首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 31 毫秒
1.
Cryo-compressed hydrogen (CcH2) is a promising hydrogen storage method with merits of high density with low power consumption. Thermodynamic analysis and comparison of several CcH2 processes are conducted in this paper, under hydrogen storage conditions of 10–100 MPa at 60–100 K. Mixed-refrigerant J-T (MRJT), nitrogen/neon reverse Brayton (RBC) and hydrogen expansion are employed for cooling hydrogen, respectively. Combined CcH2 processes such as MRJT + neon-RBC are proposed to reach higher CcH2 density at lower temperatures (<80 K). It was indicated that the specific power consumptions (SPC) of MRJT processes are obviously lower than those of nitrogen/neon-RBC or hydrogen expansion processes. For a typical storage condition of 50 MPa at 80 K, MRJT CcH2 process could achieve hydrogen density of 71.59 kg m?3, above liquid hydrogen. While its SPC of 6.42 kWh kg?1 is about 40% lower than current dual-pressure Claude hydrogen liquefaction processes (10.85 kWh kg?1).  相似文献   

2.
Hydrogen has the highest gravimetric energy density of all fuels; however, it has a low volumetric energy density, unfavorable for storage and transportation. Hydrogen is usually liquefied to meet the bulk transportation needs. The exothermic interconversion of its spin isomers is an additional activity to an already energy-intensive process. The most significant temperature drop occurs in the precooling cycle (between ?150 °C and up to ?180 °C) and consumes more than 50% of the required energy. To reduce the energy consumption and improve the exergy efficiency of the hydrogen liquefaction process, a new high-boiling component, Hydrofluoroolefin (HFO-1234yf), is added to the precooled mixed refrigerant. As a result, the specific energy consumption of precooling cycle reduces by 41.8%, from 10.15 kWh/kgLH2 to 5.90 kWh/kgLH2, for the overall process. The exergy efficiency of the proposed case increases by 43.7%; however, the total equipment cost is also the highest. The inflated cost is primarily due to the added ortho-to-para hydrogen conversion reactor, boosting the para-hydrogen concentration. From the perspective of bulk storage and transportation of liquid hydrogen, the simplicity of design and low energy consumption build a convincing case for considering the commercialization of the process.  相似文献   

3.
Hydrogen storage technology is essentially necessary to promote renewable energy. Many kinds of hydrogen storage materials, which are hydrogen storage alloys, inorganic chemical hydrides, carbon materials and liquid hydrides have been studied. In those materials, ammonia (NH3) is easily liquefied by compression at 1 MPa and 298 K, and has a highest volumetric hydrogen density of 10.7 kg H2/100 L. It also has a high gravimetric hydrogen density of 17.8 wt%. The theoretical hydrogen conversion efficiency is about 90%. NH3 is burnable without emission of CO2 and has advantages as hydrogen and energy carriers.  相似文献   

4.
Boil-off gas (BOG) is inevitable on board liquefied hydrogen tankers and must be managed effectively, by using it as fuel, re-liquefying it or burning it, to avoid cargo tank pressure issues. This study aims to develop a BOG re-liquefaction system optimized for l60,000 m3 liquefied hydrogen tankers with an LNG and hydrogen hybrid propulsion system. The proposed system comprises hydrogen compression and helium refrigerant sections with 2 J–Brayton cascade cycles. Cold energy recovery from the fuels and feed BOG exiting the cargo tanks was used. The system exhibits a coefficient of performance (COP) of 0.07, a specific energy consumption (SEC) of 3.30 kWh/kgLH2, and exergy efficiency of 74.9%, with the hydrogen BOG entering the re-liquefaction system at a feed temperature of −220 °C. The theoretical COP and SEC values at ideal conditions were 0.09 and 2.47 kWh/kgLH2, respectively. The effects of varying the hydrogen compression pressure, inlet temperature of the hydrogen expander, feed hydrogen temperature and helium compression pressure were investigated. Additionally, the LNG-to-hydrogen fuel ratio was adjusted to satisfy the Energy Efficiency Design Index (EEDI) Phase 2 and 3 emission requirements.  相似文献   

