High temperature phase stabilities and electrochemical properties of InBaCo4−xZnxO7 cathodes for intermediate temperature solid oxide fuel cells

InBaCo_4−xZn_xO₇ oxides have been synthesized and characterized as cathode materials for intermediate temperature solid oxide fuel cells (IT-SOFC). The effect of Zn substitution for Co on the structure, phase stability, thermal expansion, and electrochemical properties of the InBaCo_4−xZn_xO₇ has been investigated. The increase in the Zn content from x = 1 to 1.5 improves the high temperature phase stability at 600 °C and 700 °C for 100 h, and chemical stability against a Gd_0.2Ce_0.8O_1.9 (GDC) electrolyte. Thermal expansion coefficient (TEC) values of the InBaCo_4−xZn_xO₇ (x = 1, 1.5, 2) specimens were determined to be 8.6 × 10⁻⁶ to 9.6 × 10⁻⁶/°C in the range of 80–900 °C, which provides good thermal expansion compatibility with the standard SOFC electrolyte materials. The InBaCo_4−xZn_xO₇ + GDC (50:50 wt.%) composite cathodes exhibit improved cathode performances compared to those obtained from the simple InBaCo_4−xZn_xO₇ cathodes due to the extended triple-phase boundary (TPB) and enhanced oxide-ion conductivity through the GDC portion in the composites.     

Electrochemical properties of LiCoyMn2−yO4 synthesized using a combustion method in a voltage range of 3.5–5.0 V

LiCo_yMn_2−yO₄ (y = 0.00, 0.04 and 0.08) were synthesized using a combustion method, and the electrochemical properties were examined in the voltage range of 3.5–5.0 V. The XRD patterns of the synthesized samples were similar, and the samples had a spinel phase structure. The first charge capacity curves exhibited an inflection in the voltage range of 4.2–5.0 V, where it is believed that additional, previously unreported phase transition occurs. The voltage vs. x curves for the first to fifth cycle exhibited two distinct voltage plateaus, corresponding well to a two-phase reaction and a one-phase reaction, respectively, as reported previously. For the voltage range of 3.5–5.0 V, the first discharge capacity increased and the cycling performance improved as y increased. Among these samples, LiCo_0.08Mn_1.92O₄ had the largest first discharge capacity of 132.5 mA h/g at 600 μA/cm², and its cycling efficiency was 91.1% at the 15th cycle in the voltage range of 3.5–5.0 V.     

Effect of sintering temperature on microstructure and transport properties of Li3xLa2/3−xTiO3 with different lithium contents

Li_3xLa_2/3−xTiO₃ (LLTO) powder with different lithium contents (nominal 3x = 0.03–0.75) was synthesized via a simple sol–gel route and then calcination of gel-derived precursor at 900 °C which was much below the calcination temperature required for synthesizing the LLTO powder via solid state reaction route. The LLTO powder of sub-micron sized particles, derived from such sol–gel method, showed almost no aggregation. Starting from the sol–gel-derived powder, the LLTO ceramics with different lithium contents were prepared at different sintering temperatures of 1250 and 1350 °C. It demonstrated that our sol–gel route is quite simple and convenient compared to the previous sol–gel method and requires lower temperature for the LLTO. Our results also illustrated that lithium content significantly affects the structure and ionic conductivity of the LLTO ceramics. The dependence of the ionic conductivity on the lithium content, lattice structure, microstructure and sintering temperature was investigated systematically.     

Optimized electrochemical performance of LiMn0.9Fe0.1−xMgxPO4/C for lithium ion batteries

A series of LiMn_0.9Fe_0.1−xMg_xPO₄/C (x = 0, 0.01, 0.02, 0.05) was synthesized by a solid state reaction, and the effect of synthesis temperature and Fe/Mg ratio on the electrochemical performance of the obtained materials was investigated by X-ray diffraction, scanning electron microscopy, Raman spectroscopy and electrochemical measurements. The electrochemical performance of the Fe and Mg co-substituted LiMnPO₄ was obviously improved with increasing synthesis temperature from 650 to 800 °C, but further increase led to an abrupt capacity loss due to the impurity formation. The Fe and Mg co-substitution could remarkably enhance the electrochemical activity of LiMnPO₄ compared with the Fe substitution only, but too high level of Mg doping would worsen the rate capability. The LiMn_0.9Fe_0.09Mg_0.01PO₄/C synthesized at 800 °C demonstrated the optimum electrochemical performance with a high capacity and an excellent rate capability. Even discharged at the rate of 10 C, a capacity of 60 mAh g⁻¹ was still observed.     

