Effects of KMnO_4 on microstructure and corrosion resistance of microarc oxidation coatings on 2024 aluminum alloy

Microarc oxidation(MAO) coatings were prepared on 2024 aluminum alloy in a Na2SiO3-KOH electrolyte with KMnO4 addition varying from 0 to 4 g/L.The microstructure and phases of the coatings were characterized by scanning electron microscopy(SEM) and X-ray diffractometry(XRD),respectively.The corrosion resistance of MAO coatings was evaluated by electrochemical potentiodynamic polarization in 5%(mass fraction) NaCl solution.The results show that when KMnO4 is added into base electrolyte,the growth speed of oxide coatings is increased obviously.The main phase of oxide coatings is Al2O3,and the contents of MnO2 and Mn2AlO4 phases are increased at the top of oxide coatings with increasing the concentration of KMnO4.The solute elements participate in forming the oxide coatings.When a proper concentration of KMnO4(2.5 g/L) is added into the base solution,the micropores of the MAO coatings are small and compact,and the corrosion resistance of oxide coatings is increased largely.     

Ti6Al4V钛合金微弧氧化工艺研究

采用直流稳压电源,选用3种不同PH值的碱性微弧氧化电解液,在Ti6Al4V钛合金表面制备微弧氧化膜层;应用扫描电子显微镜分析微弧氧化膜层形貌特征。结果表明,钛合金微弧氧化膜层表面凹凸不平,带有微米级和亚微米级的孔洞,孔洞周围呈现火山丘状形貌特征;微弧氧化电解液PH值越大,火花放电时间越长;在给定电压条件下,电解液PH值越大,微弧氧化膜层厚度越大。     

SiC纳米颗粒对6060型铝合金微弧氧化膜组织结构及耐蚀性能的影响

为提高铝合金表面微弧氧化膜的耐蚀性,通过向电解液中添加SiC纳米颗粒的方式,成功获得了含有SiC纳米颗粒的复合微弧氧化膜层。采用D-MAXIIA型X射线衍射仪(XRD)、场发射扫描电镜(FESEM)和金相定量分析光学显微镜分别对陶瓷膜的相组成、微观组织结构及膜层厚度进行了检测分析;采用AutoLAB-PGSTAT302型电化学工作站对制备的微弧氧化膜进行极化曲线和交流阻抗谱的测定。结果表明:SiC颗粒在复合微弧氧化膜层中的含量随着氧化时间的增加而逐渐增加;添加SiC纳米颗粒后微弧氧化膜的厚度没有明显变化;与未添加SiC纳米颗粒的微弧氧化膜层相比,其耐蚀性明显提高。     

铝合金2024上钒酸盐转化膜的研究

利用浸渍法在铝合金表面获得钒酸盐转化膜,应用交流阻抗技术(EIS)研究了NaVO3浓度及浸泡时间对铝合金2024表面钒酸盐转化膜成膜过程的影响,扫描电子显微镜(SEM)与能量散射能谱(EDS)分析膜表面形貌与成分.结果表明,EIS显示当转化液中NaVO3的浓度为0.1 M时处理3 min得到的转化膜的阻抗值最大,达到7.17×105Ω.cm2;SEM显示在该溶液浓度下表面所形成的转化膜均匀致密,其成分主要由Al,V,Mg元素组成.钒酸盐转化膜工艺简单,对环境无污染,膜的耐蚀性强,具有一定的应用前景.     

Effects of current density on the corrosion behaviour of anodized aluminum alloy in FeCl3 solution

In the present study,2024 aluminum alloy specimen was anodized in acetic acid and oxalic acid electrolytcs.Effects of the currcnt dcnsity on thc microstructure and corrosion resistance of anodic oxide ...     

