The synthesis and fabrication of one-dimensional nanoscale heterojunctions

There are a variety of methods for synthesizing or fabricating one-dimensional (1D) nanostructures containing heterojunctions between different materials. Here we review recent developments in the synthesis and fabrication of heterojunctions formed between different materials within the same 1D nanostructure or between different 1D nanostructures composed of different materials. Structures containing 1D nanoscale heterojunctions exhibit interesting chemistry as well as size, shape, and material-dependent properties that are unique when compared to single-component materials. This leads to new or enhanced properties or multifunctionality useful for a variety of applications in electronics, photonics, catalysis, and sensing, for example. This review separates the methods into vapor-phase synthesis, solution-phase synthesis, template-based synthesis, and other approaches, such as lithography, electrospinning, and assembly. These methods are used to form a variety of heterojunctions, including segmented, core/shell, branched, or crossed, from different combinations of semiconductor, metal, carbon, and polymeric materials.     

Surface plasmon resonance spectroscopy based on evanescent field treatment

The reflectance in a surface plasmon resonance (SPR) curve can be expressed in terms of the integration of the product between the evanescent electric field and the imaginary part of the dielectric constant of all absorbing media. The evanescent field in the metal film consists of two fields, one originating at the prism/metal interface and the other at the metal/dielectric interface. Near the resonance angle, the evanescent field strength at the metal/dielectric interface is much greater than that at the prism/metal interface. The evanescent field in dielectric medium has a single origin at the metal/dielectric interface. Due to the optical enhancement at the interface, the amplitude of the evanescent electric field in the dielectric medium is much greater than that in the metal film. This field, however, is not being utilized in conventional SPR where changes in the refractive index of the nonabsorbing dielectric media are of interest. In a system with an absorbing dielectric medium, the absorption of the medium is enhanced by the strong evanescent electric field. The evanescent field distributions in the metal film and in the dielectric medium are significantly altered by the absorbing dielectric, which results in shifting of the resonance angle, increasing of the reflectance, and broadening of the SPR curve. Since the absorption contribution from the absorbing dielectric can be separated from that of the metal film via knowledge of evanescent field distribution, an in-depth analysis of the SPR curve of an absorbing medium and its relationship with the material characteristics are possible.     

Numerical simulation of characteristics of near-field microstrip probe having pyramidal shape

A pyramid-type microstrip probe (PTMP) with metal tips is proposed for scanning near-field microscopes to obtain high spatial resolution of a few nanometers and high optical efficiency. Properties of an ordinary PTMP and the PTMP with a single metal tip are investigated by using a rigorous finite-integral technique simulation (MICROWAVE STUDIO package) and analyzing characteristics of working modes of the probe. Numerical simulation has demonstrated that an ordinary PTMP and the PTMT with a single metal tip exhibit large far- and near-transmission coefficients, field enhancement, and high spatial resolution. These high parameters imply that both types of microstrip probe may be utilized for optical and magnetic data storage, nanolithography, and other types of nanotechnology that use light for modification of a thin surface layer.     

Using direct nanoimprinting of ferroelectric films to prepare devices exhibiting bi-directionally tunable surface plasmon resonances

In this paper, we describe an imprint method for the fabrication of bi-directionally tunable surface plasmon resonance (SPR) filters. A periodic metal/ferroelectric film stack exhibiting SPR phenomena was directly imprinted using a sharp mold without the need for a polymer-based resist. Both the refractive index of the surrounding lead zirconate titanate (PZT) films and the period of the textured PZT/metal/PZT structure were dependent upon both the absolute value and sign of the applied potential. The SPR wavelength of the PZT/gold/PZT-based tunable filter varied over a range of greater than 100?nm when applying potentials ranging from 0 to -15?V. This imprinting method has great potential for use in the fabrication of tunable optical filters without the need for complicated processes or specific materials.     

Elementary Excitations of Antiferromagnetic Spin-1 Bosons in an Optical Lattice

We study elementary excitations of spin-1 bosons with antiferromagnetic interaction in an optical lattice by applying the Gutzwiller approximation to the spin-1 Bose-Hubbard model. There appear various excitations associated with spin degrees of freedom in the Mott-insulator (MI) phase as well as in the superfluid (SF) phase. In this system, the ground state in the MI phase is known to exhibit a remarkable effect of even-odd parity of particle filling, in which even fillings stabilize the MI state due to formation of spin-singlet pairs. We find that excitation spectra in the MI phase exhibit characteristic features that reflect the even-odd parity effect of the ground state. We clarify evolution of elementary excitations across the quantum critical point of the SF-MI transition.     

