Crystallization kinetics of amorphous Zr65Cu25Al10 alloy

1　ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｄｅｖｅｌｏｐｍｅｎｔｏｆｇｌａｓｓｆｏｒｍｉｎｇ ｍｕｌｔｉｃｏｍｐｏ ｎｅｎｔａｌｌｏｙｓｙｓｔｅｍｓｗｉｔｈｖｅｒｙｌｏｗｃｒｉｔｉｃａｌｃｏｏｌｉｎｇｒａｔｅｓｗｉｔｈｉｎ 1～ 10 0Ｋ/ｓｈａｓｏｆｆｅｒｅｄｆｉｒｓｔ     

Interfacial defects of hard magnetic Pr2Fe14B phase from amorphous to nanostructures

The interfacial defects of hard magnetic Pr2Fe14B phase from amorphous to nanostructures have been investigated by positron lifetime spectroscopy. The nanostructure was produced by melt-spinning and nanocrystallization route. The two main components can be ascribed to vacancy-like defects in the intergranular layers or the interfaces, and microvoids or large free volumes with size compared to several missing atoms at the interactions of the atomic aggregates or the crystallites. The remarkable changes in the positron lifetimes from the amorphous structure to the nanocrystructure with varied sizes can be interpreted, indicating that the structural transformation and the grain growth induce the defect changes occurring at the interfaces with different shapes and sizes.     

Nd—Fe—B和Pr—Fe—B相图三维拓扑分析

利用三维拓扑构形分析方法.讨论确定了Nd—Fe—B三元相图1000℃截面上的相区关系.对Pr-Fe-B三元相图过Pr_2Fe_(14)B的垂直截面上的相区关系进行了讨论和必要的修正     

Zr,Nb对Fe—B合金非晶形成能力的影响

根据获得高玻璃形成能力（ＧＦＡ）非晶合金的多元化理论,研究了Ｚｒ,Ｎｂ对二元Ｆｅ－Ｂ非晶合金ＧＦＡ的影响,结果表明,高Ｂ含量Ｆｅ－Ｂ非晶合金中加入适量Ｚｒ能够促进玻璃态转变,三元Ｆｅ－Ｂ－Ｚｒ非晶合金中加入少量Ｎｂ能够有效地提高其ＧＦＡ,多元化是促进非晶合金玻璃态转变和提高其ＧＦＡ的有效方法。     

Crystallization of amorphous Zr70Cu30—xNix alloys

X－ray diffraction (XRD)and differential scanning calorimetry(DSC) were employed to investigate the influence of Ni content on the crystallization of amorphous Zr70Cu30-xNix(atom fration in%) alloys,Experimental results show that with the Ni content increasing the activation energies for crystallization of amorphous Zr70Cu30-xNix alloys increase correspondingly,indicating that the thermal stability is greatly improved.All the DSC traces of amorphous Zr70Cu30-xNix alloys exhibit two exothermic peaks,suggesting that the crystallization process via a double-stage ticles,while the second one corresponds to the precipitaion of nano-scale Zr2Ni phase and crystallization of residual amporphous phase,The mechanism on the crystallization of amorphous Zr70Cu30-xNix alloys was discussed.     

铸造Pr—Fe—B磁体的热压变形研究

研究了铸造Pr_(19)Fe_(74.5)B_5Cu_(1.5)磁体的热压变形过程,结果表明,无论经受何种变形方式,磁体易轴[001]总是沿压缩变形方向取向排列,随着热压变形的进行,磁体发生Pr_2Fe_(14)B主相晶粒的碎化和晶粒间相对滑动和转动,以及富Pr液相被挤出,最终形成细小、致密的取向组织,磁性能提高到B_r=990mT,i_H_c=880kA/m和(BH)_m=191kJ/m~3矫顽力的提高归因于主相晶粒碎化和富Pr相在晶间均匀连续分布,剩磁的提高则主要由已碎化晶粒在变形中相对滑动和转动所形成的易轴取向排列以及主相晶粒的致密化贡献,变形充分而缓慢应是获得较强易轴取向和较高磁性能的重要条件。     