Mechanochemical synthesis of kaolin-KH2PO4 and kaolin-NH4H2PO4 complexes for application as slow release fertilizer

A milling process to reduce kaolin to amorphous phase in the presence of KH₂PO₄ or NH₄H₂PO₄ and allow mechanochemical (MC) reaction for incorporation of KH₂PO₄ and NH₄H₂PO₄ into the kaolin structure was investigated in this work. Mixtures of kaolin and KH₂PO₄ and NH₄H₂PO₄ in separate systems were prepared by milling in a planetary ball mill. Tests with kaolin contents ranging from 25 to 75 wt.% and mill rotational speeds from 200 to 700 rpm were performed to evaluate incorporation of KH₂PO₄ and NH₄H₂PO₄ and release of K⁺, NH₄⁺ and PO₄³⁻ ions into solution. Analyses by XRD, DTA and ion chromatography indicated that the MC process was successfully applied to incorporate both KH₂PO₄ and NH₄H₂PO₄ into the amorphous kaolin structure. Release of K⁺ and PO₄³⁻ ions from the system (kaolin-KH₂PO₄) when dispersed in water for 24 h reached only up to 10%. Under similar conditions for the system (kaolin-NH₄H₂PO₄), release of NH₄⁺ and PO₄³⁻ ions reached between 25 and 40%. These results indicated that the MC process can be developed to allow amorphous kaolin to act as a carrier of K⁺, NH₄⁺ and PO₄³⁻ nutrients to be released slowly for use as fertilizer.     

Electrochemical and thermal studies of Li[NixLi(1/3−2x/3)Mn(2/3−x/3)]O2 (x = 1/12, 1/4, 5/12, and 1/2)

Samples of the layered cathode materials, Li[Ni_xLi_(1/3−2x/3)Mn_(2/3−x/3)]O₂ (x = 1/12, 1/4, 5/12, and 1/2), were synthesized at 900 °C. Electrodes of these samples were charged in Li-ion coin cells to remove lithium. The charged electrode materials were rinsed to remove the electrolyte salt and then added, along with EC/DEC solvent or 1 M LiPF₆ EC/DEC, to stainless steel accelerating rate calorimetry (ARC) sample holders that were then welded closed. The reactivity of the samples with electrolyte was probed at two states of charge. First, for samples charged to near 4.45 V and second, for samples charged to 4.8 V, corresponding to removal of all mobile lithium from the samples and also concomitant release of oxygen in a plateau near 4.5 V. Li[Ni_xLi_(1/3−2x/3)Mn_(2/3−x/3)]O₂ samples with x = 1/4, 5/12 and 1/2 charged to 4.45 V do not react appreciably till 190 °C in EC/DEC. Li[Ni_xLi_(1/3−2x/3)Mn_(2/3−x/3)]O₂ samples charged to 4.8 V versus Li, across the oxygen release plateau, start to significantly react with EC/DEC at about 130 °C. However, their high reactivity is similar to that of Li_0.5CoO₂ (4.2 V) with 1 μm particle size. Therefore, Li[Ni_xLi_(1/3−2x/3)Mn_(2/3−x/3)]O₂ samples showing specific capacity of up to 225 mAh/g may be acceptable for replacing LiCoO₂ (145 mAh/g to 4.2 V) from a safety point of view, if their particle size is increased.     

