Occupational stress, social support, and the costs of health care.

Relationships among health care costs, social support, and occupational stress are investigated. Health care cost data were collected over two years for 260 working individuals. Multiple regression analyses were used to control for initial health care costs, age, and gender in predicting later costs; independent variables were stress, strain, social support, and their interactions. Main effects and interactions each accounted for significant proportions of the variance in various health care costs.     

Cyclic stress response, strain resistance and fracture behavior of modified 1070 steel

A combined experimental and finite element study of fatigue crack closure in modified 1070 steel has been conducted. In this paper, the material property evaluations required for this study are presented. The monotonic and cyclic stress-strain properties, cyclic stress response, cyclic strain resistance, low cycle fatigue life and fracture behavior are examined. The low cycle fatigue tests were conducted using tension-compression cycling, under total strain amplitude control, over a wide range of strain levels. The material was found to possess medium strength and high ductility; while displaying a strain level dependent combination of cyclic strain softening and hardening behavior. The observed softening behavior is attributed to the rearrangement of dislocations produced by processing, formation of slip bands on the specimen surface and the formation of microcracks. The observed hardening behavior is ascribed to contributions from synergistic influences of dislocation multiplication, dislocation-dislocation interactions and dislocation-microstructural feature interactions. The material followed the strain-life relationships attributed to Basquin and Coffin-Manson. The fracture surfaces of the fatigue specimens showed distinct regions of crack initiation, microscopic-macroscopic crack growth and sudden fracture. The low-cycle fatigue characteristics and fracture behavior are discussed in the light of competing and mutually interactive influences of cyclic strain amplitude, concomitant response stress, intrinsic microstructural effects and dislocation-microstructure interactions during cyclic straining.     

Chain models of physical behavior for engineering analysis and design

The relationship between geometry (form) and physical behavior (function) dominates many engineering activities. The lack of uniform and rigorous computational models for this relationship has resulted in a plethora of inconsistent (and thus usually incompatible) computer-aided design (CAD) tools and systems, causing unreasonable overhead in time, effort, and cost, and limiting the extent to which CAD tools are used in practice. It seems clear that formalization of the relationship between form and function is a prerequisite to taking full advantage of computers in automating design and analysis of engineering systems.We present a unified computational model of physical behavior that explicitly links geometric and physical representations. The proposed approach characterizes physical systems in terms of their algebraic-topological properties:cell complexes, chains, and operations on them.     

Effect of heat capacity and physical behavior on strength and durability of shale, as building material

Increasing use of rock materials like shale in building, roofing, embankment filling, brick manufacturing, and in other civil structure application makes it an important rock to consider in construction engineering. Knowledge of thermal and physical properties of shale as building material is required to predict the rock??s strength and permanence against weathering. Inconsistent heat capacity of anisotropic rock can result in differential heat flow. This tendency can expand the building materials leading to reduction in strength and initiate disintegration. Authors have studied various thermo-physical properties of anisotropic shale from Tennessee, which is commonly used as building stones and bricks. Experiment was designed to measure the basic thermal property, ??heat capacity?? of shale. Series of laboratory tests including durability, strength, specific gravity, moisture content, and porosity were conducted to determine the physical and mechanical behavior of the samples. Results indicated that properties like porosity, strength and heat capacity varied significantly within samples, where as specific gravity and moisture content yielded steady values. Multivariate regression analysis was performed to evaluate possible correlations among the tested properties. Strong positive relationship was evident between heat capacity, and porosity. Heat capacity and Unconfined Compressive Strength of shale were inversely related. This study emphasized that physical and thermal properties of shale are directly linked with strength and durability of the rock mass.     

Effects of hydrophilic excipients and compression pressure on physical properties and release behavior of aspirin-tableted microcapsules.

Aspirin ethylcellulose microcapsules were tableted by compression with or without excipients (lactose or polyvinylpyrrolidone [PVP]). The effects of the amount of the excipients and microcapsule size on the crushing strength and release rate of aspirin from tableted microcapsules were investigated. Tablets without excipients had a crushing strength that was independent of the applied pressure and microcapsule size. An increase in compression pressure from 15 to 60 MPa resulted in an increase in the crushing strength of tablets containing 20% or 40% w/w lactose, but the reverse results were obtained for the tableted microcapsules containing 20% or 40% w/w PVP. Results showed that the release rate of aspirin from microcapsules containing lactose or PVP was independent of the compression pressure with the exception of tablets containing 40% w/w lactose. In vitro release profiles of aspirin from tableted microcapsules containing lactose or PVP showed that increasing the concentration of the excipients resulted in an increase in the release rate of aspirin. Values of n were changed by the compression pressure and the added excipients.     

