Radiometric calibration of the vacuum-ultraviolet spectrograph SUMER on the SOHO spacecraft with the B detector

The Solar Ultraviolet Measurement of Emitted Radiation (SUMER) vacuum-ultraviolet spectrograph was calibrated in the laboratory before the integration of the instrument on the Solar and Heliospheric Observatory (SOHO) spacecraft in 1995. During the scientific operation of the SOHO it has been possible to track the radiometric calibration of the SUMER spectrograph since March 1996 by a strategy that employs various methods to update the calibration status and improve the coverage of the spectral calibration curve. The results for the A Detector were published previously [Appl. Opt. 36, 6416 (1997)]. During three years of operation in space, the B detector was used for two and one-half years. We describe the characteristics of the B detector and present results of the tracking and refinement of the spectral calibration curves with it. Observations of the spectra of the stars alpha and rho Leonis permit an extrapolation of the calibration curves in the range from 125 to 149.0 nm. Using a solar coronal spectrum observed above the solar disk, we can extrapolate the calibration curves by measuring emission line pairs with well-known intensity ratios. The sensitivity ratio of the two photocathode areas can be obtained by registration of many emission lines in the entire spectral range on both KBr-coated and bare parts of the detector's active surface. The results are found to be consistent with the published calibration performed in the laboratory in the wavelength range from 53 to 124 nm. We can extrapolate the calibration outside this range to 147 nm with a relative uncertainty of ?30% (1varsigma) for wavelengths longer than 125 nm and to 46.5 nm with 50% uncertainty for the short-wavelength range below 53 nm.     

Radiometric calibration of the telescope and ultraviolet spectrometer SUMER on SOHO

The prelaunch spectral-sensitivity calibration of the solar spectrometer SUMER (Solar Ultraviolet Measurements of Emitted Radiation) is described. SUMER is part of the payload of the Solar and Heliospheric Observatory (SOHO), which begins its scientific mission in 1996. The instrument consists of a telescope and a spectrometer capable of taking spatially and spectrally highly resolved images of the Sun in a spectral range from 50 to 161 nm. The pointing capabilities, the dynamic range, and the sensitivity of the instrument allow measurements both on the solar disk and above the limb as great as two solar radii. To determine plasma temperatures and densities in the solar atmosphere, the instrument needs an absolute spectral-sensitivity calibration. Here we describe the prelaunch calibration of the full instrument, which utilizes a radiometric transfer-standard source. The transfer standard was based on a high-current hollow-cathode discharge source. It had been calibrated in the laboratory for vacuum UV radiometry of the Physikalisch-Technische Bundesanstalt by use of the calculable spectral photon flux of the Berlin electron storage ring for synchrotron radiation (BESSY)-a primary radiometric source standard.     

Intercalibration of SUMER and CDS on SOHO. I. SUMER detector A and CDS NIS

The results of an intercalibration between the extreme ultraviolet spectrometers Coronal Diagnostic Spectrometer (CDS) and Solar Ultraviolet Measurements of Emitted Radiation (SUMER) onboard the Solar and Heliospheric Observatory (SOHO) are presented. During the joint observing program Intercal_01, CDS and SUMER were pointed at the same locations in quiet Sun areas and observed in the same wavelength bands located around the spectral lines He i 584 A, Mg x 609 A, and Mg x 624 A. The data sets analyzed here consist of raster images recorded by the CDS normal-incidence spectrometer and SUMER detector A and span the time from March 1996 to August 1996. Effects of the different spatial and spectral resolutions of both instruments have been investigated and taken into account in the analysis. We find that CDS measures generally a 30% higher intensity than SUMER in the He i 584-A line, while it measures 9% and 17% higher intensities in Mg x 609 A and Mg x 624 A, respectively. Both instruments show very good temporal correlation and stability, indicating that solar variations dominate over changes in instrumental sensitivity. Our analysis also provides in-flight estimates of the CDS spatial point-spread functions.     

