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Hidemi Nawafune Takashi Uegaki Shozo Mizumoto Masami Ishikawa Tsuneshi Nakamura 《金属精饰学会汇刊》2013,91(6):231-234
Studies have been made of an electroless copper-nickel-phosphorus alloy from a citrate complex bath using hypophosphite as reducing agent and electroless copper-nickel binary alloy from a triethanolamine complex bath using formaldehyde as reducing agent. With an increase in copper content of alloy, the specific resistance of deposit decreased. The TCR of copper-nickel-phosphorus alloy increased remarkably because of the crystallization of Ni3P after heat treatment. But the increase in TCR of copper-nickel binary alloy was moderate and not so striking as for the phosphorus containing alloy. 相似文献
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Preparation of thin film resistors with low resistivity and low TCR by heat treatment of multilayered Cu/Ni deposits 总被引:2,自引:0,他引:2
Masami Ishikawa Hidehiko Enomoto Naohiro Mikamoto Tsuneshi Nakamura Masao Matsuoka Chiaki Iwakura 《Surface & coatings technology》1998,110(3):478-127
Thin Cu–Ni alloy film resistors were prepared by different methods using both electroless plating and electrodeposition. Alloy composition, structure and electrical properties (resistivity and TCR) were examined as a function of plating conditions. Low resistivity and low TCR performance were achieved by heating the multilayered Cu/Ni film deposited on electroless Cu. 相似文献
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低温熔盐中电沉积制备La-Mg-Ni三元合金膜及其性能研究 总被引:1,自引:0,他引:1
采用恒电位法在乙酰胺-尿素-NaBr-KBr熔体中电沉积出La-Mg-Ni三元合金膜。用扫描电镜(SEM)、X射线衍射(XRD)等方法研究了沉积层的表面形貌和结构,用Tafel极化曲线和交流阻抗(EIS)方法研究了合金薄膜的电化学性能。结果表明,随着阴极电位负移的增大,表面更平整,储氢性能更好。当沉积电位为-1.0V时,沉积层表面的表观活化自由能最小(△G≠=22.35kJ.mol-1),说明具有很高的析氢活性。在EIS中的吸附程度Q为7.98μF.cm-2,表明具有很高的储氢能力。 相似文献
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目的研究混合修饰构筑白铜超疏水表面的可行性及防腐性能。方法以白铜为基体,采用简单的化学刻蚀法,以硝酸银溶液作为刻蚀液,经肉豆蔻酸和十二硫醇的混合乙醇溶液修饰来制备超疏水白铜。采用接触角测量仪、XRD、FTIR、SEM、EDS对超疏水白铜表面性能和结构等进行了表征,并利用Tafel曲线和电化学阻抗谱研究低表面能复合膜的耐蚀性能。结果肉豆蔻酸和十二硫醇的疏水长链都组装到薄银层表面,其中肉豆蔻酸和薄银层的键合形式为双齿桥式复合模式,超疏水白铜表面形貌由微米级枝晶和纳米级乳突状结构组成,同时材料表面与水的接触角达到157.4°,表现出超疏水水平。此外,制备的超疏水白铜表面具有良好的化学稳定性和耐腐蚀性能,在水、有机溶液、3.5%Na Cl溶液中分别浸泡2 d,所有样品表面仍表现为超疏水水平。由Tafel极化曲线拟合参数计算可知,其缓蚀效率达到83.9%。结论以两种低表面能物质混合修饰来制备超疏水白铜表面的方法是可行且有效的,且该复合膜具有优良的耐腐蚀性能。 相似文献
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LIGaoren TONGYexiang LIUGuankun 《稀有金属(英文版)》2004,23(1):43-47
