Research on quantum efficiency and photoemission characteristics of exponential-doping GaN nanowire photocathode

Aimed at improving the actual photoemission performance of nanowire photocathode, an axial exponential-doping GaN nanowire photocathode is proposed. Based on two-dimensional continuity equation and finite difference method, the quantum efficiency of this exponential-doping GaN nanowire photocathode is obtained. The simulation results suggest that this structure of GaN nanowire photocathode can effectively obviate the difficulty in collecting the electrons escaping from side faces because a large part of carriers will escape from top surface under the built-in electric field. Besides, it is discovered that the optimal height of nanowires is 300 nm when the doping concentration of top surface is 1 × 10¹⁸ cm^?3 and that of back interface is 1 × 10¹⁹ cm^?3. Then, when the nanowires are arranged as array, the optimal light angle of incidence is approximately 60° by analyzing the electrons flow density of the array. By comparison of collection proportion of photoelectrons, the optimal nanowire spacing is 231 nm. This study demonstrates potential application value of exponential-doping GaN nanowire photocathode. The results can direct the preparation of this kind of photocathode.     

Mechanism of cavitation and its dependence on the corrosion resistance of metals

The role of high-frequency pulses associated with liquid microvolumes breaking away from a solid surface and the part played by corrosion in erosion damage of metals were studied. It was shown that a reduction in the intensity of cavitation is accompanied by a substantial increase in the corrosion resistance of metals.     

Determination of the length dependence of the threshold for fatigue crack propagation

A rising load amplitude crack growth test on specimens pre-cracked in cyclic compression is presented as a procedure to determine the length dependence of the threshold of fatigue crack propagation described by the R(resistance)-curve for the threshold of stress intensity factor range. The experimental results show that the residual stress field in front of the pre-crack can significantly influence the R-curve.In order to measure the material specific R-curve which is not affected by the pre-cracking condition it is important to use the smallest possible load amplitude. To achieve this goal, a very small notch root radius is essential. It is shown that at notches machined by razor blade polishing technique the load amplitude for pre-cracking can be reduced to values where the load history does not influence the R-curve for the threshold of stress intensity range.     

On the composition of a multialkali photocathode

During our technological experiments concerning the standard S-20 process, we observed appreciable deviations from the accepted Na₂KSb composition of the multialkali photocathode. First results which were achieved by the method of the double wedge developed earlier by the authors for multialkali composition, which are rather closer to NaK₂Sb, are presented in a short form.     

广泛用于电致发光器件测量的装置及其自动化控制

通过Vb程序平台编制了一套控制及数据处理系统,对测量电致发光器件的装置进行了自动化程序控制,使用户可以极为方便的获取不同偏压下电致发光器件的Ⅳ特性曲线及光学参数.该套系统已成功地用于中科院理化所、化学所,中国电子科技大学,北京大学等单位,是一种广泛用于评价电致发光器件的系统方案.     

Self-shading of upwelling irradiance for an instrument with sensors on a sidearm

The self-shading measurement error of the upwelling irradiance that is due to the presence of the instrument housing of an optical spectrometer with the irradiance meter located on a sidearm was calculated with a Monte Carlo code. The dependence of the effect on the instrument dimensions, the values of real optical parameters, sea-surface roughness, and Sun zenith angle were all studied to estimate maximum errors for two possible configurations of a proposed new marine spectrophotometer.     

Spectral response variation of a negative-electron-affinity photocathode in the preparation process

In order to research the spectral response variation of a negative electron affinity (NEA) photocathode in the preparation process, we have done two experiments on a transmission-type GaAs photocathode. First, an automatic spectral response recording system is described, which is used to take spectral response curves during the activation procedure of the photocathode. By this system, the spectral response curves of a GaAs:Cs-O photocathode measured in situ are presented. Then, after the cathode is sealed with a microchannel plate and a fluorescence screen into the image tube, we measure the spectral response of the tube by another measurement instrument. By way of comparing and analyzing these curves, we can find the typical variation in spectral-responses. The reasons for the variation are discussed. Based on these curves, spectral matching factors of a GaAs cathode for green vegetation and rough concrete are calculated. The visual ranges of night-vision goggles under specific circumstances are estimated. The results show that the spectral response of the NEA photocathode degraded in the sealing process, especially at long wavelengths. The variation has also influenced the whole performance of the intensifier tube.     

