A fast measurement technique of MOSFETI/sub d/-V/sub g/ characteristics

In this letter, we developed an improved ultrafast measurement method for threshold voltage V/sub th/ measurement of MOSFETs. We demonstrate I/sub d/--V/sub g/ curve measurement within 1 /spl mu/s to extract the threshold voltage of MOSFET. Errors arising from MOSFET parasitics and measurement setup are analyzed quantitatatively. The ultrafast V/sub th/ measurement is highly needed in the investigation of gate dielectric charge trapping effect when traps with short detrapping time constants are present. Application in charge trapping measurement on HfO/sub 2/ gate dielectric is demonstrated.     

Charge trapping in ultrathin hafnium silicate/metal gate stacks

Charge trapping characteristics of MOCVD HfSi/sub x/O/sub y/ (20% SiO/sub 2/) gate stack of n-MOSFETs during substrate injection have been investigated. Positive constant voltage stress (CVS) and constant current stress (CCS) were applied at the gate of TiN-HfSi/sub x/O/sub y/-SiO/sub 2//p-Si n-MOSFETs having EOT of 2 nm. Significant electron trapping is observed from the positive shift of threshold voltage (/spl Delta/V/sub t/) after stress. Curve fitting of the threshold voltage shift data confirms power law dependence for Hf-silicate gate stacks. Charge pumping measurements for both cases showed significant electron trapping at bulk Hf-silicate while interface trap generation was comparatively insignificant. A turn-around effect is noticed for /spl Delta/V/sub t/ as the stress current and voltage increases under CCS and CVS. Dependence of spatial distribution of charge trapping at shallow traps on stress level in the Hf-silicate film and redistribution of trapped charges during and after removal of stress is possibly responsible for the turn-around effect.     

Gate-induced drain leakage current degradation and its time dependence during channel hot-electron stress in n-MOSFETs

The effects of channel hot-electron stress on the gate-induced drain leakage current (GIDL) in n-MOSFETs with thin gate oxides have been studied. It is found that under worst case stress, i.e. a high density of generated interface states Delta D/sub it/, the enhanced GIDL exhibits a significant drain voltage dependence. Whereas Delta D/sub it/ increases significantly the leakage current at low V/sub d/, it has minor effects at high V/sub d/. On the other hand, the electron trapping was found to increase the leakage current rather uniformly over both low and high V/sub d/ regions. In addition, GIDL degradation can be expressed as a power law time dependence (i.e. Delta I/sub leak/=A.t/sup n/), and the time dependence value n varies according to the dominant damage mechanism (i.e. electron trapping against Delta D/sub it/), similar to that reported for on-state device degradation.<>     

Characterization and reliability of dual high-k gate dielectric stack (poly-Si-HfO/sub 2/-SiO/sub 2/) prepared by in situ RTCVD process for system-on-chip applications

We investigate for the first time the possibility of integrating chemical vapor deposition (CVD) HfO/sub 2/ into the multiple gate dielectric system-on-a-chip (SoC) process in the range of 6-7 nm, which supports higher voltage (2.5-5 V operation/tolerance). Results show that CVD HfO/sub 2/-SiO/sub 2/ stacked gate dielectric (EOT =6.2 nm) exhibits lower leakage current than that of SiO/sub 2/ (EOT =5.7 nm) by a factor of /spl sim/10/sup 2/, with comparable interface quality (D/sub it//spl sim/1/spl times/10/sup 10/ cm/sup -2/eV/sup -1/). The presence of negative fixed charge is observed in the HfO/sub 2/-SiO/sub 2/ gate stack. In addition, the addition of HfO/sub 2/ on SiO/sub 2/ does not alter the dominant conduction mechanism of Fowler-Nordheim tunneling in the HfO/sub 2/-SiO/sub 2/ gate stack. Furthermore, the HfO/sub 2/-SiO/sub 2/ gate stack shows longer time to breakdown T/sub BD/ than SiO/sub 2/ under constant voltage stress. These results suggest that it may be feasible to use such a gate stack for higher voltage operation in SoC, provided other key requirements such as V/sub t/ stability (charge trapping under stress) can be met and the negative fixed charge eliminated.     

Improving channel carrier mobility and immunity to charge trapping of high-K NMOSFET by using stacked Y/sub 2/O/sub 3//HfO/sub 2/ gate dielectric

A stacked Y/sub 2/O/sub 3//HfO/sub 2/ multimetal gate dielectric with improved electron mobility and charge trapping characteristics is reported. Laminated hafnium and yttrium were sputtered on silicon followed by post-deposition anneal (PDA) in N/sub 2/ ambient. The new dielectric shows a similar scalability to HfO/sub 2/ reference. Analysis on flatband voltage shift indicates positive fixed charge induced by Y/sub 2/O/sub 3/. Excellent transistor characteristics have been demonstrated. Stacked Y/sub 2/O/sub 3//HfO/sub 2/, compared to HfO/sub 2/ reference with similar equivalent oxide thickness (EOT), shows 49% enhancement in transconductance and 65% increase in the peak electron mobility. These improvements may be attributed to better charge trapping characteristics of the multimetal dielectric.     

