Effect of rare earth element yttrium addition on microstructures and properties of a 21Cr–11Ni austenitic heat-resistant stainless steel

In this comparative study, the microstructure and the mechanical properties of a 21Cr–11Ni austenitic heat-resistant stainless steel with and without addition of rare earth (RE) element yttrium have been investigated. The results show that a number of fine spherical yttrium-rich oxide particles are not uniformly distributed in the matrix of steel with yttrium; instead, they are aligned along the rolling direction. The grains surrounding the alignment are nearly one order of magnitude smaller than those farther away from the alignment. The approximate calculation results indirectly show that the grain refinement may be mainly attributed to the stimulation for nucleation of recrystallization rather than to pinning by particles. Furthermore, the alignment has resulted in significant loss in transverse impact toughness and tensile elongation at room temperature. There is a trough in the hot ductility–temperature curve, which is located between 973 and 1173 K. The ductility trough of steel with yttrium becomes shallow within a certain temperature range, especially around 1073 K, indicating that improvement on hot ductility is achieved by yttrium addition. The results may be attributed to the increase of grain boundary cohesion indicated by the effective improvement on intergranular failure tendency, and the inhibitory effect of yttrium on sulfur segregation to grain boundaries is believed to be an important cause.     

Fatigue behaviour of friction welded medium carbon steel and austenitic stainless steel dissimilar joints

This paper reports the fatigue behaviour of friction welded medium carbon steel–austenitic stainless steel (MCS–ASS) dissimilar joints. Commercial grade medium carbon steel rods of 12 mm diameter and AISI 304 grade austenitic stainless steel rods of 12 mm diameter were used to fabricate the joints. A constant speed, continuous drive friction welding machine was used to fabricate the joints. Fatigue life of the joints was evaluated conducting the experiments using rotary bending fatigue testing machine (R = −1). Applied stress vs. number of cycles to failure (S–N) curve was plotted for unnotched and notched specimens. Basquin constants, fatigue strength, fatigue notch factor and notch sensitivity factor were evaluated for the dissimilar joints. Fatigue strength of the joints is correlated with microstructure, microhardness and tensile properties of the joints.     

The rate of dynamic recrystallization in 17-4 PH stainless steel

The hot working behavior of 17-4 PH stainless steel (AISI 630) was studied by hot compression test at temperatures of 950–1150 °C with strain rates of 0.001–10 s⁻¹. The progress of dynamic recrystallization (DRX) was modeled by the Johnson–Mehl–Avrami–Kolmogorov (JMAK) kinetics equation. The flow softening was directly related to the DRX volume fraction and the DRX time was determined by strain rate. For quantification of recrystallization rate, the reciprocal of the time corresponding to the DRX fraction of 0.5% or 50% was used. Analysis of the sigmoid-shaped recrystallization curves revealed that the rate of DRX increases with increasing deformation temperature and strain rate. The Zener-Hollomon parameter (Z) was found to be inappropriate for analysis of DRX kinetics. Therefore, the dynamic recrystallization rate parameter (DRXRP) was introduced for this purpose. The DRXRP may be determined readily from the Avrami analysis and can precisely predict the rate of DRX at hot working conditions.     

Processing map for hot working characteristics of a wrought 2205 duplex stainless steel

Processing map on a wrought 2205 duplex stainless steel under hot compression conditions has been developed based on the dynamic material model theories in the range 1223–1473 K and 0.01–10 s⁻¹. The various domains in the map corresponding to different deformation characteristics have been discussed in combination of microstructural observations. The results show that the power dissipation efficiency (η) depends strongly on the dynamic recrystallization (DRX) of austenite which plays a dominant role in microstructural evolution, while the ferrite phase mainly continues to exhibit relatively well-developed dynamic recovery (DRV) at large strain. The optimum hot working domain of wrought 2205 duplex stainless steel is obtained to be in the temperature range 1373–1473 K and at strain rate of 0.01 s⁻¹, with peak efficiency 50% occurring at about 1423 K, in which more uniform microstructure is developed due to the occurrence of complete DRX of austenite. The unstable hot working regimes are predicted by Prasad instability criterion, in good agreement with the macro-and microstructural observations. As predicted, flow instability, which are manifested as twinning, bands of flow localization and the absence of DRX in austenite are observed at lower temperatures and higher strain rates (1223–1273 K and 1–10 s⁻¹); in other cases, wedge cracking is responsible for instability phenomena observed at the temperature range 1373–1423 K and strain rate of 10 s⁻¹.     

