共查询到20条相似文献,搜索用时 125 毫秒
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UV/Fenton处理苯酚废水的研究 总被引:1,自引:0,他引:1
采用UV/Fenton联合体系降解苯酚模拟废水,苯酚的初始质量浓度为300mg/L,COD。的初始质量浓度为760mg/L。探讨了pH值、H202(30%)和FeSO4·7H2O投加量、反应时间等因素对苯酚和CODcr去除率的影响。结果表明,UV/Fenton联合体系降解苯酚废水的最佳工艺条件是:溶液pH值为3、H2O2投加量为2.5mL/L、FeS04·7H20投加量为0.020g/L、反应时间为90min。此时,苯酚的去除率为95%,CODcr的去除率为90%。UV/Fenton联合体系能较好地处理苯酚废水。 相似文献
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采用Fenton法深度处理干法腈纶废水,试验中考察了Fe2+投加量、H2O2投加量、pH、反应时间等l习素对CODcr处理效果的影响,确定了反应过程中的最佳工艺参数,并分析了该法处理废水的作用机理。试验结果表明:影响Fenton氧化的因素从大到小依次为H2O2投加量、初始pH值、反应时间、Fe2+投加量。最佳试验条件为:e(Fe2+)为18.0mmol/L,dH2O2)为49.0mmol/L,pH为3.0,反应时间为30min。在此条件下出水COD。可降至47.4mg/L,去除率可达到80.3%。显示该方法对于干法腈纶废水的处理具有巨大的前景和潜力。 相似文献
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Fenton氧化技术深度处理棉浆黑液的试验研究 总被引:1,自引:0,他引:1
采用Fenton氧化技术对棉浆黑液废水进行深度处理,通过单因素与正交试验,研究了pH、FeSO4投加量、H2O2投加量和反应时间等因素对COD去除率的影响,分析了各影响因子的作用机理。结果表明,处理废水的最佳条件为:废水初始pH=7、FeSO4投加浓度80mmol/L、H2O2投加浓度0.15mol/L、反应时间40min,在此条件下黑液COD去除率98%,处理后黑液的COD为45mg/L,达到国家化纤废水一级排放标准(COD100mg/L)。 相似文献
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用硫酸亚铁和过氧化氢混合体系处理丁苯橡胶生产废水 总被引:4,自引:0,他引:4
用硫酸亚铁和过氧化氢混合体系处理了丁苯橡胶生产废水,优化了工艺条件,进行了稳定性实验,并对处理前后的废水进行了水质分析.结果表明,不必调节废水的pH值、反应温度为55℃、Fe^2+用量为200mg/L、H2O2用量为1000mg/L、反应时间为40min、加入氢氧化钙将氧化处理后废水的pH值调至中性进行絮凝、加入用量为1 mg/L的聚丙烯酰胺助凝,可显著降低废水中的铁离子质量浓度,提高化学需氧量去除率,同时废水的可生化性显著提高,为后续生物处理创造了良好的条件。 相似文献
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采用O3/H2O2氧化工艺深度处理制药废水二级生化出水,探讨了废水初始pH、H2O2投加量、O3投加量等因素对O3/H2O2氧化工艺的影响,确定了O3/H2O2氧化技术处理制药废水的最佳操作条件。结果表明,制药废水二级出水COD在480 mg/L左右时,pH为9,进臭氧质量浓度为1 247 mg/(L.h),处理时间为4.5h,COD去除率可达83%,B/C(BOD5/COD)从初始的0.007提升到0.32,较原水增高了46倍,大大提高了制药废水的生化性能,便于后续的生物处理。 相似文献
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乙烯酮(双乙烯酮)是十分重要的化工中间体,其下游产品较多。江苏某化工厂开发生产乙烯酮(双乙烯酮)下游产品三十多个,年生产规模三万多吨,是国内以乙烯酮(双乙烯酮)为中间体生产精细化学品的综合骨干企业。针对乙烯酮(双乙烯酮)下游产品废水特点,该厂结合企业实际,开展了产品优化,结构调整,清洁生产,资源循环利用,节水降耗等工作,从源头削减了污染物的生产。同时投资二千多万元新建预处理装置三套,6000m3/d废水生化处理装置一套,使全厂乙烯酮(双乙烯酮)下游产品的废水得到了有效的治理。 相似文献
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D. G. Gordeev L. F. Gudarenko M. V. Zhernokletov V. G. Kudel’kin M. A. Mochalov 《Combustion, Explosion, and Shock Waves》2008,44(2):177-189
A semi-empirical equation of state for metals is described. Its capabilities are demonstrated by the example of the equation
of state for aluminum. New experimental data are presented on the location of the isentrope of aluminum for unloading from
the state at p = 229.71 GPa on the shock adiabat to an aerogel (SiO2) of density 0.08 g/cm3.