Charge trapping and detrapping characteristics in hafnium silicate gate stack under static and dynamic stress

The V/sub th/ instability of nMOSFET with HfSiON gate dielectric under various stress conditions has been evaluated. It is shown that after constant voltage stress, the threshold voltage (V/sub th/) relaxes to its initial prestress value. The relaxation rate is strongly affected by the stress duration and magnitude rather than injected charge flux or magnitude of the V/sub th/ shift. It is proposed that spatial distribution of trapped charges, which is strongly affected by the stress conditions, determines the relaxation rate. The implications of the electron trapping/detrapping processes on electrical evaluation of the high-/spl kappa/ gate dielectrics are discussed.     

Positive oxide charge-enhanced read disturb in a localized trapping storage flash memory cell

Read disturb-induced erase-state threshold voltage instability in a localized trapping storage Flash memory cell with a poly-silicon-oxide-nitride-oxide-silicon (SONOS) structure is investigated and reported. Our results show that positive trapped charge in bottom oxide generated during program/erase (P/E) cycles play a major role. Both gate voltage and drain voltage will accelerate the threshold voltage (V/sub t/) drift. Hot-carrier caused disturb effect is more severe in a shorter gate length device at low temperature. A model of positive charge-assisted electron tunneling into a trapping nitride is proposed. Influence of channel doping on the V/sub t/ drift is studied. As the cell is in an "unbiased" storage mode, tunnel detrapping of positive oxide charges is responsible for the threshold voltage shift, which is insensitive to temperature.     

Schottky-barrier source/drain MOSFETs on ultrathin SOI body with a tungsten metallic midgap gate

This letter presents a simple low-temperature process to fabricate Schottky-barrier (SB) MOSFETs that integrates a midgap metallic gate (tungsten). The device architecture is based on a thin (10 nm) and lowly doped silicon-on-insulator film that provides a threshold voltage of -0.3 V independent on the depletion charge and therefore not sensitive to variations in film thickness and doping. A gate encapsulation technique using an SiO/sub 2/-like hydrogen silsesquioxane capping layer features 15-nm-wide spacers and ensures the compatibility with the PtSi self-aligned silicide process. Long-channel devices present an ideal subthreshold swing of 60 mV/dec, over six decades of I/sub on//I/sub off/ without any sign of sublinear upward bending of the I/sub DS/--V/sub DS/ curves at low drain voltage.     

Hf-doped and NH/sub 3/-nitrided high-K gate dielectric thin film with least drain current degradation and flatband voltage shift

A novel technique to form high-K dielectric of HfSiON by doping base oxide with Hf and nitridation with NH/sub 3/, sequentially, is proposed. The HfSiON gate dielectric demonstrates excellent device performances such as only 10% degradation of saturation drain current and almost 45 times of magnitude reduction in gate leakage compared with conventional SiO/sub 2/ gate at the approximately same equivalent oxide thickness. Additionally, negligible flatband voltage shift is achieved with this technique. Time-dependent dielectric breakdown tests indicate that the lifetime of HfSiON is longer than 10 years at V/sub dd/=2 V.     

Improved interface quality and charge-trapping characteristics of MOSFETs with high-/spl kappa/ gate dielectric

The effects of high-pressure annealing on interface properties and charge trapping of nMOSFET with high-/spl kappa/ dielectric were investigated. Comparing with conventional forming gas (H/sub 2//Ar=4%/96%) annealed sample, nMOSFET sample annealed in high-pressure (5-20 atm), pure H/sub 2/ ambient at 400/spl deg/C shows 10%-15% improvements in linear drain current (I/sub d/) and maximum transconductance (g/sub m,max/). Interface trap density and charge trapping properties were characterized with charge pumping measurements and "single pulsed" I/sub d/-V/sub g/ measurements where reduced interface state density and improved charge trapping characteristics were observed after high pressure annealing. These results indicate that high pressure pure hydrogen annealing can be a crucial process for future high-/spl kappa/ gate dielectric applications.     

The effect of gate metal interdiffusion on reliability performance in GaAs PHEMTs

While Ti metal interdiffusion of Ti-Pt-Au gate metal stacks in GaAs pseudomorphic HEMT (PHEMTs) has been explored, the effect of Ti metal interdiffusion on the reliability performance is still lacking. We use a scanning transmission electron microscopy technique to correlate Ti-metal-InGaAs-channel-separation and Ti-sinking-depth with a threshold voltage V/sub T/. It has been found that Ti-sinking-depth is insensitive to V/sub T/. However, Ti metal interdiffusion reduces the separation of the gate metal and InGaAs channel, thus affecting the I/sub dss/ degradation rate. Accordingly, we observe the dependence of /spl Delta/I/sub dss/ on V/sub T/. Devices with less negative V/sub T/ exhibit inferior reliability performance to those devices with more negative V/sub T/. The results provide insight into a critical device parameter, V/sub T/, for optimizing reliability performance based on I/sub dss/ degradation.     

