槽式聚光集热系统加热真空管的特性及应用研究

建立了槽式聚光集热真空管装置的数学模型,并与实验结果进行了对比。理论计算结果与实验结果吻合较好,误差在5.2％以内,表明可用所建立的模型对聚光式真空管加热流体的性能进行分析。在太阳辐射强度及聚光面积变化的情况下,分析了通过聚光真空管内流体的性能特性。还给出了利用槽式聚光装置驱动太阳能吸附制冷的应用实例。     

Experimental performance analysis and optimisation of medium temperature solar thermal collectors with silicon oil as a heat transfer fluid

Heat transfer fluids (HTFs) play an essential role in solar water heating systems by transferring collected energy from the collector, perhaps via a heat exchanger to the store. If the store is at a much higher temperature than the fluid, the store acts as a heat source, whereas the fluid acts as a coolant, thus reversing the collection process. This action must be avoided through good controls. Experimental performance analysis and comparison of three different types of solar collectors; a non‐concentrating evacuated tube heat pipe and two concentrating single‐sided and double‐sided coated evacuated tube heat pipes collectors are installed and tested using Dow‐corning 550® silicon oil as an HTF under the same operating in‐door control conditions, and results are presented in this paper. The performance of these solar collectors was determined from the overall increase in inlet and outlet fluid temperatures, overall fluid temperature differential, energy collection rate, optical efficiencies, and thermal performances. Temperature differential, energy, and collection efficiency diagrams plotted against time were used to represent and compare the solar collectors. Finally, a comparative analysis of these solar collectors using either pressurised water or Dow‐corning 550 silicon oil as HTF is presented. Copyright © 2011 John Wiley & Sons, Ltd.     

A proposed modified efficiency for thermosyphon solar heating systems

Conventionally, the overall performance rating of a thermosyphon solar water heater considers the thermal performance of the system during the energy-collecting phase and the system cooling loss during the cooling phase. However, this study suggests that the performance rating should also take the heat removal efficiency of the system during the system application phase into consideration. This study modifies the CNS 12557 B7276 test standard and employs a precise, on-line operation to derive the heat removal efficiency of a system. The thermal performance and heat removal efficiency of 12 systems with capacities in the range of 102–446 L are evaluated. An efficiency coefficient, η₀, is defined, which represents the synthesis of the characteristic thermal performance, η_s^*, and the characteristic heat removal efficiency, η_R^*. The proposed modified efficiency coefficient is given by η₀=η_s^*×η_R^*, and represents the quasi-overall performance of a solar heating system. The coefficient provides an effective measure of the amount of energy provided to the user from a system which collects and stores heat from solar radiation. According to prevailing regulations in Taiwan, commercial solar heating products should have a value of η_s^* in excess of 0.5 in order to attract a government subsidy. The proposed modified efficiency, η₀, is a more practical and representative indication of the actual thermal performance of a system, and accordingly, the present study suggests that the regulations should adopt a value of η₀0.41 as the standard for qualification rather than the current criterion of η_s^*0.5.     

太阳能制冷与供暖系统的设计与比较

根据上海的气候条件，以上海地区某写字楼为对象，提出4种太阳能驱动的溴化锂吸收式与电动蒸汽压缩式热泵联合制冷与供暖系统。这4种系统分别由热管式真空管集热器或抛物面槽形聚光集热器，单效或双效溴化锂吸收式制冷机，以及风冷热泵或水源热泵构成。分析比较这4种系统的节能型和经济性的结果表明，采用抛物面槽形聚光集热器＋双效溴化锂吸收式制冷机＋风冷热泵组成的系统，同时具备较好的节能性与经济性，一次能源利用率可降低约50％。     

Heat loss factor of evacuated tubular receivers

Tubular receivers with an evacuated space between the absorber and concentric glass cover to suppress convection heat loss are employed as absorbers of linear concentrators in the intermediate temperature range. A knowledge of their heat loss factor is important for a study of the thermal performance of such solar concentrating systems. The heat loss factor of a collector can be calculated by solving the governing heat transfer equations or estimated from an empirical equation, if available. The governing equations must be solved simultaneously by iterations, but this is tedious and cumbersome. Although several correlations exist for determining the heat loss factor for flat-plate collectors and non-evacuated tubular absorbers of linear solar collectors, there is no available correlation for predicting the heat loss factor of evacuated receivers.