Tuned longitudinal surface plasmon resonance and third-order nonlinear optical properties of gold nanorods

In order to elucidate the relationship for third-order nonlinear optical properties of anisotropic metal nanoparticles between the incident laser wavelength and surface plasmon resonance (SPR) wavelength, gold nanorods (GNRs) with a tuned longitudinal SPR mode in frequency were prepared by seed-mediated methods with two different surfactants, cetyltrimethylammonium bromide (CTAB) and benzyldimethylammonium chloride (BDAC). The real and imaginary parts of the third-order nonlinear optical susceptibilities χ(3) were examined by near-infrared (800 nm) femtosecond Z-scan and I-scan techniques for various gold sols with SPR wavelengths of 530 nm (spheres), 800 nm (nanorods) and 1000 nm (nanorods), named as 530GNSs, 800GNRs and 1000GNRs, respectively. All the samples showed intrinsically third-order nonlinear optical refractive responses. However, as for the real part of χ(3) for one particle, 800GNRs whose plasmon peak was tuned to the incident laser wavelength exhibited a Reχ(3) value 45 times stronger than 530GNSs. More interestingly, the imaginary part of χ(3) was more greatly influenced at the tuned SPR wavelength. Here we first demonstrate that 800GNRs showed plasmon-enhanced saturable absorption (SA) due to a longitudinal SPR tuned to the incident laser wavelength.     

Analysis of accuracy in prism coupling methods and a proposal of two simple ways for coupling to guided waves and/or for exciting surface plasmon resonance

The stationarity of the coupling spot in relation with different shapes of couplers is discussed. The accuracy in measuring the effective index by various couplers is analyzed. Two simple methods are proposed to couple light into guided waves and/or to excite surface plasmon resonance (SPR). One uses an optical block as a coupler and the incident beam falls onto it in two perpendicular directions. This method is particularly useful for exciting SPR at an interface between metal and anisotropic dielectric media, but also can be used to couple light into guided waves. Another method does not need any coupler. The incident beam is directly launched into the sample from the sustrate side. When a thin metal film is deposited on the substrate and covered either by air or another dielectric layer, SPR can be excited at the interface of metal/air of metal/dielectric. This method can be viewed as an alternative of Kretschmann configuration.     

Metallic film optimization in a surface plasmon resonance biosensor by the extended Rouard method

The extended Rouard method is applied to the computation of a multi-absorbing-layer system for the optimization of surface plasmon resonance (SPR) sensors. Specifically, the effect of the properties of a metallic layer on the shape of the reflectivity and sensitivity curve is demonstrated in the case of a Kretschmann configuration. This theoretical investigation allows us to establish the best optical properties of the metal to obtain a localized SPR, given the illuminating beam properties. Toward the development of a sensitive biosensor based on SPR, we quantify the changes in reflectivity of such an optical biosensor induced by the deposition of a nanometric biochemical film as a function of the metal film characteristics and the illumination operating conditions. The sensitivity of the system emphasizes the potential of such biophotonic technology using metallic multilayer configurations, especially with envisioned metamaterials.     

Ultrafast near-field spectroscopy of single semiconductor quantum dots

Excitonic and spin excitations of single semiconductor quantum dots (QDs) currently attract attention as possible candidates for solid-state-based implementations of quantum logic devices. Due to their rather short decoherence times in the picosecond to nanosecond range, such implementations rely on using ultrafast optical pulses to probe and control coherent polarizations. We combine ultrafast spectroscopy and near-field microscopy to probe the nonlinear optical response of a single QD on a femtosecond time-scale. Transient reflectivity spectra show pronounced oscillations around the QD exciton line. These oscillations reflect phase-disturbing Coulomb interactions between the excitonic QD polarization and continuum excitations. The results show that although semiconductor QDs resemble in many respects atomic systems, Coulomb many-body interactions can contribute significantly to their optical nonlinearities on ultrashort time-scales.     

