Exergoenvironmental analysis of a steam methane reforming process for hydrogen production

Steam methane reforming (SMR) is one of the most promising processes for hydrogen production. Several studies have demonstrated its advantages from the economic viewpoint. Nowadays process development is based on technical and economical aspects; however, in the near future, the environmental impact will play a significant role in the design of such processes. In this paper, an SMR process is studied from the viewpoint of overall environmental impact, using an exergoenvironmental analysis. This analysis presents the combination of exergy analysis and life cycle assessment. Components where chemical reactions occur are the most important plant components from the exergoenvironmental point of view, because, in general, there is a high environmental impact associated with these components. This is mainly caused by the exergy destruction within the components, and this in turn is mainly due to the chemical reactions. The obtained results show that the largest potential for reducing the overall environmental impact is associated with the combustion reactor, the steam reformer, the hydrogen separation unit and the major heat exchangers. The environmental impact in these components can mainly be reduced by improving their exergetic efficiency. A sensitivity analysis for some important exergoenvironmental variables is also presented in the paper.     

Life cycle assessment of hydrogen production from biomass gasification. Evaluation of different Spanish feedstocks

Gasification of biomass can be used for obtaining hydrogen reducing the total greenhouse gases emissions due the fixation of CO₂ during photosynthetic processes. The kind of raw materials is an important variable since has a great influence on the energy balance and environmental impacts. Wastes from forestry are considered as the most appropriate raw materials since they do not compete for land. The aim of this work is to determine the environmental feasibility of four Spanish lignocellulosic wastes (vine and almond pruning and forest waste coming from pine and eucalyptus plantation) for the production of hydrogen through gasification. LCA methodology was applied using global warming potential, acidification, eutrophication and the gross energy necessary for the production of 1 Nm³ of hydrogen as impact categories. As expected, the use of biomass instead of natural gas leads to the reduction of CO₂ emissions. Regarding to the different feedstocks, biomass coming from forestry is more environmental-friendly since does not need cropping procedures. Finally, the distribution of environmental charges between pruning wastes and fruits (grape and almond) and the use of obtained by-products have a great influence, reducing the environmental impacts.     

Catalytic steam reforming of tar for enhancing hydrogen production from biomass gasification: a review

Presently, the global search for alternative renewable energy sources is rising due to the depletion of fossil fuel and rising greenhouse gas (GHG) emissions. Among alternatives, hydrogen (H₂) produced from biomass gasification is considered a green energy sector, due to its environmentally friendly, sustainable, and renewable characteristics. However, tar formation along with syngas is a severe impediment to biomass conversion efficiency, which results in process-related problems. Typically, tar consists of various hydrocarbons (HCs), which are also sources for syngas. Hence, catalytic steam reforming is an effective technique to address tar formation and improve H₂ production from biomass gasification. Of the various classes in existence, supported metal catalysts are considered the most promising. This paper focuses on the current researching status, prospects, and challenges of steam reforming of gasified biomass tar. Besides, it includes recent developments in tar compositional analysis, supported metal catalysts, along with the reactions and process conditions for catalytic steam reforming. Moreover, it discusses alternatives such as dry and autothermal reforming of tar.     

Environmental impacts of a standalone solar water splitting system for sustainable hydrogen production: A life cycle assessment

Hydrogen is broadly utilized in various industries. It can also be considered as a future clean energy carrier. Currently, hydrogen is mainly produced from typical fuels such as coal; however, there exist some other clean alternatives which use water decomposition techniques. Water splitting via the copper-chlorine (Cu–Cl) thermochemical cycle is a superb option for producing clean carbon-free fuel. Here, the life cycle assessment (LCA) technique is used to investigate the environmental consequences of an integrated solar Cu–Cl fuel production facility for large-scale hydrogen production. The impact of varying important input parameters including irradiation level, plant lifetime, and solar-to-hydrogen efficiency on various environmental impacts are investigated next. For instance, an improve in the solar-to-hydrogen efficiency from 15% to 30%, results in a reduction in the GWP from 1.25 to 6.27E-01 kg CO₂ eq. An uncertainty analysis using Monte Carlo simulation is conducted to deal with the study uncertainties. The results of the LCA show that the potential of acidification and global warming potential (GWP) of the current system are 8.27E-03 kg SO₂ eq. and 0.91 kg CO₂ eq./kg H₂, respectively. According to the sensitivity analysis, the plant lifetime has the highest effect on the total GWP of the plant with a range of 0.63–1.88 kg of CO₂ eq./kg H₂. Results comparison with past thermochemical-based studies shows that the GWP of the current integrated system is 7% smaller than that of a solar sulfur-iodine thermochemical cycle.     