A correlation to calculate the heat loss factor (U_L) of evacuated tubular receivers as a function of variables involved (absorber temperature, emittance, diameter and wind loss coefficient) has been obtained. The correlation developed by a least square regression analysis predicts the heat loss factor to within ±1.5% of the value obtained by exact solution of the simultaneous equations in the following range of variables: wind loss coefficient, 10–60 W/m²°C; emittance, 0.1–0.95; and absorber temperature, 50–200°C.     

Comparison of the optics of non-tracking and novel types of tracking solar thermal collectors for process heat applications up to 300 °C

Evacuated CPC (compound parabolic concentrator) collectors with non-tracking reflectors are compared with two novel tracking collectors: a parabolic trough and an evacuated tube collector with integrated tracking reflector. Non-tracking low concentrating CPC collectors are mostly mounted in east–west direction with a latitude dependent slope angle. They are suitable at most for working temperatures up to 200–250 °C. We present a tracking evacuated tube-collector with a trough-like concentrating mirror. Single-axis tracking of the mirror is realized with a magnetic mechanism. The mirror is mounted inside the evacuated tube and hence protected from environmental influences. One axis tracking in combination with a small acceptance angle allows for higher concentration as compared to non-tracking concentrating collectors. Ray-tracing analysis shows a half acceptance angle of about 5.7° at geometrical concentration ratio of 3.2. Losses of well constructed evacuated tube collectors (heat conductivity through the manifolds inside the thermally insulated terminating housing are low) are dominated by radiation losses of the absorber. Hence, reducing the absorber size can lead to higher efficiencies at high operating temperature levels. With the presented collector we aim for operating temperatures up to 350 °C. At temperatures of 300 °C we expect with anti-reflective coating of the glass tube and a selective absorber coating efficiencies of 0.65. This allows for application in industrial process heat generation, high efficient solar cooling and power generation. A first prototype, equipped with a standard glass tube and a black paint absorber coating, was tested at ZAE Bayern. The optical efficiency was measured to be 0.71. This tube-collector is compared by ray-tracing with non-tracking market available tube-collectors with geometrical concentration ratios up to 1.1 and with a low cost parabolic trough collector of Industrial Solar Technology (IST) with an acceptance half angle about 1.5°, a geometrical concentration ratio of 14.4 and a measured optical efficiency of 0.69.     

Modeling and simulations of a micro solar power system

In this paper, the mathematical modeling and simulations of a concentrating solar power system located at the Middle East Technical University Northern Cyprus Campus are presented. The system consists of parabolic trough collectors (PTCs), a propane boiler, an organic Rankine cycle (ORC), and a wet cooling tower. Presently, the PTC field is severely undersized with respect to the ORC making the system impossible to operate without burning significant propane. Expanding the solar field could result in better system performance. Hourly, daily and seasonal variations in the performance of this system are simulated using hourly meteorological data for Larnaca, Cyprus, over an entire year. Because the ORC is driven using a relatively low‐temperature heat source rather than PTCs, the usage of nonconcentrating evacuated tube collectors that collect both beam and diffuse radiation is explored. The performance of east–west and north–south–tracking axis PTCs and the entire inventory of nonconcentrating evacuated tube collectors that were rated by the Solar Rating and Certification Corporation are compared in terms of annual performance metrics. Based on the simulations, several nonconcentrating evacuated tube collectors are identified with better thermal performance than PTCs, and the feasibility of using these collectors should be explored further. Copyright © 2013 John Wiley & Sons, Ltd.     

Study of a solar water heater using stationary V-trough collector

There are various types of solar water heater system available in the commercial market to fulfill different customers’ demand, such as flat plate collector, concentrating collector, evacuated tube collector and integrated collector storage. A cost effective cum easy fabricated V-trough solar water heater system using forced circulation system is proposed. Integrating the solar absorber with the easily fabricated V-trough reflector can improve the performance of solar water heater system. In this paper, optical analysis, experimental study and cost analysis of the stationary V-trough solar water heater system are presented in details. The experimental result has shown very promising results in both optical efficiency of V-trough reflector and the overall thermal performance of the solar water heater.     

