共查询到19条相似文献,搜索用时 156 毫秒
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无机颗粒的共沉积机理 总被引:8,自引:0,他引:8
一概述所谓复合电沉积是指用电沉积的方法,使金属与无机颗粒、有机颗粒或金属颗粒共同沉积,以形成复合镀层的方法,运用复合电镀,可以获得许多具有特殊功能的复合镀层,诸如耐磨镀层、耐高温镀层、减摩镀层、耐磨自润滑镀层、高温耐磨镀层、高温自润滑镀层、耐腐蚀镀层、分散强化镀层、特殊装饰性彩色镀层等等,它们在机械工业、航空工业、汽车工业,以及电子工业与航天工业中有着被广泛使用的前景,可以胜任单金属镀层与合金镀层无法胜任的场合。因此,我们可以毫不夸张地说, 相似文献
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电沉积铜基自润滑复合材料的研究进展 总被引:2,自引:0,他引:2
从4个方面综述了复合电沉积工艺制备铜基自润滑材料的研究进展,包括固体润滑剂、复合电沉积工艺、摩擦性能和复合电沉积机理。常用的固体润滑剂主要有石墨、MoS2、WS2,、PFFE等。影响复合材料性能的主要因素有电流密度、微粒浓度、搅拌程度等。关于微粒和金属共沉积的内在规律存在不同的理论模型,主要有Guhlielmi模型、MTM模型、Valdes模型、运动轨迹模型和并联吸附模型。简单介绍了纳米复合镀层和复合电铸的发展概况与趋势。提出阴极和颗粒接触局部区域的细节将成为复合电沉积机理的研究重点。 相似文献
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我国复合镀层最新进展及应用 总被引:17,自引:0,他引:17
综述了我国近年来复合镀技术的进展及应用现状,包括耐磨耐蚀复合镀层,自润滑复合镀层,具有电接触功能的复合镀层及分散强化复合镀层等。并指出了复合镀技术在应用方面所面临的问题及其改进措施。 相似文献
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复合镀层由于具有优异的耐磨性、耐蚀性、自润滑等性能而受到广泛关注.采用电沉积或化学镀可以获得复合镀层,复合电镀也是制备复合材料的一种重要方法.本文主要对近几年国内外在镍基自润滑复合镀层方面取得的研究成果进行了概述. 相似文献
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针对Cu-Sn-Zn合金镀层自润滑性能差的缺点,在Cu-Sn-Zn合金镀液中加入聚四氟乙烯(PTFE)乳液,采用电沉积方法在45#钢表面制备了Cu-Sn-Zn-PTFE复合镀层。镀液组成和工艺条件为:焦磷酸铜24g/L,氯化锌12g/L,甲基磺酸锡15g/L,焦磷酸钾20g/L,酒石酸钾钠22g/L,全氟辛基磺酸钾18g/L,PTFE乳液32g/L,温度50~60℃,pH值11.5,电流密度1.2A/dm~2,搅拌转速300~600r/min,时间120min。考察了镀液中PTFE的质量浓度对镀层的耐磨性、显微硬度、结合力、PTFE的质量分数、外观的影响,并表征了Cu-Sn-Zn-PTFE复合镀层的表面形貌、结构和成分。随着镀液中PTFE的质量浓度的增加,镀层的耐磨性改善,显微硬度和结合力下降,PTFE的质量分数先增大然后保持不变。镀液中PTFE的最佳质量浓度为32g/L,在此条件下制得的Cu-Sn-Zn-PTFE复合镀层的综合性能最佳。 相似文献
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Lidia Benea 《Journal of Applied Electrochemistry》2009,39(10):1671-1681
With the objective of producing new functional surfaces with enhanced tribo-corrosion properties we have investigated the
electrochemical codeposition of composites in which an electrodeposited metal (nickel) is the matrix and a transition metal
oxide (ZrO2) is the dispersed phase. This paper describes the effect of ZrO2 dispersed particle codeposition on nickel electrocrystallisation steps as well as the tribocorrosion behaviour of the composite
coatings obtained. This system was selected because nickel is an industrially important coating material on steel and other
support materials. The cathodic polarization curves have been plotted both in the presence and absence of the insoluble dispersed
phase. Electrochemical impedance spectroscopy was used to obtain additional information on the early steps of nickel and nickel
matrix composite electrodeposition. Impedance data were acquired with a Solartron type electrochemical interface and frequency
response analyzer. A schematic codeposition mechanism is proposed. The influence of zirconium oxide on the nickel electrodeposition
steps is discussed. The tribocorrosion properties of ZrO2–Ni composite coatings (100 μm thickness) have been studied in 0.5 M K2SO4 solution on a pin on disc tribo-corrosimeter connected to an electrochemical cell. The normal force applied was 10 N at a
rotation speed of 120 rpm. The counterbody (pin) was a corrundum cylinder (7 mm in diameter), mounted vertically on a rotating
