Study on Composition and Structure of Liaoshu Asphalt

In this article, the structure characteristics of Liaoshu paving asphalts have been studied by the methods of element analysis, SARA and E-D-M. At same time, the relation between composition and structure and using performance of Liaoshu paving asphalt were established. The experimental results show that carbon and hydrogen contents were more than 95%, the hydrogen/carbon atom ratio was about 1.5 in the Liaoshu paving asphalts. The content of saturates is between 20 and 25% in the Liaoshu paving asphalt, aromatics 35 and 40%, resin 25 and 30%, and asphaltene 8 and 10%. There are 45 carbon atoms in the average asphalt molecule, which contain 16-17 aromatic carbon atoms. The number of total ring in the average asphalt molecule is 5-6, the aromatic ring is 3-4, and the naphthene ring is 1-2.     

Study on Composition and Structure of Liaoshu Asphalt

Abstract

In this article, the structure characteristics of Liaoshu paving asphalts have been studied by the methods of element analysis, SARA and E-D-M. At same time, the relation between composition and structure and using performance of Liaoshu paving asphalt were established. The experimental results show that carbon and hydrogen contents were more than 95%, the hydrogen/carbon atom ratio was about 1.5 in the Liaoshu paving asphalts. The content of saturates is between 20 and 25% in the Liaoshu paving asphalt, aromatics 35 and 40%, resin 25 and 30%, and asphaltene 8 and 10%. There are 45 carbon atoms in the average asphalt molecule, which contain 16–17 aromatic carbon atoms. The number of total ring in the average asphalt molecule is 5–6, the aromatic ring is 3–4, and the naphthene ring is 1–2.     

Study on Composition and Structure of Liaoshu Asphalt

Abstract

In this article, the structure characteristics of Liaoshu paving asphalts have been studied by the methods of element analysis, SARA and E-D-M. At same time, the relation between composition and structure and using performance of Liaoshu paving asphalt were established. The experimental results show that carbon and hydrogen contents were more than 95%, the hydrogen/carbon atom ratio was about 1.5 in the Liaoshu paving asphalts. The content of saturates is between 20 and 25% in the Liaoshu paving asphalt, aromatics 35–40%, resin 25–30%, and asphaltene 8–10%. There are 45 carbon atoms in asphalt average molecule, which contain 16–17 aromatic carbon atoms. The number of total ring in asphalt average molecule is 5–6, the aromatic ring is 3–4, the naphthene ring is 1–2.     

用辽河高粘原油生产重交通道路沥青的研究——（Ⅲ）辽曙沥青组成与结构分析

利用元素分析,族组成分析和结构族组成分析方法,研究了辽曙沥青的组成与结构,建立了辽曙沥青组成与结构和使用性能之间的关系。辽曙沥青碳氢含量在95%以上,氢碳原子比在1.5左右;辽曙沥青平均分子全部是多环结构,每个平均分子中的含有45个碳原子,其中芳碳数为16-17个,总环数为5-6个,其中芳环数为3-4个,辽曙沥青的沥青质含量在8%-10%之间,胶质含量在25%-30%之间,芳香分含量在35%-40%之间,饮和分含量在20%-25%之间的族组成使沥青具有良好的性能。     

Study and Evaluation of Aging Performance of Petroleum Asphalts and Their Constituents During Oxygen Absorption. III. Average Molecular Structure Parameter Changes

The changes of the structural parameters of the average molecules of Chinese Shanjiasi and Shengli petroleum asphalts and their constituents during oxygen absorption were studied based on the oxygen absorption behaviors and the chemical group composition and structure changes. The results show that all the structural parameters of the average molecules of asphalts and their constituents increase clearly after oxygen absorption with the exceptions of the naphthene carbon rates and the paraffin carbon rates. The parameters include the total carbon numbers, the aromatic carbon numbers, the naphthene carbon numbers, the paraffin carbon numbers, the total ring numbers, the aromatic ring numbers, the naphthene ring numbers, the total hydrogen numbers, the aromaticities, and the concentration indexes. The most obvious are the structural parameter changes of the average molecules of the asphalt resin and asphaltene constituents. The structural parameter changes of the average molecules of Shengli asphalt and its constituents are remarkably greater than those of Shanjiasi asphalt and its constituents. The clearer changes of all the average molecular structure parameters of SHL asphalt resin and asphaltene, especially resin could possibly be one of the key factors leading to the much clearer deterioration of the colloidal stability and the serviceability than SJS asphalt in oxygen absorption.     