Potential GHG mitigation options for agriculture in China

China's agriculture accounts for about 5–15% of total national emissions of carbon dioxide (CO₂), methane (CH₄), and nitrous oxide (N₂O). Land-use changes related to agriculture are not major contributors of greenhouse gas emissions in China.

Mitigation options are available that could result in significant decrease in CH₄ and N₂O emissions from agricultural systems, and are likely to increase crop and animal productivity. Implementation has the potential to decrease CH₄ emissions from rice paddies, ruminants, and animal waste by 4–40%. Improving the efficiency of plant utilization of fertilizer N could decrease N₂O emissions from agriculture by almost 20%. Analyses of several of the proposed options show positive economic as well as environmental benefits.     

Decomposition of nitrous oxide at medium temperatures

Flow reactor experiments were done to study the decomposition of N₂O at atmospheric pressure and in a temperature range of 600–1000°C. Dilute mixtures of N₂O with H₂, CH₄, CO with and without oxygen with N₂ as carrier gas were studied. To see directly the relative importance of the thermal decomposition versus the destruction by free radicals (i.e.: H, O, OH) iodine was added to the reactant mixture suppressing the radicals’ concentrations towards their equilibrium concentrations. The experimental results were discussed using a detailed chemistry model. This work shows that there are still some uncertainties regarding the kinetics of the thermal decomposition and the reaction between N₂O and the O radical. Using the recommendations applied in this work for the reaction N₂O + M ↔ N₂ + O + M and for N₂O + O ↔ products, a good agreement with the experimental data can be obtained over a wide range of experimental conditions. The reaction between N₂O and OH is of minor importance under present conditions as stated in latest literature. The results show that N₂O + H ↔ N₂ + OH is the most important reaction in the destruction of N₂O. In the presence of oxygen it competes with H + O₂ + M ↔ HO₂ + M and H + O₂ ↔ O + OH, respectively. The importance of the thermal decomposition (N₂O + M ↔ N₂ + O + M) increases with residence time. Reducing conditions and a long residence time lead to a high potential in N₂O reduction. Especially mixtures of H₂/N₂O and CO/H₂O/N₂O in nitrogen lead to a chain reaction mechanism causing a strong N₂O reduction.     

简化CPC式全真空玻璃集热管太阳能高温空气集热器的传热模型研究

对一种新型简化CPC(非追踪式复合抛物线聚光板)式全真空玻璃集热管太阳能高温空气集热系统的传热过程进行了理论分析和数值模拟计算,通过实验数据对该传热模型进行了验证分析。该系统由多个集热单元组成,每个集热单元包括一个简化CPC集热板,一根全真空玻璃集热管,在玻璃集热管内安装一个U形铜管。流动空气在各级U形铜管内被逐级加热。计算研究表明:系统空气最大出口温度可达到200℃,系统平均集热效率达到0.3以上,整个系统表现了良好的高温集热特性。同时,计算也表明当系统工质流量增加时,只要系统增加更多的集热管以增加系统总功率即可满足工质温度达到200℃的设计要求。研究提出的新型简化CPC式全真空玻璃集热管太阳能高温空气集热系统是一种有工业实用前途的太阳能集热器;研究提出的传热模型模拟效果也可以满足一般性工程计算需求。     

Thermochemical hydrogen production from a two-step solar-driven water-splitting cycle based on cerium oxides

