Flame retardant finishing of cotton fleece fabric: Part V. Phosphorus‐containing maleic acid oligomers

The high flammability of cotton fleece makes it necessary to apply a flame retardant system on cotton fleece so that it can meet the federal regulation ‘Standard for the Flammability of Clothing Textiles’ (16 CFR 1610). The objective of this research was to reduce the flammability of cotton fleece using the phosphorus‐containing maleic acid oligomers (PMAO) synthesized by aqueous free radical polymerization of maleic acid. We found that PMAO can be bound to cotton fleece by esterifying with cotton cellulose with sodium hypophosphite as the catalyst. Both the 45^° flammability and limiting oxygen index data indicated that the treatment of cotton using PMAO reduced the flammability of cotton fleece. The micro‐scale combustion calorimetric data revealed that PMAO reduced the peak heat release rate and heat release capacity of the treated cotton woven fabric. The cotton fleece treated with PMAO/NaH₂PO₂ passed the federal flammability test (16 CFR Part 1610) and achieved ‘Class 1’ flammability. The PMAO bound to cotton was durable to multiple home laundering cycles. The treated fleece also showed high strength retention with little change in fabric whiteness. The use of triethanolamine as an additive modestly enhanced the performance of PMAO with no significant changes in fabric physical properties. Copyright © 2009 John Wiley & Sons, Ltd.     

A novel halogen‐free and formaldehyde‐free flame retardant for cotton fabrics

A novel halogen‐free and formaldehyde‐free flame retardant (FR), which contains phosphorus, nitrogen, and silicon, was synthesized for cotton fabrics considering the synergistic effect of phosphorus, nitrogen, and silicon. The structure of the new FR was characterized by Fourier‐trans‐form infrared spectroscopy, and the surface morphology of the treated fibre was observed using scanning electron microscope. The thermal property of the FR treated cotton fabric was studied through thermal gravimetric analysis. The TG results indicate that the FR can protect cotton fabric from fire to a certain degree. The vertical flammability test and limiting oxygen index results further indicate that the FR has excellent FR properties. Finally, the durability and other performance properties of the treated fabric were studied and the results show that the new materials can be used as a semi‐durable FR for cellulosic fibres. Copyright © 2011 John Wiley & Sons, Ltd.     

Flame retardant finishing of the polyester/cotton blend fabric using a cross‐linkable hydroxy‐functional organophosphorus oligomer

Blend fabrics of cotton and polyester are widely used in apparel, but high flammability becomes a major obstacle for applications of those fabrics in fire protective clothing. The objective of this research was to investigate the flame retardant finishing of a 50/50 polyester/cotton blend fabric. It was discovered previously that N,N′‐dimethyloldihydroxyethyleneurea (DMDHEU) was able to bond a hydroxy‐functional organophosphorus oligomer (HFPO) onto 50/50 nylon/cotton blend fabrics. In this research, the HFPO/DMDHEU system was applied to a 50/50 polyester/cotton twill fabric. The polyester/cotton fabric treated with 36% HFPO and 10% DMDHEU achieved char length of 165 mm after 20 laundering cycles. The laundering durability of the treated fabric was attributed to the formation of polymeric cross‐linked networks. The HFPO/DMDHEU system significantly reduced peak heat release rate (PHRR) of cotton on the treated polyester/cotton blend fabric, but its effects on polyester were marginal. HFPO/DMDHEU reduced PHRR of both nylon and cotton on the treated nylon/cotton fabric. It was also discovered that the nitrogen of DMDHEU was synergistic to enhance the flame retardant performance of HFPO on the polyester/cotton fabric.     

Flame retardant finishing of cotton fleece fabric. II. Inorganic phosphorus‐containing compounds

