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1.
Muddasir Hanif Lijian Zuo Quanxiang Yan Xiaolian Hu Minmin Shi Hongzheng Chen 《应用聚合物科学杂志》2013,127(1):161-168
Conjugated polymers having good electrochemical and thermal stability are highly desired in optoelectronics. We report a new polythiophene consisting of alternating 4,4′‐didodecyl‐2,2′‐bithiophene and terthiophene units (HPL1) synthesized via Stille coupling reaction. The optical band gap of HPL1 (1.92 eV) is similar to that of regioregular poly(3‐hexylthiophene) (rr‐P3HT, 1.89 eV). In comparison to rr‐P3HT, the HPL1 when subjected to the cyclic voltammetry as thin film shows much superior electrochemical stability and a lower highest occupied molecular orbital energy level (?4.87 eV for rr‐P3HT and ?4.95 eV for HPL1). The transient photoluminescence study of HPL1 and rr‐P3HT shows that both materials have two exciton decay processes, and the excitons of rr‐P3HT are quenched more quickly. The onset decomposition, Td for rr‐P3HT (465°C) is 4°C lower than HPL1 (469°C). Preliminary photovoltaic study disclosed that the polymer solar cell based on HPL1:[6,6]‐phenyl‐C61‐butyric acid methyl ester blend showed a power conversion efficiency of 0.63%, with a Voc of 0.6 V, and a short circuit current (Jsc) of 2.79 mA cm?2 under AM 1.5 illumination (100 mW cm?2). The whole study provided an important example to design new electrochemically and thermally stable polymers with longer exciton life time for application in bulk heterojunction polymer solar cells. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
2.
Ping Ding Cheng‐Che Chu Yingping Zou Dequan Xiao Chunyue Pan Chain‐Shu Hsu 《应用聚合物科学杂志》2012,123(1):99-107
To develop conjugated polymers with low bandgap, deep HOMO level, and good solubility, a new conjugated alternating copolymer PC‐DODTBT based on N‐9′‐heptadecanyl‐2,7‐carbazole and 5, 6‐bis(octyloxy)‐4,7‐di(thiophen‐2‐yl)benzothiadiazole was synthesized by Suzuki cross‐coupling polymerization reaction. The polymer reveals excellent solubility and thermal stability with the decomposition temperature (5% weight loss) of 327°C. The HOMO level of PC‐DODTBT is ‐5.11 eV, indicating that the polymer has relatively deep HOMO level. The hole mobility of PC‐DODTBT as deduced from SCLC method was found to be 2.03 × 10?4 cm2/Versus Polymer solar cells (PSCs) based on the blends of PC‐DODTBT and [6,6]‐phenyl‐C71‐butyric acid methyl ester (PC71BM) with a weight ratio of 1:2.5 were fabricated. Under AM 1.5 (AM, air mass), 100 mW/cm?2 illumination, the devices were found to exhibit an open‐circuit voltage (Voc) of 0.73 V, short‐circuit current density (Jsc) of 5.63 mA/cm?2, and a power conversion efficiency (PCE) of 1.44%. This photovoltaic performance indicates that the copolymer is promising for polymer solar cells applications. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
3.
