Relationship between interfacial structure and property of steel-mushy Al-28Pb bonding-pate

1INTRODUCTION SteelAl28Pbbondingplateismadeupof steelplateandAl28Pballoylayer[13].Steelplate hasahigherstrength,andAl28Pballoylayerhasexcellentheatconductivityandperfectlubricating property.Thusthisbondingplateisanidealmate rialofneotypebearingwhichiswidelyneededinmachineryandautomobilefields[46].Forthis bondingplate,theinterfacialmechanicalproperty thatdeterminesthesafetyofproductisveryim portant.Thehighertheinterfacialmechanicalproperty,thesafertheproduct.Interfacialmechanicalpropert…     

Influence of aluminum solid fraction on property of steel-mushy aluminum bonding plate

The interfacial shear property of steel-mushy aluminum bonding plate was studied, and the relationship between aluminum solid fraction and the interfacial shear strength of bonding plate was determined. The results showed that when aluminum solid fraction is 34.3 %, the maximum interfacial shear strength of bonding plate is 71 .0 MPa.     

Influence of diffusion time on property of steel—aluminum solid to liquid bonding

The bonding of solid steel to liquid aluminum was conducted using rapid solidification.The influence of diffusion time on interfacial shear strength was studied.The results show that when the temperature of aluminum liquid is 700℃and the preheat temperature of steel plate is 250℃,the relationship between diffusion time(t) and interfacial shear strength(σ)is σ=15.1 8.14t-0.37t 0.005t^3,and the maximum interfacial shear strength is 71.1MPa.     

Effect of Interface on Mechanical Property of Steel-mushy Al-20Sn Bonding Plate

1 IntroductionSteel-Al-20Sn bonding plate is an ideal material ofneotype bearing[1-3].Almost one milliontons of this bond-ing plate are needed in machinery and automobile fieldannually[4-6].Forthis bonding plate ,theinterfacial struc-ture is very important .It determines the interfacial me-chanical property.Broadly,there are there kinds of inter-face for steel-Al-20Sn bonding plate .For solid steel plateto solid Al-20Sn bonding plate ,the interface is basicallymade upof Fe-Al solidsolution…     

Effect of Interface on Mechanical Property of Steel-mushy Ak-20Sn Bonding Plate

The ratio of Fe-Al compound at interace, which could determine the quarttity of Fe-Al compound at the interace of steel-mushy Al- 20 Sn bonding plate, was used to characterize the interfacial structure of steel-mushy Al-20 Sn bonding plate quantitatively. The effect of ratio of Fe-Al compound at interface on interacial shear strength was investigated perfectly. The results show that the relationship between ratio of Fe-Al compound at interace and interfacial shear strength is S = 3.3 ＋ 1.91 t - 0.0135t^2 （ where t is ratio of Fe-Al compound at in- terface and S is interfacial shear strength ）. When the ratio of Fe-Al compound at interface is 71%, the largest interfacial shear strength 70.9 MPa is got. This reasonable ratio of Fe-Al compound at interface is a quarttitative criterion of interfacial embrittlement. When the ratio of Fe-Al compound at interface is higher than 71% , interfacial embrittlement will occur.     

The Influence of Preheat Temperature of Steel Plate on Steel-mushy Cu-graphite Bonding

The pressing bonding of steel plate to QTi3.5-3.5 graphite slurry was conducted. Under the conditions of 530 ℃ for the preheat temperature of dies, 45% for the solid fraction of QTi3.5- 3.5 graphite slurry, 50 MPa for the pressure and 2 min for the pressing time, the relationship between the preheat temperature of steel plate and interfacial mechanical property of bonding plate was studied. The results show that when the preheat temperature of steel plate is lower titan 618 ℃ , the interfacial shear strength of bonding plate increases with the increasing of the preheat temperature of steel plate. When the preheat temperature of steel plate is higher than 618 ℃ , the interfacial shear strength decreases with the increasing of the preheat temperature of steel plate. When the preheat temperature of steel plate is 618 ℃ , the highest interfacial shear strength of bonding plate of 127.8 MPa can be got.     

Study on Bonding of Steel-mushy Al-7graphite

The bonding of steel-mushy Al-7graphite was studied. The relationship between interfacial shear strength of bonding plate and solid fraction of Al-7graphite mushy was obtained, and the interfacial structure of bonding plate was determined. The results showed that: under the condition of 500℃ for preheat temperature of steel plate and 10mm/s for rolling speed, the largest interfacial shear strength of bonding plate was 70.1 MPa when solid fraction of Al-7graphite mushy was 34.6%.     

