高铝铜合金粗粉超音速等离子喷涂层的边界润滑摩擦特性

采用超音速等离子喷涂技术在45#钢基体上制备高铝铜合金粗粉涂层,对涂层进行边界润滑摩擦实验,分析涂层的摩擦磨损特征及表面元素的质量损失。结果发现:涂层的摩擦因数随外加载荷的增加呈逐渐下降趋势;尽管磨损量随载荷的增大逐渐增加,但磨损率呈下降趋势,表明随外加载荷的增加涂层耐磨性能逐渐增强。涂层在中低载荷下以磨粒磨损为主,当载荷达到高载荷540 N时,涂层由磨粒磨损向疲劳磨损转变,并在犁沟边缘发生疲劳磨损的同时表现出轻度的粘着磨损。边界润滑条件下,涂层元素的质量磨损主要表现为Cu元素的损失,磨粒磨损留下的犁沟为O元素进入摩擦界面提供通道,使涂层表面形成微氧化膜。     

TA19合金表面TiAlN硬质涂层的耐磨性能研究

为了提高TA19合金的摩擦学性能,采用磁控溅射技术在TA19合金表面制备了TiAlN硬质涂层。采用扫描电子显微镜、X射线衍射仪和能谱仪研究了TiAlN涂层的微观形貌、物相组成和成分含量及分布,利用球-盘摩擦磨损试验机研究了不同载荷条件下硬质涂层和基体的摩擦行为及其磨损机理。结果表明:TiAlN涂层厚度约为4μm,表面为细小颗粒状,颗粒间较为紧密,颗粒尺寸大小均匀。涂层表面主要由Ti、Al、N元素组成,其原子比大约为1∶1∶1,涂层和基体间结合力可达到53.3 N。磨损试验结果表明,在TA19合金表面制备TiAlN涂层后,其摩擦系数和磨损率较TA19合金基体的有了明显的降低。在低载荷下,TiAlN涂层的磨损形式主要是磨粒磨损,在高载荷时转化为磨粒磨损和氧化磨损。     

等离子喷涂WC-12Co/NiCrAl复合涂层的摩擦磨损特性

以NiCrAl涂层为粘结层,用等离子喷涂工艺在TC4钛合金表面制备了WC-12Co/NiCrAl复合涂层。通过扫描电镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)和显微硬度仪等手段分析了涂层微观形貌、化学成分和显微硬度,并用磨损试验考察了WC-12Co/NiCrAl复合涂层的摩擦磨损特性。结果表明:WC-12Co涂层表面未熔颗粒较多,涂层截面孔隙率为10.2%;WC发生部分分解,出现W2C、Co6W6C等新相;涂层与基体结合界面为机械结合+局部微冶金结合方式;显微硬度为双态Weibull分布,呈现不同位置结构的差异化。WC-12Co涂层表现出良好的减摩及耐磨性能,同载荷下摩擦因数低于基体,磨损失重为基体的1/10,磨粒磨损是其主要磨损机制。     

激光熔覆Ni60A涂层对20CrNiMo合金高温干滑动摩擦磨损性能的影响（英文）

为改善制动盘材料的耐磨性能,选用Ni60A粉末,利用光纤激光器对20CrNiMo铸钢进行激光熔覆处理,研究了涂层的微观组织、成分均匀性、硬度、干滑动磨损性能及其损伤机制。结果表明:涂层主要由γ-Ni、M_(23)C_6、Ni-Cr-Fe、Ni_3B、[Fe, Ni]、FeNi_3、NiC、FeNi等相构成,涂层平均显微硬度HV_(0.3)为4600 MPa,较基体提高2.63倍。与基体相比,涂层在高载、高温工况下具有更小的平均摩擦系数,耐磨性得到显著提升。当载荷为150 N时,在室温和400℃时,耐磨性分别提高15.3和22.0倍。随温度和载荷的增加,涂层的损伤机制由磨粒和粘着磨损向氧化和磨粒磨损转变。     