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Translated from Fizika Goreniya i Vzryva, Vol. 44, No. 2, pp. 61–75, March–April, 2008. 相似文献
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Jorge Marcelo Romero Soledad Bustillo Hugo Enrique Ramirez Maisuls Nelly Lidia Jorge Manuel Eduardo Gómez Vara Eduardo Alberto Castro Alicia H. Jubert 《International journal of molecular sciences》2007,8(7):688-694
A thermochemical rather simple experimental technique is applied to determine the enthalpy of formation of Diperoxide of ciclohexanone. The study is complemented with suitable theoretical calculations at the semiempirical and ab initio levels. A particular satisfactory agreement between both ways is found for the ab initio calculation at the 6–311G basis This set level. Some possible extensions of the present procedure are pointed out. 相似文献
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A perturbation viscometer is a differential capillary viscometer that measures the logarithmic viscosity gradient of the viscosity-composition curve for gas mixtures. Measurements are made at different gas mixture compositions. Integration of the logarithmic viscosity gradients measured over the full composition range gives the mixture viscosity relative to the viscosity of one of the pure components of the gas mixture. This method is attractive because, for measurements of equal precision, integration of the gradients is potentially an order of magnitude more precise than measurement of the viscosities directly. It can also work at high and low temperatures and perhaps high pressures.The perturbation viscometer has been used to make measurements on ideal gas mixtures at ambient and elevated temperatures. The situation is more complicated when the gas mixtures are non-ideal. Extra effects due to density differences, molar volume change on mixing and differential thermal expansion may be measured in addition to the desired viscosity change producing systematic errors in the results. Thus, a more sophisticated apparatus is required. The standard perturbation viscometer has been modified to separate out the extra effects to permit measurement of the true change in viscosity. In addition, the theoretical operation of the modified apparatus has been revised to account for the design changes to permit calculation of the viscosity-composition profiles from the results.The apparatus has been tested using helium-HFC-125 mixtures and two new viscosity-composition profiles are presented for these mixtures at 23 and . Internal consistency tests have been used to confirm that the data produced are of high quality with an estimated uncertainty in the viscosity ratio data at of 0.9% and at of 1.5%. 相似文献
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塔设备改造选型的分析 总被引:2,自引:0,他引:2
就当前扩产增容中塔设备设计和改造时板式塔和填料塔的选型问题加以分析。在评述目前国内常用的几种塔板和新型填料之后,着重介绍一种新型塔板(导向梯形浮阀塔板)和一种新型填料(波环填料——乾隆帕克)。 相似文献
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In the present article, chitin from crab shell was systematically deacetylated using a NaOH treatment with control of the reaction time. The degree of deacetylation, monitored using solid-state NMR, revealed that the reaction was pseudo-first order. Based on this, swollen and NaOH-saturated particles are proposed as the reaction system. The weight loss of the partially saponified and neutralized samples after HCl hydrolysis increased linearly with the degree of deacetylation. The crystallinity of the samples was found to increase after acid hydrolysis. According to conductimetric titration, the surface charge density of the crystallites, after acid hydrolysis, was found to increase with base treatment time. The effect of surface charge on the formation of a chiral nematic phase, due to the rodlike nature of the crystallites, was explored. These results show that because the contribution of charged particles to the ionic strength was significant the double layer compression was affected, especially since the surface charge density was close to the Manning limit. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 65:373–380, 1997 相似文献