Prediction of Young’s modulus and Poisson ratio for foamed metals using octahedron model

Abstract

The present paper deals with the mathematical–physical expression of Young’s modulus and Poisson ratio of foamed metals. As it is known that, Young’s modulus and Poisson ratio are two basic mechanical parameters of engineering materials. Foamed metal is a class of excellent engineering materials with dual attributes of structural and functional characteristics; therefore, these two parameters are investigated for these materials, and the relevant mathematical–physical expressions are derived from the ‘octahedron model’ of porous materials in the present paper. The results show that the apparent Young’s modulus displays a quite complicated mathematical relationship to porosity of the porous body, and the apparent Poisson ratio is just a characteristic of the material constant almost not relative to porosity of the foamed metal.     

Processing of polysiloxane-derived porous ceramics: a review

Abstract

Because of the unique combination of their attractive properties, porous ceramics are considered as candidate materials for several engineering applications. The production of porous ceramics from polysiloxane precursors offers advantages in terms of simple processing methodology, low processing cost, and easy control over porosity and other properties of the resultant ceramics. Therefore, considerable research has been conducted to produce various Si(O)C-based ceramics from polysiloxane precursors by employing different processing strategies. The complete potential of these materials can only be achieved when properties are tailored for a specific application, whereas the control over these properties is highly dependent on the processing route. This review deals with processing strategies of polysiloxane-derived porous ceramics. The essential features of processing strategies—replica, sacrificial template, direct foaming and reaction techniques—are explained and the available literature reports are thoroughly reviewed with particular regard to the critical issues that affect pore characteristics. A short note on the cross-linking methods of polysiloxanes is also provided. The potential of each processing strategy on porosity and strength of the resultant SiC or SiOC ceramics is outlined.     

ON THERMAL CONDUCTIVITY OF POROUS MATERIALS: COMPACTED COLD-PRESSED ZINC OXIDE AND CHARCOAL POWDERS

ABSTRACT

A semi-absolute steady-state method is applied to measure the thermal conductivity of powder material, manufactured in the form of small discs having different porosities, within the technically possible porosity range (50–70%). The results show that heat-transfer through porous materials depends on the porosity and on other factors. These results are represented by a family of curves, which tend to converge to a point as the volume fraction of the solid phase increases (porosity decreases). As a result of this work, the value of porosity is determined, at which all the samples having the same porosity will have nearly the same thermal conductivity.     

Powder Metallurgical Near‐Net‐Shape Fabrication of Porous NiTi Shape Memory Alloys for Use as Long‐Term Implants by the Combination of the Metal Injection Molding Process with the Space‐Holder Technique

A new method was developed for producing highly porous NiTi for use as an implant material. The combination of the space‐holder technique with the metal injection molding process allows a net‐shape fabrication of geometrically complex samples and the possibility of mass production for porous NiTi. Further, the porosity can be easily adjusted with respect to pore size, pore shape, and total porosity. The influence of the surface properties of powder metallurgical NiTi on the biocompatibility was first examined using human mesenchymal stem cells (hMSCs). It was found that pre‐alloyed NiTi powders with an average particle size smaller than 45 μm led to the surface properties most suitable for the adhesion and proliferation of hMSCs. For the production of highly porous NiTi, different space‐holder materials were investigated regarding low C‐ and O‐impurity contents and the reproducibility of the process. NaCl was the most promising space‐holder material compared to PMMA and saccharose and was used in subsequent studies. In these studies, the influence of the total porosity on the mechanical properties of NiTi is investigated in detail. As a result, bone‐like mechanical properties were achieved by the choice of Ni‐rich NiTi powder and a space‐holder content of 50 vol% with a particle size fraction of 355–500 μm. Pseudoelasticity of up to 6% was achieved in compression tests at 37 °C as well as a bone‐like loading stiffness of 6.5 GPa, a sufficient plateau stress σ₂₅ of 261 MPa and a value for σ₅₀ of 415 MPa. The first biological tests of the porous NiTi samples produced by this method showed promising results regarding proliferation and ingrowth of mesenchymal stem cells, also in the pores of the implant material.     