用Ti箔连接Si3N4／Ni的界面结构与元素扩散

用Ｔｉ箔在１ ３２３ Ｋ 进行Ｓｉ３Ｎ４ 与Ｎｉ之间的连接,并对连接界面区的微观形貌、成分分布和界面反应产物进行了分析研究． 结果表明：通过Ｎｉ与Ｔｉ之间的相互扩散,在Ｓｉ３Ｎ４ 表面形成浸润良好的Ｔｉ－Ｎｉ液体合金,实测Ｔｉ－２８Ｎｉ共晶合金１ ３２３ Ｋ 时在Ｓｉ３Ｎ４ 表面的浸润角为９°． 基于ＥＤＸ,ＸＲＤ 测定结果和热力学分析,确定界面结构为：Ｓｉ３Ｎ４／ＴｉＮ（反应层Ⅰ）／Ｔｉ５Ｓｉ３＋ Ｔｉ５Ｓｉ４＋ Ｎｉ３Ｓｉ（反应层Ⅱ）／Ｎｉ－Ｔｉ化合物层／Ｎｉ固溶体／Ｎｉ． 反应层Ⅰ和反应层Ⅱ均随连接时间的增加而增厚,但反应层Ⅱ的成长速率和厚度明显高于反应层Ⅰ． 这种界面结构形式在０．９～７．２ ｋｓ 的连接时间范围内始终没有发生变化．     

单纤维复合材料断裂实验表征界面研究

对不同表面处理剂处理的4种单纤维增强环氧基复合材料进行了断裂实验，从临界纤维长度、界面剪切强度和单纤维断裂实验中纤维断点周围基体形貌三方面对纤维和基体之间的界面粘结性能进行了分析和评价。实验观察得到的结果是KH-550处理纤维与环氧的界面粘结最强，其次是KH-550和KH-570混合处理纤维与环氧的界面、KH-570处理纤维与环氧的界面，最弱的是水处理纤维与环氧的界面。     

准上贝氏体BF／AR界面错配位错的TEM观察

运用透射电镜研究了含Ｓｉ钢准上贝氏体中贝氏体铁素体（ＢＦ）／残余奥氏体（ＡＲ）的界面错配位错,发现是混合型位错,使得界面能沿其法线方向作滑移运动,表明贝氏体可以切变形成。     

复合材料层板层间剪切滑移模型

针对复合材料层板层间剪切滑移现象,提出了一种精确的分析模型。位移场采用传统形式,位移变量少,平衡方程简洁,但通过构造剪切变形函数,成功地满足了非滑移界面的连续条件和滑移界面的位错条件,使模型具有很高的精度,还首次导出了各类边界条件下滑移模型的解。     

Interfacial reaction between solid nickel and liquid zinc

Interfacial reactions between solid nickel and liquid zinc at 450-650 ℃ for 30-600 s were studied. The morphology and growth behavior of intermetallic compound layers at the interface between solid nickel and liquid zinc were observed and analyzed by SEM and EDS. The results show that γ and 8 phases are formed at 450 ℃ at the Ni/Zn interface, and at 550 ℃ and 650 ℃ only ）,phase is formed at the interthce and some δ phase particles will be participated during solidification on the surface of γphase layer. The β1 phase is absent under experimental conditions. Many cracks occur in the layers due to the difference in thermal expansion coefficients of these phases. It is found that the kinetics of the intermetallic compounds growth follows a parabolic law of time, as controlled by the diffusion mechanism. The apparent activation energies are 113.9 kJ/mol for the growth of γphase and 125.87 kJ/mol for γ1 phase, respectively.     

不锈钢复合板的界面组织结构与性能

采用光学显微镜、扫描电镜等手段,对0Cr18Ni9-08Al-0Cr18Ni9不锈钢复合板在不同状态下的界面组织结构及其性能进行了研究,以期为改进和选择合理的生产工艺提供可靠的理论和实验依据.     

全金属组元铁基块体非晶的制备与性能研究

3D打印成型碳纤维接枝碳纳米管增强热塑性复合材料的强度提高

王婼楠¹,吴海宏^1,2,郭子月³,刘春太²,申长雨²

（1. 河南工业大学 机电工程学院,郑州450001; 2.郑州大学 橡塑模具国家工程研究中心,郑州450002; 3.中山大学 数学学院（珠海）,珠海519082）

创新点说明：

1) 研究了碳纤维定量接枝碳纳米管对热塑性复合材料的界面性能及拉伸性能的影响。

2) 用3D打印模压成型的工艺方法制备了热塑性复合材料。

研究目的：

研究碳纤维表面接枝不同含量的碳纳米管对复合材料微观结构、界面性能和力学性能的影响。

研究方法：

1) 采用溶液法,通过控制碳纳米管接枝反应时间,制备不同含量碳纳米管接枝碳纤维,然后用硝酸刻蚀法,去除残留溶剂,验证了碳纳米管接枝的可靠性。用扫描电镜观察碳纤维的微观形貌,用FTIR测试碳纤维表面官能团并用XPS对碳纤维的表面官能团进行分析。