Microstructure and mechanical property of 2024／3003 gradient aluminum alloy

2024/3003 gradient aluminum alloy was prepared by semi-continuous casting using double-stream-pou-ring technique. The microstructures of the as-cast, pressed and heat-treated alloys were analyzed by scanning elec-tron microscope and transmission electron microscope. And the mechanical properties of the alloy in pressed and heat-treated states were studied. The results show that the ingots with diameter of 65 mm and external thickness about 5.5 mm are obtained when the temperatures of the melt in the internal and external ladles are 1 023 and 1 003 K, respectively, and the nozzle diameter is 2.0 mm. The microstructures of the as-cast alloy consist of α(AI) θ(CuAl2)q S(Al2CuMg) in the internal region and α(Al) MnAl6 in the external region. The phases found in the internal and external layers coexist in the transition zone. The transition layer is maintained after plastic deformation and heat treatment of the alloy. The tensile strength, yield strength and elongation of the alloy are 300 MPa,132 MPa and 16.0%, respectively, after T6 treatment. The tensile and yield strength are increased by 150.0% and 94.1%, respectively, compared with that of 3003 aluminum alloy. The maximum hardness in the internal region of 2024/3003 gradient aluminum alloy can be increased from HRF 55 in the pressed state to HRF 70 in the heat-treated state.     

Influence of potential on structure and properties of microarc oxidation coating on Mg alloy

In order to obtain optimizing microarc oxidation coating on Mg alloy from a friendly-enviormental electrolyte free of Cr⁶⁺ and PO ₄ ³⁻ , constant potential regime was applied to produce it. The influence of potential on the morphology, composition, structure and other properties, such as microhardness and corrosion resistance were investigated by scanning electron microscopy (SEM), energy dispersive spectroscope (EDS), X-ray diffraction (XRD), hardness tester and electrochemical method. The results clearly show that oxidation potential plays an important role in the formation of coating’s structure and properties. The microarc oxidation coating is smooth and white, which consists of two layers. The external layer is loose and porous and enriched in Al and Si. Moreover, its content of Al and Si increases with the increasing operated potential. While the inner layer is compact and the content of Al and Si are lower than that of the external layer. The coating is composed of several phases and the major phases are MgAl₂O₄ and MgO, and the minor phases are Al₂O₃ and SiO₂ when the potential is higher. The microhardness of coating is obtained the maximum at the potential of 45 V, so does the corrosion resistance.     

中温轧制对Al-Cu-Mg-Ag耐热铝合金组织与抗腐蚀性能的影响

通过晶间腐蚀和剥落腐蚀性能测试,对经过不同中温轧制变形的Al-Cu-Mg-Ag合金的抗腐蚀性能进行研究,并通过金相分析和透射电子显微分析等对其机理进行探讨。结果表明,采用合适的中温轧制变形后,合金的抗腐蚀性能在不同程度上得到提高。随着变形量的增加,晶内析出相发生变形并向晶界移动,导致晶间无沉淀析出带变窄,合金的腐蚀通道变窄,抗晶间腐蚀性能得到提高。另一方面,沿着轧向变长的晶粒会降低合金的剥落腐蚀性能,导致变形量较小时(10%~50%)合金的抗腐蚀性能得到提高,而较大的变形量(80%)会降低合金的抗剥落腐蚀性能。     

Influence of potential on structure and properties of microarc oxidation coating on Mg alloy

In order to obtain optimizing microarc oxidation coating on Mg alloy from a friendly-enviormental electrolyte free of Cr6 and PO43-, constant potential regime was applied to produce it. The influence of potential on the morphology, composition, structure and other properties, such as microhardness and corrosion resistance were investigated by scanning electron microscopy (SEM), energy dispersive spectroscope (EDS), X-ray diffraction (XRD), hardness tester and electrochemical method. The results clearly show that oxidation potential plays an important role in the formation of coating's structure and properties. The microarc oxidation coating is smooth and white, which consists of two layers. The external layer is loose and porous and enriched in Al and Si. Moreover, its content of Al and Si increases with the increasing operated potential. While the inner layer is compact and the content of Al and Si are lower than that of the external layer. The coating is composed of several phases and the major phases are MgA12O4 and MgO, and the minor phases are Al2O3 and SiO2 when the potential is higher. The microhardness of coating is obtained the maximum at the potential of 45 V, so does the corrosion resistance.     

