Regenerated air cycle potentials in heat pump applications

Air (reversed Brayton) cycle has been utilized in the area of refrigeration and cryogenics for several decades, but its potentials in heat pump applications were longtime underestimated. In this paper, a thermodynamic model for the regenerated air heat pump cycle with practical compressor, expander and regenerated heat exchanger was developed. Based on the model, the relations between the system performance and the operating parameters were analyzed. The optimal heating COP (coefficient of performance) and the corresponding pressure ratio were derived. Then, air heat pump cycles (regenerated cycle and basic cycle) and vapor-compression heat pump cycles (CO₂ trans-critical cycle and R410A subcritical cycle) were numerically compared. The results indicated that the regenerated air heat pump cycle not only gets the heating capacity in line with the heating load under different operating conditions but also achieves higher COP over trans-critical CO₂ heat pump cycle in applications of large temperature difference.     

A propane water-to-water heat pump booster for sanitary hot water production: Seasonal performance analysis of a new solution optimizing COP

Electrical heat pumps for sanitary hot water production achieve a high performance with a good matching of water and refrigerant temperature profiles during the heat rejection stage, as it happens in CO₂ systems. This work considers the thermodynamic possibility to adapt the condenser pressure of a propane heat pump to maximize the COP, while producing sanitary hot water up to 60 °C from a heat sink equal to 15 or 25 °C. The performance of the heat pump is calculated through specific models which, in combination with a TRNSYS model of the whole system, allowed to assess its seasonal performance for a hotel in Strasbourg, also varying the control logic and the size of the storage tank. Results obtained led to the conclusion that, for achieving a high seasonal performance, the control logic of the tank has the largest influence.     

Pinch point analysis and design considerations of CO2 gas cooler for heat pump water heaters

Due to strong nonlinear variation of supercritical CO₂ specific heat capacity with temperature, pinch point would occur in water-cooled CO₂ gas cooler, which has great impacts on the heat transfer characteristics of gas cooler and overall system performance. Pinch point analysis was conducted for CO₂ gas cooler in the present study. The effects of refrigerant pressure, mass flow ratio (m_w/m_c), inlet water temperature and heat transfer area on pinch point location, approach temperature difference and heat transfer rate were analyzed in detail. Based on the analysis of pinch point location in CO₂ gas cooler, the critical flow ratios were proposed to effectively control the approach temperature difference. Furthermore, the actual conductance of gas cooler was calculated and compared with that estimated by LMTD method. The results showed that CO₂ gas cooler may be undersized by as much as a factor of 30–60% for different pressures if LMTD method is used. However, the UA value evaluated by LMTD method also may be overestimated under high refrigerant pressures when the approach temperature difference tends to be zero. Results of the present study are helpful to practical designs of CO₂ gas cooler and heat pump water heaters.     

Thermodynamic analysis and experimental investigation of a CO2 household heat pump dryer

Carbon dioxide is regarded as an optimal working fluid for heat pump dryers. The transcritical cycle well fits the closed-loop drying process which requires dehumidification and re-heating according to high temperature lift of the air stream.In this paper, the transcritical CO₂ cycle is compared with a sub-critical R134a cycle. The theoretical analysis is based on fixed temperature approach values at the heat exchangers. The study considers optimal high pressure for the transcritical cycle and optimal refrigerant subcooling for the sub-critical cycle. The theoretical analysis investigates the energy performance of the thermodynamic cycle as a function of the temperature and mass flow rate of the drying air. The optimisation of the operating conditions for CO₂ involves lower air temperature than in the case of R134a; this conditions can be satisfied by a suitable design of the appliance, whose thermal balance is achieved when the dissipated heat corresponds to the work spent by the compressor and the fan; the air temperature is a floating variable that adjusts its value to comply with the thermal balance. Experimental results, conducted on a prototype, give a positive assessment for CO₂ as working fluid for heat pump dryers: a negligible decrease in the electric power consumption, with a limited (+9%) increase in the cycle time, is shown in comparison with the reference R134a heat pump dryer.     

Working fluids for an absorption system based on R124 (2-chloro-1,1,1,2,-tetrafluoroethane) and organic absorbents