5.
Bio-waste embeds an extraordinary renewable potential, and it becomes a source of energy savings when transformed into a valuable resource, like biogas. Cogeneration (CHP) from biogas employing high-temperature Solid Oxide Fuel Cells (SOFCs) scores a high sustainability level, thanks to improved environmental and energy performances. The synergy between the niche market of small/micro biogas producers and SOFCs might act as a springboard to open market opportunities for both SOFC commercialization and business upgrade of small farms. However, local regulations, waste management, renewable energy subsidies and, above all, availability of eligible sites, determine real chances for on-the-ground implementation.Through a detailed analysis of the application scenario, this research aims at investigating opportunities for the experimentation of SOFC–CHP in small biogas plants and identifying the possible bottlenecks for future deployment. When it becomes relevant, energy conversion of livestock (especially cattle and swine) and agriculture waste requires SOFC modules from 10 kWe to 35 kWe. This is in line with the current status of SOFC suppliers. Moreover, considering the fuel cell market roll-out, the average levelized cost of electricity is expected to decrease from 0.387 €/kWh to 0.115 €/kWh, when electricity is produced from livestock waste available on-site.  相似文献   

6.
《Journal of power sources》2005,144(1):165-169
A solar hydrogen system is presented able to provide uninterrupted 200 We power to an isolated application. It is composed of a photovoltaic generator, a battery set, an electrolyser, a metal-hydride system for hydrogen storage and a fuel cell. Batteries are charged with the photovoltaic array and the fuel cell, and discharged with the electrolyser and the application load. The fuel cell switches on when the state of charge of the batteries is low, until they are recovered to a predetermined level. The electrolyser produces H2 at 30 bar, enough to feed directly the metal hydrides, avoiding pressurization steps. Metal hydrides work under pressure control in the temperature range 0–40 °C. Kinetics of absorption–desorption of hydrogen is observed as an important limiting aspect for this kind of storage. The system is able to convert about 6–7% of total solar energy irradiated in 1 year. Results and evaluation after 1-year operation are shown. Energy management is found to be a critical issue to improve the behavior of the system.  相似文献   

7.
High efficiency cogeneration is seen by the European Commission as part of the solution to increase energy efficiency and improve security of supply in the internal energy markets. Portuguese residential sector has an estimated technical market potential of around 500 MWe for cogeneration of <150 kWe in size. Additionally, in Portugal there is a specific law for power production in low voltage, where at least 50% of the produced electric energy must be own consumed and the maximum power delivered to the power utility should be less than 150 kWe. Therefore, generic application tools cannot be applied in this regard. In this work, we develop the MicroG model for planning micro-CHP plants in agreement with the Portuguese energy legal framework. The model is able to design, evaluate and optimize from the techno-economic point of view any micro-CHP plant. MicroG appeals to some data bases, such as micro-cogeneration technologies and power consumption profiles that are also described. In addition, a practical case on a gym is considered to show all the functionalities of the model. The developed model has proven to be extremely useful from the practical point of view. This model could help the development of the micro-CHP Portuguese market, which in turns contributes to accomplish the targets of Kyoto protocol and EU cogeneration Directive. Other improvements to MicroG model can be made in order to enlarge the range of application to other micro-cogeneration technologies and to accomplish with the CO2 emissions trading.  相似文献   

8.
Hydrogen is an attractive energy source for improving gasoline engine performance. In this paper, a new hydrogen nanobubble gasoline blend is introduced, and the influence of hydrogen nanobubble on the combustion characteristics of a gasoline engine is experimentally investigated. The test was performed at a constant engine speed of 2000 rpm, and engine load of 40, 60, and 80%. The air-to-fuel equivalence ratio (λ) was adjusted to the stoichiometric (λ = 1), for both gasoline, and the hydrogen nanobubble gasoline blend. The results show that the mean diameter and concentration of hydrogen nanobubble in the gasoline blend are 149 nm and about 11.35 × 108 particles/ml, respectively. The engine test results show that the power of a gasoline engine with hydrogen nanobubble gasoline blend was improved to 4.0% (27.00 kW), in comparison with conventional gasoline (25.96 kW), at the engine load of 40%. Also, the brake specific fuel consumption (BSFC) was improved, from 291.10 g/kWh for the conventional gasoline, to 269.48 g/kWh for the hydrogen nanobubble gasoline blend, at the engine load of 40%.  相似文献   