Study and Evaluation of Aging Performance of Petroleum Asphalts and Their Constituents During Oxygen Absorption. III. Average Molecular Structure Parameter Changes

Abstract

The changes of the structural parameters of the average molecules of Chinese Shanjiasi and Shengli petroleum asphalts and their constituents during oxygen absorption were studied based on the oxygen absorption behaviors and the chemical group composition and structure changes. The results show that all the structural parameters of the average molecules of asphalts and their constituents increase clearly after oxygen absorption with the exceptions of the naphthene carbon rates and the paraffin carbon rates. The parameters include the total carbon numbers, the aromatic carbon numbers, the naphthene carbon numbers, the paraffin carbon numbers, the total ring numbers, the aromatic ring numbers, the naphthene ring numbers, the total hydrogen numbers, the aromaticities, and the concentration indexes. The most obvious are the structural parameter changes of the average molecules of the asphalt resin and asphaltene constituents. The structural parameter changes of the average molecules of Shengli asphalt and its constituents are remarkably greater than those of Shanjiasi asphalt and its constituents. The clearer changes of all the average molecular structure parameters of SHL asphalt resin and asphaltene, especially resin could possibly be one of the key factors leading to the much clearer deterioration of the colloidal stability and the serviceability than SJS asphalt in oxygen absorption.     

A STUDY ON AGING KINETICS OF ANSHAN PAVING ASPHALT

The aging processes of two Anshan paving asphalts conforming to GB/T15180-94 standard have been studied by Rotation Thin Film Oven Test (RTFOT) and the aging kinetic models of two paving asphalts have been determined. The results show that the aging of the prepared paving asphalt is a first order reaction. The viscosity of the asphalt increases gradually with the aging time. The greater the aging index is, the more easily the asphalt is aged. Because the chains break down to form free radicals, oxidation reactions occur. The aging resistance of the asphalt with lower aromaticity and with less aromatic cycle numbers is weak.     

A STUDY ON AGING KINETICS OF ANSHAN PAVING ASPHALT

ABSTRACT

The aging processes of two Anshan paving asphalts conforming to GB/T15180-94 standard have been studied by Rotation Thin Film Oven Test (RTFOT) and the aging kinetic models of two paving asphalts have been determined. The results show that the aging of the prepared paving asphalt is a first order reaction. The viscosity of the asphalt increases gradually with the aging time. The greater the aging index is, the more easily the asphalt is aged. Because the chains break down to form free radicals, oxidation reactions occur. The aging resistance of the asphalt with lower aromaticity and with less aromatic cycle numbers is weak.     

道路石油沥青中蜡对沥青性质的影响

测定了大庆和辽河１００号道路石油沥青中蜡的分布,并将其中的饱和蜡,芳香蜡,总蜡分离出来,用其与脱蜡沥青调制成蜡含量不同的系列样品,考察了饱和蜡,芳香蜡对沥青物理性质的影响,总蜡对沥青路用性能的影响,对沥青质量指标中否应设置蜡含量指标进行了讨论．     

THE STUDY OF PRODUCING HEAVY TRAFFIC ASPHALT BY USING THE HIGH VISCOUS CRUDE FROM NO.l SHUGUANG ZONE OF LIAOHE OIL FIELD

The characteristics of the high viscous crude from No. 1 Shuguang Zone of Liaohe Oil Field are similar to those of residue distillates of general crude such as high density(ρ ₂₀=0·9977 g.cm^-3),high viscidity υ ₁₀₀= 1223·9 mm².s-¹) and high carbon/hydrogen ratio. This oil contains less wax, but rich in resin and asphalt, which belongs to low sulfur naphthene-base crude oil and can be used as feedstock to produce high paving asphalt. But now it is used as fuel after emulsificating. In order to make full use of this oil and resolve the problem of paving asphalt demand-supply, various paving asphalts conforming to GB50092-96 standard were produced by blending vacuum residue of the high viscous crude from No.l Shuguang Zone of Liaohe Oil Field and waste oil which is rich in aromatics and poor in wax. The laboratory test results show that modified paving asphalts have good low-temperature properties and antiaging feature.     

卡斯蒂利亚原油生产高等级道路沥青

介绍进口新油种——卡斯蒂利亚原油生产高等级道路沥青的试验情况。通过实验室研究和工业生产试验,开发出了两条混炼加工卡斯蒂利亚原油生产道路沥青的工艺路线：与伊重原油混炼,可以生产70号B和90号B高等级道路沥青;与沙中原油混炼,则可以生产出性能优良的70号A道路沥青;与沙中原油（1：1）混炼,还可以生产出性能优良的50号A道路沥青。结果表明,卡斯蒂利亚原油是好的沥青生产原料,可用于生产高等级道路沥青。     

THE STUDY OF PRODUCING HEAVY TRAFFIC ASPHALT BY USING THE HIGH VISCOUS CRUDE FROM NO.l SHUGUANG ZONE OF LIAOHE OIL FIELD

ABSTRACT

The characteristics of the high viscous crude from No. 1 Shuguang Zone of Liaohe Oil Field are similar to those of residue distillates of general crude such as high density(ρ ₂₀=0·9977 g.cm^-3),high viscidity υ ₁₀₀= 1223·9 mm².s-¹) and high carbon/hydrogen ratio. This oil contains less wax, but rich in resin and asphalt, which belongs to low sulfur naphthene-base crude oil and can be used as feedstock to produce high paving asphalt. But now it is used as fuel after emulsificating. In order to make full use of this oil and resolve the problem of paving asphalt demand-supply, various paving asphalts conforming to GB50092-96 standard were produced by blending vacuum residue of the high viscous crude from No.l Shuguang Zone of Liaohe Oil Field and waste oil which is rich in aromatics and poor in wax. The laboratory test results show that modified paving asphalts have good low-temperature properties and antiaging feature.     