WC-6%Co硬质合金的冲击磨粒磨损性能研究

用MLD-10型动载磨粒磨损试验机研究了不同晶粒度YG6硬质合金的冲击磨粒磨损性能。对试样进行了失重测量,并用FESEM分析磨损试样表面形貌。结果表明,硬质合金的耐磨性能与粘结相自由程、WC晶粒度有关;在本实验条件下,随着WC晶粒度或粘结相自由程增加,合金耐磨性先增加后减小,特定WC晶粒度配比的混晶WC-6%Co合金的抗冲击耐磨性能最好。合金的磨损失效机制也发生了转变:细晶合金主要表现为WC颗粒的剥落;随WC晶粒度增加,合金主要表现为大颗粒WC破碎后脱落。在以SiC为磨料的冲击磨粒磨损试验中,WC-6%Co合金的磨损是以WC颗粒的破碎和碎片脱落为主要的失效机制。     

Inconel 718合金在580℃下水蒸气环境中的氧化行为及摩擦学性能

通过高温氧化和高温摩擦试验研究了Inconel 718合金在580℃动态纯水蒸气环境中的氧化行为及高温摩擦学性能。结果表明：Inconel 718合金在580℃动态纯水蒸气环境中的氧化动力学曲线遵循两阶段直线规律;与在干燥空气中不同,Inconel 718合金在高温水蒸气中获得的氧化产物粗大,且有网状裂纹存在,但二者成分类似,主要由NiFe₂O₄和少量的NiO,Cr₂O₃和Fe₂O₃组成。随摩擦载荷增加,Inconel 718合金在580℃时的摩擦系数逐渐减小,而磨损率逐渐增加;其在2 N载荷下的磨损机制主要为粘着磨损,而在高于5 N载荷下的磨损机制主要为疲劳磨损和磨粒磨损。     

超音速火焰喷涂碳化钨-钴涂层磨粒磨损行为

采用超音速火焰喷涂工艺在16Mn钢上制备了WC-12Co涂层,并测试了该涂层的力学性能特别是其抗磨粒磨损性能。结果表明:WC-12Co涂层的主相为碳化钨,显微硬度为(1341.0±134.3)HV,孔隙率为0.21%±0.04%。该涂层的磨损率随着磨粒硬度、磨粒粒度和加载载荷的增加而增加。当磨粒的硬度低于涂层硬度时,涂层的磨损机制以磨耗磨损为主,磨损率低;当磨粒的硬度超过涂层的硬度时,涂层的磨损以微切削为主,磨损率高。另外,WC-12Co涂层的耐磨性相对于16Mn钢也是随着磨粒的硬度变化而变化。     

TiN/MT-TiCN/Al_2O_3复合涂层的摩擦学特性

采用化学气相沉积(CVD)技术,在YG8硬质合金基体上制备Ti N/MT-Ti CN/Al_2O_3复合涂层,利用X射线衍射仪和显微硬度计表征涂层的基本特性;用台阶仪、扫描电镜和电子能谱仪,对磨痕形貌进行微观分析,揭示复合涂层的磨损行为和磨损机理。结果表明:整个涂层由表层向基体依次为:α-Al_2O_3、Ti CN、Ti N和基体组成;摩擦因数随循环次数的增加,呈现先上升后逐渐趋于稳定;磨痕深度随载荷的增加而增加;磨痕中心可见塑性流动、犁沟、剥层等特性,磨痕边缘呈现大量片状的氧化磨屑,磨损机制主要表现为磨粒磨损、氧化磨损和剥层。     

激光熔覆Ni60A涂层对20CrNiMo合金高温干滑动摩擦磨损性能的影响

为改善制动盘材料的耐磨性能,选用Ni60A粉末,利用光纤激光器对20CrNiMo铸钢进行激光熔覆处理,研究了涂层的微观组织、成分均匀性、硬度、干滑动磨损性能及其损伤机制。结果表明：涂层主要由γ-Ni、M₂₃C₆、Ni-Cr-Fe、Ni₃B、[Fe, Ni]、FeNi₃、NiC、FeNi等相构成,涂层平均显微硬度HV_0.3为4600 MPa,较基体提高2.63倍。与基体相比,涂层在高载、高温工况下具有更小的平均摩擦系数,耐磨性得到显著提升。当载荷为150 N时,在室温和400 ℃时,耐磨性分别提高15.3和22.0倍。随温度和载荷的增加,涂层的损伤机制由磨粒和粘着磨损向氧化和磨粒磨损转变。     