9.
A fuel cell-based combined heat and power system using a high temperature proton exchange membrane fuel cell has been modelled. The fuel cell is fed with the outlet hydrogen stream from a methanol steam reforming reactor. In order to provide the necessary heat to this reactor, it was considered the use of a catalytic combustor fed with methanol. The modelling aims to fit the hydrogen production to the demand of the fuel cell to provide 1 kWe, maintaining a CO concentration always lower than 30,000 ppm. A system with 65 cells (45.16 cm2 cell area) stack operating at 150 °C and hydrogen utilization factor = 0.9 (with O2/methanol ratio = 2 at combustor; H2O/methanol ratio = 2 and temperature = 300 °C at reformer) needed a total methanol flow of 23.8 mol h−1 (0.96 L h−1) to reach 1 kWe, with a system power efficiency (LHV basis) ca. 24% and a CHP efficiency over 87%. The ability to recycle the non-converted hydrogen from the fuel cell anode to the combustor and to use the heat produced at the fuel cell for obtaining hot water increased the global energy efficiency.  相似文献   

10.
Biomass is one of the renewable energy resources which can be used instead of fossil fuels to diminish environment pollution and emission of greenhouse gases. Hydrogen as a biomass is considered as an alternative fuel which can be derived from a variety of domestically available primary sources. In this paper, a hydrogen and electricity co-generation plant with rice husk is proposed. Rice husk with water vapor and oxygen produces syngas in gasifier. In this design, electricity is generated by using two Rankine cycles. The Results show that the net electric efficiency and hydrogen production efficiency are 1.5% and 40.0%, respectively. Hydrogen production is 1.316 kg/s in case which carbon dioxide is gathered and stored. The electricity generation is 5.923 MWe. The main propose of implementing Rankine cycle is to eliminate hydrogen combustion for generating electricity and to reduce NOx production. Furthermore, three kinds of membranes are studied in this paper.  相似文献   

11.
The main objective of this research is to analyze the impact of the market share increase of hydrogen based road vehicles in terms of energy consumption and CO2, on today's Portuguese light-duty fleet. Actual yearly values of energy consumption and emissions were estimated using COPERT software: 167112 TJ of fossil fuel energy, 12213 kton of CO2 emission and 141 kton of CO, 20 kton of HC, 46 kton of NOx and 3 kton of PM. These values represent 20–40% of countries total emissions. Additionally to base fleet, three scenarios of introduction of 10–30% fuel cell vehicles including plug-in hybrids configurations were analysed. Considering the scenarios of increasing hydrogen based vehicles penetration, up to 10% life cycle energy consumption reduction can be obtained if hydrogen from centralized natural gas reforming is considered. Full life cycle CO2 emissions can also be reduced up to 20% in these scenarios, while local pollutants reach up to 85% reductions. For the purpose of estimating road vehicle technologies energy consumption and CO2 emissions in a full life cycle perspective, fuel cell, conventional full hybrids and hybrid plug-in technologies were considered with diesel, gasoline, hydrogen and biofuel blends. Energy consumption values were estimated in a real road driving cycle and with ADVISOR software. Materials cradle-to-grave life cycle was estimated using GREET database adapted to Europe electric mix. The main conclusions on CO2 full life cycle analysis is that light-duty vehicles using fuel cell propulsion technology are highly dependent on hydrogen production pathway. The worst scenario for the current Portuguese and European electric mix is hydrogen produced from on-site electrolysis (in the refuelling stations). In this case full life cycle CO2 is 270 g/km against 190 g/km for conventional Diesel vehicle, for a typical 150,000 km useful life.  相似文献   

