Moisture durability of four moisture cure urethane adhesives

Moisture durability of four low modulus adhesives was examined. The four low modulus adhesives all had the same basic moisture cure polymer but contained different fillers and additives. Hot-dipped galvanized steel was bonded to random fiber-reinforced unsaturated polyester and aged in two moisture environments for various durations. Adherend surface wipes included acetone, isopropyl alcohol and a typical surface contamination for galvanized steel (an organic lubricant). Diffusion coefficients, moisture uptake and modulus changes due to moisture environment were determined for the adhesives and the fiber-reinforced plastic (FRP). The moisture cure adhesive with clay and poly(vinyl chloride) (PVC) as fillers (adhesive 252) had the highest retained lap joint strengths. Initially, adhesive 252 had single lap joint strengths of 1.47 ± 0.08 MPa for acetone-wiped joints and 1.39 ± 0.33 MPa for organic lubricant-wiped joints. After accelerated aging in a cataplasma environment for 9 weeks, lap joint strengths fell to 0.61 ± 0.08 MPa for acetone-wiped joints and to 0.65 ± 0.11 MPa for organic lubricant-wiped joints. Environmental scanning electron microscopy (ESEM) and energy-dispersive spectrometry (EDS) showed that the actual failure locus was through a corroded zinc layer and between the adhesive and the zinc surface after aging. Dynamic mechanical analysis (DMA) showed that the modulus for adhesive 252 dropped from 21.7 to 13.9 MPa after cataplasma aging. From finite element analysis (FEA), this modulus drop corresponded to a drop in normal stress concentration from 0.75 to 0.57, and a drop in shear stress concentration from 1.41 to 1.36 at a point 0.5 mm from the end of the single lap joint overlap.     

Evaluation of Mode-II Fracture Energy of Adhesive Joints with Different Bond Thickness

A study on the mode-II edge-sliding fracture behaviour of aluminium-adhesive joints was carried out. Compact pure shear (CPS) adhesive joints of different bond thickness were produced using a rubber-modified epoxy resin as the adhesive. An analytical model was developed to calculate the stress distribution along the bond line of the joint. A crack-closure technique was used to evaluate the mode-II strain energy release rate. G _II, as a function of the adhesive bond thickness. The results indicated that for a given applied load, G _II increased gradually with the bond thickness. A finite element model (FEM) was also developed to evaluate the stress state along the bond line and the strain energy release rate of the CPS specimens. Consistent results were obtained between the theoretical model and finite element analysis. Scanning electron micrographs of the fracture surface illustrated a mainly interfacial fracture path between the adherends and the adhesive for all adhesive joint specimens. The critical fracture load increased very rapidly with bond thickness in the range 0.02 mm to 0.1 mm but remained constant thereafter. However, the mode-II critical fracture energy rose more gradually as the bond thickness was increased.     

Evaluation of Mode-II Fracture Energy of Adhesive Joints with Different Bond Thickness

A study on the mode-II edge-sliding fracture behaviour of aluminium-adhesive joints was carried out. Compact pure shear (CPS) adhesive joints of different bond thickness were produced using a rubber-modified epoxy resin as the adhesive. An analytical model was developed to calculate the stress distribution along the bond line of the joint. A crack-closure technique was used to evaluate the mode-II strain energy release rate. G_II, as a function of the adhesive bond thickness. The results indicated that for a given applied load, G_II increased gradually with the bond thickness. A finite element model (FEM) was also developed to evaluate the stress state along the bond line and the strain energy release rate of the CPS specimens. Consistent results were obtained between the theoretical model and finite element analysis. Scanning electron micrographs of the fracture surface illustrated a mainly interfacial fracture path between the adherends and the adhesive for all adhesive joint specimens. The critical fracture load increased very rapidly with bond thickness in the range 0.02 mm to 0.1 mm but remained constant thereafter. However, the mode-II critical fracture energy rose more gradually as the bond thickness was increased.     