Modeling of In segregation, stress and strain in InGaAs/GaAs(100) quantum well heterostructures

An advanced model for simulation of In segregation phenomena, stress and strain distribution during metal-organic chemical vapor deposition of InGaAs/GaAs(100) quantum well (QW) heterostructures based on representation of boundary gas layer as “quasi-liquid” has been suggested. Elastic energy was taken into account by considering epitaxy as a sequence of growth acts each resulted in the formation of ultrathin imaginary layers. The assumption that elastic influence is not distributed throughout the whole thickness of the substrate but affects only its near-surface layer has been postulated. Results of calculations of In profiles and stress distribution for heterostructures with single and multiple QWs for varied epitaxy conditions are provided. Various options of exploring the developed model for other materials and the limitations of applicability are discussed.     

Influence of granulating method on physical and mechanical properties, compression behavior, and compactibility of lactose and microcrystalline cellulose granules

The physical and mechanical properties of lactose (LC) and microcrystalline cellulose (MCC) granules prepared by various granulating methods were determined, and their effects on the compression and strength of the tablets were examined. From the force-displacement curve obtained in a crushing test on a single granule, all LC granules appeared brittle, and MCC granules were somewhat plastically deformable. Intergranular porosity ε_inter clearly decreased with greater spherical granule shape for both materials. Decrease in intragranular porosity ε_intra enhanced the crushing force of a single granule F_g. Agitating granulation brought about the most compactness and hardness of granules. In granule compression tests, the initial slope of Heckel plots K₁ appeared closely related to ease of filling voids in a granule bed by the slippage or rolling of granules. The reciprocal of the slope in the succeeding step 1/K₂ in compression of MCC granules indicated positive correlation to F_g, while in LC granules, no such obvious relation was evident. 1/K₂ differed only slightly among granulating methods. Tensile strength of tablets T_t obtained by compression of various LC granules was low as a whole and was little influenced by granulating method. For MCC granules, which are plastically deformable, tablet strength greatly depended on granulation. Granules prepared by extruding or dry granulation gave strong tablets. Tablets prepared from granules made by the agitating method showed particularly low T_t. From stereomicroscopic observation, the contact area between granule particles in a tablet appeared smaller; this would explain the decrease in intergranular bond formation.     

Microstructure,mechanical properties and high stress abrasive wear behavior of air-cooled MnCrB cast steels

Three medium carbon low alloyed MnCrB cast steels containing different Cr contents (0.3%, 0.6%, and 1.2%) were designed and the effect of Cr contents on the microstructure, mechanical properties and high stress abrasive wear behavior of the cast steels after 850 °C air-cooling and 220 °C tempering was studied. The results show that the hardenability of the MnCrB cast steels was excellent. The microstructure of the cast steels with low Cr contents (0.3% or 0.6%) consists of granular bainite and lower bainite/martensite multiphase. With increasing of Cr content, the formability of martensite was improved, the hardness and wear-resistance increased, but the impact toughness decreased in that more bainite was replaced by martensite. The air-cooled MnCrB cast steel containing 0.6% Cr, with granular bainite and lower bainite/martensite multiphase, exhibited excellent combination of strength, hardness, ductility, and impact toughness. In addition, its abrasive wear-resistance was 30% more than that of Hadfield cast steel in the high stress abrasive wear condition. This air-cooled MnCrB cast steel by simple alloying scheme and heat treatment has the advantages of high-performance, low cost, and environmentally friendly. It is a potential advanced wear-resistant cast steel for low- or even medium-impact abrasive conditions.     

Investigation of adsorption behavior of bisphenol A on well fabricated organic surfaces using surface plasmon resonance spectroscopy

Molecular adsorption of bisphenol A (BPA) on three types of self-assembled monolayers with different functionalities, such as -CH3, -SH, and -COOH, was examined using surface plasmon resonance (SPR) spectroscopy. BPA molecules in an aqueous solution were easily adsorbed onto a hydrophobic surface compared to a hydrophilic surface. Sorption behavior of BPA into poly(2-methoxyethyl acrylate) (PMEA) layer, which is known as a biocompatible polymer, was also investigated. Sorption and desorption dynamics of BPA into PMEA were found to be very rapid and quite reversible. The swelling of PMEA by sorption of BPA results in the change in SPR angle and allows one to quantify the BPA concentration below 100 ppm. In addition, the transport mechanism of BPA within the membrane of organ can be inferred by the experimental results.     