The cyclic voltammetry and potentiostatic electrolysis were used to investigate the preparing of Dy-Bi alloy films in LiCl-DMSO (dimethylsuffoxide) system. The effects of several factors including the potential of deposition, concentra-tions of main salts, and the concentration ratio of DyCl3 to Bi(NO3)3 were studied. Dy-Bi alloy films containing 4.82%-80.62% (mass fraction) dysprosium were prepared in DyCl3-Bi(NO3)3-LiCl-DMSO system by controlling the sys-tem composition and deposition conditions. The films are gray, uniform, metallic luster and adhere firmly to the copper sub-strates analyzed by SEM (scanning electron microscope), EDS (X-ray energy dispersive analysis), and XRD (X-ray diffrac-tion). After heat treatment at 718 K for 1 h, the alloy phase of Dy-Bi was found in XRD patterns. 相似文献
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钢含碳量对低温盐浴渗铬层的影响 总被引:2,自引:3,他引:2
通过 Q2 35钢、45钢、T1 0钢低温盐浴渗铬层的金相组织、相结构、厚度、铬浓度、显微硬度和耐蚀性的对比 ,表明碳含量越高 ,铬碳化合物层越厚 ,显微硬度越高 ,耐蚀性越好。 相似文献
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为了提高铝合金的耐蚀性能,采用阳极氧化法在铝表面制备多孔阳极氧化膜,并以阳极氧化膜为骨架,用原位生长法在其表面构筑具有层状双金属结构的镁铝水滑石(Mg Al-LDH)。首次利用缓蚀剂二苄基二硫代氨基甲酸锌(ZBEC)对制备的Mg Al-LDH膜层进行改性,通过SEM、EDS、XPS、FT-IR研究了改性Mg Al-LDH膜层的形貌、成分,通过电化学阻抗谱(EIS)技术研究了ZBEC浓度、改性温度、改性时间对改性膜层耐腐蚀性能的影响。结果表明,水滑石膜层呈垂直于基体表面的片状交错结构,ZBEC分子可以成功地与Mg Al-LDH膜层进行结合。当ZBEC溶液的浓度为0.03 mol/L、温度为45℃、时间为15 min时,改性前后膜层的EIS低频模值由7.94×105Ω·cm2增加到1.995×106Ω·cm2,说明ZBEC改性提高了Mg Al-LDH膜层的耐蚀性能。 相似文献
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Bin Li Shen-Gen Zhang Kun Zhang De-An Pan Jian-Jun Tian Hu Liu Alex A. Volinsky 《稀有金属(英文版)》2014,33(5):598-603
In this study, Pb was separated and used to prepare BaPbO3 conductive ceramics from leaded waste.The experimental results show that BaPbO3 powder synthesized at 700 °C has particle size of 2–5 lm. The powders were densified by sintering at 1,000 °C for 2 h in the air.Synthesized BaPbO3 ceramics have high Curie temperature and high-temperature positive temperature coefficient(PTC) resistivity characteristics. Electrical resistivity of BaPbO3 compact increases from 5 × 10^-6Ω·m at room temperature to 4 × 10^-4Ω·m at 750 °C. Compared with the one prepared by pure chemical reagents, the BaPbO3 prepared from leaded waste has the similar characteristics of high Curie temperature and PTC resistivity. 相似文献
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Mg alloy, AZ91D, which has a two-phase structure, was successfully electroplated in an alkaline Cu-plating bath. The Cu-coated Mg alloy specimen was further electroplated in eco-friendly acidic Cu and then trivalent Cr baths to obtain an anti-wear and anti-corrosion Cr/Cu coating. Experimental results show that the wear and corrosion resistance of the Mg alloy specimen was considerably improved by trivalent Cr