12.
Metal hydrides are known as a potential efficient, low-risk option for high-density hydrogen storage since the late 1970s. In this paper, the present status and the future perspectives of the use of metal hydrides for hydrogen storage are discussed. Since the early 1990s, interstitial metal hydrides are known as base materials for Ni – metal hydride rechargeable batteries. For hydrogen storage, metal hydride systems have been developed in the 2010s [1] for use in emergency or backup power units, i. e. for stationary applications.With the development and completion of the first submarines of the U212 A series by HDW (now Thyssen Krupp Marine Systems) in 2003 and its export class U214 in 2004, the use of metal hydrides for hydrogen storage in mobile applications has been established, with new application fields coming into focus.In the last decades, a huge number of new intermetallic and partially covalent hydrogen absorbing compounds has been identified and partly more, partly less extensively characterized.In addition, based on the thermodynamic properties of metal hydrides, this class of materials gives the opportunity to develop a new hydrogen compression technology. They allow the direct conversion from thermal energy into the compression of hydrogen gas without the need of any moving parts. Such compressors have been developed and are nowadays commercially available for pressures up to 200 bar. Metal hydride based compressors for higher pressures are under development. Moreover, storage systems consisting of the combination of metal hydrides and high-pressure vessels have been proposed as a realistic solution for on-board hydrogen storage on fuel cell vehicles.In the frame of the “Hydrogen Storage Systems for Mobile and Stationary Applications” Group in the International Energy Agency (IEA) Hydrogen Task 32 “Hydrogen-based energy storage”, different compounds have been and will be scaled-up in the near future and tested in the range of 500 g to several hundred kg for use in hydrogen storage applications.  相似文献   

13.
One of the major issues of the change in energy politics is the storage of renewable energy in order to facilitate a continuous energy supply to the grid. An efficient way to store energy (heat) is provided by the usage of Thermochemical Energy Storage (TES) in metal hydrides. Energy is stored in dehydrogenated metal hydrides and can be released by hydrogenation for consumption. One prominent candidate for high temperature (400 °C) heat storage is magnesium hydride. It is a well-known and investigated material which shows high cycling stability over hundreds of cycles. It is an abundant material, non-toxic and easy to prepare in bigger scales. One of the major drawbacks for heat storage applications is the low heat transfer capability of packed beds of magnesium hydrides. In this work we present results of effective thermal conductivity (ETC) which were measured under hydrogen pressure up to 25 bar and temperatures up to 410 °C in order to meet the operating conditions of magnesium hydride as a thermochemical heat storage material. We could show that the effective thermal conductivity of a magnesium hydride – hydrogen system at 410 °C and 25 bar hydrogen increases by 10% from 1.0 W m−1 K−1 to 1.1 W m−1 K−1 after 18 discharging and charging cycles. In dehydrogenated magnesium hydride this increase of the thermal conductivity was found to be at 50% from 1.20 W m−1 K−1 to 1.80 W m−1 K−1 at 21 bar hydrogen. These data are very important for the design and construction of heat storage tanks based on high temperature metal hydrides in the future.  相似文献   

14.
The severe reduction in the available fossil fuel resources highlights the need to make more use of renewable energy resources (RER), such as solar photovoltaic (PV) modules, wind turbines, hydro-turbines, etc. Hydrogen (H2) may be seen as a possible alternative fuel which can be produced from renewable energy, as mentioned and a promising contender in the energy storage domain. A hydrogen electrolyser harnesses the energy produced by the RER, in order to produce H2, which could be stored in its current form to be used at a later stage to generate electrical energy, by means of a fuel cell.In this paper, an optimal switching control of a solid polymer electrolyte membrane water electrolyser (PEMWE) water heating system is presented, in which actual historic exogenous data obtained from a weather station in the considered area is used as inputs for the established model.The main aim of this paper was to develop an optimal control model, which maximizes the removal of the undesired heat from the PEMWE and transferring it to the hot water storage tank (HWST), whilst ensuring sufficient hydrogen is being produced.Simulations of the optimal switching control of a PEMWE water heating system was conducted successfully with the SCIP (Solving Constrained Integer Programs) solver in the optimization toolbox in MATLAB.The optimal switching control model yields a daily energy consumption of 49.85 kWh by the PEMWE compared to an energy consumption of 48.86 kWh by the standard PEMWE system (baseline). The optimal switching control model resulted in 2.51 kg of hydrogen compared to 2.56 kg which is produced by the standard PEMWE system. Moreover, the optimal control model recovered 1.03 kWh of heat successfully which is transferred to the HWST.The optimal control model development and implementation for a PEMWE to maximize the thermal energy recovery from the PEMWE to the HWST whilst ensuring stable H2 production are presented as one of the main contributions to the study.Secondly, by recovering the generated heat from the PEMWE, the time period for the membrane to degrade to a thickness of 50% could be prolonged by 0.68 years, after which the membrane degradation occurs non-linearly.  相似文献   