A new thermochemical cycle for H₂ production based on CeO₂/Ce₂O₃ oxides has been successfully demonstrated. It consists of two chemical steps: (1) reduction, 2CeO₂ → Ce₂O₃ + 0.5O₂; (2) hydrolysis, Ce₂O₃ + H₂O → 2CeO₂ + H₂. The thermal reduction of Ce(IV) to Ce(III) (endothermic step) is performed in a solar reactor featuring a controlled inert atmosphere. The feasibility of this first step has been demonstrated and the operating conditions have been defined (T = 2000 °C, P = 100–200 mbar). The hydrogen generation step (water-splitting with Ce(III) oxide) is studied in a fixed bed reactor and the reaction is complete with a fast kinetic in the studied temperature range 400–600 °C. The recovered Ce(IV) oxide is then recycled in first step. In this process, water is the only material input and heat is the only energy input. The only outputs are hydrogen and oxygen, and these two gases are obtained in different steps avoiding a high temperature energy consuming gas-phase separation. Furthermore, pure hydrogen is produced (it is not contaminated by carbon products like CO, CO₂), thus it can be used directly in fuel cells. The results have shown that the cerium oxide two-step thermochemical cycle is a promising process for hydrogen production.     

Solar preparation of SiOx (x ≈ 1) nanopowders from silicon vaporisation on a ZrO2 pellet. XPS and photoluminescence characterisation

SiO_x nanoparticles were prepared by vaporisation and condensation of melted silicon droplets put on zirconia pellets in a solar reactor at the focus of a 2 kW solar furnace. The size of the grains were nanometric, generally included in the range 20–40 nm, and the O/Si atomic ratio values were close to stoichiometry (O/Si ≈ 1 ± 0.2). XPS, DRX and TEM analyses show that these nanoparticles are amorphous with various silicon chemical environments which can be described as constituted with polysubstituted Si-(O_4−nSi_n) tetrahedral configurations. The estimated oxygen atomic concentrations for these nanoparticles was in good agreement with thermodynamic equilibrium calculations for the system ZrO₂–Si at high temperature. The predominant gaseous species is the SiO molecule. The SiO_x nanoparticles present photoluminescence property similar to those currently reported for electrolytic porous silicon.     

Water-in-glass manifolds for heat extraction from evacuated solar collector tubes

Measurements are reported on three novel manifolds of the water-in-glass type for evacuated all-glasssingle-ended tubular collectors. The manifolds provide for series connection of tubes, but because there is virtually no partitioning of the inner volume of the collector tubes, the manifolds are extremely simple and exhibit low impedance to fluid flow. The efficiency of heat extraction from the tubes has been determined by measuring temperatures at various points on the surface of glass tubes in a panel of area 1.2 m² while heating the tubes electrically to simulate solar energy input. Measurements have been made for a range of tube inclinations (0–80°), water flow rates (0.5–5 lmin⁻¹, water inlet temperatures (13–70°C), and effective solar fluxes (100–1000 W/m²) for two absorber tube diameters. The results show that for a wide range of operating conditions buoyancy effects alone result in efficient heat transfer to the tops of the tubes. The manifold designs described offer a possible low cost solution to the problem of manifolding evacuated collectors for sub-100°C heat extraction for domestic and industrial applications.     

CPC内聚光式热管集热管温度特性研究

为提高太阳能热水系统的输出温度,将CPC聚光技术应用于热管式真空集热管中,开发了一种新型的CPC内聚光式热管集热管。对该集热管建立数学模型,模拟计算其传热过程,获得了导热肋片温度、热管冷凝段温度等参数随太阳辐射强度的变化规律,并通过试验验证了数学模型的可靠性;与常规热管式真空管集热管传热特性相对比,证实了该集热管可大幅提高太阳能热水器输出温度。     

Entropy generation due to conjugate natural convection in enclosures bounded by vertical solid walls with different thicknesses

Entropy generation due to conjugate natural convection heat transfer and fluid flow has been studied inside an enclosure with bounded by two solid massive walls from vertical sides at different thicknesses. Enclosure is differentially heated from vertical walls and horizontal walls are adiabatic. Governing equations which are written in streamfunction-vorticity form solved by finite difference technique for the governing parameters as Rayleigh number, 10³ ≤ Ra ≤ 10⁶, length ratio of solid walls as ₁ (for left vertical wall) and ₂ (for right vertical wall) and thermal conductivity ratio of solid to fluid (k), 1 ≤ k ≤ 10. Entropy generation contours due to fluid friction and heat transfer irreversibility, isotherms, streamlines, Nusselt numbers and velocity profiles were obtained. It is found that entropy generation increases with increasing of thermal conductivity ratio and thicknesses of the walls. Entropy generation due to heat transfer is more significant than that of fluid flow irreversibility for all values of thickness of the solid vertical walls.     

