低温密封酸溶——高分辨电感耦合等离子体质谱法测定地质样品中50个微量元素的评价

The method based on the determination of trace elements in geological samples by sector high resolution inductively coupled plasma mass spectrometry with mixed acid digestion procedure has been evaluated. The evaluation show that the results of 29 elements including Li, Cr, Co, Ni, Cu, Zn, Ga, Rb, Y, Cs, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, W, Tl, Bi, Th and U are satisfactory; V, Sr, Nb, Mo, In, Sb, Ba and Pb are acceptable; Sc, Cd, Hf, Ti, Mn, Fe, Ge and Sn have of large deviations, Be, Ta, Zr, As and Se are worse.     

微波消解-电感耦合等离子体质谱法同时测定茶叶中42种元素

建立了电感耦合等离子体质谱法（IcP—Ms）标准模式和优化的碰撞池模式（CCT）结合同时测定茶叶中Li、Be、Mg、Al、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、Ga、As、Se、Sr、Mo、Ag、Cd、Sn、Sb、Cs、Ba、Tl、Pb、Bi和16种稀土元素共42种元素的方法。样品经过微波消解,以Ge、In、Re为内标消除基体干扰,通过碰撞池技术消除多原子质谱干扰测定上述元素。对于所测元素校准曲线的相关系数均大于0．9990,回收率范围为90％-110％,相对标准偏差为0．22％-3．97％,大部分元素检出限均小于0．5μg·kg^-1。该方法简便、省时、准确、灵敏度高,适用于实际样品的检测。     

An X-ray Diffractometer with a Mobile Emitter-Detector System

An X-ray diffractometer with a mobile emitter-detector system is able to perform various X-ray examinations of a stationary sample. The design for this instrument is described, along with its operating principles and control programs. Owing to its high-precision angular movement sensors and its two detectors (one of these, a linear position-sensitive detector, has a working length of 100 mm and a resolution of <0.2 mm), the diffractometer can be used in both traditional and nontraditional experiments on X-ray reflection, scattering, and absorption. Results from using this instrument in reflectometry and X-ray tomography are presented as an example.__________Translated from Pribory i Tekhnika Eksperimenta, No. 3, 2005, pp. 99–107.Original Russian Text Copyright © 2005 by Asadchikov, Babak, Buzmakov, Dorokhin, Glagolev, Zanevskii, Zryuev, Krivonosov, Mamich, L. Moseiko, N. Moseiko, Mchedlishvili, Savel’ev, Senin, Smykov, Tudosi, Fateev, Chernenko, Cheremukhina, Cheremukhin, Chulichkov, Shilin, Shishkov.     

微波消解-电感耦合等离子体质谱法测定食品中18种元素

建立了食品中钠、镁、铝、钾、钙、钒、铬、锰、铁、镍、铜、锌、砷、硒、镉、锡、汞、铅的电感耦合等离子体质谱（ICP–MS）测定方法。样品经过微波消解,在线加入内标校正基体效应,通过修正方程校正质量数干扰,各元素校正曲线的相关系数均大于0.9995。对多种国家生物标准物质进行验证,测定值与标准值相符,相对标准偏差RSD（n=6）小于8.71%,加标回收率为71.8%～109.5%。     

Huge clusters of embryonic stem cells in human embryos: A morphologic study

Background: Nothing is known about huge clusters (HC) of embryonic stem cells (ESC) in human fetal organs (HFO). Aim: To know the status of HC‐ESC in HFO. Methods: Morphology and immunohistochemistry (IHC) in 32 HFO of 7–40 gestational weeks (GW). Results: HC‐ESC were seen in many HFO including central nervous system, spinal cords, spine, soft tissue, bone, skin, thyroid, lung, liver, pancreas, gall bladder, extrahepatic bile duct, adrenal, kidney, bladder, foregut, midgut, hindgut, female and male genital organs, and neurons. HC‐ESC's were composed of two populations depending on constituting cells. One were large cells with ample acidophilic cytoplasms with vesicular nuclei and nucleoli. The other were small cells with scant cytoplasm with hyperchromatic nuclei without nucleoli, resembling lymphocytes. The HC‐ESC were frequently showed neuronal differentiation. HC‐ESC were positive for NCAM, synaptophysin, NSE, chromogranin, PDGFRA, AFP, ErbB2, bcl‐2, KIT, MET. They were negative for CD45, CD3, CD20, EMA, CEA, CA19‐9, cytokeratin (CK) 7, CK8, CK18, CK19, MUC1, MUC2, MUC5AC, and MUC6. The mean Ki‐67 labeling index (LI) was 13% ± 7%. HC‐ESC showed a little glycogen but lacked mucins. These HC‐ESC were seen in 7–25 GW, and they were rarely seen in 26–40 GW. Conclusions: The morphology, IHC, and ontogeny of HC‐ESC were described. Microsc. Res. Tech. 77:825–831, 2014. © 2014 Wiley Periodicals, Inc.     

