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钨硅杂多酸催化合成邻苯二甲酸二壬酯的研究 总被引:4,自引:0,他引:4
用钨硅杂多酸作催化剂,对DNP的合成方法进行了研究,结果表明,用杂多酸催化酯化反应,具有反应时间短、温度低、活性和选择性高、无环境污染等优点,而且催化剂可以重复使用。 相似文献
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由硅钨杂多酸(HSIW)为催化剂,以硬脂酸与甲醇为原料催化合成硬脂酸甲酯,研究了催化剂的用量,酯化反应时间、酸醇摩尔比对酯化反应的影响,催化剂能使用多次催化效果的较好。 相似文献
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杂多酸催化合成肉桂酸正丁酯的研究 总被引:4,自引:0,他引:4
以钨硅杂多酸为催化剂,通过肉桂酸和正丁醇反应合成肉桂酸正丁酯.实验证明,钨硅杂多酸是合成肉桂酸正丁酯的良好催化剂,在酸醇物质的量比为1:2.0,催化剂用量1.0g/0.05mol肉桂酸,带水剂苯8ml,反应时间为110min条件下,肉桂酸正丁酯的酯化率可达96%. 相似文献
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研究了硅钨杂多酸对水杨酸正丁酯合成的催化性能,得出的最佳工艺条件为:n(水杨酸):n(正丁醇)=1:2、正丁醇为带水剂,催化剂硅钨杂多酸1.5g,回流反应4h,收率可达94.6%,并证明了硅钨酸为该反应良好的催化剂,具有催化活性高,化学稳定性好,重复使用性能佳,无三废排放等优点。 相似文献
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综述了杂多酸及其盐在合成芳酮的Friedel-Crafts(F-C)酰化反应和Fries重排中的应用,并与其它类型的催化剂作了比较。结果表明,杂多酸(盐)是一类性能优良的合成芳酮的催化剂,其催化性能优于沸石、分子筛等固体酸催化剂。 相似文献
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以钨硅杂多酸为催化剂,异戊酸和己醇为原料,通过酯化反应合成异戊酸己酯,对酯化反应的影响因素进行了研究,结果表明,在醇酸物质的量比为1.8:1,催化剂用量1.5%,反应时间2h的条件下,酯化率可达98%。 相似文献
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以纳米复合杂多酸为催化剂,通过马来酸和正辛醇反应合成马来酸二辛酯,探索了各种因素对酯化率的影响。实验结果表明,纳米复合杂多酸是合成马来酸二辛酯的良好催化剂,在物料比n(马来酸):n(正辛醇)=1:3、催化剂用量为反应物总质量的3%(马来酸为0.05mol)、苯10mL、反应1h的条件下,酯化率可达98.4%。 相似文献
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杂多酸催化合成己二酸二辛酯 总被引:10,自引:0,他引:10
本文介绍了以杂多酸为催化剂合成己二酸二辛酯的实验方法和结果,考察了催化剂用量、带水剂用量及酸醇比对己二醇与正辛醇酯化反应的影响,提出了反应最佳条件,实验结果表明,杂多酸催化合成己二酸二辛酯,具有活性高,选择性好,产品质量好的优点。 相似文献
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增塑剂在塑料的各种助剂中占有重要地位,采用固体超强酸代替浓硫酸催化合成增塑剂克服了传统方法中采用浓硫酸的许多缺点,将有很大的前景,本文对目前已经采用固体超强酸催化合成增塑剂的应用进行了总结. 相似文献
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环氧植物油基增塑剂的合成工艺进展 总被引:1,自引:0,他引:1
环氧植物油(EPO)是一类优良的环保型增塑剂。以合成方法和催化剂为线索,综述了近年来国内外EPO合成工艺的最新进展。同时,对现有的催化体系以及合成工艺进行了简要的分析,并指出了开发新型、高效、绿色且廉价的催化体系,仍将是今后EPO合成领域的研究方向。 相似文献
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脂肪族二元酸酯类耐寒性增塑剂催化合成的研究进展 总被引:1,自引:0,他引:1
简要介绍了脂肪族二元酸酯类耐寒性增塑剂的用途,综述了脂肪族二元酸酯类耐寒性增塑剂的催化合成研究进展,并对各类催化剂的优缺点进行了简评。 相似文献
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简要介绍了国内外苯甲酸酯类增塑剂的研究、生产和应用情况,着重阐述了该增塑剂的分类、特点、主要原材料、合成工艺及其在聚氨酯中的应用,说明这是一类多功能的增塑剂。 相似文献
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The aliphatic energetic plasticizers with three and four –CH2 between nitrate ester and nitramine were synthesized to obtain a plasticizer that is more stable than N-butyl-N-nitratoethyl nitramine (BuNENA) with two –CH2. First, amino alcohol compounds such as propylamino propanol (PAP) and ethylamino butanol (EAB) as a precursor of energetic plasticizer were synthesized. However, unlike in BuNENA synthesis, various side reactions occurred in the nitration of amino alcohols. Fortunately, it was possible to considerably suppress the formation of side products in the nitration of PAP by using a solvent and an appropriate concentration of nitric acid. In addition, an energetic plasticizer with higher oxygen content was obtained through the nitration of intermediate, amide alcohol, which was formed in the synthesis of EAB. 相似文献
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Ester‐amide based on ricinoleic acid as a novel primary plasticizer for poly(vinyl chloride)
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Utilization of ricinoleic acid as a raw material for the synthesis of green plasticizer would offer an alternative to the phthalate plasticizers. Ester‐amide of ricinoleic acid was synthesized by a two‐step reaction with dibutyl amine and benzoic acid; and then utilized as primary plasticizer in PVC. Ester‐amide plasticizer was added up to 40 phr in PVC; and the prepared PVC sheets were characterized for mechanical, X‐ray diffraction, thermal, rheological, colorimetric, and exudation properties. Addition of the ester‐amide plasticizer demonstrated good incorporation and plasticizing performance in PVC. Viscosity of PVC decreased with increased addition of ester‐amide plasticizer. The dark color of the synthesized plasticizer could have constraints on its application areas; however, the prepared samples illustrated negligible weight loss in the exudation test, attributed to better compatibility between them brought about by the ester, tertiary amide and polarizable benzene ring in the ester‐amide plasticizer with the C‐Cl polar linkage in PVC. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41913. 相似文献
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M. T. Rodríguez S. J. García R. Cabello J. J. Suay J. J. Gracenea 《Journal of Coatings Technology and Research》2005,2(7):557-564
The influence of the glass transition temperature and the mechanical and anticorrosion properties of factors such as the amount
of plasticizer added to an epoxy primer were investigated by DSC (differential scanning calorimeter), DMA (dynamic mechanical
analysis), stress-strain tests, salt fog spray tests, accelerated tests, and electrochemical tests.
The addition of plasticizer results in a decrease in the glass transition temperature and a change in the mechanical properties.
Different tests were carried out to the optimum percentage of plasticizer content (1.5–3% weight ratio to epoxy resin) required
to obtain the maximum anticorrosion performance of the epoxy primer. These changes are explained by the structural-kinetic
effect exerted by the plasticizer on the chemical crosslinking in the course of the epoxy network synthesis and the increase
in the excess free volume. 相似文献