生物质水蒸气气化制氢模拟研究

利用ASPEN PLUS软件建立了生物质水蒸气气化制氢模型,对各种影响因素进行了深入分析。结果表明:随着碳转化率的增加,H2浓度略有降低,H2产量大幅增加,在碳转化率为1时达到最大值142.54 g/kg;随着水蒸气/生物质质量比的增加,H2浓度和产量大幅增加,而后趋于稳定,水蒸气/生物质质量比取2比较适宜。适当的升温和低压对制备H2有利,在加压条件下,H2浓度与产量达到最大值的温度升高。     

Life-cycle greenhouse gas emissions and energy balances of sugarcane ethanol production in Mexico

The purpose of this work was to estimate GHG emissions and energy balances for the future expansion of sugarcane ethanol fuel production in Mexico with one current and four possible future modalities. We used the life cycle methodology that is recommended by the European Renewable Energy Directive (RED), which distinguished the following five system phases: direct Land Use Change (LUC); crop production; biomass transport to industry; industrial processing; and ethanol transport to admixture plants. Key variables affecting total GHG emissions and fossil energy used in ethanol production were LUC emissions, crop fertilization rates, the proportion of sugarcane areas that are burned to facilitate harvest, fossil fuels used in the industrial phase, and the method for allocation of emissions to co-products. The lower emissions and higher energy ratios that were observed in the present Brazilian case were mainly due to the lesser amount of fertilizers applied, also were due to the shorter distance of sugarcane transport, and to the smaller proportion of sugarcane areas that were burned to facilitate manual harvest. The resulting modality with the lowest emissions of equivalent carbon dioxide (CO_2e) was ethanol produced from direct juice and generating surplus electricity with 36.8 kgCO_2e/GJ_ethanol. This was achieved using bagasse as the only fuel source to satisfy industrial phase needs for electricity and steam. Mexican emissions were higher than those calculated for Brazil (27.5 kgCO_2e/GJ_ethanol) among all modalities. The Mexican modality with the highest ratio of renewable/fossil energy was also ethanol from sugarcane juice generating surplus electricity with 4.8 GJ_ethanol/GJ_fossil.     

A well to pump life cycle environmental impact assessment of some hydrogen production routes

In the present study, a comparative well to pump life cycle assessment is conducted on the hydrogen production routes of water electrolysis, biomass gasification, coal gasification, steam methane reforming, hydrogen production from ethanol and methanol. The CML 2001 impact assessment methodology is employed for assessment and comparison. Comparatively higher life cycle Carbon dioxide and Sulphur oxide emissions of 27.3 kg/kg H₂ and 50.0 g/kg H₂ respectively are determined for the water electrolysis hydrogen production route via U.S. electricity mix. In addition, the life cycle global warming potential of this route (28.6 kg CO_2eq/kg H₂) is found to be comparatively higher than other routes followed by coal gasification (23.7 kg CO_2eq/kg H₂)_. However, the ethanol based hydrogen production route is estimated to have comparatively higher life cycle emissions of nitrogen dioxide (19.6 g/kg H₂) and volatile organic compounds (10.3 g/kg H₂). Moreover, this route is determined to have a comparatively higher photochemical ozone creation potential of 0.0045 kg-ethene_eq/kg H₂ as well as eutrophication potential of 0.0043 kg PO_4eq/kg H_2. The results of this study are comparatively discussed to signify the importance of life cycle assessment in comparing the environmental sustainability of hydrogen production routes.     

Life cycle assessment of nuclear-based hydrogen and ammonia production options: A comparative evaluation

In this study, nuclear energy based hydrogen and ammonia production options ranging from thermochemical cycles to high-temperature electrolysis are comparatively evaluated by means of the life cycle assessment (LCA) tool. Ammonia is produced by extracting nitrogen from air and hydrogen from water and reacting them through nuclear energy. Since production of ammonia contributes about 1% of global greenhouse gas (GHG) emissions, new methods with reduced environmental impacts are under close investigation. The selected ammonia production systems are (i) three step nuclear Cu–Cl thermochemical cycle, (ii) four step nuclear Cu–Cl thermochemical cycle, (iii) five step nuclear Cu–Cl thermochemical cycle, (iv) nuclear energy based electrolysis, and (v) nuclear high temperature electrolysis. The electrolysis units for hydrogen production and a Haber–Bosch process for ammonia synthesis are utilized for the electrolysis-based options while hydrogen is produced thermochemically by means of the process heat available from the nuclear power plants for thermochemical based hydrogen production systems. The LCA results for the selected ammonia production methods show that the nuclear electrolysis based ammonia production method yields lower global warming and climate change impacts while the thermochemical based options yield higher abiotic depletion and acidification values.     

