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1.
We explore the possibilities for refrigerants having low global warming potential (GWP). A set of about 1200 candidate fluids is identified from more than 56 000 small molecules examined by applying screening criteria to estimates for GWP, flammability, stability, toxicity, and critical temperature. Methodologies for this screening have been presented in earlier works and are summarized here. The fluids with critical temperatures between 300 K and 400 K (i.e., those that could be used in current types of equipment with minor modifications) number 62. The fluids include halogenated olefins; compounds containing oxygen, nitrogen, or sulfur; as well as carbon dioxide. We discuss the tradeoffs presented by these 62 candidates, considering their thermodynamic properties and their stability and toxicity characteristics. No fluid is ideal in all regards—all have one or more negative attributes: poor thermodynamic properties, toxicity, chemical instability, low to moderate flammability, or very high operating pressures. 相似文献
2.
Two-stage vapor compression technology has high potential of performance improvement for cold climate heat pumps, and there are several types of inter-stage configurations that need to be evaluated before making a choice. A general model of these configurations is first derived from a subcooler cycle and then is extended to be capable of evaluating many other inter-stage configurations by employing an “input domain”. The model is solved with a sequential algorithm and an analytical initial solution of the intermediate pressure is presented. After an experimentally validation with additional calculations of the subcooling parameter, the evaporating and condensing pressure, this general model is then used in the performance comparison and analysis of eight different inter-stage configurations. At last, case studies show that, this general model is capable of performing performance comparison among cycles with different types of inter-stage configurations, as well as refrigerant selection and operational analysis. 相似文献
3.
This paper presents the experimental heat transfer coefficients and pressure drops measured during refrigerant HFC32 condensation inside a commercial Brazed Plate Heat Exchanger (BPHE) and compares this data with similar measurements previously obtained for refrigerant HFC410A to assess its capability as low GWP substitute for HFC410A in medium size chillers and heat pumps. The effects of saturation temperature, refrigerant mass flux, and vapour super-heating are investigated. HFC32 exhibits heat transfer coefficients much higher and frictional pressure drop slightly higher than those of HFC410A. Therefore, considering that HFC32 exhibits a GWP just one-third that of HFC410A, taking into account also its good thermodynamic properties, it seems to be a very promising low GWP substitute for HFC410A in medium size chillers and heat pumps. 相似文献
4.
Chieko Kondou Daisuke BaBa Fumiya Mishima Shigeru Koyama 《International Journal of Refrigeration》2013,36(8):2366-2378
Flow boiling of a potential refrigerant R32/R1234ze(E) in a horizontal microfin tube of 5.21 mm inner diameter is experimentally investigated. The heat transfer coefficient (HTC) and pressure drop are measured at a saturation temperature of 10 °C, heat fluxes of 10 and 15 kW m?2, and mass velocities from 150 to 400 kg m?2 s?1. The HTC of R1234ze(E) is lower than that of R32. Degradation in the HTC of the R32/R1234ze(E) mixture is significant; the HTC is even lower than that of R1234ze(E). The HTC is minimized at the composition 0.2/0.8 by mass, where the temperature glide and the mass fraction distribution are maximized. A predicting correlation based on Momoki et al. (1995) associated with the correction methods of Thome (1981) to consider the mass transfer resistance and Stephan (1992) to consider the additionally required sensible heat is proposed and validated with the experimental results. 相似文献
5.
The Constant Rate of Momentum Change (CRMC) criterion attempts to improve the design of supersonic ejectors, that can be used in heat-powered chillers for industrial or air-conditioning use. Moving from its original formulation, the CRMC design method can be advanced accounting for friction irreversibilities and real gas behaviour, as done in a previous work by our research group. Here we present an upgraded version of this analysis, supported by experimental data from a prototype chiller using R245fa as working fluid. The analysis is extended to other fluids (water, isobutane, 5 HFCs and 3 HFOs) whose performance is calculated on a wide range of heat source/sink temperatures. The existing literature, based generally on ideal gas simulations, suggests that water yields poor results in terms of COP. This paper shows that this result may be argued. Low GWP fluid HFO1233zd also gives good results. 相似文献
6.