Enhanced photoluminescence and field-emission behavior of vertically well aligned arrays of In-doped ZnO Nanowires

Vertically oriented well-aligned Indium doped ZnO nanowires (NWs) have been successfully synthesized on Au-coated Zn substrate by controlled thermal evaporation. The effect of indium dopant on the optical and field-emission properties of these well-aligned ZnO NWs is investigated. The doped NWs are found to be single crystals grown along the c-axis. The composition of the doped NWs is confirmed by X-ray diffraction (XRD), energy-dispersive spectroscopy (EDS), and X-ray photospectroscopy (XPS). The photoluminescence (PL) spectra of doped NWs having a blue-shift in the UV region show a prominent tuning in the optical band gap, without any significant peak relating to intrinsic defects. The turn-on field of the field emission is found to be ～2.4 V μm(-1) and an emission current density of 1.13 mA cm(-2) under the field of 5.9 V μm(-1). The field enhancement factor β is estimated to be 9490 ± 2, which is much higher than that of any previous report. Furthermore, the doped NWs exhibit good emission current stability with a variation of less than 5% during a 200 s under a field of 5.9 V μm(-1). The superior field emission properties are attributed to the good alignment, high aspect ratio, and better crystallinity of In-doped NWs.     

Plastic behavior of composites and porous media under isotropic stress

The macroscopic relation between isotropic stress and dilatation is analyzed for a composite consisting of elasto-plastic matrix and elastic particles or empty cavities (porous material), on the basis of the composite spheres assemblage model. Results show that plastic macro-dilatation is not significant for elastic particles but is very significant for porous materials.     

Pedestrian environment and behavior in Karachi, Pakistan.

Pedestrian road traffic accidents (RTAs) are responsible for a substantial number of injuries and deaths in Karachi. To better understand the situations facing pedestrians we selected ten of Karachi's highest risk locations for pedestrian RTAs and observed 250 pedestrians for each of three activities--crossing the street, walking on the street, and walking on the sidewalk. We also observed the extent and effect of street and sidewalk encroachments. A total of 35% of the pedestrians crossing the street caused traffic to swerve to avoid them. Pedestrians crossing one lane at a time were 2.9 times more likely to cause the traffic to swerve than pedestrians who crossed the whole street at once (53 vs. 18%, RR = 2.9, 95% CI = 1.9-4.3). Pedestrians crossing in a group were 1.8 times more likely to cause traffic to swerve compared to those crossing singly (49 vs. 28%, RR = 1.8, 95% CI = 1.3-2.5, P = 0.001). A total of 36% ran while crossing and were 1.8 times more likely to cause traffic to swerve than those who walked (48 vs. 27%, RR = 1.8, 95% CI = 1.3-2.5). An average of 77% of the sidewalk width was blocked by encroachments which forced pedestrians to step on the road resulting in vehicles swerving. An average 33% of the street width was blocked by illegally parked vehicles. Pedestrians in Karachi indulge in risky behaviors. Encroachments on streets and sidewalks compound the problem. Piloting efforts to modify pedestrian behavior and the environment they negotiate should be considered to reduce pedestrian deaths.     

On the stress field and crack nucleation behavior of a disclinated nanowire with surface stress effects

This paper studies the stress field and crack nucleation behavior in a disclinated nanowire with a continuum model. The surface stress effects of the nanowire is accounted for with the Gurtin-Murdoch model. The Green’s functions for the stress fields of a single wedge disclination and a single edge dislocation in a cylindrical nanowire are solved respectively with the complex variable method. To make the superposition principle valid, the stress field induced by the residual surface tension is properly handled in the Green’s functions. After that, the distributed dislocation method is applied to simulate the crack nucleation behavior. The influences of the surface stress effects on the stress fields of the wedge disclination and edge dislocation as well as on the Griffith crack nucleation behavior are systematically discussed.     