Conjugated polymers are highly desirable for the photovoltaic applications. We report the synthesis, characterization, optoelectronic properties, and solar cell application of two polymers, namely, poly[(9,9‐didodecylfluorene‐2,7‐diyl)‐alt‐(2,2′:5′,2″‐terthiophene‐5,5″‐diyl)] (P1) and poly[(1,4‐bis(dodecyloxy)benzene‐2,5‐diyl)‐alt‐(2,2′:5′,2″‐terthiophene‐5,5″‐diyl)] (P2). The polymers were synthesized via Stille cross‐coupling reaction, and were characterized by the gel permeation chromatography, nuclear magnetic resonance, Fourier transform infrared, UV–vis, thermogravimetric analysis, and cyclic voltammetry analyses. The two copolymers are processable due to their good solubility in organic solvents (tetrahydrofuran, CHCl3, toluene, chlorobenzene, and o‐dichlorobenzene). The optical band gaps (UV–vis, film, and Egopt) of the P1 and P2 are 2.04 and 2.00 eV, respectively. The density functional theory output structures showed that S … O space interaction is likely responsible for the higher planarity of P2. The polymers showed low HOMO energy levels (P1: −5.33 eV, P2: −5.05 eV). The EHOMO for P1 is close to the EHOMO (−5.4 eV) of an ideal polymer, which is an important, rare, and main origin of the observed higher Voc (801–808 mV). The onset decomposition temperatures (Td) for the P1 and P2 are 418°C and 365°C, respectively. The polymer solar cell based on the P1: C60 (1: 1) and P2: C60 (1: 1) blend showed a power conversion efficiency (PCE) of 0.94 and 0.71%, respectively. The composite polymer : PC60BM = 1 : 2 increased PCE of the P1 (1.65%) and P2 (1.09%) under AM 1.5 illumination (100 mW/cm2). The study provided important examples to design donor–donor (D–D) polymers for the photovoltaic applications. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42147. 相似文献
4.
Two poly(thiazole vinylene) derivatives, poly(4‐hexylthiazole vinylene) (P4HTzV) and poly(4‐nonylthiazole vinylene) (P4NTzV), were synthesized by Pd‐catalyzed Stille coupling method. The polymers are soluble in common organic solvents such as o‐dichlorobenzene and chloroform, and possess good thermal stability. P4HTzV and P4NTzV films exhibit broad absorption bands at 400–720 nm with an optical bandgap of 1.77 eV and 1.74 eV, respectively. The HOMO (the highest occupied molecular orbital) energy levels of P4HTzV and P4NTzV are ?5.11 and ?5.12 eV, respectively, measured by cyclic voltammetry. Preliminary results of the polymer solar cells based on P4HTzV : PC61BM ([6,6]‐phenyl‐C‐61‐butyric acid methyl ester) (1 : 1, w/w) show a power conversion efficiency of 0.21% with an open‐circuit voltage of 0.55 V and a short circuit current density of 1.11 mA cm?2, under the illumination of AM1.5G, 100 mW cm?2. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
5.
Ping Lu Haiquan Zhang Mao Li Yan Zheng Yuguang Ma Xinfang Chen Naoto Tamai 《Polymer International》2008,57(8):987-994
BACKGROUND: Wide bandgap semiconducting polymers are of great interest in the development of organic and polymeric emissive materials for display purposes since they can be used to generate light of all colors either by irradiation of luminescent dyes or by energy transfer to emissive dopants. The aim of the present work is to construct new fluorene‐based semiconducting polymers with a wide bandgap. RESULTS: A novel polyfluorene derivative, poly[(9,9‐dihexyl‐2,7‐fluorene)‐alt‐(5,7‐dihydrodibenz[c,e]oxepin)], with a wide bandgap, was synthesized by connecting rigidly twisted biphenyl monomers with dihexylfluorene via para‐linkages and it was compared with poly[(9,9‐dihexyl‐2,7‐fluorene)‐alt‐(spirocyclohexane‐1,6′‐dibenzo[d,f][1,3]dioxepin)], which has meta‐linkages. Both polymers emit in the ultraviolet and blue regions. Electronic spectral absorption data and electrochemical measurements demonstrate that ca 40° torsion angle of the biphenyl units induces an increase in the HOMO–LUMO gap of 0.18 eV, and that meta‐linkage of the twisted segment in the polymer induces another increase of 0.24 eV compared to polydihexylfluorene. CONCLUSION: The new twisted biphenyl compounds are efficient segments to tune the bandgaps of conjugated polymers. The two fluorene‐based copolymers have wide bandgaps and exhibit potential as host materials. Copyright © 2008 Society of Chemical Industry 相似文献
6.