Ultraviolet thermoluminscent dosimetry using high temperature peaks in KCl:Eu2+ crystals

The thermoluminescence (TL) characteristics of KCl:Eu2+ irradiated with solar and monochromatic ultraviolet (UV) light have been investigated. The glow curves exhibit at least five TL peaks between room temperature and 673 K. The low temperature peaks (<500 K) are very sensitive to the UV radiation, but their intensities practically do not depend on the duration of solar irradiation and are determined by the ratio between the creation rate by UV and the bleaching rate by visible light. The high temperature 650 K peak is not so sensitive, but it is more stable under optical bleaching and its intensity increases supralinearly as exposure time increases. The creation spectrum of the 650 K peak presents a broad band with a maximum at 230 nm that extends in the long wavelength range at least up to 360 nm. The results obtained are discussed in relation to the development of a UV dosemeter with wavelength sensitivity dependence close to the action spectra of UV-related biological effects.     

Efficiency of a grazing-incidence off-plane grating in the soft-x-ray region

Efficiency measurements of a grazing-incidence diffraction grating in the off-plane mount were performed using polarized synchrotron radiation. The grating had 5000 grooves/mm, an effective blaze angle of 14 degrees, and was gold coated. The efficiencies in the two polarization orientations (TM and TE) were measured in the 1.5-5.0 nm wavelength range and were compared with the efficiencies calculated using the PCGrate-SX code. The TM and TE efficiencies differ, offering the possibility of performing unique science studies of astrophysical, solar, and laboratory sources by exploiting the polarization sensitivity of the off-plane grating.     

Polarization sensitivity of the SUMER instrument on SOHO

The Solar Ultraviolet Measurements of Emitted Radiation (SUMER) instrument on the Solar and Heliospheric Observatory (SOHO) satellite is sensitive to the state of linear polarization of the incident radiation primarily owing to two optical elements, the holographic grating and the wavelength scan mirror. The large angle of incidence of light striking the scan mirror, which varies from roughly 73.3 degrees to 81.6 degrees (with respect to the mirror normal), causes the mirror to act as a linear polarizer. Similarly, the spectrometer grating operates at incidence angles between 16.7 degrees and 35.0 degrees , adding to the polarization effect at some wavelengths. Measurement and characterization of this polarization sensitivity as a function of wavelength were performed with the engineering model optics (scan mirror and grating) and synchrotron radiation, which is nearly 100% linearly polarized, from the Super Anneau de Collisions d'Orsay (SUPERACO) positron storage ring in Orsay. The polarization sensitivity or modulation factor of the SUMER instrument was found to be between 0.4 and 0.6, depending on the wavelength and the angle of incidence of light striking the scan mirror; this agrees with the calculated polarization properties based on the measured optical constants for the silicon carbide mirror and grating.     

Radiometric Calibration Tracking of the Vacuum-Ultraviolet Spectrometer SUMER During the First Year of the SOHO Mission

Detailed radiometric calibration tracking of the vacuum-ultravioletspectrometer SUMER (from solar ultraviolet measurements of emittedradiation) was performed during the first year of the Solar andHeliospheric Observatory (SOHO) mission and will continue. Inview of the flight history of many previous solar UV instruments, thestability of calibration of the extreme-ultraviolet instruments on SOHOhas been a major concern. Results obtained during the first year ofoperation show that excellent radiometric stability has been achievedwith SUMER. These results were accomplished by stringentcleanliness and contamination-control procedures during all phases ofthe project. We describe the strategy and results of the in-flightcalibration tracking program performed with SUMER.     

Refractometry of organosilica microspheres

The refractive index of novel organosilica (nano/micro) material is determined using two methods. The first method is based on analysis of optical extinction efficiency of organosilica beads versus wavelength, which is obtained by a standard laboratory spectrometer. The second method relies on the measurable trapping potential of these beads in the focused light beam (laser tweezers). Polystyrene beads were used to test these methods, and the determined dispersion curves of refractive-index values have been found accurate. The refractive index of organosilica beads has been determined to range from 1.60 to 1.51 over the wavelength range of 300-1100 nm.     