System-on-Chip Circuit Architecture for Eliminating Interferents in Surface Plasmon Resonance Sensing Systems

This paper presents a system-on-chip circuit architecture that enables the extraction of concentration information directly from a surface plasmon resonance (SPR) probe, independent of ambient fluctuations in the reference medium, temperature, and background light. Compensation for these baseline (bulk) interferences is embedded into the baseline integration state of the photodetectors in the optical path, creating a ldquoflat linerdquo for the baseline [no analyte present/bulk refractive index (RI)] condition and the characteristic SPR dips for the measurement (analyte present) condition. A resolution of 2 times 10^-4 RI units is possible with this system, comparable to the 5 times 10^-4 RI unit resolution of conventional signal processing (software-based) approaches to processing the same data using a similar framework. This approach demonstrates experimentally the capability of the dip-based SPR probe in a portable footprint for detecting RI at resolution levels suitable for practical applications of these probes to field environments.     

Local detection of electromagnetic energy transport below the diffraction limit in metal nanoparticle plasmon waveguides

Achieving control of light-material interactions for photonic device applications at nanoscale dimensions will require structures that guide electromagnetic energy with a lateral mode confinement below the diffraction limit of light. This cannot be achieved by using conventional waveguides or photonic crystals. It has been suggested that electromagnetic energy can be guided below the diffraction limit along chains of closely spaced metal nanoparticles that convert the optical mode into non-radiating surface plasmons. A variety of methods such as electron beam lithography and self-assembly have been used to construct metal nanoparticle plasmon waveguides. However, all investigations of the optical properties of these waveguides have so far been confined to collective excitations, and direct experimental evidence for energy transport along plasmon waveguides has proved elusive. Here we present observations of electromagnetic energy transport from a localized subwavelength source to a localized detector over distances of about 0.5 microm in plasmon waveguides consisting of closely spaced silver rods. The waveguides are excited by the tip of a near-field scanning optical microscope, and energy transport is probed by using fluorescent nanospheres.     

Side-polished multimode fiber biosensor based on surface plasmon resonance with halogen light

A side-polished multimode fiber sensor based on surface plasmon resonance (SPR) as the transducing element with a halogen light source is proposed. The SPR fiber sensor is side polished until half the core is closed and coated with a 37 nm gold thin film by dc sputtering. The SPR curve on the optical spectrum is described by an optical spectrum analyzer and can sense a range of widths in wavelengths of SPR effects. The measurement system using the halogen light source is constructed for several real-time detections that are carried out for the measurement of the index liquid detections for the sensitivity analysis. The sensing fiber is demonstrated with a series of refractive index (RI) liquids and set for several experiments, including the stability, repeatability, and resolution calibration. The results for the halogen light source with the resolution of the measurement based on wavelength interrogation were 3 x 10(-6) refractive index units (RIUs). The SPR dip shifted in wavelength is used as a measure of the RI change at a surface, and this RI change varies directly with the number of biomolecules at the surface. The SPR dip shift in wavelength, which was hybridized at 0.1 microM of the target DNA to the probe DNA, was 8.66 nm. The all-fiber multimode SPR sensor, which has the advantages of being low cost, being disposable, having high stability and linearity, being free of labeling, and having potential for real-time detection, permit the sensor and system to be used in biochemical sensing and environmental monitoring.     

Hybrid colloidal plasmonic-photonic crystals

We review the recently emerged class of hybrid metal-dielectric colloidal photonic crystals. The hybrid approach is understood as the combination of a dielectric photonic crystal with a continuous metal film. It allows to achieve a strong modification of the optical properties of photonic crystals by involving the light scattering at electronic excitations in the metal component into moulding of the light flow in series to the diffraction resonances occurring in the body of the photonic crystal. We consider different realizations of hybrid plasmonic-photonic crystals based on two- and three-dimensional colloidal photonic crystals in association with flat and corrugated metal films. In agreement with model calculations, different resonance phenomena determine the optical response of hybrid crystals leading to a broadly tuneable functionality of these crystals.     

Dispersion relation due to plasmon excitation in nanostructures by charged particles

One of the most remarkable features of nanostructured materials is that their optical response due to plasmon excitation is very sensitive to their geometry and composition. The interaction of charged particles with the electron gas of the considered system is one of the most used methods to excite and study collective excitations (plasmons). In this work we study the similarities and differences arising in these excitations due to the interaction of the charged particles with different dielectric functions in a variety of nanoscopic systems (capillaries, wires, tubules, spheres). The obtained dispersion relations are very sensitive to the chosen dielectric functions, an important aspect due to the increasing requirement of devices of reduced dimensions for their application in different areas.     