Cotton fleece is not able to meet the federal flammability standard for general apparels (CFR 1610) without flame retardant treatment. Consequently, cotton fleece is not available in the market in spite of high demands. In our previous research, we studied the application of a hydroxyl‐functional organophosphorus oligomer as a flame retardant finishing agent for cotton fleece. In this research, we investigated the use of aluminum hydroxyphosphate (AHP) formed in situ on cotton by the reaction of aluminum sulfate and sodium phosphates to reduce the flammability of cotton fleece. We found that the AHP formed on cotton is effective in reducing the cotton fleece's flammability from “Class 3” to “Class 1.” Elemental analysis of aluminum and phosphorus in the AHP shows that the mole ratio of Al/P changes as the pH value of the sodium phosphates solution changes. The pH of the sodium phosphate solutions also affect the quantity of AHP formed on the cotton fleece. The treated cotton fleece retains “Class 1” flammability after one home laundering or the combination of dry‐cleaning and hand washing procedures. The treatment increases the whiteness of the cotton fleece whereas it reduces its bursting strength. The cotton fleece thus treated is also investigated using differential scanning calorimetry and scanning electron microscopy. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Flame‐retardant finishing of cotton fleece fabric: part I. The use of a hydroxy‐functional organophosphorus oligomer and dimethyloldihydroxylethyleneurea

Cotton fleece has become a popular fashion in recent years. However, most of the 100% cotton fleece fabric is not able to meet the federal flammability standard (‘16 CFR Part 1610: Standard for the Flammability of Clothing Textiles’) without chemical treatment. In this research, we investigated the use of the combination of a hydroxy‐functional organophosphorus oligomer (HFPO) as the flame‐retarding agent and dimethyloldihydroxylethyleneurea (DMDHEU) as the binder to reduce the flammability of cotton fleece. We found that HFPO is effective in reducing the flammability of the cotton fleece whereas DMDHEU enhances the effectiveness of HFPO due to phosphorus–nitrogen synergism. The flammability as well as other properties of the treated cotton fleece is affected by both the concentration of HFPO and that of DMDHEU. The cotton fleece treated with HFPO/DMDHEU passes the federal flammability standard and shows high strength retention with little change in fabric whiteness and hand. We also found that the flame‐retardant finishing system is durable to multiple home launderings. The combination of HFPO and DMDHEU has the potential to become a practical flame‐retardant finishing system to reduce the flammability of cotton fleeces. Copyright © 2006 John Wiley & Sons, Ltd.     

Correlation between limiting oxygen index and phosphorus/nitrogen content of cotton fabrics treated with a hydroxy‐functional organophosphorus flame‐retarding agent and dimethyloldihydroxyethyleneurea

The combination of a hydroxyl‐functional organophosphorus flame‐retarding agent (FR) and dimethyloldihydroxyethyleneurea (DMDHEU) was used as a durable flame‐retardant finish system for cotton fabrics. DMDHEU functions as a binder between FR and cotton cellulose, thus making this flame‐retarding system durable to home laundering. DMDHEU also provides nitrogen to this system, therefore enhances its performance. Limiting oxygen index (LOI) is one of the most commonly used parameters to indicate the flammability of textiles and other polymeric materials. In this research, we investigated the correlation between LOI and phosphorus/nitrogen content on the cotton fabric treated with that durable flame‐retardant system. Phosphorus concentration on the fabric was analyzed by inductively coupled plasma atomic emission spectroscopy, whereas the nitrogen content was determined indirectly by measuring the carbonyl band intensity in the infrared spectra of the treated fabric. We developed a statistical model to predict LOI of the cotton fabric treated with FR and DMDHEU based on the phosphorus concentration and the intensity of carbonyl band of DMDHEU on cotton. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1885–1890, 2003     

Gamma-induced polymerization and grafting of a novel phosphorous-, nitrogen-, and sulfur-containing monomer on cotton fabric to impart flame retardancy

Diethyl (acryloyloxy) ethylthiophosphoramidate (DEAETPN), a novel phosphorus-, nitrogen-, and sulfur-containing monomer, was synthesized in a two-step reaction. The monomer was polymerized and grafted onto cotton fabric by gamma radiation method. Effect of methyl methacrylate (MMA) on percentage grafting (Pg) of DEAETPN on cotton fabric was studied, and it was found that small amount of MMA increases Pg on cotton fabric. The monomer, polymer, and the grafted cotton fabric were characterized by spectroscopic and thermogravimetric techniques. Flame retardant property of the modified cotton fabric was studied by the Shirley Manual Flammability Tester. The flame retardancy of cotton-g-DEAETPN by gamma radiation method and living radical polymerization method was compared. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Synthesis and application of a sulfur‐containing phosphoric amide flame retardant for nylon fabric