Highly oriented diamond growth on SixGe1−x (100) thin films

Highly oriented (100) diamond films have been successfully grown on Si_xGe_1−x (100) thin films by bias enhanced nucleation (BEN) in microwave plasma chemical vapor deposition (MPCVD) system. Raman spectra show the 1332 cm⁻¹ peak which proves the formation of diamond. Diamond nucleation density on Si_xGe_1−x substrate estimated by scanning electron microscopy is higher than 10⁹ cm⁻². The interface between diamond and Si_xGe_1−x substrate was characterized by transmission electron microscopy (TEM). About 20 nm decrease in thickness of the Si_xGe_1−x film was observed after bias enhanced nucleation step. TEM shows the existence of silicon carbide and heteroepitaxial diamond grains grown on Si_xGe_1−x substrate. Characterization from high-resolution TEM on the specimen of short time deposition reveals that a number of epitaxial diamond grains were directly nucleated on Si_xGe_1−x with {111} interplanar spacing ratio of diamond and Si_xGe_1−x of 2:3. The diamond nucleation is found to be preferred on the ridge position of the rough substrate surface. Diamond {100} facets were quickly developed in the early stage of growth.     

Evolution of the local structure and electrochemical properties of spinel LiNixMn2−xO4 (0 ≤ x ≤ 0.5)

A series of Ni substituted spinel LiNi_xMn_2−xO₄ (0 ≤ x ≤ 0.5) have been synthesized to study the evolution of the local structure and their electrochemical properties. X-ray diffraction showed a few Ni cations moved to the 8a sites in heavily substituted LiNi_xMn_2−xO₄ (x ≥ 0.3). X-ray photoelectron spectroscopy confirmed Ni²⁺ cations were partially oxidized to Ni³⁺. The local structures of LiNi_xMn_2−xO₄ were studied by analyzing the and A_1g Raman bands. The most compact [Mn(Ni)O₆] octahedron with the highest bond energy of Mn(Ni)O was found for LiNi_0.2Mn_1.8O₄, which showed a Mn(Ni)O average bond length of 1.790 Å, and a force constant of 2.966 N cm⁻¹. Electrolyte decomposition during the electrochemical charging processes increased with Ni substitution. The discharge capacities at the 4.1 and 4.7 V plateaus obeyed the linear relationships with respect to the Ni substitution with the slopes of −1.9 and +1.9, which were smaller than the theoretical values of −2 and +2, respectively. The smaller slopes could be attributed to the electrochemical hysteresis and the presence of Ni³⁺ in the materials.     

In situ X-ray absorption spectroscopic study for the electrochemical delithiation of a cathode LiFe0.4Mn0.6PO4 material

The electronic and local atomic structural characterization of a promising cathode material, LiFe_0.4Mn_0.6PO₄, for a lithium rechargeable battery was performed by in situ X-ray absorption fine structure (XAFS) on both Mn and Fe K-edges. Upon delithiation, the X-ray absorption near edge structure (XANES) spectra analysis showed that the Fe²⁺/Fe³⁺ electrochemical reaction was two times faster than that of Mn²⁺/Mn³⁺. The Fe and Mn K-edge extended X-ray absorption fine structure (EXAFS) spectra were effectively altered with different spectral behaviors for the local atomic structure near Fe and Mn during delithiation. Alternatively, the EXAFS spectra of LiFePO₄ changed significantly and those of LiMnPO₄ were constant through all delithiations for the corresponding reference materials of LiFePO₄ and LiMnPO₄. The present study with XAFS characterization demonstrates that initially delithiated Fe-rich domains at 3.5 V can promote more effective local structural change of the neighboring Mn-rich domains during the next second plateau at 4.1 V, which can ease delithiation in the Mn-rich domains through more flexible reaction of the local structure in the Mn octahedra.     