Harmonised carbon and energy footprints of fossil hydrogen

Life cycle assessment (LCA) is a well-established methodology for the evaluation of the environmental performance of product systems. However, a large number of combinations of methodological choices is possible in LCA studies, threatening consistency when comparing different authors’ studies. Regarding hydrogen, a specific LCA harmonisation initiative has recently been undertaken. Within the framework of this initiative, harmonisation protocols and libraries of life-cycle indicators of hydrogen have been developed in order to improve the robustness of comparative LCAs. Nevertheless, these libraries are currently affected by the lack of fossil-based hydrogen options. Hence, this study fills this gap by calculating harmonised carbon and energy footprints of hydrogen for a set of 15 new case studies involving relevant production pathways: gasification, reforming and autocatalytic decomposition of fossil feedstock, and electrolysis powered by fossil and grid electricity. Overall, the resulting extended library of harmonised life-cycle indicators stresses the role of renewable hydrogen as a key requirement in the path towards an environmentally-sustainable hydrogen economy.     

Molecular simulation of methane steam reforming reaction for hydrogen production

By means of advanced techniques of molecular simulations, we have studied the chemical equilibrium of methane steam reforming reaction. We have computed the conversion of CH₄, yield and selectivity of H₂, etc. in the gas phase by reactive canonical Monte Carlo (RCMC) method and compared with those from Gibbs energy of formation method. The consistency of the two methods encourages us to use the RCMC method to optimize the operating conditions. We found that under low pressure 0.1 MPa, high temperature 1073 K and high water-gas ratio H₂O/CH₄ = 5, the CH₄ conversion, H₂ yield and selectivity were the highest, with the values of 99.93%, 3.51 mol/molCH₄ and 99.98%, respectively. In addition, the pore size of activated carbon significantly affects the chemical equilibrium composition in the pores. Since low pressure and high temperature are not conducive to the adsorption of reactive components by activated carbon, the chemical balance in the pores cannot be improved. At 773 K, 3.0 MPa and pore width is less than 2 nm, the pores are mainly occupied by CH₄ and H₂O reactant molecules. Further increasing the temperature can increase the H₂ content in the pores, but the adsorption capacity in the pores will decrease. We use activated carbon to adsorb and separate CO and H₂ (CO:H₂ = 1:3), the main components after the gas phase reaction reaches equilibrium. At 298 K, 7.5 MPa and the optimal pore width of 0.76 nm, the CO/H₂ selectivity is 28.3 and the CO adsorption capacity is 8.45 mmol/cm³.     

Role of hydrogen storage in renewable energy management for Ontario

Effective energy storage and management is needed to manage intermittent renewable energy systems. Several jurisdictions around the world are planning to reduce or close their coal power plants to allow for renewable energy expansion, such as Ontario, Canada. Hydrogen storage, which is a promising energy storage option, is capable of meeting energy requirements that will arise from the shutdown of coal plants. In this paper, both economic and environmental feasibility of a hydrogen system linked with wind and hydroelectric plants in Ontario will be investigated. The Princefarm wind power plant and Beck1 hydro plant with production capacities of 189 MW and 490 MW, respectively, are analyzed in a case study for comparison purposes. The environmental analysis demonstrates the advantageous role of hydrogen storage and energy conversion. The overall system life-cycle yields 31.02 g CO₂ eq per 1 kW h power output of the system when hydrogen energy storage is adopted. The payback periods of the systems linked with the Princefarm and Beck1 are also analyzed and found to be about 17 years.     

Life cycle assessment of nuclear hydrogen production processes based on high temperature gas-cooled reactor

Conventional hydrogen production technologies mostly fossil fuels as energy and material basis. The rapid development of nuclear energy in recent years offers a new opportunity. Clean electricity and process heat generated by nuclear reactors can provide energy for hydrogen production, effectively reducing the environmental burden. This study used life cycle assessment (LCA) method to sort out the inputs and outputs of the nuclear hydrogen production processes and analyze the environmental impacts based on local data in China. In this study, we constructed frameworks for two nuclear energy-based processes and created four different scenarios to compare the effect of energy efficiency. Six indicators were used to quantify the environmental impact. The results showed that: (1) electrolysis cell manufacturing and spent fuel disposal generate the largest emissions in hydrogen production. (2) S–I cycle is sensitive to heat transfer efficiency, while high-temperature electrolysis is more sensitive to power generation efficiency; (3) The environmental impact of high-temperature electrolysis (without carrier gas) is slightly lower than that of S–I cycle, but the advantage will disappear as energy efficiency increases. At present, high-temperature electrolysis offers a clean alternative to conventional technologies for hydrogen energy and hydrogen economy. The S–I cycle might have a better prospect in the future. Our study results will provide a scientific assessment of the possibilities of developing nuclear energy for hydrogen production in China and help to make some decisions and policies.     