多碱光电阴极荧光半峰宽对灵敏度的影响研究

论述了Na2KSb(Cs)多碱光电阴极光电发射过程的表征和测量,提出了利用荧光谱来表征光电阴极电子跃迁几率的方法。在同样工艺条件下测量了像增强器多碱光电阴极的光谱响应和荧光谱,比较了多碱光电阴极灵敏度与逸出功、荧光谱强度、荧光谱峰值波长、半峰宽之间的关系,分析了逸出功、荧光峰值波长、峰值强度、半峰宽对多碱阴极灵敏度的影响,得出了影响多碱阴极灵敏度高低的主要原因是Na2KSb膜层的晶格完整性的结论,提出了进一步改进多碱阴极制作工艺的技术途径。     

Intercalibration of SUMER and CDS on SOHO. III. SUMER and CDS-GIS. Solar and Heliospheric Observatory

Simultaneous observation of the same solar sources with different instruments is one way to test prelaunch radiometric calibrations and to detect changes in responsivity with time of extreme-ultraviolet instruments in space. Here we present the results of intercalibration of the SUMER (Solar Ultraviolet Measurements of Emitted Radiation) spectrometer (detectors A and B) and the GIS (Grazing Incidence Spectrometer), one of two spectrometers that compose the CDS (Coronal Diagnostic Spectrometer) on the Solar and Heliospheric Observatory (SOHO). The two instruments observed simultaneously radiances of emission lines at or near the center of the solar disk. The emission line chosen for intercomparison was Ne VIII at 770 A. However, such an intercomparison of the SUMER and CDS-GIS measurements means comparing two data sets with large differences in resolution and field of view. The latter difference, especially, introduces differences in the measured intensities caused by the solar variability that is relatively strong in the 770-A line. Using a statistical approach to overcome this problem, we found that the ratio of the GIS to the SUMER average radiances amounted to 2.6 +/- 0.9 before the SOHO's loss of attitude and to 2.1 +/- 0.7 afterward. These findings confirm earlier estimates of the GIS's responsivity being too low, and an update of the GIS calibration is recommended. Despite the large differences in resolution and field of view of the two instruments, the shapes of their normalized and rescaled histograms of the radiances agree well and therefore represent characteristic features of the Ne VIII line.     

Charge-coupled device spectrograph for direct solar irradiance and sky radiance measurements

The characterization of a charged-coupled device (CCD) spectrograph developed at the Laboratory of Atmospheric Physics, Thessaloniki is presented. The absolute sensitivity of the instrument for direct irradiance and sky radiance measurements was determined, respectively, with an uncertainty of 4.4% and 6.6% in the UV-B, and 3% and 6% in the UV-A, visible and near-infrared (NIR) wavelength ranges. The overall uncertainty associated with the direct irradiance and the sky radiance measurements is, respectively, of the order of 5% and 7% in the UV-B, increasing to 10% for low signals [e.g., at solar zenith angles (SZAs) larger than 70 degrees ], and 4% and 6% in the UV-A, visible, and NIR. Direct solar spectral irradiance measurements from an independently calibrated spectroradiometer (Bentham DTM 300) were compared with the corresponding CCD measurements. Their agreement in the wavelength range of 310-500nm is within 0.5% +/- 1.1% (for SZA between 20 degrees and 70 degrees ). Aerosol optical depth (AOD) derived by the two instruments using direct Sun spectra and by a collocated Cimel sunphotometer [Aerosol Robotic network (AERONET)] agree to within 0.02 +/- 0.02 in the range of 315-870 nm. Significant correlation coefficients with a maximum of 0.99 in the range of 340-360 nm and a minimum of 0.90 at 870 nm were found between synchronous AOD measurements with the Bentham and the Cimel instruments.     

Cold electron source with an electron multiplier illuminated by ultraviolet photons

A cold electron source has been developed using a microchannel plate (MCP) electron multiplier. Primary electron emission is initiated by illumination with ultraviolet photons from a diode. Final electron emission currents of up to 10 μA in continuous wave (CW) mode and 10 mA in pulsed mode have been achieved from a MCP with an active diameter of 5.5 mm. Electron emission generated by UV photons with a wavelength of 260 nm has been shown to be about 30 times more efficient than emission generated by photons with a wavelength of 300 nm. Application of this cold electron source in mass spectrometry is discussed.     