Reducing energy consumption by utilizing heat recovery systems has become increasingly important in industry. This paper presents an exploratory assessment of heat pump type heat recovery systems using environmentally friendly refrigerants. The coefficient of performance (COP) of 4 cycle configurations used to raise the temperature of heat media to 160 °C with a waste heat at 80 °C is calculated and compared for refrigerants R717, R365mfc, R1234ze(E), and R1234ze(Z). A multiple-stage “extraction” cycle drastically reduces the throttling loss and exergy loss in the condensers, resulting in the highest COP for R1234ze(Z). A cascade cycle using R1234ze(Z) and R365mfc has a relatively high COP and provides practical benefits. Even under adverse conditions, the primary energy efficiency is greater than 1.3 when the transmission end efficiency of the electric power generation is 0.37. The assessment demonstrated that high-temperature heat pumps are a promising approach for reducing primary energy consumption for industrial applications. 相似文献
7.
In this study, nucleate boiling heat transfer coefficients (HTCs) of HFO1234yf HFC134a are measured on a flat plain, Turbo-B, Turbo-C, and Thermoexcel-E surfaces. All data are taken at the liquid pool temperature of 7 °C on small flat horizontal square copper plates (9.53 mm × 9.53 mm) at heat fluxes from 10 kW m−2 to 200 kW m−2 with an interval of 10 kW m−2. Test results show that nucleate boiling HTCs of HFO1234yf on all four surfaces are similar to those of HFC134a at all heat fluxes tested in this study. At heat fluxes below 150 kW m−2, Thermoexcel-E surface shows the highest heat transfer performance and hence is the best surface for the manufacture of the evaporators in refrigeration and air-conditioning equipment. On the other hand, at high heat fluxes above 150 kW m−2, Turbo-B and Turbo-C show better heat transfer performance than Thermoexcel-E and hence are good for electronic cooling applications. Overall, HFO1234yf is a good long term candidate with excellent environmental properties to replace successfully HFC134a from the view point of pool boiling heat transfer. Hence HFO1234yf can be readily applied to the conventional evaporators designed for HFC134a. 相似文献
8.
A multi-split VRF system operates unsteadily most of time due to the constantly varying refrigerant flow rates of associated indoor units. VRF systems require a different approach from conventional techniques to detect faults, which have developed based on steady-state operations. In this paper, two fault detection techniques are proposed. Their advantage is that they do not require the test data to be preprocessed to obtain steady-state data. The first technique is applied to detect heat exchanger fouling by a state observer, and the other technique is used to detect valve sticking by temperature variance. These techniques were not chosen haphazardly but were derived from physical reasoning. Their validity was confirmed by test data. The methodology developed in this study can be applied similarly to other HVAC equipment that operates mostly in transient states. 相似文献
9.
J.M. Corberán D. Donadello I. Martínez-Galván C. Montagud 《International Journal of Refrigeration》2013,36(8):2251-2261
This paper presents the results of an experimental campaign for the characterization of the dynamic behavior of a water-to-water refrigeration/heat-pump unit under ON/OFF operation. The unit was previously tested at different water inlet temperatures under steady state conditions, and a very good agreement was found between the instantaneous dynamic performance of the heat pump and the corresponding quasi-steady state operation. In parallel, a series of tests were carried out to quantify the coefficient of performance (COP) degradation as a function of the load ratio, and a simple formula for the Part Load Factor is presented. Results lead to the conclusion that the only non-negligible factor in the COP degradation is the stand-by electrical consumption during the OFF period, especially at low load ratios. Finally, it is concluded that the minimization of the stand-by consumption is a key point for the future improvement of the seasonal performance of water-to-water systems. 相似文献
10.
Yiqiang Jiang Jiankai Dong Minglu Qu Shiming Deng Yang Yao 《International Journal of Refrigeration》2013,36(8):2278-2288
When an air source heat pump (ASHP) unit operates for space heating at a frosting environment, periodic defrosting is necessary to maintain a high system performance. To defrost efficiently, it is necessary to find an effective defrosting control method. In this paper, an experiment was carried out on an ASHP unit with a capillary tube as a throttle device, under simulated frosting and defrosting conditions using time control defrosting method, and the experimental results are firstly presented. Secondly, a novel defrosting control method based on the degree of refrigerant superheat (DS) is reported. To validate the novel defrosting control method, a further experiment was conducted on another ASHP unit with an electronic expansion valve (EEV) as a throttle device, under simulated frosting and defrosting conditions. The experimental results demonstrated that when applying the novel defrosting control method, defrosting was initiated before the operating performances of ASHP unit rapidly deteriorated, which was more reasonable. 相似文献
11.