High hydrogen content syngas for biofuels production from biomass air gasification: Experimental evaluation of a char-catalyzed steam reforming unit

This work investigates the performance of a reformer reactor for the upgrading of syngas and char derived from a pilot-scale air gasifier. The proposed setup represents a circular approach for the production of hydrogen-rich syngas from air gasification. Specifically, the reforming-unit was operated under a range of temperatures (from 700 °C to 850 °C) and steam flow rates and for each the improvement in producer gas composition and reducing species yield is evaluated. The results highlight that an increase in hydrogen concentration is obtained at higher temperature, moving from 16.2% to 21.3%, without using steam, and to 45.6%, with steam injection on the char-bed, while CO concentration did not follow a monotonic behavior. Moreover, the gas quality index, defined as a ratio between reducing species and inert species, delivered the highest values at the highest temperatures and steam flow rates. These results provide a guide for future gas quality optimization studies.     

A life cycle impact analysis of various hydrogen production methods for public transportation sector

Reducing greenhouse gas emissions is an important task to reduce the adverse effects of climate change. A large portion of greenhouse gas emissions apparently originates from the transportation sector. Therefore, adopting cleaner technologies with lower emission footprints has become vital. For this reason, in this study, a life cycle impact analysis of hydrogen production technologies as an alternative to fossil fuels and the utilization of hydrogen in fuel cell electric buses is carried out. According to the results of this study, the operational contributions of internal combustion engines have a significant impact on life cycle impact analysis indicators. The global warming potentials of clean hydrogen production technologies result in much lower results compared to conventional hydrogen production technologies. Also, almost all indicators for biohydrogen production technologiess yield lower results because of the wastewater removal. The global warming potential results of hydrogen production methods are found to be 6.8, 1.9, 2.1, 0.5, 0.2, and 7.9 kg CO₂ eq./kg H₂ for PV electrolysis, wind electrolysis, high temperature electrolysis, dark fermentation, photo fermentation and conventional hydrogen production, respectively. However, the chemicals used in PV and wind turbine production increased the ecotoxicological indicators. On the other hand, hydrogen utilization in buses is a better option environmentally. The global warming potentials for PV electrolysis, wind electrolysis, high temperature electrolysis, dark fermentation, photo fermentation, conventional hydrogen, compressed natural gas bus, and diesel bus are found to be 0.060, 0.016, 0.018, 0.007, 0.006, 0.053, 0.082, and 0.125 kg CO₂ eq./p.km, respectively. The results are especially important in terms of reducing the effects at the source and optimizing the systems.     

Life cycle sustainability assessment of hydrogen from biomass gasification: A comparison with conventional hydrogen

Hydrogen is a key product for a cleaner energy sector. However, the suitability of the different hydrogen production options should be checked from a life-cycle perspective. The Life Cycle Sustainability Assessment (LCSA) methodology is helpful for this purpose, allowing a thorough interpretation of a product system's performance by integrating economic, environmental and social indicators. This work presents an LCSA of renewable hydrogen from biomass gasification, and its sustainability benchmarking against conventional hydrogen from steam methane reforming. Environmental (global warming and acidification), economic (levelised cost) and social (child labour, gender wage gap, and health expenditure) life-cycle indicators are characterised and jointly interpreted. The results show that hydrogen from biomass gasification cannot yet be thoroughly considered a sustainable alternative to conventional hydrogen mainly due to economic and social concerns. However, improvement actions leading to an increase in process efficiency would significantly enhance the system's performance in each of the three sustainability dimensions.     

An investigation into steam gasification of biomass for hydrogen enriched gas production in presence of CaO

Biomass steam gasification could be an attractive option for sustainable hydrogen production. Biomass, regarded as carbon neutral emitter, could be claimed as carbon negative emitter if carbon dioxide produced is captured and not allowed to emit to the environment during the process. Thus here an experimental study is carried out to find out the potential of hydrogen production from steam gasification of biomass in presence of sorbent CaO and effect of different operating parameters (steam to biomass ratio, temperature, and CaO/biomass ratio). Product gas with hydrogen concentration up to 54.43% is obtained at steam/biomass = 0.83, CaO/biomass = 2 and T = 670 °C. A drop of 93.33% in carbon dioxide concentration was found at CaO/biomass = 2 as compared to the gasification without CaO. Mathematical model based on Gibbs free energy minimization has been developed and is compared with the experimental results.     