Low-temperature solution combustion synthesis of high performance LiNi0.5Mn1.5O4

High-voltage LiNi_0.5Mn_1.5O₄ spinels were synthesized by a low temperature solution combustion method at 400 °C, 600 °C and 800 °C for 3 h. The phase composition, structural disordering, micro-morphologies and electrochemical properties of the products were investigated by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM) and constant current charge–discharge test. XRD analysis indicated that single phase LiNi_0.5Mn_1.5O₄ powders with disordered Fd-3m structures were obtained by the method at 400 °C, 600 °C and 800 °C. The crystallinity increased with increasing preparation temperatures. XRD and FTIR data indicated that the degree of structural disordering in the product prepared at 800 °C was the largest and in the product prepared at 600 °C was the least. SEM investigation demonstrated that the particle size and the crystal perfection of the products were increased with increasing temperatures. The particles of the product prepared at 600 °C with ~200 nm in size are well developed and homogeneously distributed. Charge/discharge curves and cycling performance tests at different current density indicated that the product prepared at 600 °C had the largest specific capacity and the best cycling performance, due to its high purity, high crystallinity, small particle size as well as moderate amount of Mn³⁺ ions.     

One step synthesis of Ag/Ag3PO4/BiPO4 double-heterostructured nanocomposites with enhanced visible-light photocatalytic activity and stability

Heterogeneous Ag/Ag₃PO₄/BiPO₄ photocatalyst was synthesized by a one-step low temperature chemical bath method and exhibited better photocatalytic activity and better stability than those of individual Ag₃PO₄ or BiPO₄ nanoparticles for photodegradation of organic compounds (Rhodamine B) in the absence of electron accepters under visible light (λ>420 nm). The enhanced photocatalytic performance is mainly ascribed to the strong visible-light absorption originating from high efficient separations of photogenerated electron–hole pairs through Ag₃PO₄/BiPO₄ and Ag/Ag₃PO₄ heterostructures.     

Structure and magnetic properties of Fe1−xCox nanowires in self-assembled arrays

Fe_1−xCo_x nanowires in self-assembled arrays with varying compositions were produced by the template-assisted pulsed electrochemical deposition method. The structural and magnetic properties of the arrays were investigated using several experimental techniques. TEM analyses indicated that the nanowires were regular, uniform, 8 μm in length and 50 nm in diameter. The results of X-ray diffraction indicated that the body-centered-cubic (bcc) (α), face-centered-cubic (fcc) (γ), and hexagonal-close-packed (hcp) () Fe–Co phases appeared in different compositions. Magnetic measurements showed that the coercivity and squareness of the hysteresis loops of the Fe_1−xCo_x changed with their compositions, which may be attributable to shape anisotropy. The room temperature ⁵⁷Fe Mössbauer spectra of the arrays of the Fe_1−xCo_x nanowires revealed strong shape anisotropy.     

Mechanism transition of cell-impedance-controlled lithium transport through Li1−δMn2O4 composite electrode caused by surface-modification and temperature variation

The mechanism transition of lithium transport through a Li_1−δMn₂O₄ composite electrode caused by the surface-modification and temperature variation was investigated using the galvanostatic intermittent titration technique (GITT), electrochemical impedance spectroscopy (EIS) and the potentiostatic current transient technique. From the analyses of the ac-impedance spectra, experimentally measured from unmodified Li_1−δMn₂O₄ and surface-modified Li_1−δMn₂O₄ with MgO composite electrodes, the internal cell resistance of the MgO-modified Li_1−δMn₂O₄ electrode was determined to be much smaller in value than that of the unmodified electrode over the whole potential range. Moreover, from the analysis of the anodic current transients measured on the MgO-modified Li_1−δMn₂O₄ electrode, it was found that the cell-impedance-controlled constraint at the electrode surface is changed to a diffusion-controlled constraint, which is characterised by a large potential step and simultaneously by a small amount of lithium transferred during lithium transport. This strongly suggests that the internal cell resistance plays a significant role in determining the cell-impedance-controlled lithium transport through the MgO-modified Li_1−δMn₂O₄ electrode. Furthermore, from the temperature dependence of the internal cell resistance and diffusion resistance in the unmodified Li_1−δMn₂O₄ composite electrode measured by GITT and EIS, it was concluded that which mechanism of lithium transport will be operative strongly depends on the diffusion resistance as well as on the internal cell resistance.     