15.
A proposed liquid hydrogen plant using a multi-component refrigerant (MR) refrigeration system is explained in this paper. A cycle that is capable of producing 100 tons of liquid hydrogen per day is simulated. The MR system can be used to cool feed normal hydrogen gas from 25 °C to the equilibrium temperature of −193 °C with a high efficiency. In addition, for the transition from the equilibrium temperature of the hydrogen gas from −193 °C to −253 °C, the new proposed four H2 Joule–Brayton cascade refrigeration system is recommended. The overall power consumption of the proposed plant is 5.35 kWh/kgLH2, with an ideal minimum of 2.89 kWh/kgLH2. The current plant in Ingolstadt is used as a reference, which has an energy consumption of 13.58 kWh/kgLH2 and an efficiency of 21.28%: the efficiency of the proposed system is 54.02% or more, where this depends on the assumed efficiency values for the compressors and expanders. Moreover, the proposed system has some smaller-size heat exchangers, much smaller compressor motors, and smaller crankcase compressors. Thus, it could represent a plant with the lowest construction cost with respect to the amount of liquid hydrogen produced in comparison to today’s plants, e.g., in Ingolstadt and Leuna. Therefore, the proposed system has many improvements that serve as an example for future hydrogen liquefaction plants.  相似文献   

16.
Energy crisis has led the communities around the world to use energy hubs. These energy hubs usually consist of photovoltics, wind turbines and batteries. Diesel generators are usually used in these systems as backup system. In this research, for the first time, an attempt is made to replace the traditional diesel only backup system with hydrogen only system and combined hydrogen and diesel backup system in hybrid photovoltaic and wind turbine energy systems. After introducing the available energy modeling tools and methods, explaining over advantages and disadvantages of each one, HOMER software was selected for this research. The simulations of this research show that using the traditional diesel generator as the backup system of the energy hub, creates a low cost system with the net present cost (NPC) of 2.5 M$ but also produces the highest amount carbon emission which is equal to 686 tons/year. The results of this study also indicate the hybrid renewable energy system which is supported by the hydrogen only backup system has the highest net present cost (NPC) and initial capital cost but reduces the maximum amount of carbon. The calculated NPC and carbon production of the energy hub using hydrogen only backup system are equal to 4.39 M$ and 55,205, respectively. On the other hand, the combined hydrogen/diesel backup system has reduced NPC compared with the hydrogen only backup system. The CO2 production of this system is also lower than the diesel only backup system. The calculations indicate that the NPC and CO2 production of the combined backup system are 3.53 M$ and 511,695 kg/yr. By comparing advantages and disadvantages of all 3 scenarios, the micro grid which uses the combined diesel/hydrogen backup system is selected as the most optimal system. The sensitivity analysis of the selected system shows that fluctuations of inflation rate along with the fluctuations of both fuel cells and electrolyzers capital cost do not affect the net present cost (NPC) considerably. On the other hand, fluctuations of capital cost of the main components like wind turbines affect the NPC much more than the others. If the inflation rate drops from 15% to 14% and wind turbine capital cost multiplier reduces from 1 to 0.8, the NPC value will drop by the value of 300,000 $.  相似文献   

