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疏水化水溶性两性纤维素接枝共聚物CGAO的合成及其水溶液的粘度 … 总被引:1,自引:0,他引:1
通过丙烯酸胺及甲基丙烯酰氧乙基二甲基辛基溴化铵与羧甲基纤维素钠进行接枝共聚制备疏水化水溶性两性纤维素接枝共聚物。用红外光谱与元素分析对CGAO的组成进行分析。考察了CAGO的组成,浓度及无机盐对其水溶液粘度行为的影响。 相似文献
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以BPO为引发剂合成丙烯酸乙酯丙丙烯酰胺二元共聚物,对其进行了溶解性能和提纯方法的研究,结果发现,当丙烯酸乙烯烯酰胺以3:7投料时,所得共聚物即可水溶。 相似文献
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AM-AA-ADMOAB共聚物的合成及其水溶液的黏度性能 总被引:2,自引:0,他引:2
通过丙烯酰胺 (AM)、丙烯酸 (AA)与甲基丙烯酰氧乙基二甲基辛基溴化铵 (ADMOAB)共聚 ,合成了疏水化水溶性共聚物 (HAPAM)。考察了HAPAM的组成、质量浓度及无机盐对其水溶液黏度行为的影响。发现组成对黏度有直接影响 ,水溶液黏度随共聚物的质量浓度增加而增大并存在临界缔合质量浓度 ρ ,ρ 与其组成紧密相关。结果表明 :由于在聚合物中引入了疏水结构及两性离子结构 ,这类聚合物表现出较好的抗盐性能 相似文献
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ZG-93丙烯酸共聚物阻垢分散剂的研制及阻垢机理探讨 总被引:6,自引:0,他引:6
本文采用带官能团的丙烯酸、丙烯酸酯、AGp-1、顺丁烯二酸酐为反应单体,水为溶剂,合成、制备出一种四元水溶性共聚物──ZG-93阻垢分散剂。并用静态沉淀法,研究了ZG-93在不同时间、温度、钙离子浓度、pH值、阻垢剂用量条件下,对CaCO3、Ca3(PO4)2、CaSO4垢粒的阻垢效果以及对铁红的分散作用。文中还从ZG-93分子结构、低剂量效应、晶格畸变作用以及分散作用方面对其阻垢机理进行了探讨。 相似文献
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Ch. Schaller T. Schauer K. Dirnberger C. D. Eisenbach 《Progress in Organic Coatings》1999,35(1-4):63-67
Some aspects of the molecular design of pigment stabilizers are discussed. The approach of employing copolymers with pigment-affine segments and matrix-affine segments will be particularly addressed. First experimental results obtained with amphiphilic block copolymers and amphiphilic graft copolymers with similar overall composition with regard to polar and relatively non-polar blocks of, e.g. polar backbone and relatively non-polar grafts will be presented. The comparison between the poly(acrylic acid)-polystyrene block copolymer and the graft copolymer with poly(acrylic acid) backbone and polystyrene grafts showed a similar stabilization of TiO2 in water. 相似文献
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采用接枝共聚方法,合成了高密度聚乙烯与马来酸酐,甲基丙烯酸和丙烯酸丁酯的接枝共聚物增容剂,研究了增容剂中接枝单体的种类及含量和增容剂用量等因素对高密度聚乙烯/尼龙1010共混体系力学性能的影响,结果表明在不同类型的接枝共聚物中以聚乙烯马来酸酐接枝共聚物对HDPE/PA1010共混体系的增容效果最好,在接枝单体含量和增容剂用量分别为4%-6%和5%左右时,共混体系的力学性能最好。 相似文献
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Phase diagrams of a series of copolymers of acrylonitrile (AN) and acrylic acid (AAc) were constructed using linearized cloud point correlation. The miscibility region in the phase diagram was found to increase with the increase in AAc content of the copolymers. For various compositions, χ13 (polymer–water interaction parameter) values were estimated by sorption experiment. As the hydrophilic nature of the polymer increased with the increase in the content of acrylic acid, the χ13 interaction parameter was found to decrease from poly(acrylonitrile) homopolymer to its copolymer with 50 mol % acrylic acid (AA50B). The polymer–solvent interaction parameters (χ23) and composition at the critical points for all the polymers were determined by fitting the theoretical bimodal curves to the experimental cloud point curves using Kenji Kamide equations. The polymer composition at the critical point was found to increase by 400% with increasing AAc content. The polymers were solution spun in DMF‐water coagulation bath at 30°C and their protofiber structures were investigated under scanning electron microscopy. The observed morphological differences in protofibers were explained on the changes brought about in the phase separation behavior of the polymer–solvent–nonsolvent systems. The copolymers with higher acrylic acid content could be solution spun into void free homogeneous fibers even at conditions that produced void‐filled inhomogeneous fibers in poly(acrylonitrile) and its copolymers with lower AAc content. The experiments demonstrate the important role of thermodynamics in deciding the protofiber morphology during coagulation process. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
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Acrylic acid is often used to make water‐soluble polymers while styrene is often modified to add special functions to polymers. However, when styrene and acrylic acid are copolymerized, the resulting polymer is much less water soluble. To regain water solubility, the effect of styrene sulfonic acid on solubility of poly(acrylic acid‐co‐styrene) copolymers was investigated. Even though acrylic acid polymers are known for their water solubility, the presence of styrene units within acrylic acid copolymers reduces the solubility of the copolymer substantially at the natural pH of the solutions. By adding styrene sulfonic acid as a termonomer, polymers that are water soluble at the natural pH of the polymerization could be obtained. The solubility of the polymer after removal of the solvent and by redissolving at different concentrations and pH levels is also reported. Solubility increases at higher pH especially with low styrene concentration in the copolymer. It was found that incorporation of as little as 5 mol % of styrene into poly(acrylic acid) reduced the aqueous solubility to less than 0.5 g dL?1 at pH 7. Upon adding 7 mol % styrene sulfonic acid as a termonomer, the water solubility increased to 5 g dL?1 at pH 7. At higher levels of styrene, more styrene sulfonic acid was needed, especially at low pH. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