Study of IrxRu1−xO2 oxides as anodic electrocatalysts for solid polymer electrolyte water electrolysis

Electrocatalysts of the general formula Ir_xRu_1−xO₂ were prepared using Adams’ fusion method. The crystallite characterization was examined via XRD, and the electrochemical properties were examined via cyclic voltammetry (CV) in, linear sweep voltammetry (LSV) and chronopotentiometry measurements in 0.5 M H₂SO₄. The electrocatalysts were applied to a membrane electrode assembly (MEA) and studied in situ in an electrolysis cell through electrochemical impedance spectroscopy (EIS) and stationary current density–potential relations were investigated. The Ir_xRu_1−xO₂ (x = 0.2, 0.4, 0.6) compounds were found to be more active than pure IrO₂ and more stable than pure RuO₂. The most active electrocatalyst obtained had a composition of Ir_0.2Ru_0.8O₂. With an Ir_0.2Ru_0.8O₂ anode, a 28.4% Pt/C cathode and the total noble metal loading of 1.7 mg cm⁻², the potential of water electrolysis was 1.622 V at 1 A cm⁻² and 80 °C.     

Enhanced electrochemical performances of LiNi0.5Mn1.5O4 spinel via ethylene glycol-assisted synthesis

A simple and effective method, ethylene glycol-assisted co-precipitation method, has been employed to synthesize LiNi_0.5Mn_1.5O₄ spinel. As a chelating agent, ethylene glycol can realize the homogenous distributions of metal ions at the atomic scale and prevent the growth of LiNi_0.5Mn_1.5O₄ particles. XRD reveals that the prepared material is a pure-phase cubic spinel structure (Fd3m) without any impurities. SEM images show that it has an agglomerate structure with the primary particle size of less than 100 nm. Electrochemical tests demonstrate that the as-prepared LiNi_0.5Mn_1.5O₄ possesses high capacity and excellent rate capability. At 0.1 C rate, it shows a discharge capacity of 137 mAh g⁻¹ which is about 93.4% of the theoretical capacity (146.7 mAh g⁻¹). At the high rate of 5 C, it can still deliver a discharge capacity of 117 mAh g⁻¹ with excellent capacity retention rate of more than 95% after 50 cycles. These results show that the as-prepared LiNi_0.5Mn_1.5O₄ is a promising cathode material for high power Li-ion batteries.     

X-ray photoelectron spectroscopy and electrochemical behaviour of 4 V cathode, Li(Ni1/2Mn1/2)O2

Layered Li(Ni_1/2Mn_1/2)O₂ was prepared by the solution and mixed hydroxide methods, characterised by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) and studied by cyclic voltammetry (CV) and charge discharge cycling in CC and CCCV modes at room temperature (r.t.) and at 50 °C. The XPS studies show about 8% of Ni³⁺ and Mn³⁺ ions are present in Li(Ni²⁺_1/2Mn_1/2⁴⁺)O₂ due to valency-degeneracy. The compound prepared at 950 °C, 12 h, solution method gives a second cycle discharge capacity of 150 mA h g⁻¹ (2.5-4.4 V) at a specific current of 30 mA g⁻¹ and retains 137 mA h g⁻¹ at the end of 40 cycles. CV shows that the redox process at 3.7-4.0 V corresponds to Ni²⁺↔Ni⁴⁺ and clear indication of Mn^3+/4+ couple was noted at 4.2-4.5 V. The observed capacity-fading (2.5-4.4 V) is shown to be contributed by the polarisation at the end of charging. The cathodic capacity is stable up to 40 cycles in the voltage window, 2.5-4.2 V both at room temperature and 50 °C.     