Influence of Chemical Composition on the Physical Characteristics of Paving Asphalts

The simplest general compositional model considers asphalt to be made up of asphaltenes, heavy oils, and resins. In the present study the extent of similarity between the properties and composition of various types of asphalt obtained from different sources has been carefully explored. It shows how ductility, penetration, and softening point are related to the chemical nature of paving asphalts in the range 41-58 softening points. Asphalt properties are found to be a direct function of its chemical constituents. The relationship between softening point and asphaltene content was found to be linear while asphalts of the same softening point are easily distinguished by the content of the resins. Evaluation of the two asphalt indices—the asphaltene index (I_A) and the Gaestel index (I_C), reveals that they both vary linearly with the composition of asphaltenes and resins thus confirming their suitability in the characterization of asphalts. Comparison of the two indices shows that IC is more suitable in estimating the colloidal stability of different groups of asphalts. The observed correlations can be found useful in the areas of asphalt blending and rejuvenating through the appropriate selection of asphalt components.     

废旧沥青混合料再生技术的研究

在实验室将沈铁、北环等公路段的5种废旧道路沥青混合料，采用工业苯作溶剂抽提回收出约占沥青混合料2．06％～2．79％的旧沥青，并根据其理化性质及组成选择适宜的润滑油精制过程中产生的废油作复合再生剂，与所回收旧沥青性质类似的新沥青一起，调配出符合重交通道路石油沥青质量标准(GB 50092—96)要求的AH90和AH70重交通道路石油沥青。该方法简单、易操作，预计可以节约50％以上的铺路沥青。     

风城超稠油生产道路石油沥青及其路用性能评价

针对克拉玛依风城超稠油和低凝稠油基本性质的区别,通过控制不同拔出深度的减压渣油来生产道路石油沥青,并选取其中有代表性的90号道路石油沥青进行路用性能评价,评价结果表明该工艺生产的道路石油沥青能够满足技术指标要求。     

Application of Solubility Parameter Theory in Evaluating the Aging Resistance of Paving Asphalts

In this article, asphaltene index, aging index, and Gastel index (Ic) are introduced to study the aging resistance of paving asphalts. Meanwhile, the solubility parameter theory is applied to evaluate the aging resistance of these paving asphalts. The results show that the greater the asphaltene index, the aging index or the Gastel index, the worse the aging resistance of the paving asphalt. The small difference between solubility parameters of asphaltene and maltene of the paving asphalt contributes to its good aging resistance. The analytical results in these two ways are consistent.     

煤液化油模型分子结构的研究

对神华煤在连续液化装置的加氢液化油(试样1#)和实验室获得的液化油(试样2#)进行了模型分子结构的研究。通过元素分析、平均相对分子质量的测定、核磁共振谱图和傅里叶变换红外光谱的分析,得到了两种液化油的平均分子结构式和相关的结构参数,并利用这些参数推测了模型分子的结构。实验结果表明,试样1#和试样2#的平均相对分子质量分别为228,299;平均分子式分别为C17H23N0.1S0.006O0.02和C23H21N0.02S0.002O0.1;试样1#的模型分子结构以含一个芳香环的部分氢化芳烃为主体;试样2#主要以含3~4个芳香环的缩合芳烃为结构单元;两种试样芳香环上均存在取代基,但取代基的碳数不一样,且存在少量氮和氧形成杂环。     

石油沥青类产品及其生产技术成果介绍

简要介绍了中石化股份公司抚顺石油化工研究院近几年来在石油沥青类产品的生产和应用技术开发方面所取得的主要成果，包括高等级道路沥青、改性沥青、水工沥青、乳化沥青、彩铺胶结料及其它特种沥青等产品的开发与应用情况。在近几年的研究开发工作中．该院密切注意石油沥青技术的发展动向与市场应用情况，并结合国内外原油情况，开发了包括高等级道路沥青在内的系列沥青产品生产技术。这些沥青类产品已经应用于各类工程建设中。     

Application of Solubility Parameter Theory in Evaluating the Aging Resistance of Paving Asphalts

Abstract

In this article, asphaltene index, aging index, and Gastel index (Ic) are introduced to study the aging resistance of paving asphalts. Meanwhile, the solubility parameter theory is applied to evaluate the aging resistance of these paving asphalts. The results show that the greater the asphaltene index, the aging index or the Gastel index, the worse the aging resistance of the paving asphalt. The small difference between solubility parameters of asphaltene and maltene of the paving asphalt contributes to its good aging resistance. The analytical results in these two ways are consistent.     

用辽河高粘原油生产重交通道路沥青的研究（Ⅱ）重交通道路沥青的研制

用辽曙原油作原料,选取炼厂贫蜡富芳废油作改性剂,通过减压蒸馏、加剂调和的简单工艺,研制出符合GB50092－96标准及中石化Q／SHR003－1998 1号高等级道路沥青标准的各种牌号的道路沥青,并就研制出的道路沥青与国内外四种沥青的性质作了比较。实验结果表明,调合沥青具有优越的低温性能和耐热老化性能。