共查询到19条相似文献,搜索用时 140 毫秒
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点蚀是不锈钢最有害的腐蚀形态之一,点蚀往往是应力腐蚀裂纹和腐蚀疲劳裂纹的起始部位。点蚀是一种腐蚀集中于表面的很小范围内,并深入到金属内部的腐蚀形态,一般形状为小孔状,其危害性比均匀腐蚀严重得多,会引起爆炸、火灾等事故。双相不锈钢兼有铁素体和奥氏体的特性,它将铁素体良好的强度、硬度和奥氏体优良的塑性和韧性结合起来,并具有优良的耐点蚀性能,无论是在力学性能上还是在耐腐蚀性上,双相不锈钢都明显优于铁素体不锈钢和奥氏体不锈钢,可以在点蚀环境中的特种设备上广泛使用。 相似文献
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采用化学浸泡法和模拟闭塞电池方法研究了固溶+时效和固溶+调整+时效处理的0Cr17Ni4Cu4Nb马氏体不锈钢的耐点腐蚀性能,并与18-8型奥氏体不锈钢(316L)耐点蚀性能进行了对比。结果表明,0Cr17Ni4Cu4Nb马氏体不锈钢组织内富Cu析出相促进了点蚀坑萌生,而点蚀坑发展则与组织形貌有关。固溶+调整+时效处理的0Cr17Ni4Cu4Nb马氏体不锈钢因组织内析出富Cu相多而大,其萌生的点蚀坑密度较高,但由于马氏体板条较细,其点蚀坑尺寸和深度较小;固溶+时效处理的0Cr17Ni4Cu4Nb马氏体不锈钢因组织内析出富Cu相少而小,萌生的点蚀坑密度较低,但粗大的板条马氏体组织导致点蚀坑尺寸和深度较大。与18-8型奥氏体不锈钢耐点蚀性能对比表明,通过对0Cr17Ni4Cu4Nb马氏体不锈钢进行合理的热处理,其耐点蚀性能可与18-8型奥氏体不锈钢相当。 相似文献
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含有奥氏体和铁素体的双相不锈钢用于化学加工工业和要求高强度和耐蚀性的其他用途,其屈服强度大约比奥氏体不锈钢高1倍,抗点蚀和抗应力腐蚀裂纹的能力优于316型不锈钢。由于成分和双相结构的关系,其制造和使用不同于奥氏体不锈钢。除了铬和钼的含量高以外还含有铁素体、这会促进σ相的形成。双相不锈钢和铁素体不锈钢都容易产生“475℃脆化”,这是奥氏体钢不曾有过的现象。许多不锈钢种都可能形成碳化物和金属间相但不形成σ相。双相不锈钢的等温处理可以产生各种各样的微量成分。大多数退火状态的锻压双相不锈钢,其 相似文献
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新型00Cr23Ni6Mo4Cu3铸造不锈钢的组织及其局部腐蚀行为 总被引:1,自引:0,他引:1
采用金相显微镜和x射线衍射仪进行了金相组织观察与分析,并采用快速模拟试验方法研究了新型00Cr23Ni6Mo4Cu3铸造不锈钢的局部腐蚀行为。结果表明,该钢经1050℃×2h的固溶处理,其组织为铁素体基体上分布有适量的奥氏体。该热处理使组织细化与均匀化。由于铁素体对奥氏体组织有电化学保护作用,因而这种新型双相不锈钢具有优良的耐晶间腐蚀性能和较高的抗点蚀性能,与高合金化的奥氏体C15钢相当。 相似文献
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316L不锈钢焊缝的点蚀行为 总被引:1,自引:0,他引:1
采用数显恒温水浴锅HH-4静态模拟点腐蚀的试验方法,研究316L奥氏体不锈钢焊缝在不同Cl^-浓度和温度下的三氯化铁溶液中点腐蚀行为,探讨不同的Cl^-浓度和温度变化对焊缝耐蚀性能的影响。结果表明:在三氯化铁溶液中,Cl^-浓度增加、温度升高,316L奥氏体不锈钢焊缝的耐点蚀性能下降,腐蚀速率增加,腐蚀后的表面形貌为不均匀点腐蚀。 相似文献
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目前产于高氮不锈钢的研究多集中于理论基础、制造工艺和力学性能等方面,有关耐蚀性方面的研究有限。通过循环极化、Mott-Schottky曲线以及电化学阻抗(EIS)等方法,研究了Cr23Mo1N奥氏体不锈钢(高氮钢,HNSS)和316L不锈钢在Cl-溶液中的耐点蚀性能。结果表明:与316L不锈钢相比,高氮钢具有更正的自腐蚀电位,更小的维钝电流密度。阻抗谱表明高氮钢的钝化膜比316L更加稳定,且电荷转移电阻更大。Mott-Schottky曲线表明高氮钢的点缺陷施主浓度比316L不锈钢低一个数量级,钝化膜的绝缘性更好。循环极化曲线表明高氮钢的点蚀敏感性更小,钝化膜的自修复能力更强,耐蚀性能更加优越。 相似文献
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Compatibility of ferritic and duplex stainless steels as implant materials: in vitro corrosion performance 总被引:2,自引:0,他引:2
The pitting corrosion, crevice corrosion and accelerated leaching of iron, chromium and nickel of super-ferritic and duplex stainless steels, and for effective comparison the presently used 316L stainless steel, have been studied in an artificial physiological solution (Hank's solution) by the potentiodynamic anodic polarization method. The results of the above studies have shown the new super-ferritic stainless steel to be immune to pitting and crevice corrosion attack. The pitting and crevice corrosion resistances of duplex stainless steel were found to be superior to those of the commonly used type 316L stainless steel implant materials. The accelerated leaching study conducted for the above alloys showed very little tendency for the leaching of metal ions when compared with 316L stainless steel. Thus the present study indicated that super-ferritic and duplex stainless steels can be adopted as implant materials due to their higher pitting and crevice corrosion resistance. 相似文献
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Welding of austenitic-ferritic stainless steels is a crucial operation and all the materials and parameters used in this process
must be optimized in order to obtain the suitable corrosion and mechanical properties. Since a great part of super duplex
stainless steels is used in very aggressive environment, their corrosion resistance, referred in particular to pitting and
crevice corrosion, is an all-important facet in production and processing of this type of steels. Pitting corrosion resistance
of super duplex stainless steels welded joints depends on several aspects: microstructure of the bead, elemental partitioning
between ferrite and austenite, and the possible presence of secondary phases. For these reasons, a post-weld annealing is
generally performed to homogenize the microstructure. The annealing temperature is the most important parameter to be optimized
in this heat treatment. In the present work, a comparison between the as-welded and solution-treated joints is carried out.