Low thermal conductivity and high porosity ZrC and HfC ceramics prepared by in-situ reduction reaction/partial sintering method for ultrahigh temperature applications

Porous ultra-high temperature ceramics(UHTCs) are potential candidates as high-temperature thermal insulation materials. However, high thermal conductivity is the main obstacle to the application of porous UHTCs. In order to address this problem, herein, a new method combining in-situ reaction and partial sintering has been developed for preparing porous Zr C and Hf C with low conductivity. In this process, porous Zr C and Hf C are directly obtained from ZrO_2/C and HfO_2/C green bodies without adding any pore-forming agents. The release of reaction gas can not only increase the porosity but also block the shrinkage. The asprepared porous Zr C and Hf C exhibit homogeneous porous microstructure with grain sizes in the range of 300–600 nm and 200–500 nm, high porosity of 68.74% and 77.82%, low room temperature thermal conductivity of 1.12 and 1.01 W·m~(-1) K~(-1), and compressive strength of 8.28 and 5.51 MPa, respectively.These features render porous Zr C and Hf C promising as light-weight thermal insulation materials for ultrahigh temperature applications. Furthermore, the feasibility of this method has been demonstrated and porous Nb C, Ta C as well as Ti C have been prepared by this method.     

Dependence of Ultrasonic Velocity on Porosity and Pore Shape in Sintered Materials

A new approach to predict the longitudinal and transverse ultrasonic velocities in porous materials is presented. The model is based on a previously derived Young's modulus-porosity correlation assuming spheroidal geometry of the pores. It is also assumed that the Poisson's ratio of porous materials does not change significantly with porosity. The longitudinal and transverse ultrasonic velocities are given as functions of the Young's modulus, Poisson's ratio, density of the pore-free material and of the porosity and axial ratio (z/x) of the spheroidal pores. Experimental data drawn from the literature on different porous sintered materials including SiC, Al₂O₃, YBa₂Cu₃O_7–x , porcelain, sintered iron, Si₃N₄, and sintered tungsten, were used to verify the model. A strong relationship between pore shape and the slope of the ultrasonic velocity–porosity curve was confirmed. In general, the calculated values are in fairly good agreement with the experimental data. When the actual shape (axial ratio) of the pores was known, the approach was shown to predict the experimental data better than a similar model derived by Phani. It is suggested that the present approach, coupled with the measurement of the ultrasonic velocity, may constitute a simple nondestructive technique to gain knowledge of the morphology of the porosity in sintered materials.     

Scalable Fabrication of Porous Microchannel Nerve Guidance Scaffolds with Complex Geometries

Microchannel scaffolds accelerate nerve repair by guiding growing neuronal processes across injury sites. Although geometry, materials chemistry, stiffness, and porosity have been shown to influence nerve growth within nerve guidance scaffolds, independent tuning of these properties in a high‐throughput manner remains a challenge. Here, fiber drawing is combined with salt leaching to produce microchannels with tunable cross sections and porosity. This technique is applicable to an array of biochemically inert polymers, and it delivers hundreds of meters of porous microchannel fibers. Employing these fibers as filaments during 3D printing enables the production of microchannel scaffolds with geometries matching those of biological nerves, including branched topographies. Applied to sensory neurons, fiber‐based porous microchannels enhance growth as compared to non‐porous channels with matching materials and geometries. The combinatorial scaffold fabrication approach may advance the studies of neural regeneration and accelerate the development of nerve repair devices.     

多孔材料模型分析

多孔泡沫材料的制备、应用和性能研究均不断取得新的进展.在关于多孔材料结构和性能方面的理论中,著名的经典性模型--Gibson-Ashby模型一直受到国际同行的普遍认同,迄今仍然是众多研究者在研究工作中广泛应用的理论基础.对该模型尚存在的若干不足和问题进行了一些补充思考和分析,发现其中有些缺陷甚至可以打破该模型原来表现出来的"完满性".在总结陈述这些问题的基础上,引荐了可以克服或弥补上述模型不足的另一个模型.     

Mass Transfer Performance of Porous Nickel Manufactured by Lost Carbonate Sintering Process

Open cell porous metals are excellent electrode materials due to their unique electrochemical properties. However, very little research has been conducted to date on the mass transport of porous metals manufactured by the space holder methods, which have distinctive porous structures. This paper measures the mass transfer coefficient of porous nickel manufactured by the Lost Carbonate Sintering process. For porous nickel samples with a porosity of 0.55–0.75 and a pore size of 250–1500 μm measured at an electrolyte flow velocity of 1–12 cm s^?1, the mass transfer coefficient is in the range of 0.0007–0.014 cm s^?1, which is up to seven times higher than that of a solid nickel plate electrode. The mass transfer coefficient increases with pore size but decreases with porosity. The porous nickel has Sherwood numbers considerably higher than the other nickel electrodes reported in the literature, due to its high real surface area and its tortuous porous structure, which promotes turbulent flow.

