Effect of braking pressure and braking speed on the tribological properties of C/SiC aircraft brake materials

Effects of braking pressure and braking speed on the tribological properties of C/SiC aircraft brake materials has been studied using a disk-on-disk type laboratory scale dynamometer. The braking temperature increased with increasing braking speed and was less affected by changes in braking pressure. The friction coefficient increased to the maximum value at 10 m/s and then fell with the increase of braking speed at the same braking pressure. The friction coefficient decreased with the increase of braking pressure at the same braking speed. The wear rate increased with braking speed increasing at the same braking pressure. The wear rate was little at braking speed below 20 m/s, and rapidly increased when the braking speed exceeded 20 m/s.     

C/C复合材料飞机刹车盘的三维温度场

针对C/C复合材料飞机(B757)刹车盘制动过程中温度测量过程复杂和温度场难于表征的问题,采用有限元方法结合惯性台实验对其温度场进行了分析研究。根据刹车盘制动原理和传热原理,确定了温度场有限元分析中的载荷、边界条件和加载过程。通过仿真后处理形象地描述了制动过程中刹车盘温度场的变化,直观地表现了温度场分布状态。结果表明;在正常着陆的能量条件下中间静盘处测温点在46s时达到最高温度659℃;承压盘和压紧盘的测温点则在48.5s时达到最高温度,整个过程各点温度先升高后降低,中间静盘的热负荷最大,温升最快,承压盘次之,压紧盘最小。对比实验测量与仿真结果,两者吻合较好,证实温度场的有效性。     

A carbon nanotube–enhanced SiC coating for the oxidation protection of C/C composite materials

A carbon nanotube–enhanced SiC (CNT–SiC) coating was deposited on C/C composites to improve the oxidation resistance of C/C. The CNT–SiC coating was prepared by direct growth of CNTs on C/C surface at 700 °C followed by deposition of SiC using chemical vapor deposition at 1150 °C for 1 h. SiC was deposited on the CNTs as well as the interface between CNTs and C/C, making CNTs strongly rooted on C/C surface. The final CNT–SiC coating consisted of two layers: the CNT–SiC layer and SiC layer. In comparison to the SiC coating, the CNT–SiC coating showed fewer cracks and a better oxidation resistance because the CNTs reduce the stress in the coating caused by the mismatch of the coefficient of thermal expansion between C/C and SiC.     

Micrographic studies on adhesively bonded scarf repairs to thick composite aircraft structure

The hard-patch approach to scarf repairs involves adhesively bonding a pre-formed patch into the scarf cavity. This approach has several potential advantages compared with the conventional soft-patch approach, which involves forming the patch from pre-preg and co-bonding it with the adhesive during cure of the patch directly in the repair cavity.Two methods for producing the hard-patch were investigated. The first was the moulded approach where the patch was laid up in a mould and cured prior to bonding in the repair cavity. The development and implementation of the moulded hard-patch repair technique on an F/A-18 horizontal stabiliser is described. The second approach involves machining the patch from a composite panel using digitised data obtained from the use of surface profiling equipment to capture the scarf cavity surface. Micrographic techniques were used to assess critical features of the bond-line produced from the different techniques. The results are compared with microscopic studies from a second F/A-18 horizontal stabiliser that was repaired much earlier using the soft-patch approach. Each repair is assessed in terms of the consolidation of plies along the bond-line and the conformity of the patch to the repair cavity as well as adhesive uniformity and porosity.     

Optimization of the chemical vapor deposition process for fabrication of carbon nanotube/Al composite powders

In order to optimize the chemical vapor deposition process for fabrication of carbon nanotube/Al composite powders, the effect of different reaction conditions (such as reaction temperature, reaction time, and reaction gas ratio) on the morphological and structural development of the powder and dispersion of CNTs in Al powder was investigated using transmission electron microscope. The results showed that low temperatures (500-550 °C) give rise to herringbone-type carbon nanofibers and high temperatures (600-630 °C) lead to multi-walled CNTs. Long reaction times broaden the CNT size distribution and increase the CNT yield. Appropriate nitrogen flow is preferred for CNT growth, but high and low nitrogen flow result in carbon nanospheres and CNTs with coarse surfaces, respectively. Above results show that appropriate parameters are effective in dispersing the nanotubes in the Al powder which simultaneously protects the nanotubes from damage.     