Synthesis of spherical Li[Ni(1/3−z)Co(1/3−z)Mn(1/3−z)Mgz]O2 as positive electrode material for lithium-ion battery

Li[Ni_(1/3−z)Co_(1/3−z)Mn_(1/3−z)Mg_z]O₂ (z = 0, 0.04) positive electrode materials were synthesized via a co-precipitation method. These materials have α-NaFeO₂ () structure, as confirmed by X-ray diffraction (XRD) studies. Cation mixing in Li layer seemed to be decreased by Mg substitution as examined by Rietveld refinements of XRD data. Spherical morphologies were observed for the as-synthesized final products by scanning electron microscopy. Their electrochemical properties during charge and discharge were discussed. When magnesium ions are substituted, the initial reversible capacity reduced. However, the substitution for Mn sites in Li[Ni_1/3Co_1/3Mn_1/3]O₂ did not decrease the capacity because Mn sites substitution did not result in loss of electroactive elements in the compound. Differential scanning calorimetric studies showed the exothermic peaks of the charged electrode Li[Ni_(1/3−z)Co_(1/3−z)Mn_(1/3−z)Mg_z]O₂ (z = 0.04) were significantly smaller than that of Li[Ni_1/3Co_1/3Mn_1/3]O₂, which means that thermal stability was greatly improved by Mg substitution even at highly delithiated state.     

Optimum synthesis of Li2Fe1−xMnxSiO4/C cathode for lithium ion batteries

Li₂Fe_1−xMn_xSi0₄/C cathode materials were synthesized by mechanical activation-solid-state reaction. The effects of Mn-doping content, roasting temperature, soaking time and Li/Si molar ratio on the physical properties and electrochemical performance of the Li₂Fe_1−xMn_xSi0₄/C composites were investigated. The materials were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM), charge-discharge tests and AC impedance measurements. SEM images suggest that the morphology of the Li₂Fe_1−xMn_xSi0₄/C composite is sensitive to the reaction temperature. Samples synthesized at different temperatures have different extent of agglomeration. Being charged-discharged at C/32 between 1.5 and 4.8 V, the Li₂Fe_0.9Mn_0.1Si0₄/C synthesized at the optimum conditions shows good electrochemical performances with an initial discharge capacity of 158.1 mAh g⁻¹ and a capacity retention ratio of 94.3% after 30 cycles. AC impendence investigation shows Li₂Fe_0.9Mn_0.1SiO₄/C have much lower resistance of electrode/electrolyte interface than Li₂FeSiO₄/C.     

High-performance Li4Ti5−xVxO12 (0 ≤ x ≤ 0.3) as an anode material for secondary lithium-ion battery

Powders of spinel Li₄Ti_5−xV_xO₁₂ (0 ≤ x ≤ 0.3) were successfully synthesized by solid-state method. The structure and properties of Li₄Ti_5−xV_xO₁₂ (0 ≤ x ≤ 0.3) were examined by X-ray diffraction (XRD), Raman spectroscopy (RS), scanning electronic microscope (SEM), galvanostatic charge–discharge test and cyclic voltammetry (CV). XRD shows that the V⁵⁺ can partially replace Ti⁴⁺ and Li⁺ in the spinel and the doping V⁵⁺ ion does almost not affect the lattice parameter of Li₄Ti₅O₁₂. Raman spectra indicate that the Raman bands corresponding to the Li–O and Ti–O vibrations have a blue shift due to the doping vanadium ions, respectively. SEM exhibits that Li₄Ti_5−xV_xO₁₂ (0.05 ≤ x ≤ 0.25) samples have a relative uniform morphology with narrow size distribution. Charge–discharge test reveals that Li₄Ti_4.95V_0.05O₁₂ has the highest initial discharge capacity and cycling performance among all samples cycled between 1.0 and 2.0 V; Li₄Ti_4.9V_0.1O₁₂ has the highest initial discharge capacity and cycling performance among all samples cycled between 0.0 and 2.0 V or between 0.5 and 2.0 V. This excellent cycling capability is mainly due to the doping vanadium. CV reveals that electrolyte starts to decompose irreversibly below 1.0 V, and SEI film of Li₄Ti₅O₁₂ was formed at 0.7 V in the first discharge process; the Li₄Ti_4.9V_0.1O₁₂ sample has a good reversibility and its structure is very advantageous for the transportation of lithium-ions.