超音速等离子与超音速火焰喷涂WC-10Co4Cr涂层的性能及磨损机理

采用超音速等离子喷涂和超音速火焰喷涂分别制备了WC-10Co4Cr金属陶瓷涂层,表征和分析了WC-10Co4Cr涂层的物相组成、微观组织结构,进行了硬度、孔隙率、结合强度及560和1120 r/min下的磨损对比试验。结果表明,超音速等离子喷涂制备的涂层的综合性能与超音速火焰喷涂制备的涂层性能相当。在560 r/min下磨损10 h,超音速等离子喷涂制备的涂层与基体的磨损量比为1∶122.15,超音速火焰喷涂制备的涂层与基体的磨损量比为1∶138.36,涂层的磨损机制主要表现为磨粒磨损。在1120 r/min下磨损10 h,超音速等离子喷涂制备的涂层与基体的磨损量比为1∶109.53,超音速火焰喷涂制备的涂层与基体的磨损量比为1∶127.44,涂层的磨损机制主要表现为磨粒磨损和疲劳磨损。     

不同尺度碳化物粉末冷喷沉积WC-17%Co涂层的组织及性能

采用团聚烧结和机械混合工艺制备的4种纳米与微米碳化物比例的WC-17%Co粉末,运用冷喷涂进行涂层定点沉积试验,通过扫描电镜和X-射线衍射分别分析了涂层的组织结构和相结构,并测定了涂层的显微硬度和磨粒磨损失重量.结果表明,4种碳化物尺度粉末沉积涂层具有致密的组织结构,喷涂态涂层保持与原始粉末相同的相结构,涂层显微硬度随碳化物尺度在12 897～15 925 MPa范围变化,粉末中纳米碳化物与微米碳化物颗粒重量比为50∶50时,沉积涂层具有较好的磨粒磨损性能.涂层磨损表面分析表明,涂层的磨损行为表现为涂层的磨粒磨损失重量在2.67～5.53 mg范围变化.     

Dynamic hardness of detonation sprayed WC-Co coatings

The objective of the present work was to determine the dynamic hardness of WC-Co coatings from the dynamic hardness of the coating substrate system. It was also the purpose of this work to evaluate the influence of coating composition, coating thickness, and substrate materials on the dynamic hardness of the coating. To achieve the above-mentioned objectives, WC-12%Co and WC-17%Co coatings were deposited by detonation spraying on three different substrate materials: mild steel, commercially pure (CP) aluminum, and CP titanium. The dynamic hardness of the coating/substrate composite was evaluated by a drop weight system. The dynamic hardness of the coating independent of the substrate was determined from the dynamic hardness of the coating/substrate composite.     

Effect of substrate on the 3 body abrasion wear of HVOF WC-17 wt.% Co coatings

WC-17 wt.% Co coatings were deposited using high velocity oxy-fuel (HVOF) spraying onto four different substrate materials, namely aluminium, brass, 304 stainless steel and super-invar. These substrates have different coefficients of thermal expansion which have been shown to influence the final coating microstructural properties. The abrasive wear properties of the coatings were characterised using an ASTM-G65 three body abrasive wear machine with silica sand as the abrasive. The highest mass loss was recorded for the coating on the aluminium substrate whilst the coated 304 stainless steel showed the lowest mass loss. The coatings on brass and super invar experienced similar mass losses. SEM studies of the worn surfaces showed preferential removal of the Co binder phase as well as cracking and rounding of the carbide grains. The differences in wear behaviour may be attributed to the presence of residual stresses where the highest compressive residual stress led to the highest wear rate. The coatings deposited onto brass showed compressive stresses whilst those deposited onto super-invar had tensile stresses, yet these two coatings had similar wear rates. Thus further study is required to provide conclusive evidence of the role of residual stresses on the abrasion resistance of these coatings.     

爆炸喷涂WC-12%Co涂层的滑动磨损性能

采用爆炸喷涂技术制备纳米和普通WC-12%Co涂层,用往复试验机对涂层的干滑动磨损性能进行了研究,分析了涂层磨损前后的形貌、结构及成分变化.结果表明:相同的喷涂条件下,WC-12%Co纳米涂层比普通涂层结构均匀、致密,但碳化物分解严重.尽管纳米涂层与普通涂层具有相近的硬度,但普通涂层的耐磨性优于纳米涂层,尤其是在重载条件下.普通涂层的磨损机制为微切削;纳米涂层在轻载(10 N)下,以塑性变形为主要磨损机制,随载荷增加至30 N,纳米WC粒子不能起到阻抗陶瓷球对磨副的磨削作用,而是随粘结相一起被去除,同时由于纳米涂层脱碳导致的层间结合薄弱,在滑动磨损中易发生成片剥落,耐磨性大幅下降.     

