共查询到16条相似文献,搜索用时 140 毫秒
1.
改性白炭黑对天然橡胶和环氧化天然橡胶共混物力学性能的影响 总被引:1,自引:0,他引:1
研究了白炭黑对天然橡胶和环氧化天然橡胶(NR/ENR)共混物的补强性能以及改性剂的品种和用量对白炭黑分散效果的影响。结果表明,间苯二酚六次甲基四胺(PY)、硅烷偶联剂KH-550、Si-69这3种改性剂对白炭黑都起到了很好的改性作用。PY以40/60的质量比把间苯二酚和六次甲基四胺溶解、混合所得的络合物的改性效果最好,其中硅烷偶联剂Si-69和KH-550的最佳用量以白炭黑质量用量的9%为宜。 相似文献
2.
3.
4.
5.
6.
用改性淀粉替代部分炭黑填充丁苯橡胶(SBR)/顺丁橡胶(BR)并用胶,考察了改性淀粉用量及偶联剂种类对混炼胶硫化特性及硫化胶物理机械性能和动态力学性能的影响.结果表明,用改性淀粉替代部分炭黑可对SBR/BR混炼胶的硫化产生明显的延迟作用,但改性淀粉用量的变化对焦烧时间与正硫化时间影响不大;添加偶联剂KH-570或NDZ-201延迟了混炼胶的硫化过程,KH-550能大幅度地促进硫化作用,Si-69对于体系的硫化性能略有影响;随着改性淀粉用量的增加,SBR/BR硫化胶的拉伸性能、耐磨耗性均有所降低,但弹性、动态生热和滞后性能得到了明显改善,改性淀粉最佳用量为5~8份;各种偶联剂均可提高SBR/BR硫化胶的拉伸性能,硅烷偶联剂Si-69和KH-570对弹性和动态生热也略有改善,添加偶联剂KH-550改善了SBR/BR硫化胶的抗湿滑性能,但滞后性能变差,添加偶联剂KH-570或Si-69对SBR/BR硫化胶动态力学性能的影响较小,综合考虑,以添加偶联剂KH-570较好. 相似文献
7.
8.
硅烷偶联剂KH-550和Si-69增容粉煤灰/废胶粉复合材料 总被引:1,自引:0,他引:1
采用硅烷偶联剂γ-氨丙基三乙氧基硅烷(KH-550)和双-[γ-(三乙氧基硅)丙基]四硫化物(Si-69)对粉煤灰(FA)/废胶粉(URP)复合材料进行增容,考察了偶联剂用量和加入方式对复合材料性能的影响,并对复合材料的结构和微观形貌进行了表征。结果表明,KH-550和Si-69均可以改善FA与URP的相容性,提高复合材料的力学性能;Si-69的增容效果好于KH-550,最佳的Si-69/FA/URP(质量比)为1.0/40/100。采用硅烷偶联剂与FA混合、再与URP混合的分步加入方式,与同步加入方式相比,制备的复合材料更易成型,且复合材料的力学性能、耐磨性能和耐热老化性能更好。与KH-550相比,用Si-69改性的FA/URP复合材料,其相界面更为模糊,无孔洞。硅烷偶联剂改性的FA/URP复合材料中有Si—O生成。 相似文献
9.
10.
11.
12.
Yong Yue Luo Yue Qiong Wang Jie Ping Zhong Can Zhong He Yong Zhen Li Zheng Peng 《Journal of Inorganic and Organometallic Polymers and Materials》2011,21(4):777-783
Epoxidized natural rubber (ENR)/fumed silica vulcanizates were prepared by mechanical mixing method. Fumed silica content
can affect mechanical properties of the composites, and ten parts per hundreds of rubber (phr) fumed silica lead to the best
tensile strength. The interaction between ENR and fumed silica was characterized by Kraus equation, crosslink density (tested
by NMR), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA)
and scanning electron microscope (SEM). The results showed that the dispersion of silica in ENR was better than in natural
rubber (NR), hydrogen bond was produced between ENR and fumed-silica in ENR/silica blends, and glass transition temperature
of ENR/silica vulcanizate was higher than pure ENR vulcanizate. TGA and DMA confirmed that there was intense interaction between
ENR and silica. 相似文献
13.
14.
15.
16.
This research studied the composition and behavior of natural rubber (NR) and ethylene propylene diene monomer (EPDM) blends at various carbon black concentrations (0–30 phr) in terms of electrical resistivity, dielectric breakdown voltage testing, and physical properties. The blends having electrical properties suitable for application in high‐insulation iron crossarms were selected for investigation of compatibility and increased physical properties. The effect of the homogenizing agent concentration on improvement of compatibility of blends was studied by scanning electron microscopy, pulsed nuclear magnetic resonance spectroscopy, and rheology techniques. We also examined mechanical properties such as tensile strength, tear strength, elongation at break, and hardness. The NR/EPDM blends filled with a fixed concentration of silica were investigated for ozone resistance. A carbon black content as high as 10 phr is still suitable for the insulation coating material, which can withstand electrical voltage at 10 kVac. Addition of the homogenizing agent at 5 phr can improve the mechanical compatibility of blends, as evidenced by the positive deviation of shear viscosity of the rubber blend, that is, the calculated shear viscosity being higher than that of experimental data. Moreover, the pulsed NMR results indicated that the spin‐spin relaxation (T2) of all three components of the rubber blend was compressed upon the addition of the homogenizing agent. The ratio of NR/EPDM in the blend to best resist the ozone gas is 80/20 with the addition of silica of 30 phr into the blend. Also, the NR/EPDM filled with silica had a decreased change in thermal and mechanical properties of blends after thermal aging. The synergistic effect of silica content and high NR content (80) in 20 phr EPDM could improve antioxidation by ozone in the absence of a normal antioxidant for natural rubber. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 3401–3416, 2004 相似文献