Bioinspired molecular co-catalysts bonded to a silicon photocathode for solar hydrogen evolution

The production of fuels from sunlight represents one of the main challenges in the development of a sustainable energy system. Hydrogen is the simplest fuel to produce and although platinum and other noble metals are efficient catalysts for photoelectrochemical hydrogen evolution, earth-abundant alternatives are needed for large-scale use. We show that bioinspired molecular clusters based on molybdenum and sulphur evolve hydrogen at rates comparable to that of platinum. The incomplete cubane-like clusters (Mo(3)S(4)) efficiently catalyse the evolution of hydrogen when coupled to a p-type Si semiconductor that harvests red photons in the solar spectrum. The current densities at the reversible potential match the requirement of a photoelectrochemical hydrogen production system with a solar-to-hydrogen efficiency in excess of 10%. The experimental observations are supported by density functional theory calculations of the Mo(3)S(4) clusters adsorbed on the hydrogen-terminated Si(100) surface, providing insights into the nature of the active site.     

Axial irradiance of a focused beam

The principal maximum of axial irradiance of a focused beam with a low Fresnel number does not lie at its focal point; instead it lies at a point that is closer to the focusing pupil. It has been shown by the numerical example of a weakly truncated Gaussian beam that its value increases and its location moves closer to the pupil when spherical aberration is introduced into the beam. Such an increase has been referred to as "beyond the conventional diffraction limit." Similarly, an increase in the value and a shift in the location of the principal maximum of axial irradiance of a uniform beam toward the pupil by the introduction of some spherical aberration has been characterized as an unexpected result. We explain why and how such a result comes about and that it neither invalidates any diffraction limit nor is it unexpected. We illustrate this for uniform as well as Gaussian beams of various truncation ratios. Both focused and collimated beams aberrated by spherical aberration or astigmatism are considered.     

Laser ablation threshold dependence on pulse duration for fused silica and corneal tissues: experiments and modeling

The surface ablation threshold fluence of fused silica and two porcine cornea layers, the epithelium and the stroma, is characterized as a function of the laser pulse duration in the range of 100 fs-5 ps for a wavelength of 800 nm (Ti:sapphire laser system). The plateaulike region observed between 100 fs and 1 ps for the corneal layers indicates that for use in laser surgery, laser pulse durations chosen within this range should be practically equivalent. Our model predicts that the ablation threshold will decrease rapidly for pulse durations in the low end of the femtosecond regime.     

Metal on metal oxide nanowire Co-catalyzed Si photocathode for solar water splitting

We report a systematic study of Si|ZnO and Si|ZnO| metal photocathodes for effective photoelectrochemical cells and hydrogen generation. Both ZnO nanocrystalline thin films and vertical nanowire arrays were studied. Si|ZnO electrodes showed increased cathodic photocurrents due to improved charge separation by the formation of a p/n junction, and Si|ZnO:Al (n(+)-ZnO) and Si|ZnO(N(2)) (thin films prepared in N(2)/Ar gas) lead to a further increase in cathodic photocurrents. Si|ZnONW (nanowire array) photocathodes dramatically increased the photocurrents and thus photoelectrochemical conversion efficiency due to the enhanced light absorption and enlarged surface area. The ZnO film thickness and ZnO nanowire length were important to the enhancements. A thin metal coating on ZnO showed increased photocurrent due to a catalyzed hydrogen evolution reaction and Ni metal showed comparable catalytic activities to those of Pt and Pd. Moreover, photoelectrochemical instability of Si|ZnO electrodes was minimized by metal co-catalysts. Our results indicate that the metal and ZnO on p-type Si serve as co-catalysts for photoelectrochemical water splitting, which can provide a possible low-cost and scalable method to fabricate high efficiency photocathodes for practical applications in clean solar energy harvesting.     

Evaluation of p-type PdO as a photocathode in water photoelectrolysis

The electronic and electrochemical properties of vapour-grown single-crystal PdO are reported; this PdO is a p-type semiconductor with a bandgap of about 0.8 eV, corresponding to a strongly forbidden d-d transition. A higher-energy transition, with a threshold near 2.2eV, is assigned to 0 2p — Pd 4d charge transfer. The flat-band potential PdO appears to be 0.7 ± 0.1V (NHE) in 0.5M H₂SO₄, but the photoresponse of the crystals is poor owing both to unfavourable bulk properties and to feeble faradaic kinetics for hydrogen evolution. The cathodic decomposition of PdO to palladium metal is a strongly competing reaction under potential biases that invert the surface region.     