head, above the specimen. The lower spherical end (radius = 100 mm) of the pin was then applied against the composite surface
(disc). 相似文献
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Qian Xu Yong-lian Qiao Hui-jun Liu Wei-wei Meng 《Journal of Applied Electrochemistry》2009,39(12):2513-2519
Nickel coating on the carbon–polythene composite plate was prepared by electrodeposition in a nickel sulfate solution in this
work. The morphology and cross-sectional microstructure of the nickel coating were examined by scanning electron microscope
(SEM) and optical microscope (OM), respectively. The influence of bath temperature on the nickel deposition rate was investigated
experimentally. The adhesion between the coating and the substrate was evaluated by the pull-off test. The corrosion behavior
of the coating in an aqueous solution of NaCl was studied by electrochemical methods. The results showed that the nickel electrodeposition
rate could reach up to 0.68 μm min−1 on average under conditions of cathodic current density of 20 mA cm−2 and bath temperature of 60 °C. It was confirmed that increasing the bath temperature up to 50 °C had a positive effect on
the nickel deposit rate, while an adverse effect was observed beyond 60 °C. The adhesion strength between the nickel coating
and the substrate can be more than 2.3 MPa. The corrosion potential of the bright coating in the NaCl solution was more positive
than that of the dull coating, and the anodic dissolution rate of the bright coating was also far lower at the same polarization
potential compared with the dull coating. 相似文献
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The electrochemical corrosion behavior of sealed Ni–TiO2 composite coating for sintered NdFeB magnet
Xiao-kui Yang Qing Li Jun-ying Hu Xian-kang Zhong Shi-yan Zhang 《Journal of Applied Electrochemistry》2010,40(1):39-47
In this article, a protective sealed Ni–TiO2 composite coating (SCC) was prepared on sintered NdFeB magnet by pulse current electrodeposition and sol–gel combined technique. For a comparison, unsealed Ni–TiO2 composite coating (UCC) was also studied. The surface morphologies of composite coating were studied using scanning electron microscope (SEM). The structure of sealing layer was studied by Fourier transform infrared (FT-IR) spectrum. The anticorrosive properties of composite coating in neutral 3.5 wt% NaCl solution were evaluated by potentiodynamic polarization measurements and electrochemical impedance spectroscopy (EIS). In order to further investigate the anticorrosive properties of SCC, a long-term immersion test was carried out in neutral 3.5 wt% NaCl solution. The results of corrosion tests showed that due to the blocking effect of sealing layer, SCC can suppress the corrosion process by holding back the transfer or diffusion of corrosive medium, and therefore showed the excellent anticorrosive properties for sintered NdFeB magnet. 相似文献
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近年来辐射固化材料的研究进展 总被引:11,自引:3,他引:8
综述了光化学、光自由基聚合、光引发剂UV固化、UV固化剂、电沉积光敏抗蚀剂和涂料、UV水基和粉末涂料及UV固化纳米复合材料的研究进展。 相似文献