The ammonia-water hybrid absorption-compression heat pump (HACHP) has been proposed as a relevant technology for industrial heat supply, especially for high sink temperatures and high temperature glides in the sink and source. This is due to the reduced vapour pressure and the non-isothermal phase change of the zeotropic mixture, ammonia-water. To evaluate to which extent these advantages can be translated into feasible heat pump solutions, the working domain of the HACHP is investigated based on technical and economic constraints. The HACHP working domain is compared to that of the best available vapour compression heat pump with natural working fluids. This shows that the HACHP increases the temperature lifts and heat supply temperatures that are feasible to produce with a heat pump. The HACHP is shown to be capable of delivering heat supply temperatures as high as 150 °C and temperature lifts up to 60 K, all with economical benefits for the investor. 相似文献
12.
Jisun Jeong Chengguo Li Younghwan Kwon Jaekeun Lee Soo Hyung Kim Rin Yun 《International Journal of Refrigeration》2013,36(8):2233-2241
The viscosity and thermal conductivity of ZnO nanofluids with nanoparticle shapes of nearly rectangular and of sphere, were experimentally investigated under various volume concentrations of the nanoparticles, ranging from 0.05 to 5.0 vol.%. The viscosity of the nanofluids increased with increases in the volume concentration by up to 69%. In addition, the enhancement of the viscosity of the nearly rectangular shape nanoparticles was found to be greater by 7.7%, than that of the spherical nanoparticles. The thermal conductivity of the ZnO nanofluids increased by up to 12% and 18% at 5.0 vol.% for the spherical and the nearly rectangular shape nanoparticles, respectively, compared to that of the base fluid (water). The shape of the particles is found to have a significant effect on the viscosity and thermal conductivity enhancements. 相似文献
13.
The flow and heat transfer characteristics of binary refrigerant mixtures in a heated horizontal tube were investigated numerically. The pressure drop, temperature profile, and heat transfer coefficient for non-azeotropic and near-azeotropic mixtures of different bulk compositions were obtained. It is found that the non-linear physical properties of the mixtures strongly affect the pressure drop characteristics. Both the fluid properties and mass transfer resistance are responsible for the heat transfer characteristics. The mass transfer resistance has a more significant influence on the nucleate boiling than the convective evaporation for non-azeotropic mixtures, while the resistance can be neglected for near-azeotropic mixtures. 相似文献
14.
Ice cream is a very temperature sensitive product and temperature variations during the storage and distribution steps may result in a reduction of quality. It is possible to improve the ice cream storage and transportation conditions by using an additional packaging with a low thermal diffusivity. This paper studies a phase change material (PCM) packaging and compares its performance to a polystyrene packaging configuration. The impact on temperature fluctuations and ice crystal size distribution was characterized experimentally during long term storage and temperature abuse. The results show that the use of an additional PCM packaging has a significant impact on the final quality of the product by keeping ice cream temperature stable and close to the phase change temperature of the PCM material. These results were compared with the insulation material results and discussed, showing that a material with a buffering heat capacity can be more efficient to reduce temperature fluctuations than a low conductivity material, and that the same results can be usually obtained with a much thinner layer of material. 相似文献
15.
Supermarket refrigeration systems have high environmental impact due to their large refrigerant charge and high leak rates. Consequently, the interest in using low GWP refrigerants such as carbon dioxide (CO2) and new refrigerant blends is increasing. In this paper, an open-source Life Cycle Climate Performance (LCCP) framework is presented and used to compare the environmental impact of four supermarket refrigeration systems: a transcritical CO2 booster system, a cascade CO2/N-40 system, a combined secondary circuit with central DX N-40/L-40 system, and a baseline multiplex direct expansion system utilizing R-404A and N-40. The study is performed for different climates within the USA using EnergyPlus to simulate the systems' hourly performance. Further analyses are presented such as parametric, sensitivity, and uncertainty analyses to study the impact of different system parameters on the LCCP. 相似文献
16.