A look at physical simulation of metallurgical processes,past, present and future

The year 2007 marks the 50th anniversary of the founding of Dynamic Systems Inc., the developer and manufacturer of Gleeble physical simulation systems. From the initial welding simulators in the 1950s to today's complex rolling simulators and multi-axis nano-material development tools, the evolution of equipment for physical simulation research has evolved along several paths. In each case, a need to develop or improve processes and materials has pushed the technology to new levels. This paper takes a brief look at the historical developments of physical simulation tools over the last 50 years and reviews a number of significant milestones in the evolving science of physical simulation. After a historical review, the current technologies and accomplishments are discussed. This includes a look at the most recent developing methods such as the use of laser ultrasonics to gather real-time microstructure information during the simulation. This paper also reviews recent work in simulating thin slab continuous casting. Finally a look at what may be expected in the future for physical simulation is presented.     

Cyclic stress response and fatigue behavior of Cu added ferritic steels

Steels in which Cu content was altered from 0 to 1.5 mass% were subjected to various heat treatments to change the state of Cu. Concerning these respective steels, fatigue ratio by a stress controlled fatigue test and fatigue resistance by a strain controlled fatigue test thereof were compared. Furthermore dislocation substructure and surface defect during and after cyclic straining were investigated to clarify the effect of Cu on fatigue properties. The fatigue ratios at 2.0 × 10⁶ loading cycles of the Cu added steels after aged at 450 and 750 degrees C are 0.7, remarkably high as compared with those of the Cu added steels after aged at 550 and 650 degrees C, the Cu free steels and any other conventional steels whose fatigue ratio are approximately between 0.5 and 0.6. The fatigue resistance of the as-rolled Cu added steel maintains steady cyclic hardening until fracture. To the contrary the Cu added steel after heat treatment at 550 degrees C shows cyclic hardening to the peak stress and then shows a cyclic softening until fracture. The surface roughness of the Cu added steels after cyclic straining are relatively shallow compared with those of the Cu free steel. The internal substructure of the Cu free steel shows typical cell structure but those of the Cu added steels exhibit vein structure.     

On the measurement and physical meaning of the cleavage fracture stress in steel

Elastic-plastic two-dimensional (2D) and three-dimensional (3D) finite element models (FEM) are used to analyze the stress distributions ahead of notches of four-point bending (4PB) and three-point bending (3PB) specimens with various sizes of a C-Mn steel. By accurately measuring the location of the cleavage initiation sites, the local cleavage fracture stress _f and the macroscopic cleavage fracture stress _F is accurately measured. The _f and _F measured by 2D FEM are higher than that by 3D FEM. _f values are lower than the _F, and the _f values could be predicted by _f=(0.8––1.0)_F. With increasing specimen sizes (W,B and a) and specimen widths (B) and changing loading methods (4PB and 3PB), the fracture load P _f changes considerably, but the _F and _f remain nearly constant. The stable lower boundary _F and _f values could be obtained by using notched specimens with sizes larger than the Griffiths–Owen specimen. The local cleavage fracture stress _f could be accurately used in the analysis of fracture micromechanism, and to characterize intrinsic toughness of steel. The macroscopic cleavage fracture stress _F is suggested to be a potential engineering parameter which can be used to assess fracture toughness of steel and to design engineering structure.     

Failure in laminates in tension under increasing stress,constant stress,and cyclic stress

Both monotonic and cyclic tension experiments have been carried out to fracture on transparent laminates made from flat ribbon glass and polyethylene sheets by heat bonding in a vacuum. The distribution of the measured tensile fracture stresses in monotonic loading correlates very well with the distribution of fracture stresses calculated from the measured distribution of element fracture stresses and the yield strength in shear of the polyethylene, according to a detailed statistical theory worked out earlier by Scop and Argon. Although the expected mode of fatigue damage by propagation of delamination cracks emanating from isolated stable fractures in reinforcing elements was observed, actual fatigue failure was a result of a more rapid mechanism of continued fracturing in reinforcing elements by a humidity-induced time-integrated static fatigue process. While laminates subjected to static stresses of the same magnitude as those in the dynamic experiments failed by the development of an identical form of damage during the same length of time under stress in laboratory air, other laminates tested in the same manner in dry air had 5 to 10 fold increased lives. In addition re-testing of individual elements of delaminated composites showed that elements can often be damaged during lamination, which must be taken into account in any quantitative study.