气敏元件室温光激发气敏性能研究

研究了WO3掺杂的ZnO基气敏元件在紫外(UV)光激发下,对乙醇气体的室温气敏性能。结果表明:在UV光照射下,各元件在室温下对体积分数为100×10–6的乙醇气体显示了很好的光敏、气敏性能,响应、恢复时间均在8s以内,其中以掺杂X(WO3)为1%的元件W(1)为最佳,从而实现了室温下的气敏测试。     

TiO2多孔膜上水热合成ZnO结构及其光电性能

The synthesis of ZnO architecture on a fluorine-doped SnO_2(FTO) conducting glass pre-coated with nanoporous TiO_2 film has been achieved by a one-step hydrothermal method at a temperature of 70℃.The effect of the reaction time on the morphology of the ZnO architecture has been investigated,and a possible growth mechanism for the formation of the ZnO architecture is discussed in detail.The morphology and phase structures of the as-obtained composite films have been investigated by field-emission scanning...     

Acetic acid gas sensors based on Ni2+ doped ZnO nanorods prepared by using the solvothermal method

Ni²⁺-doped ZnO nanorods with different doping concentrations are prepared via the solvothermal method. The doped ZnO nanorods are characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The amount of Ni²⁺ ions that enter the lattice of ZnO increases with increasing the Ni²⁺/Zn²⁺ molar ratio when the molar ratio of Ni²⁺/Zn²⁺ in the starting solution is lower than 3% and does not change obviously if the mole ratio of Ni²⁺/Zn²⁺ in the starting solution is in the range of 3-10 mol%. The effect of Ni²⁺ doping on the gas-sensing properties is investigated. The results reveal that the amount of Ni²⁺ has a great influence on the response (R_a/R_g) and the gas-sensing selectivity. The sensor based on 1 mol % Ni²⁺ doped ZnO nanorods (120 ℃, 10 h) exhibits a high response to acetic acid vapor, in particular, the responses to 0.001 ppm and 0.01 ppm acetic acid vapor reach 1.6 and 2, respectively. The response time and the recovery time for 0.001 ppm acetic acid are only 4 s and 27 s, respectively.