Effects of applied pressure and temperature during curing operation on the strength of tubular single-lap adhesive joints

Adhesive joints have been widely used for fastening thin adherends because they can distribute the load over a larger area than the mechanical joint, require no holes, add very little weight to the structure and have superior fatigue resistance. However, the load capabilities of adhesive joints are affected by both applied pressure and temperature during cure, as well as by service environments because the adhesion characteristics of adhesives are very sensitive to manufacturing and environmental conditions. In this study, the tensile load capabilities of tubular single-lap adhesive joints with an epoxy adhesive were experimentally investigated with respect to service temperature and the applied pressure and temperature during curing operation. The effects of the applied pressure on the tensile load capabilities of tubular single-lap adhesive joints were studied by measuring the actual cure finish temperature using thermocouples and dielectrometry. From the experiments, it was found that the actual cure finish temperature of tubular single-lap adhesive joints increased as applied pressure increased, which increased residual thermal stress in the adhesive layer to decrease the load capabilities of adhesive joints. From finite element analysis and experimental results of tubular singlelap adhesive joints, the optimal geometry condition for adhesive joints was also investigated.     

On the fatigue durability of clad 7075-T6 aluminium alloy bonded joints representative of aircraft repair

The fatigue durability of bonded joints representative of repairs to aircraft structure with and without the presence of a clad layer was investigated by testing aluminium alloy 7075-T6 double lap shear joint specimens. This was done by changing the bonding interface of the outer strap. The joint geometry, central adherend material, adhesive and surface preparation method were all kept the same. On two of the specimen types, the strap material was clad 7075-T6, with one type fabricated with the clad layer left on prior to surface preparation, and the other with the clad layer removed. On the last specimen type, the strap material was unclad 7075-T6. The test results showed that the fatigue durability was lowest when the clad layer was left in-situ, followed closely by those with the clad layer removed. The unclad specimens achieved a fatigue life one order of magnitude greater than those with the clad layer physically removed. Under constant amplitude loading, adhesive fatigue cracking was observed at the location of peak load transfer, which progressed to the interface. Analysis showed that the cracking caused a substrate stress concentration which may have caused the clad fracture. Further analysis, supported by test observations, showed that once a small notch had formed at the interface, damage progression through the outer strap was rapid.     

Effect of Autoclave Bonding Pressure and Temperature on Polycarbonate Single Lap Joints with polyurethane adhesive

Adhesive joints are good replacement for bolted and welded joints. Adhesive joint performance over the life depends on joint strength. Strength of joint depends upon curing process parameters used during bonding. This study investigates the effect of cure temperature and pressure on the mechanical performance of autoclave-bonded single lap joints (SLJ). Joint load transfer capacity (LTC) data and failure mode analysis are provided. Test joints are made of two polycarbonate lexan adherends that are autoclave-bonded together using aliphatic polyether (Polyurethane) film adhesive (Huntsman PE399). Two levels of cure pressure and cure temperature are investigated, for their effect on joint load transfer capacity, failure mode, and joint stiffness after heat cycling at a low or high level of relative humidity. Experimental results showed higher cure temperature increases joint performance.     

Three-dimensional finite element analysis of single-lap adhesive joints under impact loads

This paper deals with the stress wave propagation and stress distribution in single-lap adhesive joints subjected to impact tensile loads with small strain rate. The stress wave propagations and stress distributions in single-lap joints have been analyzed using an elastic three-dimensional finite-element method (DYNA3D). An impact load was applied to the single-lap adhesive joint by dropping a weight. One end of one of the adherends in the single-lap adhesive joint was fixed and the other adherend to which a bar was connected was impacted by the weight. The effects of Young's modulus of the adherends, the overlap length, the adhesive thickness and the adherend thickness on the stress wave propagations and stress distributions at the interfaces have been examined. It was found that the maximum stress occurred near the edge of the interface and that it increased with an increase of Young's modulus of the adherends. It was also seen that the maximum stress increased as the overlap length, the adhesive thickness and the adherend thickness decreased. In addition, strain response of single-lap adhesive joints subjected to impact tensile loads was measured using strain gauges. Fairly good agreements were observed between the numerical and experimental results.     

Experimental Analysis of Static and Fatigue Strength Properties in Press-Fitted and Adhesively Bonded Steel–Aluminium Components

Press-fitted and adhesively bonded joints (Hybrid Joints) are increasingly used as an alternative way to traditional structural joining techniques. The main achievable benefits can be summarized in the possibility of maximizing the load transfer (torque or axial) and reducing both the weight and the stress field of the components, by taking advantage of the adhesive strength. Hybrid joints studies can be found in literature mainly on steel–steel components (Steel Hybrid Joints). The aim of this paper is to provide some relevant information on the static and fatigue strength properties in the case of steel–aluminium components (Mixed Hybrid Joints), from the experimental tests performed on a high strength, single-component adhesive which cures anaerobically. The use of the adhesive increases the press-fitted joint performances, with respect to its release force: the adhesive static shear strength is about 9 MPa, whereas the adhesive endurance limit is about 6 MPa, in presence of a stress ratio R = 0.1.     