     

Carbonization and oxidation of metal–organic frameworks based on 1,4-naphthalene dicarboxylates

Abstract

Three new isostructural metal–organic frameworks (MOFs), [V(OH)(NDC)] (1), [Cr(OH)(NDC)] (2), and [Ga(OH)(NDC)] (3) have been synthesized hydrothermally using 1,4-naphthalene dicarboxylate (NDC) as the linker. These MOFs (1, 2 and 3) have been used as a template for the synthesis of metal-oxide-inserted nanoporous carbon materials. The newly synthesized MOFs and the resulting porous carbon hybrid functional materials have been characterized using powder x-ray diffraction, scanning electron microscopy, transmission electron microscopy, and energy dispersive x-ray spectroscopic analysis. Results show that compounds 2 and 3 form their respective metal oxide nanoparticles on the surface of the carbon materials during carbonization at 800 °C. The gas sorption properties of the new MOFs and their corresponding carbon frameworks have been reported.     

多孔材料吸声性能分析与设计优化

多孔材料的吸声性能依赖于基体材料的性质、孔的形状与尺寸以及孔隙分布方式。利用多孔材料的高吸声性能和可设计性特点,研究和设计高吸声制材料与结构意义重大。采用表面阻抗法和传递矩阵法研究规则有序的圆柱形孔多孔金属材料与结构的声传播特性,建立声能吸收率与孔的尺寸和孔隙率之间的解析关系,并以圆柱形孔的尺寸沿材料厚度方向的变化规律为设计参数,建立以特定频率下层状多孔结构声能吸收率为目标的优化问题的提法和求解方法,得到一种具有较高声能吸收率的梯度多孔结构。     

Porous Organic Polymers for Post‐Combustion Carbon Capture

One of the most pressing environmental concerns of our age is the escalating level of atmospheric CO₂. Intensive efforts have been made to investigate advanced porous materials, especially porous organic polymers (POPs), as one type of the most promising candidates for carbon capture due to their extremely high porosity, structural diversity, and physicochemical stability. This review provides a critical and in‐depth analysis of recent POP research as it pertains to carbon capture. The definitions and terminologies commonly used to evaluate the performance of POPs for carbon capture, including CO₂ capacity, enthalpy, selectivity, and regeneration strategies, are summarized. A detailed correlation study between the structural and chemical features of POPs and their adsorption capacities is discussed, mainly focusing on the physical interactions and chemical reactions. Finally, a concise outlook for utilizing POPs for carbon capture is discussed, noting areas in which further work is needed to develop the next‐generation POPs for practical applications.     

Evaluating electrical resistivity for high porosity metals

Abstract

The resistivity behaviour of high porosity nickel foam as a function of porosity has been investigated experimentally. The results were compared with a number of empirical and theoretical models. It was found that a new model based on structural properties gave the closest fit to the experimental data. This provides a convenient means of controlling the resistivity of porous metals in production and thus enables manufacture of better porous electrodes.     

多孔氮化硅表面封孔增强涂层研究

以CaO-SiO2-B2O3体系作为α-Si3N4的结合剂和助烧剂,采用溶胶-凝胶法在多孔氮化硅表面制备了防潮增强涂层.采用X射线衍射(XRD)方法对涂层进行了相结构分析;用扫描电子显微镜(SEM)观察了涂层的微观形貌;用阿基米德法测量了封孔前后基体的密度、吸水率和显气孔率;分别在SANS电子式材料实验机和1MHz LCR测试仪上测量了封孔前后材料的抗弯强度、介电常数和介电损耗.结果表明:封孔防潮处理使基体吸水率下降了90.99%～96.97%,强度提高了9%～22%,而对多孔体的密度、介电常数和介电损耗影响很小.     

Preparation of zirconium pyrophosphate bonded silicon nitride porous ceramics

Abstract

A new method for preparing high bending strength porous silicon nitride ceramics with controlled porosity was developed using a pressureless sintering technique, using zirconium pyrophosphate as a binder. The fabrication process was described in detail and the sintering mechanism of porous ceramics was analysed by an X-ray diffraction method. The microstructure and mechanical properties of the porous Si₃N₄ ceramics were investigated, as a function of the content of ZrP₂O₇. The resultant porous silicon nitride ceramics sintered at low temperature (1000 and 1100°C) showed fine micropore structure and a high bending strength. Porous silicon nitride ceramics with porosity of 34–47%, a bending strength of 40–114 MPa and a Young's modulus of 20–50 GPa were obtained.     

A statistical approach to strength evaluation incorporating porosity effect for porous ceramics

ABSTRACT It has not been clear whether the conventional effective volume proposed for dense brittle materials can be applied satisfactorily to the strength evaluation of porous ceramics. In the present study, a modified effective volume was proposed by incorporating the porosity effect in the statistical evaluation of strength properties of porous ceramics. The modified effective volume was derived as the conventional effective volume multiplied by a function of porosity p. In this work, a power function of (1 + p)^a was adopted as the simplest porosity function. To clarify the applicability of the modified effective volume, bending tests were conducted using smooth and notched specimens of 3 wt% MgO partially stabilised zirconia with six different porosities. The porosity dependence appeared in the relation between the conventional effective volume and the mean strength of various zirconia ceramics with different porosities. The exponent a of the porosity function was determined from experimental data obtained by using identically shaped specimens with distinct porosities, and the modified effective volume was calculated for several types of specimens used in the experiments. It was revealed that the mean strength was almost uniquely correlated with the modified effective volume independent of porosity. The experimental correlation verified the applicability of the modified effective volume to strength evaluation of porous ceramics.     