Zhenhua Zhang Bo Peng Ping Ding Bo Liu Yuehui He Kechao Zhou Yongfang Li Chunyue Pan Yingping Zou 《应用聚合物科学杂志》2011,120(5):2534-2542
Two new alternating copolymers based on dithienyl benzotriazole segment and phenylene vinyl unit were synthesized by Heck cross coupling method. The polymers exhibited broad absorption bands (from 300 nm to 752 nm for P1 , and from 300 nm to 654 nm for P2 ) in the UV‐visible region with optical bandgap ranging between 1.6 and 1.9 eV and proper electronic energy levels measured by cyclic voltammetry. The photovoltaic properties of the polymers as electron donors with 6.6‐phenyl C61‐butyric acid methyl ester as the electron acceptor in a bulk heterojunction structures were reported. Preliminary results showed moderate power conversion efficiency of 0.36% and 0.4%, respectively, under the illumination of AM 1.5, 100 mW/cm2 with a device structure of ITO/PEDOT : PSS/polymer : PC60BM (1 : 3)/Ca/Al. Furthermore, the side chain effect on properties has also been investigated. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
7.
Ignacio A. Jessop Josefa Cutipa Yasmín Perez Cesar Saldías Denis Fuentealba Alain Tundidor-Camba Claudio A. Terraza María B. Camarada Felipe A. Angel 《International journal of molecular sciences》2022,23(21)
A new benzodithiophene and benzotriazole-based terpolymer bearing a fluorescein derivative as a side group was synthesized and studied for organic solar cell (OSC) applications. This side group was covalently bounded to the backbone through an n-hexyl chain to induce the intramolecular Förster Resonance Energy Transfer (FRET) process and thus improve the photovoltaic performance of the polymeric material. The polymer exhibited good solubility in common organic chlorinated solvents as well as thermal stability (TDT10% > 360 °C). Photophysical measurements demonstrated the occurrence of the FRET phenomenon between the lateral group and the terpolymer. The terpolymer exhibited an absorption band centered at 501 nm, an optical bandgap of 2.02 eV, and HOMO and LUMO energy levels of −5.30 eV and −3.28 eV, respectively. A preliminary study on terpolymer-based OSC devices showed a low power-conversion efficiency (PCE) but a higher performance than devices based on an analogous polymer without the fluorescein derivative. These results mean that the design presented here is a promising strategy to improve the performance of polymers used in OSCs. 相似文献
8.
Maluvadi G Murali Udayakumar Dalimba Vandana Yadav Ritu Srivastava 《Polymer Engineering and Science》2013,53(6):1161-1170
Two new thiophene‐based donor–acceptor (D–A) conjugated polymers, PDTOFV and PDTOCN, are synthesized and characterized. The polymers are readily soluble in common organic solvents and exhibit good thermal stability with onset decomposition temperature (Td) in the range 310?330°C. Cyclic voltammetry studies revealed that polymers possess low‐lying highest occupied molecular orbital (HOMO) energy levels (?5.94 eV for PDTOFV and ?5.86 eV for PDTOCN) and low‐lying lowest unoccupied molecular orbital (LUMO) energy levels (?3.35 eV for PDTOFV and ?3.55 eV for PDTOCN). The optical band gap is calculated from onset absorption edge of the polymer film. The polymers exhibit green fluorescence with fluorescence quantum yields (?fl) of 38% and 42%, respectively, for PDTOFV and PDTOCN. Polymer light‐emitting diodes (PLEDs) are fabricated using these polymers with a device configuration of ITO/PEDOT:PSS/polymer/Al. The device based on PDTOFV emitted green light with Commission Internationale de I'Eclairage (CIE) coordinate values of (0.25, 0.39). Whereas, the device based on PDTOCN showed white light emission with CIE coordinate values of (0.32, 0.35), which is very close to the values (0.33, 0.33) of standard white light emission. The threshold voltages of the PLEDs are determined by current density‐voltage characteristics and are found to be 7.3 and 3.9 V for PDTOFV and PDTOCN, respectively. POLYM. ENG. SCI., 2013. © 2012 Society of Plastics Engineers 相似文献
9.