Finite element analysis of the effect of welding heat input and layer number on residual stress in repair welds for a stainless steel clad plate

Stainless steel clad plate is widely used in petroleum, chemical and medicine industries due to its good corrosion resistance and high strength. But cracks are often formed in clad layer during the manufacture or service, which are often repaired by repair welding. In order to ensure the structure integrity, the effects of residual stress need to be considered. The objective of this paper is to estimate the residual stress and deformation in the repair weld of a stainless steel clad plate by finite element method. The effects of heat input and welding layer number on residual stresses and deformation have been studied. The results show that large residual stresses have been generated in the repair weld. The heat input and layer number have great effects on residual stress distribution. With the heat input and welding layer number increasing, the residual stresses are decreased. Using multiple-layer welding and higher heat input can be useful to decrease the residual stress, which provides a reference for optimizing the repair welding technology of this stainless steel clad plate.     

On the behavior of nitrogen in a low-Ni high-Mn super duplex stainless steel

The present work describes an investigation on a new series of low-Ni high-Mn super duplex stainless steels (DSSs) 25Cr–2Ni–3Mo–10Mn–xN with nitrogen concentrations varying in the range between 0.37 and 0.50 wt.%. It was observed that these alloys have a ferrite–austenite structure. Under the same heat-treatment conditions, the austenite shows a marked upward tendency with an increase in N content. Nitrogen delays the precipitation of σ phase. The increase in nitrogen enhances the yield strength (YS), ultimate tensile strength (UTS) and ductility as well as the pitting corrosion potential of the materials. The pitting corrosion occurs in the austenite phases in the case of low N content (0.37 wt.%), but in the case of high N content (0.50 wt.%) it happens in the ferrite phases.     

Design of a new nanostructured,high-Si bainitic steel with lower cost production

To reduce cost production, a bainitic steel with a new chemical composition was designed using MUCG83 thermodynamic model. The steel was cast as cylinder bar using a high frequency induction furnace under argon gas atmosphere. The cast cylinder was electro-slag remelted (ESR) for obtaining clean steel. Hot rolling was carried out after ESR to reduce the thickness and to change the cast structure to a wrought structure. To obtain a bainitic structure the austenitized samples were transformed isothermally at the temperature range of 200–300 °C for different times and finally were quenched into water. The microstructures were characterized by X-ray diffraction, scanning electron and transmission electron microscopes. The tensile and Charpy impact tests were carried out to evaluate the mechanical properties. The results show a good combination of high tensile strength and impact toughness which is ideal for high performance applications. The prominent mechanical properties are due to the unique microstructural characteristics which are evolved during isothermal transformation.     

Process parameter influence on performance of friction taper stud welds in AISI 4140 steel

Friction taper stud welding is a new variant of friction welding which has been developed from the principles of friction hydro-pillar processing. This paper considers the effect of weld process parameters on weld defects, macrostructure and mechanical properties in AISI 4140 steel. It also presents 3D residual stress data for a typical friction taper stud weld. Applied downwards force, rotational speed and plunge depth (equivalent to consumable length) of the stud tool were systematically varied whilst measuring tool torque and temperature at several locations during welding. A simple Taguchi analysis was then used to relate process parameters and weld tensile strength. The combinations of parameters leading to high tensile strength are identified and linked to the occurrence of specific weld defects.     

Synergistic investigation into the marine parameters’ effect on the corrosion rate of AISI 316 stainless steel

In this paper, the corrosion rate of the austenitic stainless steel AISI 316, under the synergistic effect of environmental factors, has been assessed via potentiodynamic polarization scan. Salinity, velocity, pH and temperature are the factors that induce effects on the corrosion rate of the considered metal. Quantitative analysis is applied using the full two-level factorial experimental design method. This analysis calculates the contribution value of each parameter in changing the quantity of average corrosion rate in both individual and synergistic cases. In addition, qualitative analysis has been used to predict the variation direction. These two analyses show the important role of the synergistic action that changes the variation direction of corrosion rate and the contribution percentage of each parameter in varying the value of corrosion rate. Applying both quantitative and qualitative analyses can show the magnitude and quality of each parameter’s effect, which is remarkably valuable in marine application designs.     

Mechanical behaviour of Zn–Fe alloy coated mild steel

Zinc alloy coatings containing various amounts of Fe were deposited by electrodeposition technique on a mild steel substrate. The concentration of Fe in the produced alloy coatings ranged from 0 to 14 wt.%, whereas the thickness of the coatings was about 50 μm. Structural and metallurgical characterization of the produced coatings was performed with the aid of X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) techniques. This study aims in investigating the mechanical behaviour of Zn–Fe coated mild steel specimens, as no research investigation concerning the tensile behaviour of Zn alloy coated ferrous alloys has been reported in the past. The experimental results indicated that the ultimate tensile strength of the Zn–Fe coated mild steel was lower than the bare mild steel. In addition, the ductility of the Zn–Fe coated mild steel was found to decrease significantly with increasing Fe content in the coating.     