In the present paper, the refrigerant mixture R32/R290 (68%/32% by weight) is investigated as the drop-in replacement for R410A in household air conditioners. The GWP of it is only 22% of that of R410A. Theoretical and experimental investigations are conducted on the performance of the air conditioners working with both R32/R290 and R410A. Experimental results show that the refrigerant charge amount of R32/R290 is reduced by 30.0%–35.0%; the cooling and heating capacities are increased by 14.0%–23.7%. For further reducing charge amount and flammability, the micro-channel heat exchanger (condenser) is employed to replace the finned tube one. Compared with the R32/R290 system using finned tube heat exchanger, the R32/R290 charge amount and the power consumption are reduced by 34.1% and 0.4%, respectively; the cooling capacity and the COP are increased by 6.4% and 6.8%, respectively. 相似文献
17.
Electrical heat pumps for sanitary hot water production achieve a high performance with a good matching of water and refrigerant temperature profiles during the heat rejection stage, as it happens in CO2 systems. This work considers the thermodynamic possibility to adapt the condenser pressure of a propane heat pump to maximize the COP, while producing sanitary hot water up to 60 °C from a heat sink equal to 15 or 25 °C. The performance of the heat pump is calculated through specific models which, in combination with a TRNSYS model of the whole system, allowed to assess its seasonal performance for a hotel in Strasbourg, also varying the control logic and the size of the storage tank. Results obtained led to the conclusion that, for achieving a high seasonal performance, the control logic of the tank has the largest influence. 相似文献
18.
Desiccant coated heat exchanger provides a promising option for desiccant cooling system, since it can handle sensible load and latent load simultaneously within one component. It is fabricated by coating desiccant material on the surface of conventional fin-tube heat exchanger. In order to enhance the performance of conventional silica gel coated heat exchanger (SGCHE), a novel composite silica gel coated heat exchanger (CCHE) is proposed and fabricated. An experimental setup is built to test and compare the dynamic performance of SGCHE and CCHE. Influences of main operation parameters including water temperatures and inlet air conditions on system performance are analyzed in terms of average dehumidification capacity (Davg) and thermal coefficient of performance (COPth). Optimization of cycle switch modes is also discussed. Experimental results show that CCHE has better dehumidification performance compared with SGCHE. In addition, pre-cooling before dehumidification process is found to be advantageous to both Davg and COPth. 相似文献
19.
A large amount of operational and economic constraints limit the applicability of heat pumps operated with natural working fluids. The limitations are highly dependent on the integration of heat source and sink streams. An evaluation of feasible operating conditions was carried out considering the constraints of available refrigeration equipment and a requirement of a positive net present value of the investment. Six heat pump systems were considered, corresponding to an upper limit of the sink temperature of 120 °C. For each set of heat sink and source temperatures the best available technology was determined. The results showed that four different heat pump systems propose the best available technology at different parts of the complete domain. Ammonia systems presented the best available technology at low sink outlet temperature. At high temperature difference between sink in- and outlet, the transcritical R744 expands the working domain for low sink outlet temperatures. 相似文献
20.
Nanofluids technology has been rapidly developing over the last two decades. In this paper, the performance of a lithium bromide (LiBr) solution with and without nanoparticles in plate heat exchanger (PHE) for various chevron angles and mass flow rates was investigated. As a result, the heat transfer rate and the overall heat transfer coefficient in 60°/60° PHE is over 100% higher than that of 30°/30° PHE, and the effectiveness of the PHE in 60°/60° PHE is about 70% higher than that of 30°/30° PHE. By using nanoparticle in the working fluid, the heat transfer performance can increase significantly. The heat transfer rate of 3 vol.% nanofluids increased about 3–8% compare to that of LiBr solution for all chevron PHEs. Besides, the 60°/60° PHE using 3 vol.% nanofluids produced the largest heat transfer rate and heat exchange effectiveness under given operating conditions. 相似文献