A sulfur‐containing flame retardant (SFR) was synthesized from polyphosphoric acid, epoxy chloropropane, and thiourea. Using a water‐soluble isocyanate‐terminated (WIT) cross‐linker, the flame retardant was applied as a flame‐retardant finishing on nylon fabric. WIT is a compound that not only cross‐links SFR and nylon cellulose but also contains no formaldehyde. Comparisons of the main performances of SFR with those of N‐methyloldimethylphosphonopropionamide (known as ‘Pyrovatex CP’) and a bicyclic phosphonite (known as ‘Antiblaze 19T’) indicate that the presence of sulfur in SFR plays a crucial role in decreasing the flammability of the nylon fabric. The limiting oxygen index value and damaged carbon length of the finished nylon fabric were 29.4% and 5.7 cm, respectively, when the concentrations of SFR and WIT were 200 and 40 g/L, respectively, and the baking temperature and time were 150 °C and 3 min, respectively. After 10 laundry cycles, the fabric still retains some flame retardancy. Copyright © 2016 John Wiley & Sons, Ltd.     

Layer‐by‐layer assembly of halogen‐free polymeric materials on nylon/cotton blend for flame retardant applications

Thin films of environmentally safe, halogen free, anionic sodium phosphate and cationic polysiloxanes were deposited on a Nyco (1:1 nylon/cotton blend) fabric via layer‐by‐layer (LbL) assembly to reduce the inherent flammability of Nyco fabric. In the coating process, we used three different polysiloxane materials containing different amine groups including, 35–45% (trimethylammoniummethylphenythyl)‐methyl siloxane‐55‐65% dimethyl siloxane copolymer chloride salt (QMS‐435), aminoethylaminopropyl silsesquioxane‐methylsilsesquioxane copolymer oligomer (WSA‐7021) and aminopropyl silesquioxane oligomers (WSA‐991), as a positive polyelectrolyte. Thermo‐gravimetric analysis showed that coated fabric has char yield around 40% at 600 °C whereas control fabric was completely consumed. The vertical flame test (VFT) on the LbL‐coated Nyco fabric was passed with after flame time, 2 s, and the char length of 3.81 cm. Volatile and nontoxic degradation products of flame retardant‐coated fabric were analyzed by pyrolysis gas chromatography mass spectroscopy (Py‐GCMS). Surface morphology of coated fabrics and burned fabric residues were studied by scanning electron microscopy. Copyright © 2014 John Wiley & Sons, Ltd.     

Effect of chicken‐feather protein‐based flame retardant on flame retarding performance of cotton fabric

A new kind of eco‐friendly chicken‐feather protein‐based phosphorus–nitrogen‐containing flame retardant was synthesized successfully with chicken‐feather protein, melamine, sodium pyrophosphate, and glyoxal. And its structure was characterized by Fourier transform infrared spectroscopy, and the thermogravimetry of the agent was analyzed. Then the flame retarding performances of the chicken‐feather protein‐based flame retardant and in combination with the borax and boric acid in application to a woven cotton fabric were investigated by the vertical flammability test and limited oxygen index test. In addition, the surface morphologies of the treated and untreated fabrics were conducted by the scanning electron micrographs (SEM), and the thermogravimetric analyses of the treated and untreated cotton were explored, and the surface morphologies of char areas of the treated and untreated fabrics after burnt were tested by the SEM. The results showed that the flame retardancy of the cotton fabric treated by the chicken‐feather protein‐based flame retardant in combination with borax and boric acid was improved further, and the combination of the chicken‐feather protein‐based flame retardant and borax and boric acid could facilitate to form a homogenous and compact intumescing char layer, and the combination of them plays a good synergistic effect in the improvement of the flame retardancy of the treated cotton fabric. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40584.     

