Adhesion in Polymer/Steel Sandwiches

Polymer/steel sandwiches are able to reduce the nuisance due to vibrations and noise in automotive applications, for example. Thin layers of polymer are inserted between two metal sheets. The deformation of the polymer is responsible for the damping properties of the sandwiches and, therefore, the viscoelastic behavior of the polymer is of major importance. However, adhesion between the two materials is also required. The polymer studied in the present work is a copolymer of ethylene and vinyl acetate (EVA) containing 28 wt% of vinyl acetate grafted with maleic anhydride (1 wt%). A wedge test is used to measure the interfacial strength and the durability of the adhesive bond. The influence of the surface treatment of the steel substrate on the adhesive behavior and the effect of water has been studied. FTIR surface analysis after cleavage helped us to identify the nature of the interfacial bonds.     

Adhesion in Polymer/Steel Sandwiches

Polymer/steel sandwiches are able to reduce the nuisance due to vibrations and noise in automotive applications, for example. Thin layers of polymer are inserted between two metal sheets. The deformation of the polymer is responsible for the damping properties of the sandwiches and, therefore, the viscoelastic behavior of the polymer is of major importance. However, adhesion between the two materials is also required. The polymer studied in the present work is a copolymer of ethylene and vinyl acetate (EVA) containing 28 wt% of vinyl acetate grafted with maleic anhydride (1 wt%). A wedge test is used to measure the interfacial strength and the durability of the adhesive bond. The influence of the surface treatment of the steel substrate on the adhesive behavior and the effect of water has been studied. FTIR surface analysis after cleavage helped us to identify the nature of the interfacial bonds.     

附着力促进剂对光固化金属涂层附着力提升的研究

为了探究附着力促进剂对光固化金属基涂层附着力的影响,本文通过划格法、拉拔法及搭接剪切实验,系统研究了磷酸酯类附着力促进剂、硅烷偶联剂对光固化金属基（低碳钢、铝板）涂层附着力的促进作用。结果表明：磷酸类附着力促进剂能够显著提高光固化金属基（低碳钢、铝板）涂层的附着力,而硅烷偶联剂对光固化金属基（低碳钢、铝板）涂层的附着力无明显提升作用。     

工业钢结构用涂料

简介了钢结构的表面处理,钢结构用底漆及各类涂料的特点。     

室内用超薄膨胀型钢结构防火涂料

概述了超薄膨胀型钢结构防火涂料的组成、原理及制备,经试验,研制的防火涂料的相关指标达到了预想的要求。     

钴盐对钢丝帘线与橡胶粘合性能的影响

对环烷酸钴，硼酰化钴，新癸酸钴等钴盐粘合增进剂对高和低铜质量分数钢丝帘线与橡胶粘合性能的影响进行了研究。结果表明，胶料中加入钴盐能够提高强伸性能和与钢丝帘线的初始粘合唱 力及耐盐水老化能力。     

影响钢丝帘线与橡胶粘合性能的主要因素

分析了影响子午线轮胎用钢丝帘线与橡胶粘合性能的主要因素,其中包括钢线帘线的镀层组分及厚度、结构、表面状态、操作、包装贮存条件以及子午线轮胎的结构和胶料配方设计及生产工艺等因素。     

New Polymer Materials for Steel/Polymer/Steel Laminates in Automotive Applications

The present works aims to develop multi‐materials such as steel/polymer/steel hybrid system for weight savings in automotive industries. This laminate must be compatible with processing on the industrial line (steel/polymer lamination under 200 °C) and the structure must be flow‐resistant during the paint process curing (200 °C for 30 min). Consequently, a yield stress polymer system based on compatibilized PA11/copolymer of ethylene and octene blends has been developed. The yield stress property (for T > 200 °C) depends on the phase concentration and compatibilization strategy. It is observed that an annealing process (heating treatment for 1 h at 200 °C), simulating the painting process, provides a strong benefit for the polymer/steel properties after aging under humidity conditions.

