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1.
采用金属有机化学气相沉积工艺在碳纳米管(CNTs)表面包覆了W金属层。采用磁力搅拌和放电等离子体烧结工艺制备了镀钨碳纳米管(W-CNTs)与CNTs增强的铝基复合材料。组织观察结果表明钨金属层有效的加强了CNTs与Al基体的界面结合。随着W-CNTs含量增加,W-CNTs/Al复合材料的热导率先增加后降低,且当W-CNTs含量体积分数为1.5%时,复合材料获得最大热导率;W-CNTs/Al复合材料的热导率高于CNTs/Al复合材料。热膨胀系数结果表明随CNTs含量增加,复合材料热膨胀系数降低,且W-CNTs/Al热膨胀系数低于CNTs/Al复合材料。  相似文献   

2.
以羰基钨为前驱体,采用金属有机化学气相沉积在碳纳米管表面镀覆了金属W。利用磁力搅拌混粉和放电等离子体烧结制备了镀W碳纳米管(W-CNTs)/Mg复合材料,并研究了W-CNTs含量对材料力学性能和电导率的影响。结果表明:W-CNTs含量为0.75%(质量分数,下同)时,复合材料抗拉强度和维氏硬度最大,较纯Mg增加了40.1%和35.1%;基体中添加W-CNTs虽然使复合材料电导率下降,但0.75%W-CNTs/Mg复合材料电导率仍可达到纯Mg的94.8%;W-CNTs/Mg复合材料的力学性能和电导率均高于CNTs/Mg复合材料。  相似文献   

3.
采用球磨混粉和放电等离子体烧结制备了镀钨碳纳米管/铝(W-CNTs/Al)复合材料,对复合材料组织形貌进行了透射电镜和扫描电镜观察,研究了W-CNTs含量和摩擦实验载荷对复合材料摩擦系数、磨损量和表面磨损形貌的影响.结果表明:低含量的W-CNTs可实现在A1基体中的良好分散,但高含量的W-CNTs会形成团聚体.随W-CNTs含量增加,复合材料的摩擦系数和磨损量均先减小后增加,且当W-CNTs含量为0.75%(质量分数)时,复合材料的摩擦系数和磨损量较纯A1分别降低了24.4%和39.1%.随实验载荷增加,复合材料摩擦系数变化不明显,但磨损量增大显著,材料表面磨损粗糙度也增加.  相似文献   

4.
以羰基钨为前驱体, 采用金属有机化学气相沉积在碳纳米管表面镀覆了金属钨, 利用磁力搅拌混粉和放电等离子体烧结制备了镀钨碳纳米管增强镁基复合材料((W-CNTs) /Mg), 研究了W-CNTs质量分数对复合材料摩擦磨损性能的影响。结果表明: W-CNTs的加入可对镁基体起到降低摩擦系数、减少磨损量的作用; 当W-CNTs质量分数为0.75%时, 复合材料的摩擦系数和磨损量均最小, 分别较纯镁降低了43.7%和71.4%;增加或降低复合材料中的W-CNTs质量分数, 材料的摩擦系数、磨损量均将增大。(W-CNTs) /Mg复合材料的摩擦磨损性能高于CNTs/Mg复合材料。  相似文献   

5.
机械球磨与烧结W基材料的组织与性能   总被引:1,自引:0,他引:1  
采用机械球磨与热压工艺制备了W-TiC、W-Ni、W-CNTs(碳纳米管)和W-Ni-CNTs 4种W基材料。研究结果表明,机械球磨能显著降低复合粉的晶粒尺寸和增加晶格畸变。经机械球磨后热压的样品中W-TiC的致密度最好,密度达到18.36g/cm3;W-Ni和W-CNTs的密度分别为17.97g/cm3和18.23g/cm3,具有较好的致密性;W-Ni-CNTs样品密度为15.84g/cm3,致密度略低。微观组织分析表明:添加TiC粒子可以显著改善材料的烧结行为,但晶粒较大;添加少量Ni制备的样品,不仅致密度高,而且晶粒较小;添加CNTs可以改善W的烧结行为,同时能够抑制晶粒长大和对W晶界起到强化作用;同时添加Ni和CNTs样品的致密度较低,需要对Ni和CNTs的添加量及烧结工艺条件进一步优化。结合微观组织分析与显微硬度测试结果,发现W烧结体的显微硬度不仅和材料密度有关,而且和W晶粒大小及掺杂相有关。  相似文献   