Specklegram in a multiple-mode fiber and its dependence on longitudinal modes of the laser source

A specklegram in a multimode fiber (MMF) has successfully been used as a sensor for detecting external disturbance. Our experiments showed that the sensitivity in the sensor with a multiple longitudinal-mode laser as its source was much higher than that with a single longitudinal-mode laser. In addition, the near-field pattern observations indicated that the coupling between different transverse modes in the MMF is quite weak. Based on the experimental results, a theoretical model for the speckle formation is proposed, taking a bend-caused phase factor into consideration. It is shown in the theoretical analysis that the interferences between different longitudinal modes make a larger contribution to the specklegram signals.     

On the asymmetrical dependence of the threshold pressure of infiltration on the wettability of the porous solid by the infiltrating liquid

A general equation has been derived for the threshold pressure of infiltration of liquids into porous solids. From this equation all the known equations for the threshold pressure can be obtained, using different assumptions on the morphology of the porous solid and on the way how the liquid infiltrates the solid. Particularly, the Young-Laplace equation, the Carman-equation, and the modification of the Carman equation, suggested by White and later by Mortensen and Cornie have been reproduced as particular cases of the general equation. A new particular solution of this general equation is also suggested, taking into account that the original solid/gas interface inside the porous body is not fully replaced by the solid/liquid interface during infiltration, especially for the case of non-wetting liquids. The new, general equation consists of three semi-empirical parameters, which should be found experimentally for a given type of morphology of the porous solid and for the given ratio of the surface tension to the density of the infiltrating liquid metal. The new equation provides a value of the threshold contact angle to be between 65.5° and 90°, depending on the morphology of the porous solid. Consequently, the threshold pressure appears to be an asymmetrical function of the contact angle. Based on the new equation, the practical constancy of the threshold pressure is predicted in the interval of the contact angles between 120° and 180°.     

Action of ultrasound on the rise of a liquid in a capillary tube and its dependence on the properties of the liquid

The dependence of the ultrasonic capillary effect on the viscosity, vapor pressure, surface tension, and gas content of the liquid is investigated.Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 3, pp. 513–519, September, 1980.     

Wavelength dependence of repetitive-pulse laser-induced damage threshold in beta-BaB2O4

The dependence on wavelength of repetitive-pulse (10 Hz, 8-10 ns) laser-induced damage on beta barium metaborate (BBO) has been investigated. The thresholds of dielectric breakdown in bulk crystal have been found to be 0.3 GW/cm(2) at 266 nm, 0.9 GW/cm(2) at 355 nm, 2.3 GW/cm(2) at 532 nm, and 4.5 GW/cm(2) at 1064 nm. Results indicate two-photon absorption at 266 and 355 nm, which helps to produce an avalanche effect that causes breakdown at each of the four wavelengths tested. Neither the BBO refractive indices nor the absorption spectrum change until breakdown occurs.     

Modeling of the influence of snow reflectance on ultraviolet irradiance for cloudless sky

The amplification of UV irradiance at the Earth's surface that is due to successive reflections between the snow-covered ground and the scattering atmosphere is analyzed by a method based on decoupling the atmosphere and the surface functions. For a uniform Lambertian surface the amplification factor for the global irradiance depends only on the product of the surface reflectance and the atmospheric backscatter. It varies with wavelength, reaching a maximum near 320 nm; this maximum is close to 50% for clean snow. In UV-B the amplification depends strongly on tropospheric ozone. For non-Lambertian, nonuniform surfaces it is possible, by the same method, to define effective or average reflectances.     

Development of a mathematical model for the degradation of the parameters of photoemission detectors and converters

The results are given of the development of a mathematical model for the degradation of the quantum yield of photoemission detectors and converters which takes account of structural changes in emission-active surface of the sensitive elements and is based on using the apparatus of the Fokker-Planck-Kolmogorov equations.Translated from Izmeritel'naya Tekhnika, No. 1, pp. 19–20, January, 1995.     

Improved entrance optic for global irradiance measurements with a Brewer spectrophotometer

A new entrance optic for a Brewer spectrophotometer has been designed and tested both in the laboratory and during solar measurements. The integrated cosine response deviates by 2.4% from the ideal, with an uncertainty of +/- 1%. The systematic uncertainties of global solar irradiance measurements with this new entrance optic are considerably reduced compared with measurements with the traditional design. Simultaneous solar irradiance measurements between the Brewer spectrophotometer and a spectroradiometer equipped with a state-of-the-art shaped diffuser agreed to within +/- 2% during a five-day measurement period.