CRH3高速动车组空调通风口胶接结构设计

通过理论分析和计算确定了动车组空调通风口部件与铝合金车体胶接用胶粘剂的强度指标。介绍了胶粘剂的选择及胶接结构的设计原则,考查了搭接长度、搭接宽度、胶层厚度和被粘接材料厚度等对胶接件粘接强度的影响。结果表明:车体与空调通风口部件的胶接接头选择受剪切应力作用的搭接接头较适宜,并且搭接接头的承载能力随搭接长度或宽度增加呈先快速上升后趋于稳定态势;当搭接长度为10 mm、胶层厚度为6 mm、铝合金板厚度为5 mm且常温湿固化型单组分PU(聚氨酯)胶粘剂的剪切强度超过0.23 MPa时,搭接接头的承载能力相对最大。     

Three-dimensional finite element stress analysis of single-lap adhesive joints of dissimilar adherends subjected to impact tensile loads

The stress-wave propagations and stress distributions in single-lap joints of dissimilar adherends were analyzed using an elastic three-dimensional finite-element method (DYNA3D). An impact tensile load was applied to the single-lap adhesive joint by dropping a weight. One end of the upper adherend in the single-lap adhesive joint was fixed and the other adherend (lower adherend) which was connected to a bar was impacted by the weight. The effects of Young's modulus and the thickness of each adherend on the stress wave propagations and stress distributions at the interfaces were examined. It was found that the maximum value of the maximum principal stress occurred near the edge of the interface of the fixed adherend. The maximum principal stress increased as Young's modulus of the fixed adherend increased. It was also observed that the maximum principal stress increased as the fixed adherend thickness decreased. In addition, strain responses in the single-lap adhesive joints of dissimilar adherends subjected to impact tensile loads were measured using strain gauges. Fairly good agreements were found between the FEM calculations and the experimental measurements.     

Mechanical damage and strain in carbon fiber thermoplastic‐matrix composite,sensed by electrical resistivity measurement

The volume electrical resistivity of a unidirectional continuous carbon fiber thermoplastic (nylon‐6) matrix composite was found to be an indicator of strain and damage during repeated loading in the fiber direction. The through‐thickness resistivity irreversibly and gradually decreased upon damage (probably fiber‐matrix debonding) during repeated compression or tension. Moreover, it reversibly and abruptly increased upon matrix damage, which occurred reversibly near the peak stress of a stress cycle. In addition, the resistivity increased reversibly upon tension in every stress cycle, and decreased reversibly upon compression in every stress cycle. On the other hand, the longitudinal resistivity irreversibly and gradually increased upon damage. Moreover, it decreased reversibly upon tension in every stress cycle and increased reversibly upon compression in every stress cycle. The through‐thickness resistivity was a better indicator of damage and strain than the longitudinal resistivity.     

Load transfer in adhesive double-sided patch joints

In this work, the application of adhesively bonded joints to connect two structural elements with a double-sided patch is studied. On the basis of the shear lag model, a simple closed-form solution was obtained. The analytical solutions can be used to predict the shear stress in the adhesive and the load transfer between the structural elements and the external patches. The load and shear stress distributions in the adhesively bonded region are presented. For verification of the analytical model, finite element analyses were employed to calculate the load transfer and shear stress for the double-sided patch joint under static tensile loadings. Good agreement was found between the theoretical predictions and numerical results. To obtain a better understanding of the joints, the effects of adhesive thickness, adhesive shear modulus and patch Young's modulus on the load transfer and shear stress distributions were investigated. The results show that the maximum shear stress occurs at the edge of the adhesive. The maximum value of the shear stress increases as the adhesive shear modulus and patch Young's modulus increase and as the adhesive thickness decreases. A more gradual load transfer can be achieved by increasing the adhesive thickness and decreasing the adhesive shear modulus. The simple analytical solution presented in this paper has the advantages of avoiding the numerical difficulties and giving explicit relationship between the stress state and joint parameters. Moreover, from the designer's point of view a closed-form and easy-to-use solution is preferred.     