Infrared metamaterial phase holograms

As a result of advances in nanotechnology and the burgeoning capabilities for fabricating materials with controlled nanoscale geometries, the traditional notion of what constitutes an optical device continues to evolve. The fusion of maturing low-cost lithographic techniques with newer optical design strategies has enabled the introduction of artificially structured metamaterials in place of conventional materials for improving optical components as well as realizing new optical functionality. Here we demonstrate multilayer, lithographically patterned, subwavelength, metal elements, whose distribution forms a computer-generated phase hologram in the infrared region (10.6 μm). Metal inclusions exhibit extremely large scattering and can be implemented in metamaterials that exhibit a wide range of effective medium response, including anomalously large or negative refractive index; optical magnetism; and controlled anisotropy. This large palette of metamaterial responses can be leveraged to achieve greater control over the propagation of light, leading to more compact, efficient and versatile optical components.     

Mass sensitivity calculation of the protein layer using love wave SAW biosensor

Love waves, a variety of surface acoustic waves (SAWs), can be used to detect very small biological surface interactions and so have a wide range of potential applications. To demonstrate the practicality of a Love wave SAW biosensor, we fabricated a 155-MHz Love wave SAW biosensor and compared it with a commercial surface Plasmon resonance (SPR) using glycerol-water solution with known densities and viscosities to calibrate the response signals of the biosensors. And the mass per unit area of anti-mouse IgG bound with protein G onto the sensitive layer of the biosensor was calculated on the basis of the calibration result. The sensitivity of the Love wave SAW biosensor was the same as or greater than that of the SPR biosensor. Furthermore, the Love wave SAW biosensor was capable of measuring a much wider range of viscosities than the SPR biosensor. Although the operating principle of the Love wave SAW biosensor is completely different from that of the SPR biosensor, the subtle changes in the viscoelastic properties of the biological layer that accompany biological binding reactions on the sensitive layer can be monitored and measured in the same ways as with the SPR biosensor.     

Sensitivity of optical sensors based on laser-excited surface-plasmon waves.

We investigate the effect of the divergence of a Gaussian laser beam on the resonance curve and the sensitivity of optical sensors based on surface-plasmon resonance (SPR). For He-Ne laser beams it is found that, for beams with a waist radius of less than 300 mum, the SPR-curve characteristics differ appreciably from the case in which a plane wave is considered. Simple expressions for the sensitivity of (bio)chemical sensors are given. A simple Lorentzian model is used to estimate the maximum possible sensitivity when a multilayer system is used to enhance the resonance peak. It was found that the sensitivity can reach its highest value when the width of the SPR curve is equal to the laser-beam divergence. The results could be particularly important when a SPR curve is used to measure the absolute value of the refractive index of a sample or the dielectric constant and the thickness of a metal layer.     

Waveguide analysis of heat-drawn and chemically etched probe tips for scanning near-field optical microscopy

We analyze two basic aspects of a scanning near-field optical microscope (SNOM) probe's operation: (i) spot-size evolution of the electric field along the probe with and without a metal layer, and (ii) a modal analysis of the SNOM probe, particularly in close proximity to the aperture. A slab waveguide model is utilized to minimize the analytical complexity, yet provides useful quantitative results--including losses associated with the metal coating--which can then be used as design rules.     

Influence of skew rays on the sensitivity and signal-to-noise ratio of a fiber-optic surface-plasmon-resonance sensor: a theoretical study

We have theoretically analyzed the influence of skew rays on the performance of a fiber-optic sensor based on surface plasmon resonance. The performance of the sensor has been evaluated in terms of its sensitivity and signal-to-noise ratio (SNR). The theoretical model for skewness dependence includes the material dispersion in fiber cores and metal layers, simultaneous excitation of skew rays, and meridional rays in the fiber core along with all guided rays launching from a collimated light source. The effect of skew rays on the SNR and the sensitivity of the sensor with two different metals has been compared. The same comparison is carried out for the different values of design parameters such as numerical aperture, fiber core diameter, and the length of the surface-plasmon-resonance (SPR) active sensing region. This detailed analysis for the effect of skewness on the SNR and the sensitivity of the sensor leads us to achieve the best possible performance from a fiber-optic SPR sensor against the skewness in the optical fiber.