Development of A Series NV-F Grade Extra High Strength Plate Steels for Offshore Structure and Shipbuilding

Systematic research on developing a series of extra high strength steel plates for shipbuilding via thermomechanical control process (TMCP) is introduced.A microalloyed low carbon-equivalent SiMnCrNiCu steel was used to develop F460 steel.Ultra low carbon Cu-Ni containing steels were used to develop NV-F550,NV-F620 and NV-F690 steel plates.The effect of TMCP parameters on microstructure and properties was investigated by test-scale plant trials.Industrial production trials were conducted to verify the validity of the laboratory studies on the F460 steel.Heavy plates in 45-60 mm thickness met Det Norske Veritas NV-F460 specification.The effect of heat-input on the mechanical properties of the coarse-grained-heat-affect-zone (CGHAZ) of the advanced heavy plates was studied.     

海洋平台用钢EH40-Z35的开发

通过向钢中添加Nb、V、Ti等微合金元素和采用TMCP工艺,开发出符合ABS、CCS、DNV等九国船级社认证规范的海洋平台用钢EH40-Z35。产品具有良好的抗层状撕裂性、低冷裂纹敏感性以及良好的焊接性能和低温韧性。     

海洋平台用钢的研发生产现状与发展趋势

介绍了国内外海洋平台用钢发展现状,总结出海洋平台用钢生产的主要特点,对传统海洋平台用钢的成分、工艺、组织、性能特征及其局限性进行了分析,提出了开发"Mn/C"合金化新型高强韧海洋平台用钢的发展思路,对海洋平台用钢今后的发展趋势加以展望。鉴于我国高级别海洋工程用钢与国外相比仍存在一定的差距,关键产品还依赖于进口,今后应重点研制屈服强度为690 MPa级的海洋平台用高强韧钢。     

TMCP工艺生产E420海洋平台用钢板的组织与性能研究

介绍了E420海洋平台用钢板的成分性能要求,根据成分和工艺参数对力学性能的影响,对采用TMCP工艺生产的钢板组织与性能进行了研究,通过回火工艺验证,最终成功研发出组织和性能符合要求的E420钢板,为更高级别、更大厚度海洋平台用钢板的开发提供了技术储备。     

高性能船舶及海洋工程用钢的开发

 对高性能船舶及海洋工程用钢的需求背景与研究进展进行了综述,并介绍了高品质船舶及海洋工程用钢的发展方向。海洋石油工业的飞速发展给造船及海洋工程用钢提出了高强度、高韧性、大线能量焊接、良好的耐腐蚀性以及大厚度、大尺寸规格的要求。     

500MPa级高性能桥梁钢板的焊接性研究

结合焊接性理论分析,对500 MPa级高性能桥梁钢板开展了焊接热影响区最高硬度、斜Y坡口焊接裂纹和对接接头系列温度冲击试验研究。试验结果表明,试验钢的碳当量CEV为0.44%,Pcm为18%,在室温下焊接热影响区最高硬度为274 HV10,淬硬倾向小;采用焊条电弧焊和气体保护焊时,板厚≤32 mm时不需要预热;板厚32~60 mm时需要预热80℃;焊接热影响区的ETT50达到-60℃,具有良好的低温冲击韧性。试验钢板焊接性良好,可应用于高性能桥梁的建设。     

大线能量焊接用船体结构钢的研究进展

介绍了大线能量焊接在船舶建造中的应用,对比了船体结构钢与其它钢种对大线能量焊接适应性的不同要求。针对大线能量焊接热影响区韧性下降问题,提出了目前提高热影响区韧性的主要措施。指出降低碳当量、细化热影响区奥氏体晶粒尺寸、利用有益氧化物诱导晶内铁素体析出是提高船体结构钢大线能量焊接适应性的有效途径。介绍了鞍钢在热影响区组织调控技术和氧化物诱导机理研究等方面取得的成果。     

V-N微合金化海洋石油平台用钢实验室研究

采用V-N微合金化技术思路成功设计出E36级海洋石油平台用钢的化学成分,采取第三代TMCP工艺进行试验钢轧制,其力学性能满足GB712-2000《船体结构钢》的要求.     