Preparation of a halogen-free P/N/Si flame retardant monomer with reactive siloxy groups and its application in cotton fabrics

A novel halogen-free phosphorus-nitrogen-silicon flame retardant monomer with reactive siloxy groups,N-(diphenylphosphino)-1,1-diphenyl-N-(3-(triethoxysilyl)propyl) phosphinamine (DPTA) has been synthesized and was applied to the fire-resistant finishing of cotton fabrics.The molecular structure of DPTA has been well characterized by elemental analysis,FTIR,1H NMR,and 31p NMR spectroscopies.The chemically-grafted cotton fabrics,which were treated with 25 wt％ DPTA,were obtained and confirmed by attenuated total reflectance Fourier infrared spectroscopy (ATR-FTIR).The flame retardancy and thermal property of the treated samples were investigated by limited oxygen index (LOI),vertical flammability test (VFT),thermogravimetric analysis (TGA) and microscale combustion calorimeter (MCC).It is noted that in vertical flammability test,the treated samples extinguished immediately upon removing the ignition source,whereas the untreated one was completely burned out.Furthermore,TGA and MCC tests revealed that the treated samples produced a high char formation and a low heated release during combustion.The surface morphology of the untreated and treated samples and the char residues after LOI tests were observed by scanning electron microscopy (SEM).Therefore,all the results showed that the treated cotton fabrics with 25 wt％ DPTA apparently improved the fireresistant and thermal performances.     

Flame‐retardant finishing of cotton fabrics using polyamino carboxylic acids and sodium hypophosphite

The purpose of this research was to use polyamino carboxylic acids (PACAs) and their combination with sodium hypophosphite (NaH₂PO₂) as a flame‐retardant finishing system for cotton fabrics. Flammability of cotton fabric was evaluated by 45° flammability test, differential scanning calorimetry and measuring the char yield. The combination of polyamino carboxylic acids and sodium hypophosphite as a phosphorus‐containing catalyst reduces the flammability of cotton. The pyrolysis properties and the results of char yield of the finished cotton show that with increasing amount of catalyst, the flame retardancy increases. Fastness against multiple laundering, whiteness and tensile strength of the cotton finished with PACAs/NaH₂PO₂ to multiple standard laundering have been studied, too. The flame retardancy effect has an acceptable washing fastness. Whiteness and tensile strength of the finished cotton do not change significantly. Copyright © 2012 John Wiley & Sons, Ltd.     

Synthesis of carborane acrylate and flame retardant modification on silk fabric via graft copolymerization with phosphate‐containing acrylate

A novel carborane acrylate monomer (1‐acryloyloxyethyl carborane) was synthesized by addition reaction, hydrolysis, and esterification and characterized by proton nuclear magnetic resonance (¹H NMR) spectroscopy and Fourier transform infrared spectroscopy (FT‐IR) analysis. Subsequently, the carborane monomer and a phosphate‐containing methacrylate monomer were applied on the modification of a silk fabric. The heat resistance and flame retardancy of the silk fabric before and after modification were compared. Energy‐dispersive X‐ray spectrometer (EDS) and FT‐IR showed that carborane monomer and phosphate‐containing methacrylate were grafted onto the surface of the fibers. The cross‐sectional morphology of silk fabrics after burning was observed by scanning electron microscope (SEM), and the flame‐retardant mechanism was analyzed. Thermal‐gravimetric analysis (TGA) and differential scanning calorimetry (DSC) analysis revealed that the thermal stability of the modified silk increased with the increase of the grafting yield. The MCC‐2 microcalorimeter (MCC) test showed that, when using 1‐acryloyloxyethyl carborane as monomer and blending with phosphate‐containing methacrylate, the maximum heat release rate (PHRR) of the modified silk fabric decreased from 97.6 W/g (before grafting) to 51.3 and 45.8 W/g, respectively, and the total heat release (THR) decreased from 10.2 kJ/g (before grafting) to 5.9 and 5.2 kJ/g, respectively. The limiting oxygen index (LOI) test revealed that using 1‐acryloyloxyethyl carborane and phosphate‐containing methacrylate as mixed monomers to modify the silk fabric obtained good flame retardancy, whose LOI value reached 29.8%.     