     

Polymer Masks Fabrication by Micropatterning Surfaces of Composite Polymer Coatings

Abstract

Micropatterning of surfaces has been demonstrated using composite polymer coatings of PS and PMMA of equal molecular weights in different volume proportions with varying surface topographies on silicon surfaces. The creation of PMMA masks with various surface morphological features has also been demonstrated by removal of PS from the composite coatings using cyclohexane. Atomic force microscopy (AFM) investigations revealed that the surface pattern and the dimensions of these masks significantly changed with the change in the volume proportions of each homopolymer. The composite coatings of 20/80 vol% PS/PMMA, 50/50 vol% PS/PMMA, and 80/20 vol% PS/PMMA resulted in PMMA masks with holes (depth ～300 nm), wrinkles (height ～350 nm) and pillars (height ～600 nm), respectively. Surface compositional analysis carried out using FTIR and XPS investigations confirmed the presence of polymer coatings of PS, PMMA and PS/PMMA. XPS investigations also confirmed the successful removal of PS from the PMMA mask by showing the presence of the silicon substrate on those masks where PS was previously present. The water contact angle of the composite polymer masks ranged from 70 to 90° which increased with the increase of PS vol% in the composite. The wetting behavior of certain PMMA masks showed hydrophobicity with water contact angle values above 90°.     

冷轧薄钢板磷化发蓝问题的原因及对策

冷轧薄钢板在使用时出现三种形态的磷化发蓝缺陷；点状，条状及整个磷化面蓝色，其原因主要有以下几种，钢板的化学活性高，催化剂的浓度高以及磷化段入口处磷化液流量小等，通过作相应的调整，获得了合格的磷化膜。     

浅析胶料与镀铜钢丝帘线粘合的影响因素

采用正交设计法和对比试验法，考察了硫黄、氧化锌、促进剂、炭黑以及某些工艺条件对胶料与镀铜钢丝帘线粘合力的影响。结果表明，硫黄品种对粘合力的影响不大；氧化锌用量增大，粘合力增大；用１．０份促进剂ＣＺ时的粘合力大于用１．３份促进剂ＤＺ；使用高结构炭黑可增大粘合力；胶料的混炼方法和硫化时间对粘合力的影响较大。     

不锈钢涂装前处理工艺实践

不锈钢设备长时间在腐蚀性介质环境中运行,表面会出现腐蚀,需要进行涂装防护。但不锈钢表面光滑,涂料对其附着力差、防护能力弱,探索了不锈钢涂装的前处理工艺。实验发现,除油处理并不能完全解决漆膜的附着力问题,除油后增加酸洗工序,可以有效提高漆膜的附着力,增强漆膜对不锈钢基材的防护能力,经有机酸处理后漆膜的附着性能及防护性能最强,附着力达到0级。     

钢结构的重防腐涂装

概述了钢结构重防腐涂装体系的选择、表面处理和施工要求;介绍了ISO12944钢结构防腐蚀涂料涂装设计标准的应用。     

Adhesion of Polymer Blends. I. Phenomenological Model

A phenomenological model based on the Takayanagi approach is proposed to describe the adhesion of polymer blends to a solid support. The model consists of three elements corresponding to two components of the blend and a solid surface. The conditions for failure of the adhesion joints at the interface between the solid surface and the polymer blend are found to depend on the blend composition and the moduli and adhesion joint strength of each component to the solid.     

Adhesion of Polymer Blends. I. Phenomenological Model

A phenomenological model based on the Takayanagi approach is proposed to describe the adhesion of polymer blends to a solid support. The model consists of three elements corresponding to two components of the blend and a solid surface. The conditions for failure of the adhesion joints at the interface between the solid surface and the polymer blend are found to depend on the blend composition and the moduli and adhesion joint strength of each component to the solid.     