Micro-scale Abrasion and Medium Load Multiple Scratch Tests of PVD Coatings

THIN film coatings such as titanium nitride(TiN)orDiamond Like Carbon(DLC)are commonly used toprovide wear resistance to tools and mechanicalcomponents.Many tests have been developed to assesstheir characteristics;these tests can determine thehardness,the adhesion and the wear resistance of thecoatings;they can be performed as part of a QualityControl(QC)procedure or as a way of investigating thecoatings properties.As wear by abrasion is an important cause of wearproblems in industry and…     

Tribological behaviour of HVOF sprayed near-nanostructured and microstructured WC-17wt.%Co coatings

A ‘duplex cobalt coated’ near-nanostructured WC-17wt.%Co powder was used to produce nanostructured coatings. The tribological performance of this coating was compared with a commercial WC-17wt.%Co microstructured coating using a pin-on-plate method (ASTM G133-05 standard) with a data acquisition software to perform a real time analysis of the sliding wear process. The wear rate was studied using loads from 10 to 60 N and for various sliding distances. The metallurgical analysis of the coatings showed that the duplex Co coated powder could be sprayed to produce dense coating. Furthermore, the near-nanostructured coating showed better fracture toughness values and this corresponded to a difference in wear mechanism between the two types of coatings. The greater “plasticity” in the near-nanostructured coating was recorded as microgrooves in the wear tracks and, in comparison, brittle fracture was observed in the wear tracks produced on the microstructured coating.     

Friction and wear behavior of the PVD (Zr,Ti)N coated cemented carbide against 40Cr hardened steel

(Zr,Ti)N hard coatings were deposited on WC/TiC/Co cemented carbide by multi arc ion plating. Friction and wear behavior of the (Zr,Ti)N coatings against 40Cr hardened steel were evaluated using a ball-on-disk tribometer. The friction coefficients and wear rates were measured with varying applied loads and sliding speeds. The results showed that the friction coefficient increased with the increase of the applied load, and decreased with the increase of sliding speed. The wear rate decreased with both increasing applied load and sliding speed. The wear mechanism of the coatings at low friction loads was mild abrasive wear and flake while brittle fracture and flake at high applied loads. The wear mode of the (Zr,Ti)N coatings changed from adhesive wear and brittle fracture to mild abrasive wear as the sliding speed increased. The EGC coating which presents a graded distribution of coefficient of thermal expansion shows best wear resistant properties, in particular at high load and sliding speed conditions. Cracks, flakes and delamination fracture of the coatings were observed. The major failure mechanisms of the coatings are flaking and delamination.     

TC4合金表面WC-12Co激光熔覆层耐磨性研究

将WC-12Co合金粉末通过等离子喷涂预制在钛合金基体上，然后进行激光熔覆，通过耐磨性试验，分析了不同涂层材料与GCr15对滚后的磨损量。结果表明：WC-12Co等离子喷涂层经激光熔覆后耐磨性至少提高了2倍。     

等离子喷涂WC-20Cr3C2-7Ni/8YSZ复合涂层的组织及摩擦学性能

为提高连铸机拉矫辊的服役寿命,通过等离子喷涂技术在模具钢H13表面制备不同质量比的WC-20Cr₃C₂-7Ni+8YSZ复合涂层,分析各涂层的微区组织、显微硬度、抗划伤性、耐磨性和磨损形式。结果表明,在WC-20Cr₃C₂-7Ni粉末中分别加入30wt%、50wt%的8YSZ,其复合涂层的致密性明显提高,且涂层晶粒明显得到细化;WC-20Cr₃C₂-7Ni涂层中出现WC_1-x与W相,且随着8YSZ的添加WC相的结晶强度变弱;WC-20Cr₃C₂-7Ni+30wt%8YSZ涂层平均硬度(1172 HV0.2)相对于WC-20Cr₃C₂-7Ni涂层(1152 HV0.2)并没有明显变化,WC-20Cr₃C₂-7Ni+50wt%8YSZ涂层硬度(1052 HV0.2)相对于WC-20Cr₃...