6.
采用羰基热分解法对多壁碳纳米管表面进行镀钨处理,并以镀钨碳纳米管和电解铜粉为原料,进行机械球磨混粉和放电等离子体烧结,制备了镀钨碳纳米管/铜基复合材料.采用场发射扫描电镜观察了粉体和复合材料的组织形貌,并对复合材料物相进行了X射线衍射分析.探讨了镀钨碳纳米管含量和放电等离子体烧结温度对复合材料致密度、抗拉强度、延伸率和电导率的影响.结果表明,镀钨碳纳米管质量分数为1%和烧结温度为850℃时,复合材料的致密度、抗拉强度和电导率最高.与烧结纯铜相比,复合材料的抗拉强度提高了103.6%,电导率仅降低15.9%.  相似文献   

7.
高能球磨Ti/Al复合粉体的反应烧结致密行为   总被引:6,自引:0,他引:6  
研究高能球磨Ti/Al复合粉反应烧结过程的致密行为 ,并进行反应烧结热力学和动力学分析。结果表明 ,与增加烧结压力、提高烧结温度或延长烧结时间的作用相同 ,高能球磨对Ti/Al粉末体反应烧结过程的致密化具有促进作用 ,且效果更加显著。球磨时间越长 ,烧结体越致密。球磨 3h的Ti/Al复合粉坯料经6 30℃× 2h预烧、12 5 0℃× 8h无压烧结后 ,获得的TiAl基合金试样的致密度高达 99 87%。球磨对Ti/Al粉末体反应烧结时致密化的促进作用 ,主要是由于Ti、Al反应组元及其晶粒尺寸的细化 ,晶格畸变能增加 ,从而显著提高了烧结驱动力和烧结动力学因子 ,缩短了反应扩散距离 ,抑制了kirkendall孔隙的形成。  相似文献   

8.
机械活化-放电等离子烧结FeAl/Al2O3复合材料   总被引:1,自引:0,他引:1  
利用机械活化-放电等离子烧结的方法,将Fe-Al-Al2O3粉末经机械活化后快速烧结,得到致密且晶粒细小的FeAl/Al2O3,块体复合材料.研究表明,在球粉质量比13:1、转速170r/min、球磨时间25h的球磨条件下,Fe-40%(原子数分数)Al-10%(质量分数)Al2O3粉体中的纳米级Al2O3颗粒,在细化和活化Fe、Al金属粉末的同时,还能有效地阻止金属粉末在烧结前合金化生成金属间化合物.在烧结压力40MPa、烧结温度1 050℃、加热时间15min、保温时间10min的工艺条件下,制备的FeAl/Al2O3复合材料的相对密度达96.4%.  相似文献   

9.
本文采用高能球磨、原位反应合成及热压技术制备了致密的Al2O3p-TiCp/Al复合材料,并用XRD、SEM以及EDAX等手段分析了复合材料的相组成、显微组织.结果表明:Al-TiO2-C三元体系在热压反应烧结后,可制得致密度较高的Al2O3p-TiCp/Al原位复合材料,其显微组织中Al2O3和TiC颗粒尺寸为1μm左右,分布均匀.高能球磨有利于增强颗粒细化弥散分布和反应进行完全.  相似文献   

10.
AlN/Al复合材料是一种高导热复合材料,但现有制备工艺较为复杂.本文采用高能球磨的方式制备混合粉末,随后采用放电等离子烧结方法成功制备出AlN-20%Al材料.测试结果表明:制备的AlN/Al复合材料的相对密度大于97%,热导率为52.8W/m·K,烧结温度与传统的AlN相比降低了约200℃.  相似文献   

11.
机械球磨与放电等离子体烧结制备碳纳米管/铜复合材料   总被引:2,自引:0,他引:2  
采用机械球磨和放电等离子体烧结(SPS)工艺制备了碳纳米管(CNTs)/铜复合材料.利用SEM和TEM对材料组织和形貌进行了表征,研究了球磨时间、CNTs含量、SPS烧结压力对复合材料组织和性能的影响.结果表明:质量分数为1%的CNTs可在铜基体中获得良好分散;CNTs与铜基体界面结合良好,有利于应力在基体与CNTs之...  相似文献   