High-efficiency dye-sensitized solar cell based on a nitrogen-doped nanostructured titania electrode

A highly efficient dye-sensitized solar cell (DSC) was fabricated using a nanocrystalline nitrogen-doped titania electrode. The properties of the nitrogen-doped titania powder, film, and solar cell were investigated. The substitution of oxygen sites with nitrogen atoms in the titania structure was confirmed by X-ray photoemission spectroscopy (XPS). The UV-vis spectrum of the nitrogen-doped powder and film showed a visible light absorption in the wavelength range from 400 to 535 nm. An enhancement of the incident photon-to-current conversion efficiency (IPCE) in the range of 380-520 nm and 550-750 nm was observed. An 8% overall conversion efficiency has been achieved. The results of the stability test indicated that the solar cell fabricated by the nitrogen-doped titania exhibited great stability.     

Performance of ion-figured silicon carbide SUMER telescope mirror in the vacuum ultraviolet

Measured and theoretical encircled energy and small-angle scatter of the telescope mirror (SST) of the solar ultraviolet measurements of emitted radiation (SUMER) instrument are compared at the wavelength of 123.6 nm. Mirror performance modeling was accomplished with the Optical Surface Analysis Code software package. The modeling is based on measured mirror-surface figure error data and roughness characteristics covering all important spatial frequencies that affect imaging in the vacuum ultraviolet wavelength region. Mirror-surface errors were measured with a Zygo Mark IV interferometer, Bauer Model 200 Profiler, and WYKO Topo 2-D (two-dimensional) interferometer. Performance of the SST mirror, including encircled energy and small-angle scatter, was also directly measured. A good agreement is found between measured and theoretical encircled energy within 6 arcsec and small-angle scatter up to ~50 arcmin from the peak. The 80% encircled energy diameter of the SST mirror is ~1.9 arcsec, and the amount of scattered light drops to approximately 1.0 × 10(-10) of peak irradiance (normalized to 1 arcsec(2) in the focal plane) 50 arcmin from the peak. Vacuum ultraviolet performance of the mirror is degraded primarily by midfrequency errors.     

Simulation and experiment of packaging of the fibre Bragg grating sensors using brazing/soldering methods

Abstract

To manufacture fibre Bragg grating (FBG) transducer, finite element model simulation and experimental verification of packaging of the FBG by brazing/soldering were investigated. The packaging processes and their impacts on the wavelength change of FBG were analysed. Simulation results showed that the Bragg wavelength of packaged FBG shifted down a level of ~10 nm. For experimental verification, temperature sensitivity of the packaged FBG was enhanced about twice of the bare FBG, while its spectrum was well preserved. The Bragg wavelength was shifted down a level of ~10 nm which was in accordance with the simulation.     

Determination of Lean Burn Combustion Temperature Using Ultraviolet Emission

Measurements of the ultraviolet emission spectrum emitted from a lean burn premixed natural gas flame were taken over a range of flame temperatures using a fiber-optic/CCD spectrometer. Combustion temperatures were determined by two methods: by measuring the unburned oxygen in the exhaust and by calculating the temperature using the fuel and airflows. These temperatures were correlated to ratios composed of the integrated intensity of the long wavelength region of the OH band between 310 to 340 nm (ratio's numerator) and that between 305 and 310 nm (ratio's denominator). Average local combustor flame temperatures at the end of the combustion zone may then be determined by tracking these ratios during combustor operation. The sensitivity of these ratios yields a 0.8% change in the ratios every 20 degF with a precision of plusmn30 degF or plusmn1% at 3000 degF with 95 % confidence bounds demonstrating the feasibility of this technique for use as a potential control parameter for gas turbine combustors burning natural gas and air mixtures. This method is well suited for the low equivalence ratios (< 1) required to reduce NOx and CO emissions. Other methods using peak ratios of different emission bands exhibit nonlinearity, lower sensitivity and greater uncertainty.     