The possibility of using R124 (2-chloro-1,1,1,2,-tetrafluoroethane, CHClFCF₃) and organic absorbents as working fluids in absorption heat pumps was investigated. Various classes of organic compounds, all commercially available, were tested as absorbents for possible combination with R124; the absorbents included DMAC (N′, N′-dimethylacetamide, C₄H₉NO), NMP (N-methyl-2-pyrrolidone, C₅H₉NO), MCL (N-methyl ε-caprolactam, C₇H₁₃NO), DMEU (dimethylethylene urea, C₅H₁₀N₂O), and DMETEG (dimethylether tetraethyleneglycol, C₁₀H₂₂O₅). To evaluate the performance of a candidate refrigerant-absorbent pair in a refrigeration or heat pump cycle, the thermophysical properties of the pure components and the mixture and the equilibrium and transport properties have to be determined, either from experimental data or by prediction methods. The thermal stability of the refrigerant-absorbent must also be tested. A method for the calculation of the concentration in the liquid and gas phases and the excess thermodynamic properties of the mixture as a function of the system temperature and pressure based on our experimental setup is described. On the basis of vapor-liquid equilibrium measurements, density and viscosity measurements and thermostability testing, enthalpy-concentration diagrams were constructed. The performance characteristics of the investigated working fluids in terms of the coefficient of performance (COP) and the circulation ratio (f) were calculated for a single-stage absorption cycle. In terms of overall performance (COP, f and stability) R124-DMAC was found to be the superior combination, followed by R124-NMP, R124-DMEU and R124-MCL (the three pairs for which stability problems were found at high temperatures), and finally by R124-DMETEG.     

Theoretical and experimental analysis of a CO2 heat pump for domestic hot water

This paper describes the development of a CO₂ air/water heat pump for the production of tap hot water in a residential building. The basic design consists of a single-stage piston compressor, a coaxial type gas cooler, an electronic expansion valve, a finned tube evaporator and a low pressure receiver. The heat pump is combined with a storage tank designed to maintain internal water stratification.The gas cooler pressure optimisation in the case of fixed water delivery temperature was theoretically analysed.A new control method for the upper cycle pressure was developed to maximise the COP of the heat pump, while the water mass flow was adjusted to maintain the set water temperature at the gas cooler exit.Before commissioning, the heat pump was factory tested to verify its energy performance and to validate the high pressure control logic.     

Investigation of the optimal intermediate water temperature in a combined r134a and transcritical CO2 heat pump for space heating

In this paper, the effect of intermediate water temperature on the performance of a combined R134a and transcritical CO₂ heat pump was studied theoretically and experimentally. The mathematical model was first validated using experimental data and then applied to analyze the performance of the combined system. The results show that there exists an optimal intermediate water temperature (water inlet temperature at the gas cooler) at which the combined system has the highest COP. This optimal intermediate water temperature varies with the ambient air temperature. Furthermore, the effect of intermediate water temperature on individual R134a and transcritical CO₂ subsystems was investigated. The results show that both heating capacity and power consumption in the R134a subsystem increase as the intermediate water temperature increases. However, power consumption in the CO₂ system drops slightly, and heating capacity reaches an optimal value as the intermediate water temperature increases from 15 to 32 °C under ambient air temperatures ranging from −20 to 7 °C.     

Investigation on Heat Transfer Properties of Supercritical Water in a Rock Fracture for Enhanced Geothermal Systems

Supercritical water (SCW) has shown promise as a working fluid to extract heat from hot dry rock (HDR); however, fundamental research on its heat transfer characteristics in HDR fractures is still required. A 2D heat transfer model that considers the variable thermophysical properties was updated to numerically investigate the effects of mass flow rate, thermal reservoir temperature, and fracture aperture size on the heat transfer characteristics of SCW flow through a single HDR fracture. The heat transfer performance of SCW and supercritical CO₂ (scCO₂) was compared under the same conditions. The results indicate that the heat transmission performance of SCW is superior to scCO₂ at high temperature and high pressure. It is essential to synthesize the thermal reservoir temperature and pressure, site conditions, and heat transmission fluids during HDR development.     

CO2-heat pump water heater: characteristics, system design and experimental results

CO₂ is one of the few non-toxic and non-flammable working fluids that do not contribute to ozone depletion or global warming, if leaked to the atmosphere. Tap water heating is one promising application for a trans-critical CO₂ process. The temperature glide at heat rejection contributes to a very good temperature adaptation when heating tap water, which inherits a large temperature glide. This, together with efficient compression and good heat transfer characteristics of CO₂, makes it possible to design very efficient systems. A heating-COP of 4.3 is achieved for the prototype when heating tap water from 9°C to 60°C, at an evaporation temperature of 0°C. The results lead to a seasonal performance factor of about 4 for an Oslo climate, using ambient air as heat source. Thus, the primary energy consumption can be reduced with more than 75% compared with electrical or gas fired systems. Another significant advantage of this system, compared with conventional heat pump water heaters, is that hot water with temperatures up to 90°C can be produced without operational difficulties.     