electrodeposition. The hardness of the as-plated Cr deposit was drastically increased by using reduction-flame heating for 0.5 s. The above-mentioned results were measured via bonding strength, hardness, wear and corrosion tests. A superior wear and corrosion resistance was obtained when a Cu-coated Mg alloy specimen was electroplated with a trivalent Cr deposit, followed by heating with reduction-flame heating for 0.5 s. 相似文献
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镀液温度对AZ31镁合金表面锌钙系磷酸盐转化膜耐蚀性的影响 总被引:1,自引:0,他引:1
采用化学沉积方法在AZ31镁合金表面制备锌钙系磷酸盐转化膜。利用扫描电子显微镜(SEM)和电化学方法研究镀液温度对镁合金AZ31表面磷酸盐转化膜表面形貌及其耐蚀性能的影响。利用电子能谱仪(EDS)、光电子能谱(XPS)和X射线衍射仪(XRD)分析膜层化学成分、相结构。研究表明:当温度为50℃时,转化膜层晶粒均匀、完整,耐蚀性较好;膜层化学成分主要由O、P、Zn和Mg元素以及微量Ca组成,主要相组成为Zn3(PO4)2·4H2O;锌钙磷酸盐转化膜比磷酸锌转化膜具有更小的晶粒和更好的耐蚀性。 相似文献
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电阻应变计是将被测构件的应变量转换为电阻变化的测试单元,是发动机涡轮叶片应力/应变分析监测的有效手段,而电阻应变敏感栅材料是电阻应变计的关键材料。随着发动机推重比不断增大,涡轮前温度越来越高,要求敏感栅材料的工作温度也越来越高。本文阐述了高温电阻应变材料的发展现状,重点介绍贵金属钯基合金、铂基合金电阻应变材料的成分设计、组织与性能、使用温度等特性。其中PtWReNiCr(Y)合金已经成功应用到1000 ℃动态应变测试;PtRhWZr(Y)可以用于1138 ℃的动态应变测试;PtRhMoWZr(Y)可望用于1150 ℃的动态应变测试,工作温度比传统的电阻应变合金Pt-8W提高了近350 ℃。最后介绍了使用温度更高的金属氧化物应变计的研究现状。 相似文献
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利用电刷镀技术在铝合金表面制备了稀土铈转化膜,得到的稀土膜层厚度均匀,呈层状结构,与基体结合良好,在NaCl溶液中具有良好的耐蚀性。研究了刷镀电压和铈盐浓度对膜层耐蚀性的影响,得到在7 V电压和20 g/L铈盐浓度下制备的膜层具有良好耐蚀性能,经过480 h盐雾试验后,其表面耐蚀性评价达到8级以上,镀膜试样与原始LY12铝合金试样相比,腐蚀电流密度降低一个数量级,低频阻抗值则增大约30倍。该铝合金表面稀土转化膜电刷沉积溶液中不含强氧化剂,因此溶液长时间稳定且便于循环利用,可以对铝合金表面进行现场大面积常温刷镀,提高耐蚀性。 相似文献
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目的 发现最优工艺条件,了解Zn-Ni电沉积机理。方法 通过场发射电镜分析、能谱分析以及电化学分析等方法,研究以一种胺羧多官能团配体为Ni2+络合剂的碱性锌酸盐电解液体系中,锌/镍离子物质的量之比与锌镍离子总浓度对镀层的光泽度、镍含量、耐蚀性、表观质量和微观结构的影响。结果 锌/镍离子物质的量之比增加会使得镀层镍含量降低,最后稳定在15%~19%,镀层微观结构由晶粒细致平滑型转化为粗大疏松型。物质的量之比为1.9时,镀层的腐蚀电流最小。锌镍离子总浓度增加会使得镀层镍含量缓慢减小,镀层微观结构由晶粒细致疏松型转化为细致紧密型,最后又转变为粗大疏松型,镀层的腐蚀电流先减小后急剧增大,即镀层的耐蚀性先增加后急剧降低。结论 在锌/镍离子物质的量之比为1.9、锌镍离子总浓度为0.12 mol/L时,所得镀层的综合性能最好。镀层锌/镍含量变化趋势符合Brenner吸附膜理论。 相似文献
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通过化学镀镍、水热法和浸泡法在AZ31镁合金上制备出Ni-P/NiO超疏水表面。首先通过化学镀镍的方法,在镁合金表面形成了一个Ni-P隔离层,有效地阻止外界与镁合金基底的接触,然后在Ni-P之上构筑NiO粗糙结构并对其表面进行疏水修饰,进一步对镁合金基底进行保护。通过电化学阻抗分析得出,其阻抗模值可达1×108 Ω·cm2,比未经处理的镁合金高出6个数量级,腐蚀电流密度降低到0.587 μA·cm-2,表明制备出的Ni-P/NiO超疏水表面具有优良的耐腐蚀性能。 相似文献
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采用拉伸性能及电导率测试、透射电镜观察、低应变拉伸试验等手段 ,研究了不同时效工艺对低频电磁铸造Al Zn Mg Cu合金组织和性能的影响。发现合金的T6态峰值时效制度为 12 0℃× 4 8h ,T6处理可使合金强度达到峰值 ,但抗应力腐蚀性能差 ;T73处理后合金强度下降了 5 %~ 6 % ,抗应力腐蚀性能大幅度提高 ;而RRA时效 (回归再时效 )处理基本保持了T6态的强度 ,且抗应力腐蚀性能接近T73态。微观组织分析表明 ,不同时效制度下合金性能的差异主要是由晶内和晶界析出相的大小、形貌及其分布状态决定的。T73和RRA时效处理改善了合金晶界特性 ,有助于阻止氢脆、减缓晶界阳极溶解速度 ,提高合金的抗应力腐蚀能力 相似文献