This study was carried out to determine the shear strength of an adhesive on weathered wood, impregnated with a boron compound, using a long term dipping method. The shear strength of D-VTKA adhesive on two types of wood species each containing one of two types of the impregnated material, under different weathering conditions, was measured. The results showed that the highest shear strength (11.01 N/mm2) was obtained with the control samples of untreated, oriental beech wood, and the lowest was obtained for Scots pine impregnated with boric acid after two seasons of exposure (six months). Weather conditions affected the shear strength in a negative way. Finally the results showed that if the boron compounds were supported with non-leaching chemicals, they could be recommended as fire-retardant additives and would extend the life of wood bonded with D-VTKA adhesive. 相似文献
In this study we investigated the effects of using four additives, wheat flour (WF), tannin, rice husk (RH) and charcoal, to melamine-formaldehyde (MF) resin for decorative veneer and base plywood in engineered flooring in order to reduce the formaldehyde emission levels and improve the adhesion properties. We determined the effects of variations in hot-press time, temperature and pressure on the bonding strength and formaldehyde emission. Blends of various MF resin/additive compositions were prepared. To determine and compare the effects of the additives, seven MF resin blends were prepared with the four different additives: four with a wt ratio of 8:2 (MF/WF, MF/tannin, MF/RH and MF/charcoal), and three in the wt ratio of 8:1:1 (MF/WF/tannin, MF/WF/RH and MF/WF/charcoal). The desiccator and perforator methods were used to determine the level of formaldehyde emission. The formaldehyde emission level decreased with all additives, except for RH. At a charcoal addition of only 20%, the formaldehyde emission level was reduced to nearly 0.1 mg/l. Curing of the high WF and tannin content in this adhesive system was well processed, as indicated by the increased lap-shear strength. In the case of WF, the lap shear strength was much lower due to the already high temperature of 130°C. The adhesive layer was broken when exposed to high temperature for extended time. In addition, both WF and tannin showed good mechanical properties. With increasing WF or tannin content, the initial adhesion strength increased. The MF resin samples with 20% added tannin or WF showed both good lap shear and initial adhesion strengths compared to the pure MF resin. 相似文献
The aim of this study, is to describe the effects of adhesives (PVAc-Desmodur VTKA and Urea formaldehyde) on wooden materials (walnut and poplar) cut tangentially and radially impregnated with Protim Solignum, CCA and Celcure AC 500 and exposed to: humid–water–heat resistance; heating; and cooling tests. All these tests show a decreased in bonding strength. The conclusion is that poplar wood cut tangentially and impregnated with CCA, bonded with D-VTKA adhesive can be used as a material in damp conditions where good bond strength is required. 相似文献
Water-washed cottonseed meal (WCSM) has been shown as a promising bio-based wood adhesive. In this work, we tested the bonding strength of WCSM slurries with high solid contents and low press temperatures per industrial input for non-structural applications as European Standard Class D1 wood adhesives. Increasing the WCSM content from 11 to 20% and 30% did not substantially change the adhesive strength but increased the viscosity of WCSM slurries dramatically. The shear strength at break of the maple wood pairs bonded at 40 and 60 °C was lower than that of maple pairs bonded at 100 °C. However, the shear strength of the pairs bonded at lower temperatures (40 and 60 °C) could be improved by extending the press time from 20 to 120 min. Addition of citric acid (CA) improved the viscosity of the WCSM adhesive at 20% solid content, but lowered the adhesive strength. The addition of denaturing reagent sodium dodecyl sulfate (SDS) showed reverse impacts on the adhesive strength and viscosity, compared to CA addition. Based on these observations, eight adhesive slurries were formulated with 20 and 30% of WCSM, 3% of CA or SDS, or 9.6% or 19.1% of denaturing reagent guanidine hydrochloride (GdmCl), and their bonding strengths were tested. These formulations could be used as the basis for developing low temperature WCSM-based wood adhesives to meet the criteria of both operational flowability and shear strength of the domestic furniture and small utensils niche markets for forest products. 相似文献