Influence of diamine structure on the low temperature dielectric relaxation of some poly(ether imide)s
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Geoffrey C. Eastmond John Paprotny Richard A. Pethrick Fernan Santamaria‐Mendia 《应用聚合物科学杂志》2015,132(17)
Broadband dielectric relaxation spectra are reported on a range of poly(ether imide) polymers in which the chemical structure of the diamine used to create the polymer is systematically varied with the anhydride structure based on 2,2‐bis‐[4‐(3′,4′‐dicarboxyphenoxy)phenyl]hexafluoroisopropylidine dianhydride. In all the polymers examined, a dipole relaxation was observed below room temperature. The magnitude and activation energy associated with the relaxation process varied with the chemical structure reflecting the effects of steric hindrance on the conformational change associated with the N? C and C? O? C linkages. Values of the activation energies varied between 29 and 34 kJ/mol?1, and are consistent with the observed relaxation being associated with constrained local oscillatory motions of small elements of the polymer backbone. The glass transition temperatures of these polymers are in the range 195–243°C and are associated with the large scale motion of the polymer backbone. Changes in the backbone structure influence the extent of inter chain–chain interaction and are reflected in the amplitude of the relaxation process and the high frequency limiting dielectric permittivity ε∞ values which are important when these polymers are used in thin film electronic applications. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41684. 相似文献
10.
Lili An Junfeng Tong Chunyan Yang Xu Zhao Xunchang Wang Yangjun Xia 《Polymer International》2020,69(2):192-205
Three donor‐π‐acceptor (D‐π‐A) type alternating conjugated polymers, namely PIDTT‐DTNT‐C16, PIDTT‐DTNT‐HD and PIDTT‐DTNT‐OD bearing the same backbone of indacenodithieno[3,2‐b]thiophene (IDTT) as the D unit and naphtho[1,2‐c:5,6‐c′]bis[1,2,5]thiadiazole (NT) as the A moiety but with different flexible side chain (n‐hexadecyl (C16), 2‐hexyldecyl (HD) and 2‐octyldodecyl (OD)) substituted thiophene employed as π‐bridges, were synthesized and characterized. The effects of the side chain on absorption, photostability, energy levels, aggregation, backbone conformation, morphology and photovoltaic properties were systematically investigated. Because moderate D and strong A units were selected to construct the polymer backbone, a medium optical bandgap (ca. 1.66 eV) and low‐lying highest occupied molecular orbital energy level (EHOMO ≈ ?5.36 V), thus resulting in a relatively higher open‐circuit voltage (VOC) of 0.80–0.83 V, were achieved. It was found that the side chain gave rise to an insignificant impact on absorption, aggregation and photostability in chlorobenzene solution and energy levels but a non‐negligible influence on absorption, photostability and aggregation behavior in the film state. It was found that PIDTT‐DTNT‐C16 with the densest and most ordered packing structure exhibited the best photostability. Inverted bulk heterojunction polymer solar cells based on PIDTT‐DTNT‐HD:PC61BM ([6,6]‐phenyl‐C61‐butyric acid methyl ester) showed at least a 1.5‐fold increase in power conversion efficiency, chiefly originating from its slightly improved absorption, more balanced μh/μe ratio and favorable morphology of the active layer as a result of incorporating branched HD side chains into the IDTT‐alt‐DTNT backbone. © 2019 Society of Chemical Industry 相似文献
11.