MOS Compatibility of High-Conductivity TaSi/sub 2//n+ Poly-Si Gates

The MOS-VLSI parameters and process compatibility of a high-conductivity refractory silicide gate with a sheet resistance of -2 Omega//spl square/ have been evaluated. The gate metallization typically consisted of 2.5 k/spl Aring/ TaSi/sub 2//2.5 k/spl Aring/ poly-Si, which was sintered prior to patterning with a CF/sub 4//O/sub 2/ plasma etch. Measurements were made to determine the metal work function, oxide freed charge, surface-states density, dielectric strength, oxide defect density, lifetime, current leakage, and the flat-band voltage stability with respect to mobile charge contamination, slow trapping, and hot-electron trapping. On IGFET's (500-/spl Aring/ SiO/sub 2/, As-implanted source/drain), V/sub T/ and Beta measurements were made as a function of the back-gate bias and the channel length as small as 2 µm. The MOS and IGFET parameters are nearly ideal and correspond to those expected of n+ poly-Si gates. Static and dynamic bias-temperature aging stability of the V/sub FB/ is excellent. These characteristics are preserved through subsequent standard VLSI process steps. However, certain process and structure limitations do exist and these have been defined.     

Charge trapping and dielectric reliability of SiO/sub 2/-Al/sub 2/O/sub 3/ gate stacks with TiN electrodes

A detailed study on charge trapping and dielectric reliability of SiO/sub 2/-Al/sub 2/O/sub 3/ gate stacks with TiN electrodes has been carried out. Due to the inherent asymmetry of the dual layer stack all electrical properties studied were found to be strongly polarity dependent. The gate current is strongly reduced for injection from the TiN (gate) electrode compared to injection from the n-type Si substrate. For substrate injection, electron trapping occurs in the bulk of the Al/sub 2/O/sub 3/ film, whereas for gate injection mainly hole trapping near the Si substrate is observed. Furthermore, no significant interface state generation is evident for substrate injection. In case of gate injection a rapid build up of interface states occurs already at small charge fluence (q/sub inj/ /spl sim/ 1 mC/cm/sup 2/). Dielectric reliability is consistent with polarity-dependent defect generation. For gate injection the interfacial layer limits the dielectric reliability and results in low Weibull slopes independent of the Al/sub 2/O/sub 3/ thickness. In the case of substrate injection, reliability is limited by the bulk of the Al/sub 2/O/sub 3/ layer leading to a strong thickness dependence of the Weibull slope as expected by the percolation model.     

Electrical characteristics of epitaxially grown SrTiO/sub 3/ on silicon for metal-insulator-semiconductor gate dielectric applications

We have found excellent electrical characteristics of epitaxially grown SrTiO/sub 3/ by molecular beam epitaxy (MBE) for silicon metal-insulator-semiconductor (MIS) gate dielectric application. For thin SrTiO/sub 3/ film, the equivalent oxide thickness (EOT) and leakage current density was 5.4 /spl Aring/ and 7 /spl times/ 10/sup -4/ A/cm/sup 2/ (@V/sub g/ = V/sub fb/ - 1 V), respectively. In addition, the dispersion and hysteresis characteristics were negligible. As-deposited samples show relatively high fixed oxide charge density and interface state density, but both of these characteristics are substantially reduced by an optimizing low temperature (< 450 /spl deg/C) post-metal forming gas anneal (FGA).     

A study of relaxation current in high-/spl kappa/ dielectric stacks

Dielectric relaxation currents in SiO/sub 2//Al/sub 2/O/sub 3/ and SiO/sub 2//HfO/sub 2/ high-/spl kappa/ dielectric stacks are studied in this paper. We studied the thickness dependence, gate voltage polarity dependence and temperature dependence of the relaxation current in high-/spl kappa/ dielectric stacks. It is found that high-/spl kappa/ dielectric stacks show different characteristics than what is expected based on the dielectric material polarization model. By the drain current variation measurement in n-channel MOSFET, we confirm that electron trapping and detrapping in the high-/spl kappa/ dielectric stacks is the cause of the dielectric relaxation current. From substrate injection experiments, it is also concluded that the relaxation current is mainly due to the traps located near the SiO/sub 2//high-/spl kappa/ interface. As the electron trapping induces a serious threshold voltage shift problem, a low trap density at the SiO/sub 2//high-/spl kappa/ interface is a key requirement for high-/spl kappa/ dielectric stack application and reliability in MOS devices.     