A four-variable refined shear-deformation beam theory for thermo-mechanical vibration analysis of temperature-dependent FGM beams with porosities

This article proposes a four-variable shear deformation refined beam theory for thermo-mechanical vibration characteristics of porous, functionally graded (FG) beams exposed to various kinds of thermal loadings by using an analytical method. Thermo-mechanical properties of functionally graded material (FGM) beams are supposed to vary through the thickness direction, and are estimated through the modified power-law rule in which the porosities with even and uneven types are approximated. The material properties of FGM beams are supposed to be temperature dependent. Porosities possibly occur inside FGMs during fabrication because of technical problems that lead to the creation of microvoids in these materials. The variation of pores along the thickness direction influences the mechanical properties. Thus, it is incumbent to predict the effect of porosities on the thermo-mechanical vibration behavior of FG beam in the present study. Four types of thermal loading, namely, uniform, linear, nonlinear, and sinusoidal temperature rises through the z-axis direction are discussed. The governing differential equations and boundary conditions of FG porous beams subjected to thermal loadings are formulated through Hamilton's principle, based on a four-variable refined theory that considers a constant transverse displacement and higher order variation of axial displacement through the depth of the beam without the need of any shear correction factors. An analytical solution procedure is used to achieve the natural frequencies of porous FG beams subjected to various temperature fields. The impact of several specific parameters such as power-law exponent, porosity volume fraction, different porosity distribution, and thermal effect on the vibration of the porous FG beams is perused and discussed in detail. It is deduced that these parameters play a notable role on the thermo-dynamic behavior of porous FG beams. Presented numerical results can serve as benchmarks for the future analyses of FG beams with porosity phases.     

Determination of the elastic modulus of highly porous samples by nanoindentation: a case study on sea urchin spines

Nanoindenation studies were carried out on single crystal calcite and on sea urchin spines from Heterocentrotus mammillatus, Phyllacanthus imperialis, and Prinocidaris baculosa. Unlike dense calcite single crystals resin embedded porous sea urchin spine segments showed a strong dependence of the indentation modulus, but not the indentation hardness, on the local porosity. This implies that the sampled volume for the indentation modulus in nanoindentation with forces down to 15 mN is not nanoscopic but extends approximately 50 μm around the indentation spot. Only for indentation depths ≪100 nm more or less mount-unaffected values of the indentation modulus could be found. The Voigt model for composite materials (calcite/resin) was found to be applicable for the dependency of the indentation modulus on the porosity. This is attributed to the network type of porosity and opens strategies for the control of stiffness in porous networks.     

多孔金属流场双极板研究进展

多孔金属是一种兼具结构与功能的材料,得益于其低密度、高孔隙率、可控渗透性的优点,在许多领域都有广泛应用。本文综述了多孔金属在质子交换膜燃料电池(proton exchange membrane fuel cell,PEMFC)双极板流场中的研究进展,相较于传统流道流场,高开孔率(>70%)的多孔金属具有相互连通的三维立体结构,可以增加气体分布均匀性、并加强气体传质、增强电子和热的传导及水的排出,从而对电池性能有较大提升。同时探讨多孔金属参数、流场结构设计、服役参数目和多孔材料本身对多孔金属流场在PEMFC应用中的影响。目前阻碍多孔金属在PEMFC应用的最大问题是腐蚀,且多孔金属内部结构复杂对涂层制备工艺提出更大挑战,因此如何有效解决多孔金属在PEMFC两极环境中的腐蚀问题,对推进多孔金属在燃料电池领域中的应用意义重大。     

Automated tracking of liquid velocities in a refractive index matched porous medium

Abstract

Particle tracking velocimetry is applied to flow inside a porous column at Reynolds number Re = 28. The column is composed of refractive‐index‐matched solid and liquid materials, allowing seeding particles to be tracked in a laser‐illuminated axial slice. To complement earlier results acquired for 7 mm spheres, we conduct new experiments with larger 12 mm spheres. By improving the image acquisition and analysis, we are able to process the new experiments using fully automated algorithms instead of manual tracking. As a result, greater vector yields, more accurate velocity data, and a more complete spatial coverage are achieved.