Characterization of microstructure,mechanical properties and corrosion resistance of dissimilar welded joint between 2205 duplex stainless steel and 16MnR

The joint of dissimilar metals between 2205 duplex stainless steel and 16MnR low alloy high strength steel are welded by tungsten inert gas arc welding (GTAW) and shielded metal arc welding (SMAW) respectively. The microstructures of welded joints are investigated using scanning electron microscope, optical microscope and transmission electron microscopy respectively. The relationship between mechanical properties, corrosion resistance and microstructure of welded joints is evaluated. Results indicate that there are a decarburized layer and an unmixed zone close to the fusion line. It is also indicated that, austenite and acicular ferrite structures distribute uniformly in the weld metal, which is advantageous for better toughness and ductility of joints. Mechanical properties of joints welded by the two kinds of welding technology are satisfied. However, the corrosion resistance of the weldment produced by GTAW is superior to that by SMAW in chloride solution. Based on the present work, it is concluded that GTAW is the suitable welding procedure for joining dissimilar metals between 2205 duplex stainless steel and 16MnR.     

Microstructure and mechanical properties of resistance spot welded dissimilar thickness DP780/DP600 dual-phase steel joints

In this study, resistance spot welding (RSW) experiments were performed in order to evaluate the microstructure and mechanical properties of single-lap joints between DP780 and DP600. The results show that the weld joints consist of three regions including base metal (BM), heat affected zone (HAZ) and fusion zone (FZ). The grain size and martensite volume fractions increase in the order of BM, HAZ and FZ. The hardness in the FZ is significantly higher than hardness of base metals. Tensile properties of the joints were described in terms of the failure modes and static load-carrying capabilities. Two distinct failure modes were observed during the tensile shear test of the joints: interfacial failure (IF) and pullout failure (PF). The FZ size plays a dominate role in failure modes of the joints.     

The development of Ti-alloyed high strength microalloy steel

Microalloy steels are generally Nb, V, or Nb, V, Ti composite microalloyed. Because of the high price of niobium and vanadium, the development of titanium microalloyed steels is a very interesting subject. In this study, steels with different Ti contents were refined and forged. Tensile tests were conducted and microstructures of samples were analyzed. Fine precipitates were observed using a transmission electron microscope. The results show that nanoscale Ti precipitates is the main factor enhancing strength of steels. The strength of steels increases with the Ti content. The optimum content range of titanium is between 0.04 and 0.10 wt.% while below 0.04 wt.% and higher than 0.10 wt.%, Ti has little effect on the strength of steels.     

Microstructure and mechanical properties of friction spot welded 6061-T4 aluminum alloy

Friction spot welding (FSpW) is a relatively new solid state joining technology developed by GKSS. In the present study, FSpW was applied to join the 6061-T4 aluminum alloy sheet with 2 mm thickness. The microstructure of the weld can be classified into four regions, which are stir zone (SZ), thermo-mechanically affected zone (TMAZ), heat affected zone (HAZ) and the base material (BM), respectively. Meanwhile, defects such as bonding ligament, hook and voids are found in the weld, which are associated to the material flow. The hardness profile of the weld exhibits a W-shaped appearance and the minimum hardness is measured at the boundary of TMAZ and SZ. Both the tensile/shear strength and cross-tension strength reach the maximum of 7117.0 N and 4555.4 N at the welding condition of the rotational speed of 1500 rpm and duration time of 4 s. Compared to cross-tension strength, the tensile/shear strength were stable with the variation of processing parameters. Three different fracture modes are observed under tensile/shear loading, which are plug type fracture, shear fracture and plug-shear fracture. There are also there different fracture modes under cross-tension loading, which are plug type fracture (on the upper sheet), nugget debonding and plug type fracture (on the lower sheet).     

Study of the characteristics of duplex stainless steel activated tungsten inert gas welds

The purpose of this study is to investigate the effects of the specific fluxes used in the tungsten inert gas (TIG) process on surface appearance, weld morphology, angular distortion, mechanical properties, and microstructures when welding 6 mm thick duplex stainless steel. This study applies a novel variant of the autogenous TIG welding, using oxide powders (TiO₂, MnO₂, SiO₂, MoO₃, and Cr₂O₃), to grade 2205 stainless steel through a thin layer of the flux to produce a bead-on-plate joint. Experimental results indicate that using SiO₂, MoO₃, and Cr₂O₃ fluxes leads to a significant increase in the penetration capability of TIG welds. The activated TIG process can increase the joint penetration and the weld depth-to-width ratio, and tends to reduce the angular distortion of grade 2205 stainless steel weldment. The welded joint also exhibited greater mechanical strength. These results suggest that the plasma column and the anode root are a mechanism for determining the morphology of activated TIG welds.     