Thiophene π‐bridge effect on photovoltaic performances of dithienosilole and bithiazole backboned polymers
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Huilin Zheng Chuantao Gu Qianqian Zhu Xichang Bao Shuguang Wen Meng Qiu Dangqiang Zhu Mingliang Sun Renqiang Yang 《应用聚合物科学杂志》2015,132(46)
In this article, two dithienosilole (DTS) and bithiazole (BTz) backboned donor–acceptor (D‐A) copolymers with (poly{5‐(5‐(4,4‐bis(2‐ethylhexyl)‐4H‐silolo[3,2‐b:4,5‐b']dithiophen‐2‐yl)thiophen‐2‐yl)‐4,4'‐dinonyl‐5'‐(thiophen‐2‐yl)‐2,2'‐bithiazole} (PDTS‐DTBTz)) and without (poly{5‐(4,4‐bis(2‐ethylhexyl)‐4H‐silolo[3,2‐b:4,5‐b']dithiophen‐2‐yl)‐4,4'‐dinonyl‐2,2'‐bithiazole} (PDTS‐BTz)) thiophene π‐bridge were synthesized to study the influence of thiophene π‐bridge on their photovoltaic performances. Both polymers show similar band gap, but polymer with thiophene π‐bridge (PDTS‐DTBTz) has a higher molecular weight, narrower polydispersity index (PDI), more planar geometry, higher crystallinity, higher hole mobility, and better miscibility with fullerene (polymer solar cells (PSCs) acceptor). Although PDTS‐BTz polymer based PSCs devices show higher open circuit voltage (Voc), PDTS‐DTBTz polymer does show higher power conversion efficiency (PCE) with improved short circuit current density (Jsc) and fill factor (FF). The present results indicate that thiophene π‐bridge does contribute to the PSCs performances of dithienosilole and bithiazole backboned copolymer. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42798. 相似文献
12.
In this work, two thiazole‐containing monomers N‐(thiazol‐2‐yl)?2‐(thiophen‐3‐yl)acetamide (ThDBTH) and N,N′‐([4,4′‐bithiazole]‐2,2′‐diyl)bis(2‐(thiophen‐3‐yl)acetamide) (Th2DBTH) were synthesized through amidification reaction of 2‐(thiophen‐3‐yl)acetyl chloride with aminothiazole derivatives and characterized by FTIR and 1H and 13C‐NMR. The monomers were subjected to electrochemical polymerization and optoelectronic properties of the resultant conducting polymers were investigated. Additionally, copolymerization of ThDBTH in the presence of thiophene was achieved. PThDBTH, PTh2DBTH, and P(ThDBTH‐Th) exhibited optical band gaps of 2.15, 2.30, and 1.95 eV, respectively. Switching time and optical contrast of the polymers were evaluated via kinetic studies. The P(ThDBTH‐Th) revealed satisfactory switching time and appropriate optical contrast of 1.27 s and 24.97%, respectively. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42206. 相似文献
13.
Synthesis of two D‐π‐A polymers π‐bridged by different blocks and investigation of their photovoltaic property
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Ruiping Qin Yurong Jiang Kaixuan Zhang Haoxing Zhang Qunying Zhang Meng Li Heng Ma 《应用聚合物科学杂志》2015,132(10)
The synthesis, characterization, photophysical and photovoltaic properties of two 5,6‐bis(octyloxy)benzo[c][1,2,5]thiadiazole‐containing wide‐band‐gap donor and acceptor D‐π‐A alternating conjugated polymers (HSD‐a and HSD‐b) have been reported. These two polymers absorb in the range of 300–700 nm with a band gap of about 1.88 and 1.97 eV. The HOMO energy levels were ?5.44 eV for HSD‐a and ?5.63 eV for HSD‐b. Polymer solar cells with HSD‐b :PC71BM as the active layer demonstrated a power conversion efficiency (PCE) of 2.59% with a high Voc of 0.93 V, a Jsc of 7.3 mA/cm2, and a comparable fill factor (FF) of 0.38 under simulated solar illumination of AM 1.5G (100 mW/cm2) without annealing. In addition, HSD‐a :PC71BM blend‐based solar cells exhibit a PCE of 2.15% with a comparable Voc of 0.64 V, Jsc of 8.75 mA/cm?2, and FF of 0.40. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41587. 相似文献
14.