Analyses of Microarc Oxidation Coating Formed on AZ91D Alloy in Phosphate Electrolytes

This paper studied the appearance transition of microdischarges, the phase composition and the morphology evolution of the oxide film formed by microarc oxidation on AZ91D magnesium alloy. The appearance of microdischarges population experienced apparent changes in size, spatial density and color, which was related with the changes of the type and quantity of the disintegrated gas bubbles generated at the interface between the electrolyte and substrate. Correspondingly, the diameter of micropores together with net-like fine microcracks increased when a higher voltage was employed. The coating was composed of MgO, MgAl2O4 and there existed a fluoride-enriched zone of about 3-5μm at the film/substrate interface.     

镁合金阳极氧化膜的微观结构与耐蚀性能研究

为了提高镁合金的耐蚀性能，采用扫描电镜(SEM)、电化学测试和盐雾试验等技术，对不同阳极氧化液中得到的镁合金AZ91D阳极氧化膜层的微观结构及其耐蚀性能进行了评价.所有工艺采用交流电源、氧化液无氟、铬和无磷，有利环境保护.先后对外加交流电压、Na2SiO3浓度、NaAlO2浓度，以及Na2SiO3和NaAlO2的协同作用对膜层腐蚀性能的影响规律进行了考察.结果表明，外加电压和氧化液组成对氧化膜的微观结构及其性能有着至关重要的影响.在碱性溶液中，NaAlO2和Na2SiO3的协同作用下，得到的阳极氧化膜的综合耐蚀性能优异，自腐蚀电流密度达到1.87×10-7A/cm2，耐中性盐雾大于500 h（氧化膜未封孔）.     

Effects of Ag on microstructure and mechanical properties of 2519 aluminum alloy

The effects of Ag on the microstructure and mechanical properties of 2519 aluminum alloy were investigated by means of tensile test, micro-hardness test, transmission electron microscope and scanning electron microscope. The results show that the addition of 0.3 % （mass fraction） Ag accelerates 2519 aluminum alloy＇s age-hardening, increases its peak hardness and reduces 4 h of peak aged time at 180 ℃. The addition of 0. 3% （mass fraction） Ag increses the tensile strength at room temperature and elevated temperature. This increment at room temperature and 200 ℃ is 24 MPa and 78 MPa, respectively. In contrast, the elongation of 2519 aluminum alloy is decreased with Ag addition. The increase of tensile strength of 2519 aluminum alloy with Ag addition is attributed to the high volume fraction of Ω phase.     

W对Co基合金熔覆层组织和耐锌蚀性能的影响

为了提高热镀锌生产线关键部件的使用寿命并节约热镀锌成本,采用半导体激光器在316L不锈钢表面制备了具有不同成分的两种钴基合金熔覆层.分别对激光熔覆层的组织形貌、成分、相结构、显微硬度及耐锌蚀性能进行了研究.结果表明,W元素的加入使得熔覆层晶粒发生细化,熔覆层组织主要由γ-Co固溶体、Co_3Mo_2Si相和少量Cr_7C_3相组成,同时还生成了少量弥散分布的Co_6W_6C相.添加W元素后熔覆层的平均硬度可达986 HV,相比未添加W元素的Co基合金熔覆层约增加了114 HV,且约为316L不锈钢的4.5倍.与原Co基合金熔覆层相比,添加了W元素的Co基合金熔覆层中弥散分布的Co_6W_6C相使熔覆层耐锌蚀性能大幅度提高.     

2024铝合金喷丸粗糙度试验与数值模拟

为研究喷丸处理对2024铝合金表面粗糙度的影响,提出一种利用数值模拟预测喷丸粗糙度的有效方法。 对铝合金试件进行喷丸处理,测量得到粗糙度特征值Ra。 利用有限元软件ABAQUS对喷丸过程建立多丸粒模型并进行数值模拟,基于所提出的Ra离散化计算式,通过对采样路径上节点位移的统计处理,得到R_a模拟值,最后通过改变模型相关参数,分析喷丸参数对粗糙度的影响规律。 试验结果表明:模拟值与实测值相对误差分别为16.7%、2.5%、4.3%,两者吻合良好,验证了仿真模型及结果的正确性,另外模拟得出喷丸工件表面粗糙度随丸粒直径的增大而增加;随喷丸速度的增加而增加;随丸粒覆盖率的增大先大幅增长,后增速减缓。     