Flame‐retardant finishing in cotton fabrics using zinc oxide co‐catalyst

In this article, N‐Methylol dimethylphosphonopropionamide (FR) in combination with a melamine resin (CL), phosphoric acid (PA) catalyst and zinc oxide (ZnO) or nano‐ZnO co‐catalyst were used (FR‐CL‐PA‐ZnO or nano‐ZnO system) to impart flame‐retardant property on cotton fabrics. FR‐CL or FR‐CL‐PA‐treated cotton specimen showed roughened and wrinkled fabric surface morphology, which was caused by the attack of the FR with slightly acidity. In addition, FTIR analysis showed some new characteristic peaks, carbonyl, CH₂ rocking and CH₃ asymmetric and CH₂ symmetric stretching bands, in the chemical structure of treated cotton specimens. Apart from these, the flame ignited on the flame‐retardant‐treated fabrics (without subjected to any post‐wet treatment) extinguished right after the removal of ignition source. However, FR‐CL treated specimens were no longer flame‐resistant when the specimens subjected to neutralization and/or home laundering, while FR‐CL‐PA treated specimens showed opposite results. By using 0.2% and 0.4% of ZnO or nano‐ZnO as co‐catalyst, the flame spread rate of neutralized and/or laundered test specimens decreased, even the specimens were undergone 10 home laundering cycles. Moreover, flame‐retardant‐treated cotton specimens had low breaking load and tearing strength resulting from side effects of the crosslinking agent used, while addition of ZnO or nano‐ZnO co‐catalyst could compensates for the reduction. Furthermore, the free formaldehyde content was dropped when ZnO and nano‐ZnO co‐catalyst was added in the treatment. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Flammability and thermal degradation of epoxy acrylate modified with phosphorus‐containing compounds

A series of UV‐curable flame‐retardant resins was obtained by blending phosphate acrylate (BTP) in different ratios with epoxy acrylate resin (EA). The flammability was characterized by limiting oxygen index (LOI), UL 94 flammability rating and cone calorimeter, and the thermal degradation of the flame‐retardant resins was studied using thermo gravimetric analysis (TGA), and real‐time Fourier transform infrared (RTFTIR). The results indicated that the flame‐retardant efficiency increases with the addition of BTP. The heat release rate with the addition of BTP decreases greatly. The TGA data showed that EA/BTP blends have lower initial decomposition temperatures and higher char residues than pure EA, whereas BTP has the lowest initial decomposition temperature and the highest char residue. The RTFTIR study indicates that the EA/BTP blends have lower thermal oxidative stability than the pure EA. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Synthesis,characteristic of a novel flame retardant containing phosphorus and its application in poly(ethylene‐co‐vinyl acetate)

A novel flame retardant (SPDH) containing phosphorus was synthesized through the reaction of 10‐(2, 5‐dihydroxyphenyl)‐9, 10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide (DOPO‐HQ) and synthesized intermediate product 3, 9‐dichloro‐2, 4, 8, 10‐tetraoxa‐3, 9‐diphosphaspiro(5.5)undecane‐3, 9‐dioxide (SPDPC). The structure and properties of SPDPC and SPDH were characterized by Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR) spectroscopy and thermogravimetric analysis (TGA). After blending with poly(ethylene‐co‐vinyl acetate) (EVA), the flame‐retardant properties of EVA/SPDH composites were estimated by cone calorimeter, limited oxygen index (LOI) and UL‐94 tests, whereas the thermal stabilities were investigated using TGA. The morphological microstructure of the char formed by EVA/SPDH composite after combustion in cone calorimeter was investigated by scanning electron microscopy (SEM). The results indicate that the flame retardant and thermal stability were improved by incorporation of SPDH. The rich foamy char layers were observed from the residues after combustion in a cone calorimeter, which exactly benefits the improvement of thermal stability and flame retardant property of materials. Copyright © 2010 John Wiley & Sons, Ltd.     

Durable flame‐retardant treatment of polyethylene terephthalate (PET) and PET/cotton blend using dichlorotribromophenyl phosphate as new flame retardant for polyester

Dichlorotribromophenyl phosphate (DCTBPP) was synthesized via the reaction of tribromophenol and phosphorous oxychloride and characterized by elemental analysis, IR, ¹H‐NMR, thermogravimetric analysis, and differential scanning calorimetry. To impart durable flame retardancy the poly(ethylene terephthalate) (PET) fabric was treated with DCTBPP via pad–dry–thermosol fixation and the PET/cotton (50/50) blend fabric was treated with both DCTBPP and tetrakis(hydroxymethyl) phosphonium chloride (THPC)/urea precondensate via a two‐bath sequential treatment. The treated PET fabric's increased limiting oxygen index value was proportional to the increasing DCTBPP application level and showed self‐extinguishing properties at 8.1% add‐on, even after 50 washes. The blend fabric treated with 15% DCTBPP and 30% THPC/urea precondensate became self‐extinguishable and durable to 50 washes, and the treated fabric retained over 85% of its breaking strength without excessive stiffness. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 793–799, 2001     