Mice embryology: A microscopic overview

In this work, we studied the embryology of mice of 12, 14, and 18 days of gestation by gross observation, light microscopy, and scanning electron microscopy. Grossly, the embryos of 12 days were observed in C‐shaped region of the brain, eye pigmentation of the retina, first, second, and third pharyngeal arches gill pit nasal region on the fourth ventricle brain, cervical curvature, heart, liver, limb bud thoracic, spinal cord, tail, umbilical cord, and place of the mesonephric ridge. Microscopically, the liver, cardiovascular system and spinal cord were observed. In the embryo of 14 days, we observed structures that make up the liver and heart. At 18 days of gestation fetuses, it was noted the presence of eyes, mouth, and nose in the cephalic region, chest and pelvic region with the presence of well‐developed limbs, umbilical cord, and placenta. Scanning electron microscopy in 18 days of gestation fetuses evidenced head, eyes closed eyelids, nose, vibrissae, forelimb, heart, lung, kidney, liver, small bowel, diaphragm, and part of the spine. The results obtained in this work describe the internal and external morphology of mice, provided by an integration of techniques and review of the morphological knowledge of the embryonic development of this species, as this animal is of great importance to scientific studies. Microsc. Res. Tech. 2012. © 2012 Wiley Periodicals, Inc.     

The CMD-2 cryogenic magnetic detector

The CMD-2 cryogenic magnetic detector used in a set of experiments on the VEPP-2M electron-positron collider at energies as great as 1.4 GeV is described. The design of the detector subsystems and the algorithms for reconstructing tracks in the drift chamber and the CsI and BGO calorimeters are presented. The spatial and energy resolutions of the detector systems have been determined from analysis of experimental data. The design of the superconducting solenoid and the layout of its powering by means of a superconducting transformer are shown. The trigger system of the detector and the conditions for recording “charged” and “neutral” events on a magnetic tape are described. The procedure used to monitor the parameters of the detector systems during the experiment is presented. Original Russian Text ? E.V. Anashkin, V.M. Aul’chenko, R.R. Akhmetshin, V.Sh. Banzarov, L.M. Barkov, S.E. Baru, N.S. Bashtovoi, D.V. Bondarev, A.E. Bondar’, A.V. Bragin, N.I. Gabyshev, D.A. Gorbachev, A.A. Grebenyuk, D.N. Grigor’ev, D.A. Epifanov, I.V. Zhuravkov, V.G. Zavarzin, A.S. Zaitsev, S.G. Zverev, F.V. Ignatov, V.F. Kazanin, S.V. Karpov, G.M. Kolachev, P.P. Krokovnyi, A.S. Kuz’min, I.B. Logashenko, P.A. Lukin, K.Yu. Mikhailov, V.A. Monich, M.A. Nikulin, A.B. Nomerotskii, V.S. Okhapkin, S.G. Pivovarov, A.S. Popov, T.A. Purlats, S.I. Redin, N.I. Root, A.A. Ruban, N.M. Ryskulov, A.L. Sibidanov, V.A. Sidorov, A.N. Skrinskii, V.P. Smakhtin, I.G. Snopkov, E.P. Solodov, P.Yu. Stepanov, A.I. Sukhanov, V.M. Titov, V.E. Fedorenko, G.V. Fedotovich, B.I. Khazin, A.G. Shamov, Yu.M. Shatunov, B.A. Shvarts, B.N. Shuvalov, D.V. Chernyak, S.I. Eidel’man, Yu.V. Yudin, 2006, published in Pribory i Tekhnika Eksperimenta, 2006, No. 6, pp. 63–79.     

中国成年男子肺及肾脏中的Hg、I

在我国四个不同膳食类型地区,采集16例急死正常成年男子尸体的肺和肾脏样品。采用HNO3 H2O2为消解液,微波消解样品,用ICP-MS法直接测定样液中Hg、I、Mo等25种微量元素,内标元素Re可补偿机体效应。对猪肝标准物质(GBW08551)及人发标准物质(GBW09101)测定,测得值与标准值吻合。方法简便,快速,灵敏,准确。     

ICP-MS顺次分析鸡蛋壳中微量元素

本研究基于顺次电离质谱分析技术,发展了一种直接质谱分析方法分析鸡蛋蛋壳中微量元素.在仅需少量样品预处理的条件下,分别用水和5％稀硝酸作为洗脱液,对鸡蛋壳中水溶性微量元素组分和酸溶性微量元素组分进行顺次提取,然后在线传输至ICP-MS进行分析.该方法可在10 min内实现单个样品中15种微量元素水溶性组分和酸溶性组分的顺...     

ICP-MS测定硼矿区饮用水和尿样中的硼及多种元素

The application of inductively coupled plasma mass spectrometry (ICP-MS) for determination of boron in water and urine samples was described. The detect limit (3σ) was 0.057 μg/L. The precision of the method was less than 2%. Multi-elements including Cr, Cu, Cd, Ba, Sr, Mn, Co, Tl, Li, Pb, Ca, Fe, K, Na, Mg, P, Si and Zn could be measured simultaneously. The method was successfully used in practice.