用化学还原法制备的Fe—Zr—B非晶超细颗粒的结构研究

用Mossbauer谱，X射衍射分析和DAT研究了用硼氢化物还原法制取的Fe56Zr5B39非晶超细颗粒，并与Fe68B32非晶合金作了对比。Mossbauer谱和X射线衍射分析研究结果揭示Fe56Zr5B39超精细场的低场分量与以相当数量的锆原子为近邻的铁原子相关；而超精细场的高场分量所相关的铁原子，其近邻主要是铁原子和硼原子，以及可能有部分锆原子。     

Effects of quenching conditions on crystallization behavior of amorphous Al90Ni5Ce5 alloys

X-ray diffraction and DSC were used to investigate the crystallization behavior of amorphous Al90Ni5Ce5 alloys at different quenching temperatures.All the amorphous Al90Ni5Ce5 alloys quenched at different temperatures crystallize by two stages.The first stage corresponds to FCC Al phase precipitating from the amorphous matrix.The crystallization onset temperature increases with increasing quenching temperature.The quenching temperature also influences the isothermal behaviors.At low quenching temperatures,the FCC Al precipitation is only through grain growth.At high quenching temperatures,the FCC Al precipitation is through growth of quenched-in Al unclei and nucleation and growth of new crystallites.The reason that the crystallization onset temperature varies with quenching temperature is likely as that the quenched-in Al nuclei decreases with increasing temperature.     

Zr对PrFeB非晶合金晶化的影响

采用DTA(差热分析仪）,XRD（X射线衍射）研究添加元素Zr对PrFeB非晶合金的形成,组织结构的影响,结果表明,PrFeB非晶薄带最终晶化为α－Fe和Pr2Fe14B相,晶化过程中析出亚稳相Pr2Fe23B3,非晶合金中添加1、2at%zr元素可使αFe相的起始晶化温度升高,且无亚稳相Pr2Fe23B3析出,同时细化α－Fe晶粒。     

非晶合金的晶化动力学与初生相的内在联系

通过差示扫描量热法(DSC)研究了Zr60Al15Ni25非晶合金的晶化动力学。X射线衍射(XRD)和能谱(EDS)分析结果表明:Zr60Al15Ni25非晶合金晶化过程中的初生相为复杂三元化合物Al2NiZr6和AlNi4Zr5。非晶合金的有效晶化激活能反映了晶化初生相与非晶相间的结构差异,二者结构差异越大,有效晶化激活能就越高,Zr60Al15Ni25非晶合金的有效晶化激活能高达345 kJ/mol;当合金高温熔体快冷过程中的初生相与非晶合金的晶化初生相一致时,晶化动力学参数能够实际反映合金的玻璃形成能力,相反则不能。     

Applicability of Johnson-Mehl-Avrami model to crystallization kinetics of Zr60Al15Ni25 bulk amorphous alloy

The applicability of Johnson-Mehl-Avrami（JMA） model to the crystallization kinetics of Zr60Al15Ni25 bulk amorphous alloy is investigated by differential scanning calorimetry（DSC） under isochronal and isothermal conditions. A criterion Xm, at which a defined function z（x） exhibits the maximum value, is introduced to check the validity of JMA model to the kinetics analysis. The value Of Xm has a constant of 0.632 for JMA model. It is found that the values Of Xm at different isothermal annealing temperatures （743,748, 753 and 758 K） are almost near 0.632, which indicates that the isothermal crystallization kinetics can be modeled by JMA equation. However, the values Of Xm at different heating rates （10, 20, 30 and 40 K/min） are about 0.52, implying that JMA model is not valid to the isochronal crystallization kinetics. The reason why the JMA model is not valid to the isochronal crystallization kinetics is discussed.     

Al1.49Si1.45Zr0.26(TiCaMg)0.37O6.43非晶的非等温晶化动力学

采用非等温差示扫描量热分析方法,结合X射线衍射和红外光谱,研究了Al1.49Si1.45Zr0.26(TiCaMg)0.37O6.43非晶晶化动力学.结果表明:非晶在1223～1273 K附近发生了四方氧化锆的析出反应,析晶活化能为518～538 kJ/mol;在1423～1473 K附近发生了莫来石和方石英的析出反应,其析晶活化能为522～545 kJ/mol,且氧化锆的存在能有效地降低莫来石的析晶活化能.     