Amino-p-benzoquinone Adducts and Polymers as Adhesion Promoters for Steel

Phenolic and quinonoid compounds are widely studied in biological sciences because of their ability to chelate heavy metals like iron and copper and recently have found new applications in synthetic macromolecules. Amino-p-benzoquinone polymers, poly[(2,5-hexamethylenediamino)-1,4-benzoquinone] and poly{[2,5-(2,2′-bistrifluoromethyl)-4,4′-biphenylenediamino]1,4-benzoquinone} were synthesized and evaluated as adhesion promoters for steel/epoxy joints. An improvement in the torsional shear strength of these joints was observed when these polymers were used as adhesion promoters. The durability of the adhesive bond was also improved after boiling water treatment, relative to untreated and silane-treated joints. The improvement in adhesion could be attributed to the formation of a chelate between the polyaminoquinone (PAQ) and the iron surface and a chemical reaction between the PAQ and the epoxy resin. A low molecular weight model compound, bis[2,5-(4-methylanilido)]-1,4-benzoquinone, was also used to study coupling between the epoxy adhesive and the steel surface. Electron spin resonance (ESR), atomic absorption spectroscopy and infrared spectroscopy were used to document the epoxy-coupling agent reaction and the chelate formation.     

铝及铝合金表面处理后的表面特征和粘接特性

本文介绍了铝材表面处理的目的与要求、经过各种机械和（电）化学方法处理后的表面特性,如表面形貌、表面粗造度、表面化学组成、表面润湿特性、表面氧化物的环境稳定性及其粘度接特性。其中以磷酸阳极化作最后表面处理工序获得的效果最好,在此前的化学处理工序基本不影响最后表面处理效果。     

钴盐用量对橡胶与钢丝帘线粘合性能的影响

对硼酰化钴ＭＣ２３（钴质量分数为２３％）用量（０６～１６份）对橡胶与钢丝帘线粘合性能的影响进行研究。采用的基本配方为：ＮＲ１０００；炭黑Ｎ３２６６２０；芳烃油８０；氧化锌９０；硬脂酸０５；防老剂４０２０２０；不溶性硫黄ＩＳ７０２０６０；促进剂ＤＺ１０；粘合剂ＲＳ３５；粘合剂Ａ２３；沉淀法白炭黑５０。结果表明，随着钴盐用量的增大，在未老化、热空气老化及盐水老化条件下，胶料与钢丝的粘合强度有所提高；在湿热老化条件下，粘合强度由于热量和湿气的交互作用而发生较大幅度的下降，但钴盐用量在１０份时粘合强度的下降为最小。综合胶料初始和老化后的应力应变性能和粘合强度，以１０份钴盐用量为最佳。     

室内薄型钢结构防火涂料的研制

介绍了一种室内薄型钢结构防火涂料的配制方法。通过采用聚合物乳液和无机黏结材料的复配技术,提高了涂膜的耐水性;采用羟丙基甲基纤维素与膨润土配用增加体系的悬浮性,从而改进涂料的贮存稳定性和施工性能。为研制综合性能高的室内薄型钢结构防火涂料提供设计思路和理论依据。     

环氧粉末涂层对金属基材附着力的影响因素

环氧粉末涂料具有附着力好、耐腐蚀性强、耐温性能好等优点,在金属防腐特别是重防腐领域应用非常广泛。在环氧粉末涂层的诸多性能中,涂层对基材的附着力是非常重要的一项技术指标,也是满足其他性能的基础,附着力的好坏直接影响着涂层对基材的保护寿命。本文主要从喷涂温度、基材表面处理的表面粗糙度以及粉末涂料原材料等方面讨论了环氧涂层对金属基材表面附着力的影响因素。研究表明:喷涂温度提高有利于涂层附着力的提高,表面粗糙度提高且锚纹深度相对均匀有利于涂层附着力的提高,填料以及助剂的种类对附着力具有一定的影响。