2) 用扫描电镜观察碳纤维与基体的结合情况并用接触角测量仪测试碳纤维与基体的接触角。

3) 通过 3D打印成型法成型了热塑性复合材料样条,并用扫描电镜观察碳纤维热塑性复合材料的界面微观形貌。

4) 采用万能试验机测试3D打印成型热塑性碳纤维复合材料的拉伸性能,并观察复合材料断口形貌。

结果：

1) 溶液法.扫描电镜观察发现碳纳米管在碳纤维表面均匀分布,表明碳纤维与碳纳米管之间存在较强的键合关系。但随着接枝时间的增加,碳纤维表面的碳纳米管含量逐渐增加,但达到0.4%时,出现分散不均匀现象。碳纤维表面含有上浆剂和去掉上浆剂的对比发现,无上浆剂的碳纤维表面沟壑明显,这些沟槽可以增加碳纤维的比表面积和表面能,增强了基体与碳纤维的机械相互作用。用FTIR测试碳纤维表面官能团并用XPS对碳纤维的表面官能团进行分析,结果表明,经偶联剂改性后,C=O键含量明显增加,碳纤维表面引入含氧官能团。C1,O1S峰增强,表明碳纳米管接枝到了碳纤维表面。

2) 扫描电镜结果表明,与表面未接枝碳纳米管的碳纤维相比,接枝碳纳米管的碳纤维与基体PA6具有更好的润湿性。接触角测试结果对比发现,接枝碳纳米管的碳纤维与基体的接触角,明显小于未接枝碳纳米管的。

3) 通过扫描电镜观察复合材料的界面微观形貌,结果表明：纤维与基体之间存在一定厚度的界面层,界面层的存在可以减轻纤维与基体之间的力学性能突变引起的应力集中,并防止界面缺陷的扩展。

4）界面结合强度测试结果表明,当碳纳米管的质量分数增加到0.25%时,复合材料的界面结合强度比未接枝碳纳米管的碳纤维增强的PA6复合材料提高了20%,比表面有环氧的碳纤维复合材料提高了41.8%。然而当碳纳米管含量大于0.4%时,界面结合强度不再继续增加。力学测试表明碳纳米管含量为0.25%的复合材料具有最高的平均模量、拉伸强度和界面剪切强度。接枝碳纳米管的碳纤维复合材料断口形貌可以观察到界面处基体中的韧窝。表明基体树脂在拔出纤维前经历了较大的塑性变形,表明纤维与基体有很好结合性。

结论：

实验结果表明,碳纳米管可以提高表面的润湿性和CF表面粗糙度。碳纳米管接枝碳纤维增强PA6与环氧上浆的碳纤维复合材料相比,当碳纳米管的质量分数达到0.25%时,复合材料的界面结合强度增加了41.8%,拉伸强度提高了130%,界面剪切强度提高了238%。然而,随着碳纳米管含量的继续增加到0.4%时,界面结合强度和力学性能就会下降。

关键词：热塑性复合材料,界面结合强度,界面剪切强度,3D打印成型

     

废弃陶瓷再生混凝土及界面研究

将废弃陶瓷破碎筛分制成再生骨料以不同比例(50%、80%、100%)代替相应天然骨料配制混凝土.在对废弃陶瓷再生骨料混凝土和天然骨料混凝土的力学性能进行对比研究的基础上,进一步对再生骨料与水泥石的粘结性能进行了对比研究.研究表明:混凝土中虽然随着再生骨料代替量的增加,力学性能有所下降但下降幅度大都没超过15%,且表现出较好的界面粘结性能,因此,废弃陶瓷再生骨料完全可以代替天然骨料用于混凝土的配制.     

聚合物—水泥界面粘结层的结构分析

本文采用解粘实验方法和高效液相色谱检测技术,对聚合物水泥基复合材料中几种聚合物与高铝水泥间的复合界面层进行了组成和结构分析;讨论了不同粘结力在界面层中的作用形式及其对材料设计和复合性能的影响。在此基础上,对聚合物水泥基复合材料界面粘结层的结构模型进行了描述。     

热轧复合板的界面结合强度的实验与理论研究

界面结合强度是影响层合板整体力学性能的主要因素,但是当层合板总厚度小,弹性模量较低,绝对刚度较小时采用常规测试方法难以获得其准确的界面结合强度.针对具有上述特点的薄层状复合材料提出了一种新的测试方法,即采用胶黏剂将测试试样固定于刚度远大于复合板以及胶黏剂的钢棒上形成对接接头,并对其进行单轴拉伸和四点弯曲测试.实验结果表明,对接接头中的胶黏剂固化时,在边缘环状区域内由于气泡的溢出而呈现理想结合状态,因此在该区域内可以承受更高的断裂应力.四点弯曲时高应力出现在该边缘区域内,因而可以测试界面结合强度高于胶黏剂平均拉伸强度的复合板的结合性能.同时由于弯曲时钢棒的弹性模量远高于胶黏剂,界面的应力分布规律和同一均匀材料的分布规律不同,常规的弯曲应力公式不再适用.依据新的变形方式和新的应力分布规律推导了新的弯曲应力公式.并针对两种具有不同界面微结构的Al/Mg/Al热轧复合板为例进行了界面结合强度的理论和实验研究及验证.