Sc对Zr基块体非晶合金晶化动力学的影响

以海绵锆为原材料,利用浇包型坩埚电弧炉倾斜铸造法制备Zr52.5Cu17.9Ni14.6Al10Ti5五元块体非晶合金楔形试样,研究活性元素Sc对合金玻璃形成能力及晶化动力学参数的影响。结果表明:Sc的加入可显著增大合金的最大非晶形成厚度,但对合金过冷液相区温度范围所表征的热稳定性影响较小。Sc虽然使合金的晶化激活能降低,但使晶化孕育期时间常数增大,晶化频率因子减小,二者的综合作用使合金晶化孕育期延长,过冷倾向增大,玻璃形成能力提高。     

Crystallization kinetics of （Ni0.75Fe0.25）78-xNbxSi10B12 （x = 0, 5） amorphous alloys

Amorphous ribbons of （Ni0.75Fe0.25）78-xNbxSi10B12 （x = 0, 5） were prepared by a single roller melt-spinning technique in air atmosphere. The crystallization kinetics of the alloys were investigated by means of continuous heating, and the activation energies of the alloys were calculated using Kissinger plot method and Ozawa plot method on the basis of differential thermal analysis data. The crystallization products were analyzed by X-ray diffraction. After the （Ni0.75Fe0.25）78Si10B12 amorphous alloy was annealed at the temperatures 715 and 745 K, a single phase of γ-（Fe, Ni） solid solution with grain sizes of about 10.3 and 18.5 nm, respectively, precipitates in the amorphous matrix. The crystallized phases are γ-（Fe, Ni） solid solution, Fe2Si, Ni2Si, and Fe3B after annealing at 765 K. The （Ni0.75Fe0.25）73NbsSi10 B12 amorphous alloy was annealed at 720, 750, and 800 K; and the crystallization phases, γ（Fe, Ni） solid solution, （Fe, Ni）23B6. Ni31Si12 and Nb2NiB0.16 form simultaneously.     

Effect of preannealing on crystallization process of amorphous Sm5Fe80Cu1Si5B3C2.5Zr3.5 alloy

In the view of crystallization activation energy of amorphous alloy,the mechanism of coarse grain in annealed Sm5Fe80Cu1Si5B3C2.5ZR3.5 amorphous alloy was analyzed.It reveals the e4ffect of preannealing on the process crystallization.The results show that preannealing can be used to change the crystallization behavior of the α-Fe phase in the Sm5Fe80Cu1Si5B3C2.5Zr3.5 amorphous alloy,whick is helpful for forming α-Fe phase grains;and it is not large for Sm2Fe17Cx phase.     

氢对Zr41.2 Ti13.8 Cu12.5 Ni10 Be22.5 大块非晶合金晶化特性的影响

利用电弧熔炼及铜模快速铸造的方法制备Zr41.2Ti13.8Cu12．5Ni10Be22．5大块非晶合金，通过电解丙三醇和磷酸的电化学法向大块非晶中充入氢。测试了大块非晶态合金中充入氢的含量及体积变化规律，采用XRD，DSC技术研究了氢对大块非晶的晶化特征的影响。结果表明：Zr41．2Ti13．8Cu12．5Ni10Be22．5大块非晶可充入的氢与金属的摩尔比为0．92，体积膨胀3．5％；随着氢含量的增加，玻璃转变温度和晶化温度稍有提高，并使结晶过程不同阶段的放热峰变弱。     

Ni-P非晶薄膜晶化相与相变动力学的XRD分析

用原位XRD技术分析了连续加热过程中电沉积Ni-P薄膜晶化与相变行为．通过定量分析,确定出不同温度下各相的析出量,由此计算出各相的晶化与相变激活能以及晶化结晶度．结果表明, Ni-P非晶薄膜的晶化与相变行为与薄膜中P的含量有关．在晶化过程中出现了四种亚稳相即NiP,Ni2P,Ni12P5及Ni5P2．计算得到:亚稳相NiP,Ni2P及稳定相Ni3P的相变激活能分别为133±15,172±19及190±20 kJ／mol;单个析出相的相变激活能低于Ni-P合金晶化激活能和Ni原子的自扩散激活能．