17.
Hydrogen as a clean energy carrier for solar energy can be produced by using photovoltaic-electrolyser (PVE) direct-coupling system that is well known as a kind of simple and low investment but unstable system for solar energy conversion. The key to improve hydrogen yield of a direct-coupling system is to keep its working points around maximum power point (MPP) of photovoltaic (PV) modules. The coupling of three different connection patterns of six PV modules with one electrolyser were investigated in summer, autumn and winter, three typical seasons in a year, to seek the optimum arrangement for higher system efficiency in Beijing (116°E, 40°N). A corresponding mathematics model of the system is applied to simulate and analyze the instantaneous efficiency of the system, which agreed well with the experimental results. The variation rate of the system instantaneous efficiency varies with the solar irradiation intensity, the ambient temperature and the resistance of the electrolyser. The working point that distinguishes the variation trends of the system efficiency is called the efficiency changing point (ECP). The author use a parameter V/Vm, the ratio between the voltage of the working point to the voltage of the maximum power point, to analyze the respective ECP of each factor above. It can be concluded that the variation rate of system instantaneous efficiency changes little with the above factors when the value of V/Vm of working point is smaller than that of the ECP and is sensitive to those factors when the value of V/Vm is larger than that of the ECP. Following the annual historical climate data in Beijing, the result of the annual analysis is that the best scheme for the experiment system with a 1 m2 PV panel covering 1.05 m2 areas of ground can convert 78.4 kWh of solar energy to hydrogen energy in 2012.  相似文献   

18.
Hydrogen is seen as an energy carrier of the future and significant research on hydrogen generation, storage and utilization is accomplished around the world. However, an appropriate intermediate step before wide hydrogen introduction will be blending conventional fuels such as natural gas, oil or diesel with hydrogen and follow up combustion through conventional means. Due to changes in the combustion and flame characteristics of the system additional research is needed to access the limits and the impact of the fuel mix on the combustion systems performance. The hybrid system consists of a 5 kWel electrolyzer and a residential 15 kWth high efficiency gas fired furnace. The electrolyzer was integrated with the furnace gas supply and setup to replace 5–25% of the furnace natural gas flow with hydrogen. A mean for proper mixing of hydrogen with natural gas was provided and a control system for safe system operation was developed. Prior to the start of the field trial the hybrid system was investigated in laboratory environment. It was subjected to a variety of steady state and cycling conditions and a detailed performance and optimization analysis was performed with a range of hydrogen/natural gas mixtures. The optimized system was then installed at the Canadian Centre for Housing Technologies (CCHT) Experimental research house. The energy performance of the hybrid system was compared to the energy performance of an identical high efficiency furnace in the Control research house next door.  相似文献   

19.
In contrast to conventional technologies of hydrogen production like water electrolysis or coal gasification we propose a method based on the atmospheric pressure microwave plasma. In this paper we present results of the experimental investigations of the hydrogen production from ethanol in the atmospheric pressure plasma generated in waveguide-supplied cylindrical type nozzleless microwave (915 MHz and 2.45 GHz) plasma source (MPS). Argon, nitrogen and carbon dioxide were used as a working gas. All experimental tests were performed with the working gas flow rate Q ranged from 1500 to 3900 NL/h and absorbed microwave power PA up to 6 kW. Ethanol was introduced into the plasma as vapours carried with the working gas. The process resulted in the ethanol conversion rate greater than 99%. The hydrogen production rate was up to 210 NL[H2]/h and the energy efficiency was 77 NL[H2] per kWh of absorbed microwave energy.  相似文献   

20.
《Journal of power sources》2006,158(1):403-416
In the near future, fuel cell-based residential micro-CHP systems will compete with traditional methods of energy supply. A micro-CHP system may be considered viable if its incremental capital cost compared to its competitors equals to cumulated savings during a given period of time. A simplified model is developed in this study to estimate the operation of a residential solid oxide fuel cell (SOFC) system. A comparative assessment of the SOFC system vis-à-vis heating systems based on gas, oil and electricity is conducted using the simplified model for a single-family house located in Ottawa and Vancouver. The energy consumption of the house is estimated using the HOT2000 building simulation program. A financial analysis is carried out to evaluate the sensitivity of the maximum allowable capital cost with respect to system sizing, acceptable payback period, energy price and the electricity buyback strategy of an energy utility. Based on the financial analysis, small (1–2 kWe) SOFC systems seem to be feasible in the considered case. The present study shows also that an SOFC system is especially an alternative to heating systems based on oil and electrical furnaces.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号