明显提高了Ni原子的扩散系数.     

工业纯铁自纳米化组织的EBSD分析

运用高能喷丸技术实现了工业纯铁表面自纳米化,利用电子背散射衍射（ElectronBackscatteredDiffraction,EBSD）对自纳米化组织的结构特征进行了分析,在此基础上探讨了工业纯铁自纳米化机理。结果表明,工业纯铁自纳米化组织由三个典型区域组成,分别含有大量残存住错,大角度晶界及大量小角度晶界。自纳米化组织含有再结晶织构和形变织构,但由于晶粒取向差不同,变形难易程度不同导致两种织构的比例不同。位错运动、晶粒取向差不同导致变形不同步及发生再结晶是工业纯铁表面自纳米化过程中晶粒细化的主要原因。     

脉冲加压镍原子在纳米晶铁中扩散行为研究

利用高能喷丸技术实现电工纯铁表面自纳米化,通过X射线衍射分析对表面变形层晶粒度进行表征;然后在Gleeble 1500型热模拟试验机上进行Ni的扩渗;利用扫描电子显微镜作能谱分析,对常规粗晶和纳米晶试样的扩散效果进行分析。结果表明,电工纯铁经喷丸处理,表面得到了纳米结构层;Ni在纳米晶中的扩散系数比同等条件下常规粗晶试样高1倍。     

金属材料表面自纳米化研究现状

综述了金属材料表面自纳米化技术的研究现状。表面机械加工自纳米化的原理是在一定的应力作用下，使金属材料表面层产生剧烈的塑性变形，导致晶粒细化。晶粒的细化机理主要取决于金属材料的晶格结构和层错能；表面自纳米化能显著提高金属材料的综合性能。展望了表面自纳米化技术的发展前景。     

金属材料表面自纳米化研究现状

综述了金属材料表面自纳米化技术的研究现状.表面机械加工自纳米化的原理是在一定的应力作用下,使金属材料表面层产生剧烈的塑性变形,导致晶粒细化.晶粒的细化机理主要取决于金属材料的晶格结构和层错能;表面自纳米化能显著提高金属材料的综合性能.展望了表面自纳米化技术的发展前景.     

镁、铝合金表面自纳米化研究现状

综述了目前镁、铝合金表面自纳米化制备方法、性能、耐蚀性等方面的研究.材料经表面自纳米化后,表面纳米层有良好的热稳定性,表面硬度明显提高,不同的工艺对耐蚀性影响不同.提出了表面自纳米化技术研究还需解决的问题及趋势.     

塑性变形诱发表面自纳米化的研究及其应用

详细介绍了强烈塑性变形诱发表面自纳米化的研究进展,即形变诱发表面自纳米化的方法与设备、表面自纳米化层的结构及其表征、形变诱发表面自纳米化的机理及其相关应用,并展望了形变诱发表面自纳米化的研究与应用.     

镁合金表面纳米化与稀土扩渗合金化改性技术简析

一、镁合金表面改性的背景及意义镁合金是目前工程应用中最轻的金属结构材料,具有高比强度、高比模量、优良的阻尼减震性等优点,被誉为"21世纪绿色工程材料"[1];镁合金应用于航空航天、汽车、电子通讯等行业具有塑料和其他金属所不可比拟的优势。同时,中国是世界上最大的原镁生     

金属材料表面自纳米化及其研究现状

文章综述了材料表面自纳米化的国内外研究现状,包括表面自纳米化的制备方法、基本原理、表层结构及机理、性能研究,展望了表面自纳米化技术的发展前景及目前有待解决的问题。     

An investigation on the laser surface alloying of copper on iron

Laser surface alloying of iron substrate with copper under different processing conditions has been systematically studied. The microstructural analysis reveals a predominantly cellular microstructure with copper wetting the cell boundaries. Globular distribution of copper at higher laser scanning speeds can be observed occasionally indicating the system under these conditions to be near the metastable miscibility gap. The concentration of copper in the pool is related to the laser scanning speed. In all cases a banded morphology indicating unsteady growth towards the bottom of the alloyed zone is observed. The hardness of the alloyed zone is significantly higher and is attributed to work hardening due to differential thermal contraction of the two phases in the alloyed zone.     