Heat sources — technology, economy and environment

Heat sources for heat pumps in buildings as well as in industry are discussed. Furthermore, some environmental aspects concerning choice of heat source are highlighted. Only systems for heat pumping are included, i.e. air-conditioning types which can also partly work as heat pumps are excluded. Recent heat pump installations in Sweden are mainly in small systems. Ambient air, exhaust air, soil and rock are the most common heat source types. Data on COP, investment costs, working fluids, present Swedish market etc. for these types of heat sources are given. Data on industrial heat pump installations in some countries and distribution of these according to heat pump type and industry sector as well as heat source temperatures are reported. Process integration aspects when choosing heat source size and temperature are also discussed as well as the relation between these parameters and the choice of heat pump type. Finally, the influence on the economy of the heat source temperature is presented. The cost-effectiveness of heat pumps for reducing CO₂ emissions compared with other heating technologies is discussed. The main results are: (1) heat pumps can in many cases in the future contribute to a reduction of CO₂; (2) there is a rather big difference, for larger systems a major difference, between the water-based and the ambient air-based heat pumps in terms of efficient reduction of greenhouse gas emissions.     

Simulation based identification of the ideal defrost start time for a heat pump system for electric vehicles

Resistance heating with PTC elements to cover the heat demand of electric vehicles reduces significantly the cruising range at low outside temperatures. Reversible heat pump systems are one of the most promising solutions for this problem. However, in heat pump mode the frost formation on the exterior heat exchanger reduces the performance and efficiency of the system. Therefore, an efficient defrost method is crucial to benefit from the heat pump also under frosting conditions. In the present paper, a transient Modelica simulation model of a reversible CO₂-heat pump system with hot gas defrost was set up in order to assess the impact of different defrost start times. The model is able to handle frost growth on the exterior heat exchanger as well as defrosting. The simulation results showed an optimal point of time to conduct defrost at chosen operating conditions in order to maximize the average COP including the frosting and defrost period.     

A study on the performance of multi-stage condensation heat pumpsEtude sur la performance des pompes à chaleur à condensation en plusieurs étages

In this study, computer simulation programs were developed for multi-stage condensation heat pumps and their performance was examined for CFC11, HCFC123, HCFC141b under the same condition. The results showed that the coefficient of performance (COP) of an optimized ‘non-split type’ three-stage condensation heat pump was 25–42% higher than that of a conventional single-stage heat pump. The increase in COP differed among the fluids examined. The improvement in COP was due largely to the decrease in average temperature difference between the refrigerant and water in the condensers, which resulted in a decrease in thermodynamic irreversibility. For the three-stage heat pump, the highest COP was achieved when the total condenser area was evenly distributed to the three condensers. For the two-stage heat pump, however, the optimum distribution of total condenser area varied with working fluids. For the three-stage system, splitting the condenser cooling water for the use of intermediate and high pressure subcoolers helped increase the COP further. When the individual cooling water for the intermediate and high pressure subcoolers was roughly 10% of the total condenser cooling water, the optimum COP was achieved showing an additional 11% increase in COP as compared to that of the ‘non-split type’ for the three-stage heat pump system.     

Technical and economic working domains of industrial heat pumps: Part 2 – Ammonia-water hybrid absorption-compression heat pumps

The ammonia-water hybrid absorption-compression heat pump (HACHP) has been proposed as a relevant technology for industrial heat supply, especially for high sink temperatures and high temperature glides in the sink and source. This is due to the reduced vapour pressure and the non-isothermal phase change of the zeotropic mixture, ammonia-water. To evaluate to which extent these advantages can be translated into feasible heat pump solutions, the working domain of the HACHP is investigated based on technical and economic constraints. The HACHP working domain is compared to that of the best available vapour compression heat pump with natural working fluids. This shows that the HACHP increases the temperature lifts and heat supply temperatures that are feasible to produce with a heat pump. The HACHP is shown to be capable of delivering heat supply temperatures as high as 150 °C and temperature lifts up to 60 K, all with economical benefits for the investor.     

An experimental study on heat transfer and pressure drop characteristics of carbon dioxide during gas cooling process in a horizontal tube

The heat transfer coefficient and pressure drop during gas cooling process of CO₂ (R744) in a horizontal tube were investigated experimentally. The experiments are conducted without oil in the refrigerant loop. The main components of the refrigerant loop are a receiver, a variable-speed pump, a mass flow meter, a pre-heater and a gas cooler (test section). The water loop consists of a variable speed pump, an isothermal tank, and a flow meter. The refrigerant, circulated by the variable-speed pump, condenses in the inner tube while water flows in the annulus. The gas cooler of tube diameter is 6000 mm in length, and it is divided into 12 subsections.The pressure drop of CO₂ in the gas cooler shows a relatively good agreement with those predicted by Blasius's correlation. The local heat transfer coefficient of CO₂ agrees well with the correlation by Bringer–Smith. However, at the region near Pseudo-critical temperature, the experiments indicate higher values than the Bringer–Smith correlation. Based on the experimental data presented in this paper, a new correlation to predict the heat transfer coefficient of supercritical CO₂ during in-tube cooling has been developed. The majority of the experimental values are within 18% of the values predicted by the new correlation.     