Erfu Huo Daobin Yang Zhanyuan Zhang Zhiyun Lu Huiqin Sun Xing Xin Yan Huang Yu Liu Qing Jiang 《应用聚合物科学杂志》2013,128(3):1632-1639
In this work, two very low band‐gap (~1.0 eV) alternate conjugated copolymers bearing bispyrrolylvinylthiophene‐based polysquaraine backbone (PVTVPS) have been synthesized. In comparison with their analogous polymer with 2‐ethylhexyl side chain on the pyrrole segment, which possesses poor solubility after long‐time storage, the two target polymers with 4‐dodecyloxyphenyl (PVTVPS‐Ph) or (4′‐dodecyloxy‐4‐biphenyl)methylene (PVTVPS‐Ph2) side chains exhibit dramatically improved solubility. Furthermore, PVTVPS‐Ph shows unexpected thermochromism in the Vis–near‐infrared (NIR) region of 600–1100 nm at 80–160°C in solution and thin film. This may be attributed to the presence of relatively rigid phenyl substituent restricting the free rotation between the D (pyrrole) and A (squaraine) segments of the main chain. To our knowledge, this is the first report on NIR thermochromic polysquaraines. Nevertheless, in the case of PVTVPS‐Ph2, no thermochromism could be observed because of the existence of free‐rotating methylene linkage bridge between biphenyl unit and the conjugated polymer skeleton. When compared with PVTVPS‐Ph, PVTVPS‐Ph2 has much improved thermostability and broader absorption property. Hence, PVTVPS‐Ph2 is a more prospective candidate as photovoltaic materials. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
15.
Arylamine polymers prepared via facile paraldehyde addition condensation: an effective hole‐transporting material for perovskite solar cells
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Arylamine polymers were prepared via the facile one‐step addition condensation of N,N′‐diphenyl‐N,N′‐bis(4‐methylphenyl)‐1,4‐phenylenediamine and 4‐methoxytriphenylamine with paraldehyde. The polymers were highly soluble in common organic solvents. The non‐conjugated arylamine polymer structure was characterized and found to form tough, homogeneous, amorphous layers with a glass transition temperature above 200 °C on a substrate by a simple spin‐coating process. The polymer layers exhibited a hole mobility of the order of 10?5 cm2 V?1 s?1, which was comparable with those of previously reported arylamine polymers, and a highest occupied molecular orbital level of ?5.38 eV appropriate for the hole‐transporting layer of perovskite solar cells. The perovskite cells fabricated with the polymers gave a photovoltaic conversion efficiency of 16.0%. © 2018 Society of Chemical Industry 相似文献
16.
Aiichiro Nagaki Yiyuan Jiang Hiroki Yamashita Naoshi Takabayashi Yusuke Takahashi Jun-ichi Yoshida 《化学工程与技术》2019,42(10):2113-2118
The lithiation of 5,5′‐dibromo‐2,2′‐bithiophene with one equivalent of an alkyllithium such as n‐BuLi or s‐BuLi was studied by varying the residence time in flow microreactors. With a short residence time, the product 2,2′‐bithiophene (3) derived from dilithiation was obtained preferentially and a significant amount of the starting material 5,5′‐dibromo‐2,2′‐bithiophene remained unchanged. An increase in the residence time caused a higher yield of the product 5‐bromo‐2,2′‐bithiophene derived from monolithiation with expense in the yields of 2,2′‐bithiophene and 5,5′‐dibromo‐2,2′‐bithiophene. The lithiation using MeLi gave the product 5‐bromo‐2,2′‐bithiophene preferentially even with a very short residence time. 相似文献
17.
18.