Effects of surface alloying on microstructure and wear behavior of ductile iron

In this research, the effect of austenitic stainless steel cladding on improving the wear behavior of ductile iron was studied. Samples made of ductile iron were coated with steel electrodes (E309L) by manual shielded metal arc welding. The effect of coated layer thickness on microstructure, hardness, and wear resistance of the surface were investigated. Wear resistance of the samples was measured using the pin-on-plate technique. Optical microscopy and scanning electron microscopy were used to investigate microstructure and wear mechanisms. The phases in the interface of both the coating and the substrate were studied by X-ray diffraction. The results showed that a film of white chromium-enriched iron formed at the interface between the substrate and coating which contained iron–chromium complex carbides. It was, therefore, concluded that enhanced properties would be obtained if the coating thickness and the carbides deposited on the surface were reduced. In samples with a thin coating, surface hardness rose to above 1150 HV (five times higher than that of the substrate) and wear resistance increased significantly.     

Study on double-glow plasma niobium surface alloying of pure titanium

A niobium modified layer on a pure titanium surface was obtained by means of a double-glow plasma surface alloying technique. Microstructure and phases resident in the alloy layer were analyzed. The processing parameters and effects of cathode sputtering before the diffusion process were also studied. The results show that the surface niobium content in the modified layer is similar to that in the Ti-45Nb alloy, and decreases gradually from the surface into the underlying substrate. The oxidation behavior of the modified pure titanium at 900 °C was noticeably improved after the niobium alloying process. Characterization was performed using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The oxidation mechanism is also discussed.     

Ni-based superalloy surface alloying by double-glow plasma surface alloying technique

The double-glow surface alloying technique, also called the Xu-Tec/Xu-Loy process, is a novel technique in the field of surface alloying. This technique allows alloy layers with unique physical, chemical and mechanical properties, such as nickel-based alloy layers, stainless-steel layers and age-hardened surface high-speed steel layers to be formed at the surface of treated metallic materials. In this paper, recent research of the application of the double-glow plasma surface alloying technique in the formation of corrosion resistance alloy layers is briefly reviewed. The results of a study of Ni-Cr-Mo-Nb and Ni-Cr-Mo-Cu corrosion-resistant alloying layers as well as composite alloying layers with an electric brush plating Ni interlayer are reported.     

Study on plasma discharge parameters in double-glow plasma surface alloying furnace

Double Langmuir probe technique was used for plasma diagnostics of discharge process in double-glow plasma alloying furnace. Investigated that the effect of changes of voltage of the source pole and air pressure on plasma parameters. Results show that plasma density increases, electron temperature decreases and potential of the probe decreases, with the rise of voltage of the source pole under condition of fixed cathode potential and fixed air pressure. During increasing of air pressure in furnace, electron temperature decreases and probe potential increases. The change of probe potential is smart at start of the measuring and probe potential goes to stabilization only when degas process goes to finishing.     

Effects of alloying elements on the electrochemical characteristics of iron aluminides

Effects of alloying elements on the electrochemical characteristics of iron aluminides in the H2SO4, H2SO4+KSCN and HCl solutions were investigated using electrochemical tests. The corrosion morphologies in iron aluminides were analysed by utilising optical microscopy. It was found that the addition of Cr and Mo to iron aluminides increased the corrosion potential, pitting potential and repassivation potential. The active current density, passive current density and reactivation current density decreased as Cr and Mo were added. In the case of Mo addition, the passive current density was slightly higher in the H2SO4 solution than in solutions containing SCN- and Cl-. When B was added to samples, the corrosion potential and repassivation potential decreased, whereas the active current density, passive current density, reactivation current density and pitting potential increased. Iron aluminides containing Mo and Cr showed remarkably improved intergranular and pitting corrosion resistance to SCN- and Cl- solution. On the other hand, B addition accelerated granular and intergranular corrosion by precipitation of borides. This revised version was published online in November 2006 with corrections to the Cover Date.     

Effect of electric contact surface treatment on microstructure and wear behaviour of ductile iron

Abstract

A study of electric contact surface treatment to ductile iron has been carried out. This technology was based on the application of the contact resistance heating between the electrode and workpiece. For comparison, the experiments of induction hardening to ductile iron were studied. The microstructure, microhardness, surface residual stress and wear properties were investigated using optical microscope, scanning electron microscope, X-ray diffraction, Vickers microhardness and rolling contact wear tests. Electric contact surface treatment resulted in the formation of fine ledeburite (white bright layer) and martensite in the ductile iron surface, in which the hardness in these areas was higher than that of induction hardened surface. The wear test results showed that the ductile iron surface after electric contact surface treatment had better wear resistance owing to the fine microstructure, high hardness and residual compressive stress.