共查询到18条相似文献,搜索用时 62 毫秒
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SmCl3—PbCl2和SmCl3—PbCl2—CaCl2系相图的研究 总被引:4,自引:0,他引:4
利用DTA和X射线衍射技术研究了SmCl_3-PbCl_2二元系和SmCl_3-PbCl_2-CaCl_2三元系相图。发现SmCl_3-PbCl_2系有一个异份熔化化合物3SmCl_3 PbCl_2,体系转熔点p为465℃,42.0mol-%SmCl_3,低共熔点e是452℃,33.0mol-%SmCl_3,SmCl_3-PbCl_2-CaCl_2三元系有对应SmCl_3,PbCl_2,CaCl_2,和3SmCl_3·PbCl_2四个液相面,五条二次结晶线,一个三元低共熔点E[396℃,29.5mol-%SmCl_3,58.0mol-%PbCl_2],一个三元转熔点P[417℃,36.0mol-%SmCl_3,50.0mol-%PbCl_2),对应的两个四相平衡反应为: L=PbCl_2+CaCl_2+3SmCl_3·PbCl_2 L+SmCl_3=3SmCl_3·PbCl_2+CaCl_2 相似文献
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KF—LiCl—CaCl2系相图研究 总被引:1,自引:0,他引:1
用目测变温法,差热分析法及X射线粉末法测定了KF-LiCl-CaCl2系熔盐相图,发现KF在LiCl-CaCl2熔盐溶液中呈负偏差,并对KF-LiCl-CaCl2系相图和已经研究的KF-LiCl-BaCl2及KF-LiCl-CrCl2系相图进行了讨论,发现碱土金属氟化物的初晶面积和溶解能参数之间存在一定的关系。 相似文献
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EuCl3—CaCl2二元系相图 总被引:4,自引:1,他引:4
用差热分析法研究了EuCl3CaCl2二元体系相图,发现该体系有一个异份熔化化合物EuCl3·3CaCl2。体系转熔点为570℃,EuCl3摩尔分数45.4%;低共熔点为522℃,EuCl3摩尔分数66.8%。 相似文献
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EuCl3-KCl二元系相图 总被引:3,自引:0,他引:3
利用差热分析法研究了EuCl3 KCl二元系相图 ,发现该体系有两个固液同组成化合物EuCl3 ·3KCl和2EuCl3 ·KCl,体系相变点分别为 76 5℃ ,EuCl3 2 5 %(摩尔分数 )和 5 5 5℃ ,EuCl3 6 6 .7%(摩尔分数 ) ;一个异分熔化化合物EuCl3 ·2KCl,转熔点为 5 6 4℃ ,EuCl3 42 %(摩尔分数 ) ;3个低共熔点分别为 6 5 0℃ ,EuCl3 12 %(摩尔分数 ) ,5 0 0℃ ,EuCl3 5 5 %(摩尔分数 )和 490℃ ,EuCl3 85 %(摩尔分数 )。同时探讨了相图的某些规律。 相似文献
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优化评估了RECl3-CaCl2(EE:La、Ce、Pr和Nd),RECl3-MgCl2和CaCl2-MgCl2九个侧边二元系相图和热力学性质,运用Hillert不对称模型,以MgCl为不对称组元计算了RECl3-CgCl2-MgCl2系列三元系相图,并简要讨论了不对称组元的选取原则。 相似文献
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使用自行设计的受控气氛热重装置研究了MoO3-MoO2-H2O-H2系平衡,在PH2O/PH2从0.412至0.609,温度从400至534℃范围内直接测定了反应:MoO3+H2=MoO2+H2O(g)的平衡常数与温度间的关系为1gKp=0.702-739.8/T。获得298.15K下MoO3标准生成焓及绝对熵分别为:-845.75kJ·mole^-1及78.16J·K^-1·mole^-1.实验 相似文献
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ZHENG Chaogui BAO Chenglin QIAO Zhiyu YE Yupu Peking University Beijing China University of Science Technology Beijing Beijing China Associate Professor Department of Chemistry Peking University Beijing China 《金属学报(英文版)》1993,6(7):46-51
Five fields corresponding to the primary crystallization of PrCl_3,Sr_3PrCl_9,α(SrCl_2,CaCl_2),α_1(CaCl_2,SrCl_2)and α_2(SrCl_2,CaCl_2)respectively,six univariant lines relatedto the secondary crystallization,one ternary eutectic(48.0 wt-% PrCl_3,23.5 wt-% SrCl_2;590℃)and ternary peritectic point(45.5 wt-% PrCl_3,24.5 wt-% SrCl_2;614℃)were determined by DTA.Attempts were also made to explore the rule governing thealteration in the phase diagram containing rare earth chloride,formation of compoundand its stability by means of polarization and counter-polarization. 相似文献
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ZHENG Chaogui LIU Hongping YE Yupu 《金属学报(英文版)》1990,3(10):284-286
Three surfaces corresponding to the primary crystallization of PrCl_3,CaCl_2 andMgCl_2 respectively,3 univariant curves related to the secondary crystallization and a ternaryeutectic(44.8 wt-% PrCl_3,31.8 wt-% CaCl_2,546℃)were found in systemPrCl_3-CaCl_2-MgCl_2 by means of DTA.A reaction occurs in this system:L=PrCl_3+CaCl_2+MgCl_2. 相似文献