Composite materials manufactured from wood with different adhesives are being used increasingly in the construction of furniture frames and buildings. In this study, it is aimed to describe the effects of adhesives (PVAc, VTKA and UF) on white oak cut tangentially and radially impregnated with Protim WR 230, CCA, and Celcure AC 500 and exposed to humid-water-heat resistance and heating and cooling tests. Impregnation chemicals have decreased the bonding strength, and control samples gave higher bonding strength value. According to the control samples, it can be said that humid-resistance test, water-resistance test, heat-resistance test have decreased the bonding strength. As a result of the tests, white oak cut tangentially and impregnated with Protim WR 230 and bonded with VTKA adhesive can be used as a material in damp condition where the strength is required. 相似文献
Wood moisture content (MC) affects the glued laminated beam (glulam) bonding strength. Selected adhesives were Phenol-Resorcinol-Formaldehyde (PRF) and Melamine-Urea-Formaldehyde (MUF) adhesives with 1, 1.5 and 2% (w/w) carboxymethyl cellulose (CMC) formic acid solutions. Douglas fir (pseudotsuga menziesii) from North America was used in the test. The bonding behavior of these adhesives with wood at 12 and 18% MC were investigated. The study focused on the effect of 18% MC on shear strength performance of MUF and PRF adhesives and optimizing the formula of CMC formic acid solution. Compressive shear strength of wood with MUF adhesive with 2% (w/w) formic acid solution at 12 and 18% MC stabilized at 10.6 and 10.0 MPa, respectively, which were 17 and 16% higher than that with PRF adhesive at the same condition. At 12–18% MC, MC had a little effect on bonding strength. However, 18% MC wood with PRF adhesive had 52.2% less initial strength increasing rate than that of 12% MC wood. 18% MC wood with MUF adhesives with 1, 1.5 and 2% (w/w) CMC formic acid solutions had 16.0, 15.5 and 27.0% less initial strength increasing rates than that of 12% MC wood, respectively. MUF adhesive using 2% CMC formic solution required the shortest press time at 12 and 18% MC about 1.6 and 2.7 h, respectively. The strength of PRF adhesive was significantly affected by wood MC and enough press time is essential for the proper bonding strength. 相似文献
Aiming at the development of sustainable materials, in this study, a biobased wood polyurethane adhesive (PUA), derived from castor oil (CO), was synthetized and its properties were compared with a conventional wood adhesive. Different NCO/OH ratios have been used to assess its effect on the properties of the ensuing adhesives. FTIR, and DMA were used to monitor the extent of reaction and the glass transition temperature of the adhesive, respectively. In turn, the wood bonding properties of the PUA over time were assessed by lap shear using pine wood specimens. Is was observed that the lap shear strength increases with the increase of the RNCO/OH up to RNCO/OH = 2.50. Above this ratio, the adhesive performance decreases slightly, due to the rigidity of the PUA. Comparison with a conventional wood adhesive showed that CO derived adhesives presented similar strength properties but required less time to develop the ultimate bonding strength. The chemical and thermal stability of the most promising CO adhesive was also assessed. Despite of being sensitive to the chemical environment, the castor oil derived adhesives presented higher thermal stability than conventional wood adhesives.Finally, the cure process of CO derived adhesives was studied by differential scanning calorimetry and the Kissinger and Ozawa methods were used to determine the activation energy (Ea). The former afforded a value for Ea = 80.55 and the latter Ea = 87.07 kJ mol−1. Moreover, it was observed that the activation energy is dependent on the degree of cure, increasing slightly up to 0.6 and decreasing significantly afterwards. 相似文献