真空集热型太阳能固体吸附式制冷的理论研究

为提高太阳能吸附制冷系统的集热性能。提出了采用真空集热管式吸附床的太阳能固体吸附制冷系统,并对选择吸收式和直接吸热式的真空集热制冷系统分别进行了理论分析与计算模拟。这两种系统均具有较高的制冷性能,前者宜以沸石-水为制冷工质对,而后者则宜采用活性碳-甲醇工质对。分析了工作参数对这两种真空集热型制冷系统的影响,并对系统结构进行了优化研究。     

太阳能热水器传热传质和强化传热研究

在低温太阳能光热光伏联合应用试验台的基础上,结合GB/T 17049—2005,利用Gambit、Ansys Fluent和Tecplot软件,对全玻璃真空管太阳能热水器进行传热传质和强化传热分析。结果表明:所建立的二维数值计算模型,能准确反映同一条件下,全玻璃真空管太阳能热水器的变化趋势;在数值模拟基础上,确定了单面受热时的最佳安装角度为51°,加装反光板类似双面受热的最佳安装角度为38°;在粗略估算和细化分析的基础上,确定了不同真空管结构的最佳导流板长度及安装位置;通过实验和数值模拟,确定了58mm×1 800mm为优化的全玻璃真空管结构。     

Experimental Study on Performance Enhancement of Evacuated Tube by Constant Heat Flux Mode

The evacuated tube collector with U shape copper absorber tube is considered for the analysis. The experimental investigation is conducted on parabolic trough collector with U shape tube as absorber tube. The effect of the sudden fluctuations in the solar radiation on the performance of the collector is reduced by means of evacuated tube collector filled with thermic fluids. The analysis is performed with different thermic fluids such as dowtherm, therminol66, glycol water and ethylene glycol, are filled in the annular space between inner glass tube and U shape copper absorber tube. The experimentation is carried out at various mass flow rates from 20 to 100 LPH with the step-up flow rate of 20 LPH. A comparative study is carried out on various parameters such as effect of mass flow rate over instantaneous efficiency, useful heat gain and work input, etc. The characteristic curve of cylindrical parabolic trough collector (PTC) is also discussed. Experimental results show that, ethylene glycol gives better efficiency over mass flow rate and therminol66 gives best power heat ratio. Heat transfer mediums and its properties [specific heat capacity, thermal conductivity and dynamic viscosity] for all specified heat transfer fluids are also discussed. The results obtained with various specified heat transfer fluids filled in the annulus space of evacuated tube are compared with plain evacuated tube. It is observed that there is significant enhancement of overall instantaneous collection efficiency of the parabolic trough collector.     

NaBH4-assisted ethylene glycol reduction for preparation of carbon-supported Pt catalyst for methanol electro-oxidation

A carbon-supported Pt catalyst (40 wt.% loading) is prepared by a modified ethylene glycol reduction method (Pt–EG-complex). In this procedure, a complex produced by reacting ethylene glycol with sodium borohydride (NaBH₄), serves as a reducing agent for the Pt precursor and as a stabilizer for preventing the growth of Pt particles. For purposes of comparison, two types of carbon-supported Pt catalyst (40 wt.% loading) are also prepared by a NaBH₄ reduction method, in which the Pt precursor is reduced in a ethylene glycol solution (Pt–EG–NaBH₄) and in de-ionized water (Pt–H₂O–NaBH₄). Analysis by X-ray diffraction and transmission electron microscopy reveal that the Pt–EG-complex catalyst is comprised of highly-dispersed Pt nanoparticles with a uniform size (2.9–3.1 nm) on the carbon support, while large Pt particles are observed in the Pt–EG–NaBH₄ (3.3–3.6 nm) and Pt–H₂O–NaBH₄ (5.7–6.2 nm) catalysts. The Pt–EG-complex catalyst has the highest electrochemical surface area and shows the highest catalytic performance for methanol electro-oxidation.