Piezoelectric monitoring of the reliability of adhesive joints

Since the reliability of adhesively bonded joints for composite structures is dependent on many parameters such as the shape and dimensions of joints, type of applied load, and environment, so an accurate estimation of the fatigue life of adhesively bonded joints is seldom possible, which necessitates an in-situ reliability monitoring of the joints during the operation of structures. In this study, a self-sensor method for adhesively bonded joints was devised, in which the adhesive used works as a piezoelectric material to send changing signals depending on the integrity of the joint. In order to validate the method, the piezoelectric properties of the adhesive were measured during the fatigue test. Electrically conducting adherends were used as electrodes without embedded sensors, and the adhesively bonded joint was modeled as the equivalent parallel circuit composed of electric charge and capacitance. From the investigation, it was found that the electric charge increased gradually as cracks initiated and propagated in the adhesive layer, and had its maximum value when the adhesively bonded joint failed. So it is feasible to monitor the integrity of the joint during its lifetime. Finally, a relationship between the piezoelectric property of the adhesive and crack propagation was obtained from the experimental results.     

Influence of Fabrication Residual Thermal Stresses on Rubber-toughened Adhesive Tubular Single Lap Steel-Steel Joints under Tensile Load

The tensile load bearing capability of adhesively-bonded tubular single lap joints which is calculated under the assumption of linear mechanical adhesive properties is usually much less than the experimentally-determined because the majority of the load transfer of adhesively-bonded joints is accomplished by the nonlinear behavior of rubber-toughened epoxy adhesives. Also, as the adhesive thickness increases, the calculated tensile load bearing capability with the linear mechanical adhesive properties increases, while, on the contrary, the experimentally-determined tensile load bearing capability decreases.

In this paper, the stress analysis of adhesively-bonded tubular single lap steel-steel joints under tensile load was performed taking into account the nonlinear mechanical properties and fabrication residual thermal stresses of the adhesive. The nonlinear tensile properties of the adhesive were approximated by an exponential equation which was represented by the initial tensile modulus and ultimate tensile strength of the adhesive.

Using the results of stress analysis, the failure criterion for the adhesively-bonded tubular single lap steel-steel joints under tensile load was developed, which can be used to predict the load-bearing capability of the joint. From the failure criterion, it was found that the fracture of the adhesively-bonded joint was much influenced by the fabrication residual thermal stresses.     

Determination of the impact tensile strength of structural adhesive butt joints with a modified split Hopkinson pressure bar

The impact tensile strength of structural adhesive butt joints was determined with a modified split Hopkinson pressure bar using hat-shaped specimens. A typical two-part structural epoxy adhesive (Scotch weld^® DP-460) and two different adherend materials (Al alloy 7075-T6 and commercially pure titanium) were used in the adhesion tests. The impact tensile strength of adhesive butt joints with similar adherends was evaluated from the peak value of the applied tensile stress history. The corresponding static tensile strengths were measured on an Instron testing machine using joint specimens of the same geometry as those used in the impact tests. An axisymmetric finite element analysis was performed to investigate the static elastic stress distributions in the adhesive layer of the joint specimens. The effects of loading rate, adherend material and adhesive thickness on the joint tensile strength were examined. The joint tensile strength was clearly observed to increase with the loading rate up to an order of 10⁶ MPa/s, and decrease gradually with the adhesive thickness up to nearly 180 μm, depending on the adherend materials used. The loading rate dependence of the tensile strength was herein discussed in terms of the dominant failure modes in the joint specimens after static and impact testing.     

Impact response of adhesive reversible joints made of thermoplastic nanomodified adhesive

The impact response of a reversible adhesive joint is experimentally assessed in this work. Joint reversibility is improved with a system that uses nanomodification of the thermoplastic adhesive used for bonding plastic components. This system, coupled with electromagnetic induction, is able to guarantee the separation of joints without any damage to the substrates. Drop dart tests at different impact velocities are carried out on neat and nanomodified bonded joints in order to compare the impact behavior before and after the introduction of nanoparticles. Experimental results show that the impact response, assessed in terms of peak load, absorbed energy, and flexural stiffness, can be affected by the introduction of nanoparticles. This work shows that adhesive nanomodified joints represent an effective and applicable solution for the reversible assembling of semi-structural components subjected to low-velocity impact loads.     