Additive manufacturing, also known as 3D printing technology, has experienced massive growth in the last decade. Instead of printing the entire product, 3D printing can be used to produce only the most complex parts, which are then combined with simple, non-printed parts from other materials to make the final product. In addition to mechanical connections, adhesive bonding is most commonly used to combine printed parts with other elements. In this study, the influence of 3D-printing parameters on the bond shear strength of 3D-printed Acrylonitrile-butadiene-styrene copolymer parts bonded to beech wood was investigated. Three printing settings with different layer thicknesses (0.39, 0.19, 0.09 mm) and a posttreatment method that utilized acetone vapour were used. The three different adhesives applied were commercial one-component polyurethane adhesive, hot melt adhesive for edge bonding, and a two-component polyurethane adhesive. The results show that the type of adhesive had the biggest influence on the strength of the bond. The highest bond strength was achieved using a two-component polyurethane adhesive. The type of failure (failure in wood, plastic, adhesive, or cohesive failure) depended greatly on the type of adhesive and thickness of the printed layer. 相似文献
Summary: The effects of bio‐scavengers on the formaldehyde emission, bonding strength, curing behavior, and thermal decomposition properties of MF resins for engineered flooring and adhesion for wood were investigated. Four varieties of bio‐scavengers, tannin powder, wheat flour, rice husk flour, and charcoal, were added to MF resin at 5 wt.‐%. To determine formaldehyde emission and bonding strength, we manufactured engineered floorings. MF‐charcoal was most effective in reducing formaldehyde emission because of its porous nature, but its bonding strength was decreased. Tannin powder and wheat flour, which contain more hydroxyl groups, showed higher bonding strength and curing degree than pure MF resin did. Although the hydroxyl groups of the bio‐scavengers were effective in reducing formaldehyde emission and improve bonding strength and curing degree, rice husk flour and charcoal behaved like inorganic substances, thereby disturbing the adhesion between MF resin and wood and thus reducing the bonding strength. In thermogravimetric analysis, MF‐tannin showed the highest thermal stability in the low‐temperature range from 100 to 300 °C.
Storage modulus (E′) of MF resin with various bio‐scavengers at a heating rate of 10 °C · min?1. 相似文献
The selection of the most appropriate surfacing technique is influential in the success of bonding, painting and varnishing processes. The objective of the study was to determine which surfacing technique was the most appropriate when applied as the final process in the production of structural wood members, which were subjected to shearing. The study also includes the effect on shear strength of the variables, such as type of wood, plane of cut, type of adhesive and pressing pressure, as they are directly related to the main objective of the study. In view of this objective, the changes in shear strength on radial and tangential cut surfaces of Oriental beech (Fagus orientalis Lipsky) and Scotch pine (Pinus sylvestris L.) woods having different roughness values as a result of sawing with a circular ripsaw, planing and sanding, and bonded with polyurethane (PU) and poly(vinyl acetate) (PVAc) adhesives at 3, 6 and 9 MPa pressure, were studied. The 936 specimens prepared with the objective of determining the effects of variables on bond performance were subjected to a shear test in a universal test equipment in accordance with the ASTM D 905-98 standard. The highest shear strength (13.85 N/mm2) was obtained for the Oriental beech specimens cut from their tangential surfaces with a circular ripsaw, which were glued with PVAc adhesive by applying a pressure of 9 MPa. The lowest value (4.22 N/mm2) was obtained in the specimens planed from their tangential surfaces, which were glued with PU adhesive by applying a pressure of 3 MPa. The specimens obtained from Oriental beech wood showed a higher shear strength compared to the specimens obtained from Scotch pine. In general, in both species of wood, the specimens glued with PVAc adhesive, both on the tangential surfaces and on the radial surfaces, produced higher shear strengths compared to the specimens glued with PU adhesive. 相似文献
In this paper, the bonding properties of polyvinylchloride (PVC)-based wood–plastic composite (WPC) materials bonded with acrylic adhesive have been studied. The results showed that dry compression shear strength of bonded specimens glued with acrylic adhesive was 6.12?MPa, and reached 58.8% of the strength of the PVC-based WPCs. The results also showed that wet compression shear strength in accordance with Chinese standard GB/T17657 was 0.9 times the dry compression shear strength of 5.48?MPa. In addition, the retention rate of the compression shear strength of the bonded specimens gluing with acrylic adhesive after UV aging for 7?days and 14?days was 69.1 and 66.8%, respectively. The aging was done in accordance with UV-aging test process as given in this paper. The scanning electron microscopy (SEM) analysis of the bonded specimens of PVC-based WPCs showed that the J-39 acrylic adhesive penetrated into the adjacent porous regions of the PVC-based WPC which had resulted from foaming. This penetration enhanced the mechanical interlocking between the substrate and the acrylic adhesive. 相似文献