Combination of a hydroxy‐functional organophosphorus oligomer and a multifunctional carboxylic acid as a flame retardant finishing system for cotton: Part II. Formation of calcium salt during laundering

Multifunctional carboxylic acids, such as 1,2,3,4‐butanetetracarboxylic acid (BTCA), were used to bond a hydroxy‐functional organophosphorus oligomer (FR) to cotton fabric in the presence of a catalyst, such as sodium hypophosphite (NaH₂PO₂). Previously, it was found that the cotton fabric treated with FR and BTCA showed a high level of phosphorus retention after one home laundering cycle. However, the flame retardant properties quickly deteriorated as the number of home laundering cycles was increased. In this research, it was found that the free carboxylic acid groups bound to the cotton fabric form an insoluble calcium salt during home laundering, thus diminishing the flame retardant properties of the treated cotton fabric. It was also found that the free carboxylic acid groups on the treated cotton fabric were esterified by triethanolamine (TEA), and that the formation of calcium salt on the fabric was suppressed by the esterification of the free carboxylic acid groups by TEA. The cotton fabric treated with BTCA and the hydroxy‐functional organophosphorus oligomer significantly improved its flame retardance when a new catalyst system consisting of hypophosphorous acid (H₃PO₂) and TEA was used in the system. Copyright © 2003 John Wiley & Sons, Ltd.     

Poly(methyl methacrylate)/montmorillonite nanocomposites prepared with a novel reactive phosphorus–nitrogen‐containing monomer of N‐(2‐(5,5‐dimethyl‐1,3,2‐dioxaphosphinyl‐2‐ylamino)ethyl)‐ acrylamide and its thermal and flame retardant properties

A novel reactive phosphorus–nitrogen‐containing monomer, N‐(2‐(5,5‐dimethyl‐1,3,2‐dioxaphosphinyl‐2‐ylamino)ethyl)‐acrylamide (DPEAA), was synthesize and characterized. Flame retardant poly(methyl methacrylate)/organic‐modified montmorillonite (PMMA‐DPEAA/OMMT) nanocomposites were prepared by in situ polymerization by incorporating methyl methacrylate, DPEAA, and OMMT. The results from X‐ray diffraction and transmission electron microscopy (TEM) showed that exfoliated PMMA‐DPEAA/OMMT nanocomposites were formed. Thermal stability and flammability properties were investigated by thermogravimetric analysis, cone calorimeter, and limiting oxygen index (LOI) tests. The synergistic effect of DPEAA and montmorillonite improved thermal stability and reduced significantly the flammability [including peak heat release rates (PHRR), total heat release, average mass loss rate, etc.]. The PHRR of PMMA‐DPEAA/OMMT was reduced by about 40% compared with pure PMMA. The LOI value of PMMA‐DPEAA/OMMT reached 27.3%. The morphology and composition of residues generated after cone calorimeter tests were investigated by scanning electronic microscopy (SEM), TEM, and energy dispersive X‐ray (EDX). The SEM and TEM images showed that a compact, dense, and uniform intumescent char was formed for PMMA‐DPEAA/OMMT nanocomposites after combustion. The results of EDX confirmed that the carbon content of the char for PMMA‐DPEAA/OMMT nanocomposites increased obviously by the synergistic effect of DPEAA and montmorillonite. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

复配阻燃剂阻燃纯棉织物的工艺研究

采用聚磷酸铵(APP),季戊四醇(PER),聚磷酸蜜胺(MPP)复配作为阻燃纯棉织物的阻燃剂,以乙二醛(GLY)为交联剂,研究APP的最佳溶解温度及织物的焙烘条件,并在此条件下以APP/MPP/PER/GLY(10/7/1/2)为复配阻燃剂整理纯棉织物。通过氧指数、垂直燃烧、热降解等表征其阻燃性能。研究结果表明:APP的最佳溶解温度为85℃,复配阻燃剂整理纯棉织物的烘焙条件140℃×150s,阻燃纯棉织物的阻燃性能较好。