An effort has been made to correlate the main factors that affect pitting corrosion of the welded joints (microstructure,
secondary phases, chemical composition of single phases) with the experimental data obtained from corrosion tests. In this
first part of the work the results regarding microstructure and partitioning of elements are presented. The phase balance
and the austenite morphology are locally upset during submerged-arc welding of UNS S32750. In the fusion zone, the two phases
(ferrite and austenite) result to have approximately the same composition regarding Cr, Mo, and Ni content, while nitrogen
is heavily concentrated in austenite. After annealing treatment, the austenite volume fraction increases and the partitioning
ratios of elements reach the equilibrium values. The base material results to be less sensitive to annealing treatment than
the fusion zone, and the partitioning of elements in the base material is in agreement with previous works reported in the
literature. 相似文献
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Effect of annealing temperature on the pitting corrosion resistance of super duplex stainless steel UNS S32750 总被引:1,自引:0,他引:1
Hua Tan Yiming Jiang Bo Deng Tao Sun Juliang Xu Jin Li 《Materials Characterization》2009,60(9):1049-1054
The pitting corrosion resistance of commercial super duplex stainless steels SAF2507 (UNS S32750) annealed at seven different temperatures ranging from 1030 °C to 1200 °C for 2 h has been investigated by means of potentiostatic critical pitting temperature. The microstructural evolution and pit morphologies of the specimens were studied through optical/scanning electron microscope.Increasing annealing temperature from 1030 °C to 1080 °C elevates the critical pitting temperature, whereas continuing to increase the annealing temperature to 1200 °C decreases the critical pitting temperature. The specimens annealed at 1080 °C for 2 h exhibit the best pitting corrosion resistance with the highest critical pitting temperature. The pit morphologies show that the pit initiation sites transfer from austenite phase to ferrite phase as the annealing temperature increases. The aforementioned results can be explained by the variation of pitting resistance equivalent number of ferrite and austenite phase as the annealing temperature changes. 相似文献
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研究经1100℃等温处理2~20 h后022Cr25Ni7Mo4N双相不锈钢的显微组织演变。观察钢中奥氏体晶粒形态变化并对其尺寸进行定量表征,测量铁素体/奥氏体两相中的元素含量变化,并探讨组织演变对实验钢中铁素体相体积分数的各向异性和低温冲击韧性的影响。结果表明:随着保温时间的延长,奥氏体晶粒发生聚集、长大、粗化现象,并伴随显著的晶粒形态变化,a/b值≥4.0时细长棒状晶粒体积分数从近20%骤降至5%以下,a/b值介于1.0~1.9的等轴晶粒体积分数显著上升的同时,尺寸≥20μm的晶粒体积分数快速增加。保温时间的延长使得Mo,Cr元素进一步向铁素体相扩散、富集,并提高铁素体相抗点蚀当量(pitting resistance equivalent number,PREN)值。细长棒状奥氏体晶粒比例的显著下降,是奥氏体体积分数各向异性改善和实验钢低温冲击韧性提高的主要原因。 相似文献
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Alvarez K Hyun SK Fujimoto S Nakajima H 《Journal of materials science. Materials in medicine》2008,19(11):3385-3397
The corrosion behavior of three kinds of austenitic high nitrogen Lotus-type porous Ni-free stainless steels was examined in acellular simulated body fluid solutions and compared with type AISI 316L stainless steel. The corrosion resistance was evaluated by electrochemical techniques, the analysis of released metal ions was performed by inductively coupled plasma mass spectrometry (ICP-MS) and the cytotoxicity was investigated in a culture of murine osteoblasts cells. Total immunity to localized corrosion in simulated body fluid (SBF) solutions was exhibited by Lotus-type porous Ni-free stainless steels, while Lotus-type porous AISI 316L showed very low pitting corrosion resistance evidenced by pitting corrosion at a very low breakdown potential. Additionally, Lotus-type porous Ni-free stainless steels showed a quite low metal ion release in SBF solutions. Furthermore, cell culture studies showed that the fabricated materials were non-cytotoxic to mouse osteoblasts cell line. On the basis of these results, it can be concluded that the investigated alloys are biocompatible and corrosion resistant and a promising material for biomedical applications. 相似文献