An Analysis on Application and Trend of Low-Alloy Steel in Shipbuilding and Offshore Engineering Industry

Since 2003,China shipbuilding industry has stepped into the orbit of fast growth.In this paper,a brief analysis has been made on application of low-alloy steel in the shipbuilding and offshore engineering industry,and the further requirements on the marine steel plates elaborated in combination with the future development trend in this industry.Meanwhile,a reference approach is proposed for potential cooperation between the shipbuilding industry and steel industry.     

Different Roles for Vanadium as a Microalloying Element in Structural Steels

Vanadium is the most versatile of the microalloying elements used in steels.The present paper describes three separate ways in which vanadium is used to optimize mechanical properties in different products.Firstly,precipitation of V(C,N) during the γ→α transformation or in ferrite during cooling provides strengthening that is especially useful in long products and forgings.Additionally,VN particles which precipitate in austenite act as efficient intra-granular nucleants for ferrite,contributing improved strength and toughness in suitable process routes such as seamless pipe production.Thirdly,vanadium is supremely effective in preventing recovery in martensite and bainite.In this way it can be applied to maintain strength and reduces variability of properties in hot rolled strip steels.     

高强船板探伤缺陷原因分析

采用金相显微镜、扫描显微镜对14 mm厚高强船板超声波探伤不合格原因进行分析。结果表明,连铸过程中结晶器液位波动致使结晶器保护渣卷入连铸坯,形成的球状氧化物及超出评级标准的超大硅酸盐类非金属夹杂物是探伤不合格的原因。采取优化结晶器保护渣性能、严控浇铸过程中氩气流量,调整浸入式水口浸入深度等措施后,高强船板在后续生产中能够满足探伤要求。     

特厚EH47止裂钢板及焊接热影响区的组织性能

为开发大型集装箱船用特厚EH47止裂钢板,提出了一种低碳微合金MnCrNiCu钢,研究了其变形奥氏体连续冷却相变规律,使用控轧控冷工艺(TMCP)试制出最大厚度为85 mm特厚EH47级钢板,使用埋弧焊(SMA)和药芯焊丝气保焊(FCAW)技术对最厚钢板进行焊接试验,研究钢板和焊接接头的显微组织和性能.通过系列V缺口 ...     

硼对低焊接裂纹敏感性高强钢组织性能的影响

 分析了在控轧、控轧加回火、调质等不同工艺条件下,硼对低焊接裂纹敏感性钢显微组织和力学性能的影响。结果表明,硼抑制先共析铁素体形成,提高淬透性,在控轧工艺下含硼钢形成粗大的贝氏体和马氏体组织,并保留了原始奥氏体晶界;调质工艺得到回火索氏体组织,但含硼钢的大角度晶界比例与无硼钢相比较低。硼在强度上的作用显著,上述3种工艺下含硼钢的抗拉强度分别比无硼钢高300, 214, 101MPa,屈服强度分别高320,259,144MPa,但伸长率和冲击韧性均有所降低。无硼钢在调质工艺下、含硼钢在控轧加回火工艺下具有较好的强韧性匹配。     

80mm厚高韧性工程机械用Q460级TMCP钢的研制

采用低碳Cr-Mo系添加微量强碳化物形成元素的成分设计,通过TMCP工艺控制,获得均匀铁素体/贝氏体组织,充分发挥析出强化、细晶强化和贝氏体组织强化作用,研制80 mm厚高韧性工程机械用Q460钢。试制钢板力学性能均匀,不仅具有良好的拉伸力学性能,且低温冲击韧性优良,-60℃冲击功大于180 J,冲击断口呈明显塑性变形;SEM分析表明,断口微观形貌韧窝特征明显,面积约为55%,韧窝内圆形氧化物夹杂细小;钢板厚度方向铁素体/贝氏体组织均匀,晶粒尺寸约为8～10μm;TEM分析表明,晶内存在高密度位错,大量细小弥散的第二相粒子沿位错线析出。     