Low voltage copper phthalocyanine organic thin film transistors with a polymer layer as the gate insulator

Low voltage organic thin film transistors(OTFTs) were created using polymethyl-methacrylate-co g-lyciclyl-methacrylate(PMMA-GMA) as the gate dielectric.The OTFTs performed acceptably at supply voltages of about 10 V.From a densely packed copolymer brush,a leakage current as low as 2×10~(-8) A/cm~2 was obtained.From the measured capacitance-insulator frequency characteristics,a dielectric constant in the range 3.9-5.0 was obtained. By controlling the thickness of the gate dielectric,the threshold voltage ...     

Characterization of accumulation layer capacitance for extracting data on high-/spl kappa/ gate dielectrics

A new parameter extraction technique has been outlined for high-/spl kappa/ gate dielectrics that directly yields values of the dielectric capacitance C/sub di/, the accumulation layer surface potential quotient, /spl beta//sub acc/, the flat-band voltage, the surface potential /spl phi//sub s/, the dielectric voltage, the channel doping density and the interface charge density at flat-band. The parallel capacitance, C/sub p/(=C/sub sc/+C/sub it/), was found to be an exponential function of /spl phi//sub s/ in the strong accumulation regime, for seven different high-/spl kappa/ gate dielectrics. The slope of the experimental lnC/sub p/(/spl phi//sub s/) plot, i.e., |/spl beta//sub acc/|, was found to depend strongly on the physical properties of the high-/spl kappa/ dielectric, i.e., was inversely proportional to [(/spl phi//sub b/m/sup *//m)/sup 1/2/K/C/sub di/], where /spl phi//sub b/ is the band offset, and m/sup */ is the effective tunneling mass. Extraction of /spl beta//sub acc/ represented an experimental carrier confinement index for the accumulation layer and an experimental gate-dielectric direct-tunneling current index. /spl beta//sub acc/ may also be an effective tool for monitoring the effects of post-deposition annealing/processing.     

Fabrication and characterization of 100-nm In/sub 0.53/Ga/sub 0.47/As-In/sub 0.52/Al/sub 0.48/As double-gate HEMTs with two separate gate controls

In this letter, we demonstrate successful operation of 100-nm T-gates double-gate high electron mobility transistors with two separate gate controls (V/sub g1s/ /spl ne/ V/sub g2s/). These devices are fabricated by means of adhesive bonding technique using enzocyclocbutene polymer. The additional gate enables the variation of the threshold voltage V/sub th/ in a wide range from -0.68 to -0.12V while keeping high cutoff frequency f/sub t/ of about 170 GHz and high maximum oscillation frequency f/sub max/ of about 200 GHz. These devices are considered as being very effective for millimeter-wave mixing applications and are promising devices for the fabrication of velocity modulation transistor (VMT) (Sakaki et al., 1982).     

Mobility enhancement in TaN metal-gate MOSFETs using tantalum incorporated HfO/sub 2/ gate dielectric

TaN metal-gate nMOSFETs using HfTaO gate dielectrics have been investigated for the first time. Compared to pure HfO/sub 2/, a reduction of one order of magnitude in interface state density (D/sub it/) was observed in HfTaO film. This may be attributed to a high atomic percentage of Si-O bonds in the interfacial layer between HfTaO and Si. It also suggests a chemical similarity of the HfTaO-Si interface to the high-quality SiO/sub 2/-Si interface. In addition, a charge trapping-induced threshold voltage (V/sub th/) shift in HfTaO film with constant voltage stress was 20 times lower than that of HfO/sub 2/. This indicates that the HfTaO film has fewer charged traps compared to HfO/sub 2/ film. The electron mobility in nMOSFETs with HfO/sub 2/ gate dielectric was significantly enhanced by incorporating Ta.     

Si interlayer passivation on germanium MOS capacitors with high-/spl kappa/ dielectric and metal gate

We have demonstrated the advantages of silicon interlayer passivation on germanium MOS devices, with CVD HfO/sub 2/ as the high-/spl kappa/ dielectric and PVD TaN as the gate electrode. A silicon interlayer between a germanium substrate and a high-/spl kappa/ dielectric, deposited using SiH/sub 4/ gas at 580/spl deg/C, significantly improved the electrical characteristics of germanium devices in terms of low D/sub it/ (7/spl times/10/sup 10//cm/sup 2/-eV), less C- V hysteresis and frequency dispersion. Low leakage current density of 5/spl times/10/sup -7/ A/cm/sup 2/ at 1 V bias with EOT of 12.4 /spl Aring/ was achieved. Post-metallization annealing caused continuing V/sub fb/ positive shift and J/sub g/ increase with increased annealing temperature, which was possibly attributed to Ge diffusion into the dielectric during annealing.