Internal stress analysis of epoxy adhesively-boned joints based on their thermomechanical properties at cryogenic temperature

Internal stress analysis is essential to structural design of materials applied in cryogenic engineering. In this contribution, thermomechanical properties including dynamic thermomechanical properties and thermal expansion behavior of four epoxy resins, namely the polyurethane modified epoxy resin (PUE), diglycidyl ether of bisphenol A (DGEBA), tetraglycidyl-4,4′-diaminodiphenylmethane (TGDDM) and triglycidyl-p-aminophenol (TGPAP) were studied by dynamic thermomechanical analysis. Internal stress of the epoxy layer in the bonded joint was calculated based on the thermomechanical properties. Meanwhile, the structure-cryogenic property relationship of epoxy resins were investigated. Results demonstrate that internal stress in the four epoxies bonded joints is 6 ~ 21 MPa at −150°C, and is positively correlated with the average thermal expansion coefficient (CTE) of epoxy resins. TGDDM and TGPAP showed higher retention of lap shear strength both at −196°C and after temperature cycling due to their lower CTE. Morphology of the fractured surface of bonded joints demonstrated that internal stress is responsible for the severe interface failure at −196°C. It reveals that selection of epoxy resins with low CTE is beneficial for designing high-performance epoxy adhesive systems served at cryogenic temperature.     

Ageing of adhesively bonded joints—fracture and failure analysis using video imaging techniques

An investigation into the durability of adhesively bonded joints has been undertaken to help improve the prediction of joint lifetimes. Polymethylmethacrylate (PMMA) substrates have been bonded with a two-part acrylic adhesive to make single lap-shear joints. Joints have been aged in a hot/wet environment (40°C and 95% humidity) with no applied stress for up to 4000 h and were tested in tension. The novel aspect of the research has been the development of a video imaging analysis technique which allows damage initiation and propagation within the joint to be detected as load is applied to the joint. Images of fracture initiation and damage propagation have been correlated with stress/displacement data for joints under tensile loading. The data from aged samples is compared with data from un-aged samples. Both the stresses at which damage is seen to initiate and the final failure stress of the joints decrease as the ageing time increases. The failure mode changes from cohesive failure within the PMMA substrate to failure within the adhesive, near the PMMA/acrylic adhesive interface.     

Behaviour of Bi-adhesive Joints

The use of relatively low modulus adhesive at the ends of overlap in a bi-adhesive bondline of a bonded joint can reduce the stress concentration significantly and, therefore, potentially lead to higher strength of the joint. This study presents the two-dimensional and three-dimensional nonlinear (geometric and material) finite element analyses of adhesively bonded single lap joints having modulus-graded bondline under monotonic loading conditions. The adhesives were modelled as an elasto-plastic multi-linear material, while the substrates were regarded as both linear elastic and bi-linear elasto-plastic material. The computational simulations have been performed to investigate the bondline behaviour by studying the stress and strain distributions both at the mid-plane as well as at the interface of the bondline. It has been observed that the static strength is higher for joints with bi-adhesive bondlines compared to those with single adhesives in bondline. Higher joint strength has also been observed for optimum bi-adhesive bondline ratio through parametric studies. Effects of load level, and bondline thickness on stress distribution in the bi-adhesive bondline have also been studied. 3D analysis results reveal the existence of complex multi-axial stress/strain state at the ends of the overlap in the bondline which cannot be observed in 2D plane strain analysis. About 1/3rd of the width of the joint from the free edge in the width direction has 3D stress state, especially in the compliant adhesive of the bondline. Magnitudes of longitudinal and lateral stress/strain components are comparable to peel stress/strain components. It has also been analytically shown that the in-plane global stiffness of the joint remains unaffected by modulus gradation of the bondline adhesive.     

An efficient analysis model for functionally graded adhesive single lap joints

Employing a functionally graded adhesive the efficiency of adhesively bonded lap joints can be improved significantly. However, up to now, analysis approaches for planar functionally graded adhesive joints are still not addressed well. With this work, an efficient model for the stress analysis of functionally graded adhesive single lap joints which considers peel as well as shear stresses in the adhesive is proposed. Two differential equations of the displacements are derived for the case of an axially loaded adhesive single lap joint. The differential equations are solved using a power series approach. The model incorporates the nonlinear geometric characteristics of a single lap joint under tensile loading and allows for the analysis of various adhesive Young׳s modulus variations. The obtained stress distributions are compared to results of detailed Finite Element analyses and show a good agreement for several single lap joint configurations. In addition, different adhesive Young׳s modulus distributions and their impact on the peel and shear stresses as well as the influence of the adhesive thickness are studied and discussed in detail.