Life cycle assessment of hydrogen production by methane decomposition using carbonaceous catalysts

Methane decomposition to yield hydrogen and carbon (CH₄ ? 2H₂ + C) is one of the cleanest alternatives, free of CO₂ emissions, for producing hydrogen from fossil fuels. This reaction can be catalyzed by metals, although they suffer a fast deactivation process, or by carbonaceous materials, which present the advantage of producing the catalyst from the carbon obtained in the reaction. In this work, the environmental performance of methane decomposition catalyzed by carbonaceous catalysts has been evaluated through Life Cycle Assessment tools, comparing it to other decomposition processes and steam methane reforming coupled to carbon capture systems. The results obtained showed that the decomposition using the autogenerated carbonaceous as catalyst is the best option when reaction conversions higher than 65% are attained. These were confirmed by 2015 and 2030 forecastings. Moreover, its environmental performance is highly increased when the produced carbon is used in other commercial applications. Thus, for a methane conversion of 70%, the application of 50% of the produced carbon would lead to a virtually zero-emissions process.     

Environmental life cycle feasibility assessment of hydrogen as an automotive fuel in Western Australia

A life cycle assessment has been undertaken in order to determine the environmental feasibility of hydrogen as an automotive fuel in Western Australia. The criterion for environmental feasibility has been defined as having life cycle impacts equal to or lower than those of petrol. Two hydrogen production methods have been analysed. The first is steam methane reforming (SMR), which uses natural gas (methane) as a feedstock. The second method analysed is alkaline electrolysis (AE), a mature technology that uses water as a feedstock. The life cycle emissions and impacts were assessed per kilometre of vehicle travel.     

Life cycle evaluation of hydrogen and other potential fuels for aircrafts

In the present study, hydrogen and some other alternative fuels (such as ammonia, methanol, ethanol, liquefied natural gas) are considered for aviation applications under a comprehensive life cycle assessment study and are evaluated comparatively with the conventional kerosene based jet fuel for various impact categories. Therefore, this study is performed with a well-to-wake approach to evaluate the overall life cycle of an aircraft running on these conventional and alternative fuels. Both conventional and renewable fuel routes are considered for the production of ammonia and hydrogen fuels. Although there are modifications required to fulfill the aviation fuel specifications for such alternative fuels, the long term viability and environmental sustainability make them attractive solutions for the future of aviation industry. This study uses a life cycle assessment of an average aircraft utilizing various alternative aviation fuels to determine the relative environmental impact of each life cycle phase. The life cycle phases included in the analyses are as follows: (i) production, operation and maintenance of the aircraft, (ii) construction, maintenance and disposal of the airport, (iii) production, transportation and utilization of the aviation fuel in the aircraft. The results show that hydrogen and liquefied natural gas represent more environmentally benign alternatives although fuel costs are higher compared to ammonia, jet fuel and methanol. The total GHG emissions from hydropower based ammonia and hydrogen are calculated to be about 0.24 kg CO₂ eq. per traveled tonne-km and 0.03 kg CO₂ eq. per traveled tonne-km, respectively. Renewable based ammonia and hydrogen fueled aircrafts can further decrease the overall environmental impact in many categories allowing a brighter future for aviation industry.     

Optimal design of a sleeve-type steam methane reforming reactor for hydrogen production from natural gas

The three-dimensional computational fluid dynamics (CFD) model was used in a sleeve-type steam methane reforming (SMR) reactor for H₂ production of 2.5 Nm³/h from natural gas. The feed and combustion gases acted as a counter-current heat exchange owing to a narrow sleeve equipped between the combustor and catalyst-bed. The CFD results were validated against the experimental data of the SMR reactor with a sleeve gap size of 3 mm. The effect of the sleeve gap size and the flame shape on process performances such as H₂ production rate, thermal efficiency, and uniformity of catalyst-bed temperature was investigated using the CFD model. The sleeve gap size influenced the gas velocity inside the sleeve gap and the convective heat transfer. The SMR reactor with a sleeve gap size of 7 mm showed the highest H₂ production rate and thermal efficiency when comparing six sleeve gap sizes ranging from 2 to 10 mm. A new flame shape for the SMR reactor with the sleeve gap size of 7 mm was proposed to improve the process performances.