12.
The structure and mechanical properties of nano- and ultradispersed mechanically activated heavy W-Ni-Fe and W-Ni-Fe-Co tungsten alloys (VNZh and VNZhK alloys, respectively) are studied. Mechanically activated nano- and ultradispersed charge powders are sintered by free sintering (thermally activated) and spark plasma sintering. The dependence of the density of the alloys made of the mechanically activated powders on the sintering temperature is found to have a nonmonotonic character with a maximum corresponding to the optimum sintering temperature. It is shown that an increase in the mechanical activation time and the acceleration of the milling bodies during mechanical activation lead to a decrease in the alloy particle size and the formation of nonequilibrium solid solutions and are accompanied by a decrease in the optimum sintering temperature of heavy tungsten alloys. Ultrahigh-strength tungsten alloys the mechanical properties of which are substantially higher than those of standard coarse-grained analogs are fabricated due to the optimization of the conditions of ball milling and high-rate spark plasma sintering of W-Ni-Fe powders.  相似文献   

13.
Highly concentrated zirconia-carbon nanotube (CNT) water suspensions were prepared using an advanced milling technique. The bead-milling operation parameters were optimized for this system and used to prepare zirconia-stabilized water-based suspensions with different CNT contents. The effects of different milling conditions were studied. The particle dispersion was evaluated by SEM observations on dried suspension. Green’s density and SEM observations of compacts were used to follow the colloidal dispersability of the composites. Materials of tetragonal zirconia and CNTs were prepared with a high concentration of CNTs (1, 5, and 10 wt pct CNT). The homogeneous dispersion and distribution of the fibers in the bulk material after slip casting of the suspension were examined. The samples were sintered using spark plasma sintering (SPS) at 1473 K (1200 °C) and finally, fully dense materials were obtained. The mechanical properties were evaluated using the Vickers indentation technique.  相似文献   

14.
Al-3 vol pct carbon nanotube (CNT) composites are fabricated by consolidation through high-pressure torsion (HPT) at room temperature. The densification behavior, microstructural evolution, and mechanical properties of Al/CNT composites are studied. The results show that density and microstructural homogeneity increase with increasing number of revolutions under a high pressure of 6 GPa. Substantial grain refinement is achieved after 10 turns of HPT with an average grain thickness of ~38 nm perpendicular to the compression axis of HPT. The Al/CNT composite shows a considerable increase in hardness and strength compared to the Al matrix. The strengthening mechanisms of the Al/CNT composite are found to be (i) grain refinement of Al matrix and (ii) Orowan looping. Raman spectroscopy and high-resolution transmission electron microscopy reveal that the structure of most of CNTs is changed during processing through mechanical milling and HPT.  相似文献   

15.
采用磁力搅拌与放电等离子烧结技术制备了碳纳米管(CNT)增强铝基复合材料.对试样进行了扫描电镜和透射电镜表征,测试了试样的力学性能、摩擦性能、电学性能和热学性能.当碳纳米管在试样中的质量分数为1%时,可在铝基体中均匀分布且CNT/Al界面结合良好,此时试样的抗拉强度和硬度较纯A1分别提高了29.4%和15.8%.在获得最佳力学性能强化和最佳减磨效果的同时.试样电导率较纯Al仅降低8.0%.碳纳米管可提高基体的热导率.但强化效果不明显.  相似文献   

16.
Aluminum alloy AA2219-Graphene/MWCNT composites with near theoretical density have been successfully processed through high energy ball milling followed by spark plasma sintering. Effectiveness of varying content of Graphene and MWCNT as reinforcements was studied on different aspects of processing of the composites. The particle size increased during milling due to agglomeration but presence of reinforcement restricted the agglomeration process. Significant change in particle size of milled composite powders was not observed for the type (Graphene/MWCNT) or content (0.5–2 wt%) of the reinforcements. The increase of reinforcement (Graphene/MWCNT) content above 0.5 wt% resulted in lower hardness for spark plasma sintered composites. Further, both AA2219-Graphene and AA2219-MWCNT composites revealed similar hardness values. Finally, different aspects of processing (mechanical alloying, densification) and characterization (microstructure, hardness, electrical conductivity) revealed similar results irrespective of type of reinforcement i.e. Graphene or MWCNT.  相似文献   

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