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QIAO Zhiyu WANG Mingsheng ZHENG Chaogui DUAN Shuzhen University of Science Technology Beijing Beijing China Qiao Zhiyu Professor Dept.of Physical Chemistry University of Science Technology Beijing Xueyuan Road Beijing China 《金属学报(英文版)》1990,3(7):15-19
PrCl_3-NaCl-LiCl phase diagram has been constructed from the phase diagrams of itssub-binary systems and of six quasi-binary systems measured by DTA technique.It is foundthat this ternary system is composed of five liquidus surfaces,seven second crystallizationlines,two peritectic points and one eutectie point.The temperatures and compositions ofinvariant points are as follows:P_1(416℃,30.3 mol% NaCl,44.2 mol% LiCl,25.5 mol%PrCl_3);P_2(409℃,25.0 mol% NaCl,50.0 mol% LiCl,25.0 mol% PrCl_3);E(404℃,20.0mol% NaCl,55.4 mol% LiCl,24.6 mol% PrCl_3). 相似文献
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本文用差热分析法重新测定了组成PrCl_3-NaCl-LiCl三元系的三个侧边二元系相图,测定了该三元系中6个不同组成的变温截面,从而构筑了PrCl_3-NaCl-LiCl三元相图。该三元系由分别对应于PrCl_3,NaCl,2NaCl·LiCl,NaCl·LiCl和LiCl的5个液相面,7条二次结晶线,两个转熔点和一个共晶点构成。转熔点和共晶点的温度和组成分别为:P_1(416℃,30.3mol%NaCl,44.2mol%LiCl,25.5mol%PrCl_3);P_2(409℃,25.0mol%NaCl,50.0mol%LiCl,25.0mol%PrCl_3);E(404℃,20.0mol%NaCl,55.4mol%LiCl,24.6mol%PrCl_3)。二元和三元相图液相限的测量误差约为±5℃和±7℃。 相似文献
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LI Ruiqing Beijing General Research Institute for Non-ferrous Metals Beijing ChinaZHOU Guozhi University of Science Technology Beijing Beijing China 《金属学报(英文版)》1989,2(12):380-385
The mathematical formulas are given for calculating the partial molar thermodynamic proper-ties in a ternary system from its three corresponding binary systems based on the new ternarysymmetric model presented by the authors in the foregoing paper.Applying this model toNaCl-BaCl_2-SrCl_2 system,the phase diagram of which as well as some isothermal sectionshave been calculated.The devations of temperature between the calculated and experimen-tal diagrams are less than five degrees. 相似文献
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ZHANG Yifeng MENG Bo GU Yunyan Northeast University of Technology Shenyang China Professor Department of Chemistry Northeast University of Technology Shenyang China 《金属学报(英文版)》1992,5(9):219-220
The phase diagrams of binary systems SmCl_3-CaCl_2 and SmCl_3-LiCl were determined byDTA and X-ray diffraction analysis.The system SmCl_3-CaCl_2 is of a simple eutectic typewith eutectic point of 55.8mol-% SmCl_3 at 545℃.The system SmCl_3-LiCl is of the typewith incongruent melting phase 2SmCl_3·LiCl at peritectic point 434℃ and with eutecticpoint of 31.5 mol-% SmCl_3 at 395℃. 相似文献
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用室温、高温X射线衍射及淬火的方法,测定了Bi-Pb-Tl三元系25℃的等温截面及该体系中的相结构。 相似文献
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M.ELLNER 《金属学报(英文版)》1992,5(9):221-223
Isothermal section at 25℃ of phase diagram and phase structure of Bi-Pb-Tl ternary systemhave been studied by means of room and high temperature X-ray diffraction and quenching. 相似文献