On the mechanical behavior at sharp indentation of materials with compressive residual stresses

The correlation between residual stresses and the global properties, i.e. hardness and size of the contact area, given by a sharp indentation test have been studied quite frequently in recent years. The investigations presented have been based on experimental, theoretical and numerical methods and as a result, the basic features of the problem are now well understood. Furthermore, in this context quantitative relations, for the determination of residual stresses using sharp indentation, have been presented. Such relations have proven to be reliable in case of predominantly tensile residual stresses while the accuracy of predictions is much worse at compressive stress states. It is therefore the aim of the present study to investigate this matter in some detail and to present possible mechanisms for the difference in indentation behavior between tension and compression. Accordingly, the results are essentially qualitative but necessary and detailed investigations needed for a quantitative understanding are suggested. The present analysis is based on theoretical and numerical methods and in the latter case, the finite element method (FEM) is relied upon. Classical Mises elastoplastic material behavior is assumed throughout the investigation.     

Wear assessment of plasma nitrided AISI H11 steel

Plasma nitriding is one of the effective methods for improvement of the hardness, wear and corrosion resistance of steels. In this research AISI H11 hot working tool steel was plasma nitrided in various gas mixtures for different times and temperatures. The morphology, size and composition of nitride nanoparticles formed on the surface of the specimens were investigated using scanning electron microscopy (SEM), atomic force microscopy (AFM), X-ray diffraction (XRD). The wear behavior of plasma nitrided samples was studied by means of unlubricated pin-on-disc method under constant load of 80 N, sliding speed of 1 m/s, sliding distance of 2000 m at room temperature. The results showed plasma nitriding process improved the wear behavior of H11 steel. The increase in time and temperature of plasma nitriding decreased the hardness and increased the wear weigh loss of the specimens.     

Springback and time-dependent springback of 1Cr18Ni9Ti stainless steel tubes under bending

In this paper, the springback and time-dependent springback of 1Cr18Ni9Ti stainless steel tubes subject to bending is explored. Rotary draw bending tests have been carried out and marked time-dependent springback has been observed. A novel model in which time-dependent springback is associated with strain hardening is presented as an attempt to analyze this behavior. Using this model, the formulae of time-dependent springback, time-independent springback and total springback are derived. In addition, finite element analysis has been performed to investigate the stress distribution as well as to calculate the magnitude of springback. Comparison between analytical and experimental results shows good agreement.     

Microstructural and tribological characterization of plasma- and gas-nitrided 2Cr13 steel in vacuum

Plasma- and gas-nitrided 2Cr13 samples were characterized using optical microscopy, scanning electron microscopy (SEM), X-ray diffraction (XRD), and microhardness testing techniques. Nitrogen concentration profiles in the cross-sections of the nitrided samples were obtained by glow discharge optical spectroscopy (GDOS). Residual stress profiles along depth of the nitrided samples were measured using an X-ray stress tester. The tribological behaviour of the plasma- and the gas-nitrided samples in vacuum was investigated in order to analyse the effect of nitriding on wear resistance of the 2Cr13 steel. The results show the tribological properties of the 2Cr13 steel in vacuum are improved considerably by plasma nitriding and gas nitriding resulted from microstructure modification and surface hardening during nitriding. The plasma-nitrided samples have better wear resistance than the gas-nitrided samples under 30 N, while the gas-nitrided samples have higher wear resistance under 90 N. With increasing normal load from 30 N to 90 N, the wear mechanism shows a transition from mild adhesive and abrasive wear to severe adhesive or even delamination wear. The plasma-nitrided sample has thicker compound layer than the gas-nitrided sample, resulting that it exhibits more intensive delamination under high load of 90 N.     

Characterization of friction stir welded boron carbide particulate reinforced AA6061 aluminum alloy stir cast composite

Development of welding procedures to join aluminum matrix composite (AMCs) holds the key to replace conventional aluminum alloys in many applications. In this research work, AA6061/B₄C AMC was produced using stir casting route with the aid of K₂TiF₆ flux. Plates of 6 mm thickness were prepared from the castings and successfully butt joined using friction stir welding (FSW). The FSW was carried out using a tool rotational speed of 1000 rpm, welding speed of 80 mm/min and axial force of 10 kN. A tool made of high carbon high chromium steel with square pin profile was used. The microstructure of the welded joint was characterized using optical and scanning electron microscopy. The welded joint showed the presence of four zones typically observed in FSW of aluminum alloys. The weld zone showed fine grains and homogeneous distribution of B₄C particles. A joint efficiency of 93.4% was realized under the experimental conditions. But, FSW reduced the ductility of the composite.