A new diamine, 2,2′‐bis(3,4,5‐trifluorophenyl)‐4,4′‐diaminodiphenyl ether (FPAPE) was synthesized through the Suzuki coupling reaction of 2,2′‐diiodo‐4,4′‐dinitrodiphenyl ether with 3,4,5‐trifluorophenylboronic acid to produce 2,2′‐bis(3,4,5‐trifluorophenyl)‐4,4′‐dinitrodiphenyl ether (FPNPE), followed by palladium‐catalyzed hydrazine reduction of FPNPE. FPAPE was then utilized to prepare a novel class of highly fluorinated all‐aromatic poly(ether‐imide)s. The chemical structure of the resulting polymers is well confirmed by infrared and nuclear magnetic resonance spectroscopic methods. Limiting viscosity numbers of the polymer solutions at 25 °C were measured through the extrapolation of the concentrations used to zero. Mn and Mw of these polymers were about 10 000 and 25 000 g mol?1, respectively. The polymers showed a good film‐forming ability, and some characteristics of their thin films including color and flexibility were investigated qualitatively. An excellent solubility in polar organic solvents was observed. X‐ray diffraction measurements showed that the fluoro‐containing polymers have a nearly amorphous nature. The resulting polymers had Tg values higher than 340 °C and were thermally stable, with 10% weight loss temperatures being recorded above 550 °C. Based on the results obtained, FPAPE can be considered as a promising design to prepare the related high performance polymeric materials. Copyright © 2011 Society of Chemical Industry 相似文献
19.
The lower the highest occupied molecular orbital (HOMO) energy level of the conjugated polymer is, the higher the open-circuit voltage (VOC) of the obtained polymer solar cell (PSC) is. To achieve this goal, a new conjugated polymer (PDTPTPD) alternating dithienopyrrole (DTP) and thienopyrroledione (TPD) units was designed and synthesized by Stille coupling reaction. Through UV-vis absorption and cyclic voltammetry (CV) measurements, it was found that the resulting copolymer exhibited both a low optical band gap of 1.62 eV and a low HOMO energy level of −5.09 eV owing to the electronegativity of TPD moiety. Preliminary photovoltaic study disclosed that the PSC based on PDTPTPD:PCBM ([6,6]-phenyl-C61 butyric acid methyl ester) blend showed a power conversion efficiency (PCE) of 1.9%, with a VOC of 0.70 V, and a short circuit current (ISC) of 6.97 mA/cm2, suggesting that PDTPTPD is a promising photovoltaic polymer. 相似文献
20.
Indolo[3,2‐b]carbazole‐based poly(arylene vinylene)s. The influence of substitution position on spectroscopic and electrochemical properties
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Three novel soluble poly(arylene vinylene)s containing indolo[3,2‐b]carbazole moiety inserted in the polymer chain at 2,8‐, 3,9‐ and 6,12‐positions were synthesized and used to study the influence of the linking topology on the optical and electronic properties. The new polymers were obtained through a palladium‐catalysed cross‐coupling Stille reaction between bis‐bromine[3,2‐b]indolocarbazoles and trans‐1,2‐bis(tributylstannyl)ethane in toluene. Polymers were soluble in chlorinated, aromatic and aprotic polar solvents. The structures of polymers were investigated using Fourier transform infrared, 1H NMR and 13C NMR spectroscopies. The number‐average molecular weights determined using gel permeation chromatography are in the range (6.3–9.4) × 103 g mol?1 while thermogravimetric analysis showed the polymers to possess high thermal stability. UV‐visible and emission spectroscopy evidenced a bathochromic shift of λmax for indolocarbazole linking topology in the polymer backbone, in the order: 6,12 < 2,8 < 3,9. Electrochemical properties were investigated by cyclic voltammetry using thin films cast on platinum disc working electrodes and highest occupied and lowest unoccupied molecular orbital energy levels were determined. © 2016 Society of Chemical Industry 相似文献