Cassava starch was cyanoethylated to different degrees of substitution (DS) and then used in adhesive preparations. The adhesives were used in bonding wood substrates and the adhesive strength of the bonded substrates was evaluated using a tensometer. The effects of the DS, solids content, pH and moisture on adhesive strength were investigated. The adhesive strength increased with increasing DS; with respect to the percentage solids, it increased to a maximum and then decreased again; with pH, it showed a minimum at a neutral pH; while it decreased with length of exposure to saturated moisture conditions. The experimental data were subjected to regression analysis to find the best fitting models. The results showed that the adhesive strength varied polynomially with DS (R2 = 0.97), pH (R2 = 1.0), percentage solids content (R2 = 0.94), and exponentially with the length of exposure to saturated moisture conditions (R2 = 0.96). Cyanoethylation significantly enhanced the adhesive property of starch (p < 0.05) and the cyanoethyl starch adhesives were found effective for bonding wood. However, cyanoethyl starch adhesive is not suitable as structural adhesive in a high moisture environment. The performance of cyanoethyl starch adhesive was compared with two commercial adhesive pastes. 相似文献
In wood materials, the species of wood, its humidity, and the type of the adhesive have an important role to make the wood material durable for a long period both in inner space and outer space. In this study, it is aimed to determine the resistance characteristics of adhesive using different impregnation chemicals and different types of adhesives before and after steam treatment. In this study, beech and poplar as wood materials; mixture of Protim-WR 235, Tanalith-C, and Celcure-AC 500 as impregnation materials; and poly vinyl acetate (PVAc), urea formaldehyde (UF), and desmodur vinyl trie ketonol acetate (D-VTKA), resistant to water, as adhesives materials were used. All samples were kept in a steaming equipment for 2, 6, 12, 24, 48, and 96?h, afterwards the maximum force of the samples were measured for each waiting period, and then their bonding strength was determined. According to the results of the study, beech control samples had higher strength than poplar control samples. Control samples bonded with D-VTKA is the least affected one compared to all original control samples in the steam test. D-VTKA can be offered as the proper adhesive for humid places. The results also showed that Tanalith-C is the least affecting impregnation material on the bonding strength. 相似文献
The aim of this study was to investigate the effect of adding powdered dentin to primer or adhesive in a self-etch system on the shear bond strength of three resin-based sealers. Seventy-two premolars were sectioned buccolingually, and 144 root halves were divided into three groups according to the sealer used: epoxy resin-based sealer (AH Plus), methacrylate resin-based (RealSeal, Hybrid Root SEAL) n = 48. The surfaces were irrigated with 5% NaOCl, 17% EDTA, distilled water for 5 min. Four subgroups were created (n = 12): control group; Clearfil Liner Bond 2 V treated group; powdered dentin added to the primer of Clearfil Liner Bond 2 V (40 wt.%); and powdered dentin added to the adhesive of Clearfil Liner Bond 2 V (20 wt.%). Dentin powder was prepared. Three mm high buildups with a constant surface area of 3.45 mm2 were created using the sealers and allowed to set (37 ºC, 100% humid, 72 h). The samples were tested to failure for shear bond strength (1 mm/min). The data were calculated (MPa) and analyzed using two-way ANOVA, one-way ANOVA, and Tukey HSD tests. Adhesive use decreased the bonding performance of AH Plus (p = 0.00). Mean bond strength of the other sealers was found similar to control. Primer or adhesive resin with powdered dentin did not increase the adhesive performance of the self-etch system used. The shear bond strength of RealSeal was significantly increased when powdered dentin was added to primer or adhesive (p = 0.00). The effect of adding powdered-dentine to primer or adhesive in a self-etch system on the shear bond strength was sealer-dependent . 相似文献