Solar-driven microbial photoelectrochemical cells with a nanowire photocathode

We report a self-biased, solar-driven microbial photoelectrochemical cell (solar MPC) that can produce sustainable energy through coupling the microbial catalysis of biodegradable organic matter with solar energy conversion. The solar MPC consists of a p-type cuprous oxide nanowire-arrayed photocathode and an electricigen (Shewanella oneidensis MR-1)-colonizing anode, which can harvest solar energy and bioenergy, respectively. The photocathode and bioanode are interfaced by matching the redox potentials of bacterial cells and the electronic bands of semiconductor nanowires. We successfully demonstrated substantial current generation of 200 μA from the MPC device based on the synergistic effect of the bioanode (projected area of 20 cm2) and photocathode (projected area of 4 cm2) at zero bias under white light illumination of 20 mW/cm2. We identified the transition of rate-limiting step from the photocathode to the bioanode with increasing light intensities. The solar MPC showed self-sustained operation for more than 50 h in batch-fed mode under continuous light illumination. The ability to tune the synergistic effect between microbial cells and semiconductor nanowire systems could open up new opportunities for microbial/nanoelectronic hybrid devices with unique applications in energy conversion, environmental protection, and biomedical research.     

One‐Step Fabrication of Unique Mesoporous NiO Hollow Sphere Film on FTO for High‐Performance P‐Type Dye‐Sensitized Solar Cells

P‐type dye sensitized solar cells (p‐DSCs) deliver much lower overall efficiency than their inverse model, n‐DSCs. However, they have fundamental and practical significance, in particular, their tandem structured solar cells with both p‐ and n‐photoelectrodes could offer great potential to significantly improve the efficiency of existing solar cells. A facile and environmentally friendly method is developed to directly one‐step grow hollow NiO spherical structures on fluorine‐doped tin oxide (FTO) substrate, in which a Ni²⁺ and polymer complex spherical structure is self‐constructed through a controlled solvent evaporation process, followed by calcination‐converting to a unique NiO hollow sphere film. The prepared material is further used as a photocathode in p‐type dye sensitized solar cells, resulting in 41% increase of an open‐circuit voltage and 18% enhancement of power conversion efficiency than NiO nanoparticles photocathode. The improved performance can be ascribed to suppressed charge recombination at the photocathode/electrolyte interface. This template‐free approach could be universally used to fabricate other nanostructured hollow spheres for a wide range of energy conversion applications such as electrochemical capacitors, chemical sensors, and electrochromic devices.     

Enhancing efficiency of crystalline silicon solar cells by the mixture of downshifting CaAlSiN3:Eu2+ and Y2O3:Eu3+ phosphors

Y₂O₃:Eu³⁺ (YO) phosphors which have high quantum yield in the range 200–280 nm are mixed with downshifting CaAlSiN₃:Eu²⁺ (CASN) phosphors to improve CASN’s low quantum yield in the wavelength range below 280 nm. The luminescence downshifting ethyl vinyl acetate films with the mixture of YO and CASN phosphors are fabricated and then used to package crystalline silicon solar cells. Experimental results show that the introduction of YO phosphors not only improves the external quantum efficiency of the solar cells in the range below 280 nm but also leads to the better absorption of the light in the range 280–500 nm due to the scattering by YO phosphors. The conversion efficiency of the solar cells with the mixed phosphors can be enhanced from 19.60 to 19.98% after packaging.

     

Visible and near-ultraviolet absorption spectrum of ice from transmission of solar radiation into snow

Snow is a scattering-dominated medium whose scattering is independent of wavelength at 350-600 nm. The attenuation of solar radiation in snow can be used to infer the spectral absorption coefficient of pure ice, by reference to a known value at 600 nm. The method is applied to clean Antarctic snow; the absorption minimum is at 390 nm, and the inferred absorption coefficient is lower than even the lowest values of the Antarctic Muon and Neutrino Detector Array (AMANDA) experiment on glacier ice: The absorption length is at least 700 m, by comparison with 240 m for AMANDA and 10 m from laboratory attenuation measurements.