Effect of metallic phase species on the corrosion resistance of 17M/（10NiO-NiFe2O4） cermet inert anode of aluminum electrolysis

1 INTRODUCTIONThere are many disadvantages in the presentaluminumelectrolysis with carbon anode ,such assevere energy consumption,carbon wasting,envi-ronmental pollution and so on.Inert electrode sys-tem can overcome these disadvantages[1 3]. Re-cently ,the researches of the inert anode materialshave mainly been concentrated on alloys[4]and cer-met materials[5 ,6]. NiFe2O4based cermets , whichpossess not only high electrical conductivity ofmetal but also good corrosion resistance of cera…     

Effect of copper ions implantation on the corrosion behavior of ZIRLO alloy in 1 mol/L H2SO4

1. IntroductionZIRLO alloy is widely used in the nuclear industrybecause of its low thermal neutron capture cross sec-tion, favorable mechanical properties, and good corro-sion resistance. For example, ZIRLO alloy can serve asfuel cladding, spreaders for …     

Composition and hardness of mullite coatings formed with direct current power supply on LY12 aluminum alloy surface

The surface modification of aluminum and its alloys using plasma technology is increasingly being investigated, Thick ceramic coatings with high hardness on aluminum alloys can be prepared successfully using a micro-plasma oxidation （MPO） technique. In this work, the composition, microstructure and elemental distribution of ceramic coatings formed by MPO on LY 12 almnlnum alloy and its hardness are investigated using XRD, EPMA and microhardness instruments. The results show that the ceramic coatings consist of mullite,γ-Al2O3 and a lot of amorphous matter. The content of silicon in the coatings increases from interface to the coatings, however, the content of aluminum decreases along this direction. The maximum hardness of ceramic coatings is up to 9.2 GPa.     

铝合金电阻点焊预压接触分析

为了探究铝合金电阻点焊的接触压力分布及初始导电区域,利用ABAQUS软件建立球面形电极条件下的预压接触二维轴对称有限元模型并对模型施加不同的电极压力.在可视化模块中得到了各个接触面上接触压力随载荷变化曲线、电极上的轴力分布云图及工件内的有效塑性应变云图.有限元分析结果表明,各接触面上的接触压力分布是不均匀的,电极-工件间的接触压力受电极球形端面轴向应力分布影响;工件间接触压力与材料所处状态有关;随着电极压力的增大,工件间接触半径呈线性增长.说明电阻点焊时可以通过选取不同截面的电极来改善接触压力的分布,进而改变初始导电区域的大小.     

铝及铝合金化学着黄红色探讨

采用除油、碱蚀、化学着色和后处理四步法，将铝或铝合金着黄红色，丰富了多彩的装饰红色．通过实验得出了着色的最佳配方：硫酸镍45g／L，高锰酸钾20g／L，硫酸6g／L，西红素6g／L，着色促进剂A2g／L工艺过程中的处理液可循环利用．具有工艺简单、成本低和着色效率高等优点．生成的氧化膜既具有装饰性又具有耐蚀性．     

纳米TiO2复合涂层的制备及其对LY12铝合金的防护性能影响

为了改善铝合金材料的耐腐蚀性能,研究了以正硅酸乙酯（TEOS）为主要原料,加入一定量的-氨丙基三乙氧基硅烷（KH550）,并引入纳米TiO2进行复合,以冰乙酸为催化剂,采用溶胶-凝胶法在铝合金基体表面形成复合涂层,并利用氟硅烷进行表面修饰。腐蚀电化学测试分析结果表明,纳米TiO2掺杂制备的复合涂层能够明显的提高铝合金基体的防护性能。并考察了纳米TiO2含量对涂层性能的影响,结果表明,在纳米TiO2质量分数为0.04%时制备的涂层性能最佳,相应的试样在3.5%（质量分数）NaCl溶液中的腐蚀电流密度约为5.965×10 9 A/cm2,而同等实验条件下铝合金基体腐蚀电流密度为7.216×10 5 A/cm2,涂层的存在使腐蚀速率降低了4个数量级,说明涂层对铝合金基体具有显著的防护效果,并且利用扫描电镜（SEM）和接触角测试来考察涂层的致密性和憎水性。