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共聚物阻垢分散剂中官能团对硫酸钙阻垢协同作用研究 总被引:1,自引:0,他引:1
以水为溶剂,过硫酸胺为引发剂,丙烯酸、异丙烯膦酸、丙烯酰胺为单体,分别合成了低分子量的丙烯酸/丙烯酰胺、异丙烯膦酸/丙烯酰胺二元共聚物,以及不同配比的丙烯酸/异丙烯膦酸/丙烯酰胺三元共聚物.用红外光谱对产物进行了表征。研究了在相同条件下,所舍相同基团的共聚物阻垢剂与复配型阻垢剂对硫酸钙的阻垢性能,以及不同组成的共聚物阻垢剂对硫酸钙的阻垢性能。用扫描电镜观察了共聚物阻垢剂与复配型阻垢剂对硫酸钙结晶形态的影响。结果表明,同一分子链上的基团间具有较好的阻垢协同效应,且基团组成不同,其阻垢协同效应也不同。 相似文献
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Bruno S. Fernandes José Carlos Pinto Elaine C.M. Cabral‐Albuquerque Rosana L. Fialho 《Polymer Engineering and Science》2015,55(6):1219-1229
The main objective of the present study is to produce copolymers of urea, acrylic acid, and glycerol through aqueous solution free‐radical polymerizations and analyze the structural, thermal, rheological, and release properties of the obtained materials. To do this, aqueous solution copolymerizations were performed in different reaction conditions and the obtained copolymers were characterized by Fourier transform infrared spectroscopy, differential scanning calorimetry, rheological analyses, thermogravimetry, gel permeation chromatography, and rates of urea release in distilled water. The obtained results indicate that all constituents of the reacting mixture (potassium persulfate, glycerol, urea, and acrylic acid) affect the characteristics of the produced copolymers. In particular, it is shown that urea can be incorporated into the final copolymer through the proposed reaction scheme, that glycerol promotes crosslinking of polymer chains and that the obtained copolymer materials can be used in agricultural applications. POLYM. ENG. SCI., 55:1219–1229, 2015. © 2015 Society of Plastics Engineers 相似文献
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Copolymers of styrene, divinylbenzene, and acrylic acid that have undergone sulfonation exhibited good water absorbency properties. Removal of the lower molecular weight fraction in the surface region of the copolymer particles by toluene extraction before sulfonation has further increased the water swelling capacity of the sulfonated copolymers. The extent of swelling of the UV‐irradiated copolymer could be related to the ratio of divinylbenzene to styrene. The less crosslinked copolymers were shown to absorb more water. The incorporation of more carboxylate groups in the copolymer could further increase its swelling capacity. Without UV irradiation, the carboxylate containing copolymer was found to absorb more water than the sulfonated copolymer. UV irradiation has induced more effective crosslinking in the carboxylate containing copolymer, hence impairing its water absorbency. By replacing styrene and divinylbenzene partially with butyl acrylate, whereby the amount of crosslinking was reduced, the copolymer was able to absorb water 110 times of its dry weight. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
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Louise Hespel Elise Kaifas Laurence Lecamp Luc Picton Gaëlle Morandi Fabrice Burel 《Polymer》2012,53(20):4344-4352
This paper reports the synthesis of an amphiphilic copolymer from linseed oils and its successive auto-association in water into pH-sensitive micelles. An original ATRP lipoinitiator is first designed from linseed oil in two steps. tert-butyl acrylate (tBA) polymerization is consequently initiated from this original initiator and amphiphilic copolymers are obtained after subsequent acidolysis of the PtBA block into poly(acrylic acid) (PAA). The ability of a lipid-b-PAA copolymer to auto-associate in water is finally investigated through different techniques (Fluorescence, Surface Tension, QELS). This copolymer forms well-defined micelles in acidic media with a low critical micellar concentration (cmc) of 7.6 mg L?1 and dissociates when the pH is raised above 7. 相似文献
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Polysiloxane‐containing copolymers were synthesized and characterized by nuclear magnetic resonance and elemental analysis. These copolymers were neutralized by triethylamine. The copolymers could be self‐emulsified to form emulsions in water with and without cosolvent PCS and exhibited excellent defoaming abilities. These copolymers were also used as emulsifiers to emulsify silicone oil in water to form stable oil‐in‐water emulsions. This emulsion again exhibited defoaming properties, more efficiently than that of the self‐emulsified emulsion of siliconized acrylic copolymer (SAA). © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 71: 805–811, 1999 相似文献
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马来酸乙二醇酯、丙烯酸共聚物合成与在水质稳定上的应用研究 总被引:5,自引:0,他引:5
合成了马来酸与乙二醇的酯化物。用该酯化物与丙烯酸二元共聚,及用该酯化物、丙烯酸、马来酸酐三元共聚,得到了两种共聚物。讨论了二元共聚物的特性粘数与单体用量的关系,并测定了二元共聚物及三元共聚物对Ca2+的螯合能力。 相似文献