CO2 heat pump systems

After the CFCs and the HCFCs were deemed unfit as working fluids in refrigeration, air conditioning, and heat pump applications, there has been a renaissance for carbon dioxide technology. Heat pumps is one of the application areas where theoretical and experimental investigations are now performed by an increasing number of research institutions and manufacturers. This paper gives an overview of some of the current activities in the CO₂ heat pump field. Discussed are the important characteristics of the transcritical CO₂ process applied to heat pumps, and also discussed are theoretical and experimental results from several heat pump applications. Provided that calculations and system designs are performed on the premises of the working fluid, and that test plants are constructed and operated to fully exploit the specific characteristics of both the fluid and the transcritical process, the results show that CO₂ is an attractive alternative to the synthetic fluids. Competitive products may be launched in the near future.     

Fluids for high temperature heat pumps

The theoretical performances of some 250 potential work fluids in vapour compression heat pumps condensing at 150°C and evaporating at 100°C have been predicted, using expression for coefficient of performance (COP) and minimum superheat that involve only easily accessible physical properties. Expected correlations were found between COP and critical temperature, between specific compressor displacement and normal boiling point, T_bp, and between condensing pressure and T_bp. Correlations were also found between minimum superheat and both molecular weight and critical pressure. From these correlations, the desirable basic properties of a high temperature heat pump fluid are deduced. The principle of corresponding states is invoked to explain the connection between minimum superheat and critical pressure, and hence the reason why perfluorinated compounds tend to make poor work fluids.     

Condensation of pure and near-azeotropic refrigerants in microfin tubes: A new computational procedure

Microfin tubes are widely used in air cooled and water cooled heat exchangers for heat pump and refrigeration applications during condensation or evaporation of refrigerants. In order to design heat exchangers and to optimize heat transfer surfaces, accurate procedures for computing pressure drops and heat transfer coefficients are necessary. This paper presents a new simple model for the prediction of the heat transfer coefficient to be applied to condensation in horizontal microfin tubes of halogenated and natural refrigerants, pure fluids or nearly azeotropic mixtures. The updated model accounts for refrigerant physical properties, two-phase flow patterns in microfin tubes and geometrical characteristics of the tubes. It is validated against a data bank of 3115 experimental heat transfer coefficients measured in different independent laboratories all over the world including diverse inside tube geometries and different condensing refrigerants among which R22, R134a, R123, R410A and CO₂.     

A study of working fluids for heat driven ejector refrigeration using lumped parameter models

This paper studies the influence of working fluids over the performance of heat driven ejector refrigeration systems performance by using a lumped parameter model. The model used has been selected after a comparison of different models with a set of experimental data available in the literature. The effect of generator, evaporator and condenser temperature over the entrainment ratio and the COP has been investigated for different working fluids in the typical operating conditions of low grade energy sources. The results show a growth in performance (the entrainment ratio and the COP) with a rise in the generator and evaporator temperature and a decrease in the condenser temperature. The working fluids have a great impact on the ejector performance and each refrigerant has its own range of operating conditions. R134a is found to be suitable for low generator temperature (70–100 °C), whereas the hydrocarbons R600 is suitable for medium generator temperatures (100–130 °C) and R601 for high generator temperatures (130–180 °C).     

Performance evaluation of a heat pump cycle using NARMs by a simulation with equations of heat transfer and pressure drop

Simulation analyses for a vapour compression heat pump cycle using nonazeotropic refrigerant mixtures (NARMs) of R22 and R114 are conducted under the condition that the heat pump thermal output and the flow rate and inlet temperatures of the heat sink and source water are given. The heat transfer coefficients of the condensation and evaporation are calculated with empirical correlations proposed by the authors. The validity of the evaluation method and the correlations is demonstrated by comparison with experimental data. The relations between the coefficient of performance (COP) and composition are shown under two conditions: (1) the constant heat transfer length of the condenser and evaporator; and (2) the constant temperature of refrigerant at the heat exchanger inlet. The COP of the NARMs is higher than that of pure refrigerant when the heat transfer lengths of the condenser and evaporator are sufficiently long.     

混合工质回热式大温跨供热热泵循环的理论分析

物料干燥、印刷、印染纺织、电镀等领域普遍需要65～100℃的热源供应,常规热泵技术难以实现。本文充分利用非共沸混合工质相变过程中的大温度滑移,实现与水侧更好的热当量匹配,提出一种混合工质回热式大温跨热泵循环,建立了热力学模型,分析了运行压力、混合工质组分、环境温度、出水温度等关键参数对系统性能的影响,基于遗传算法优化了系统吸排气压力和工质配比,结果表明:混合工质回热式热泵可在常规空调压缩机的正常工况内运行,在环境温度为25℃、入水温度为15℃、出水温度为90℃时,系统理论COP最高可达5. 5,与同工况下CO₂跨临界热泵性能相当。