北极海洋平台用Q355E热轧H型钢连续冷却转变规律

在实验室利用Gleeble-3500热模拟试验机对3种Nb、V微合金化Q355E热轧H型钢进行了连续冷却转变规律测试,研究了冷却速度对试验钢组织与硬度的影响。结果表明:在冷速为0.5℃/s时,组织中开始出现贝氏体;冷速大于7℃/s时,珠光体转变即终止。在中等冷速下,Nb的加入促进了贝氏体的形成,抑制了铁素体与珠光体的形核;并且Nb的加入使铁素体转变区右移。Cr的加入降低了较高冷速下铁素体与珠光体相变点,并促进了高冷速下马氏体的形成。由于受V析出的影响,含V试验钢在冷速为1℃/s时其硬度曲线有一个"波谷"。3种试验钢的冷速在0.5~3℃/s之间时,试验钢可获得强韧性较好的细小准多边形铁素体、少量珠光体与贝氏体的复合组织。     

Effect of Tempering Temperature on Microstructure and Properties of E690 Offshore Plate Steel

 A new kind of Mn-Mo-Nb-Cu-B bainite steel which satisfied mechanical demands of E690 offshore plate steel was designed. The effect of two processes——thermomechanical control process (TMCP)+tempering (T) and thermomechanical control process (TMCP)+reheating and quenching (RQ)+tempering (T)——on microstructure and mechanical properties were studied by means of scan electron microscope (SEM), transmission electron microscope (TEM) and electron back scatter diffraction (EBSD). The results showed that optimal mechanical properties were available when tempering at 550 ℃ for both processes. The microstructure of the TMCP+T treated sample tempering in the range of 450 to 550 ℃ for 1 h did not change dramatically yet the lath in the TMCP+RQ+T treated sample merged together and transformed into polygonal ferrite. At the same time, the sub-structure of grain bainite transformed from lath to cell-shape to refine grains with tempering temperature mounting. Lots of sub-grain boundaries were located within bainite and adjacent bainite grain boundaries were high angle.     

珠钢Ti微合金化高强耐候钢系列产品开发与应用

在薄板坯连铸连轧流程上,经过对Ti微合金化技术研究,有效地解决了Ti微合金化性能波动大的问题,开发出屈服强度450～700 MPa高强耐候钢.通过对试制钢的组织性能和应用研究,表明该产品具有良好的通板性能,成形性能和焊接性能,满足集装箱和汽车制造行业要求,具有广阔市场前景.     

海洋石油平台用H型钢生产工艺分析与改进

针对莱钢在生产SM490YB海洋石油平台用H型钢时出现的腹板开裂、冲击功不合等问题,取样进行了成分、断口和金相分析。结果表明,包晶反应、夹杂物、魏氏组织及晶粒度不均是导致缺陷产生的原因。经实施调整C含量控制范围,加强精炼控制,采用全程保护浇注,控制加热温度和终轧温度等措施,H型钢腹板裂纹问题得到彻底解决,组织细化均匀,冲击功明显提高。     

Q345C低合金高强度结构钢板的试制

介绍采用氧气顶吹转炉→吹氩喂丝→板坯连铸→控制轧制生产Q345C低合金高强度结构钢板的生产工艺。通过对化学成分的合理设计及制订适合该厂冶炼、连铸、轧制的工艺，采取微合金化和控轧控冷相结合的有效技术措施，提高钢板的综合性能，特别是低温冲击韧性。生产的Q345C钢板，其产品质量完全符合GB／T1591—94标准要求。