Thermal buckling and postbuckling behavior of functionally graded carbon nanotube-reinforced composite plates

Thermal buckling and postbuckling behavior is presented for functionally graded nanocomposite plates reinforced by single-walled carbon nanotubes (SWCNTs) subjected to in-plane temperature variation. The material properties of SWCNTs are assumed to be temperature-dependent and are obtained from molecular dynamics simulations. The material properties of functionally graded carbon nanotube-reinforced composites (FG-CNTRCs) are assumed to be graded in the thickness direction, and are estimated through a micromechanical model. Based on the multi-scale approach, numerical illustrations are carried out for perfect and imperfect, geometrically mid-plane symmetric FG-CNTRC plates and uniformly distributed CNTRC plates under different values of the nanotube volume fractions. The results show that the buckling temperature as well as thermal postbuckling strength of the plate can be increased as a result of a functionally graded reinforcement. It is found that in some cases the CNTRC plate with intermediate nanotube volume fraction does not have intermediate buckling temperature and initial thermal postbuckling strength.     

Experimental investigation of drying shrinkage cracking of composite mortars incorporating crushed tile fine aggregate

Drying shrinkage is generally classified as an important hardened concrete property. It expresses the strain occurring in hardened concrete due to the loss of water. During the drying process, free and absorbed water is lost from the concrete. When the drying shrinkage is restrained, cracks can occur, depending on the internal stresses in the concrete. The ingress of deleterious materials through these cracks can cause decrease in the compressive strength and the durability of concrete. In this study, being as a fine aggregate in mortars, crushed tile (CT) effect on drying shrinkage and drying shrinkage cracking is investigated. Thus, compressive and flexural strength, modulus of elasticity, and free and restrained drying shrinkage tests are conducted on mortar specimens produced with and without crushed tile fine aggregate. The ring test has been used in order to investigate the cracks induced by restrained drying shrinkage. In this way, free drying shrinkage strain, along with the number and development of drying shrinkage cracks, of the crushed tile fine aggregate mortar composites are quantified and observed.     

Fabrication of homogeneous titania/MWNT composite materials

MWNT/titania nanocomposites were prepared by an impregnation method and subsequent heat treatment at 400 °C. Precursor compounds such as titanium (IV) propoxide and titanium (IV) ethoxide were used to cover the surface of CNTs under solution conditions. Electron microscopy and X-ray diffraction techniques were carried out to characterize the as-prepared titania layers.     

Novel composite interconnecting ceramics La0.7Ca0.3CrO3−δ/Ce0.8Sm0.2O1.9 for solid oxide fuel cells

In this paper, an interconnecting ceramic for solid oxide fuel cells was developed, based on the modification from La_0.7Ca_0.3CrO_3−δ by addition of Ce_0.8Sm_0.2O_1.9. It is found that addition of small amount Ce_0.8Sm_0.2O_1.9 into La_0.7Ca_0.3CrO_3−δ dramatically increased the electrical conductivity. For the best system, La_0.7Ca_0.3CrO_3−δ + 5 wt.% Ce_0.8Sm_0.2O_1.9, the electrical conductivity reached 687.8 S cm⁻¹ at 800 °C in air. In H₂ at 800 °C, the specimen with 3 wt.% Ce_0.8Sm_0.2O_1.9 had the maximal electrical conductivity of 7.1 S cm⁻¹. With the increase of Ce_0.8Sm_0.2O_1.9 content the relative density increased, reaching 98.7% when the Ce_0.8Sm_0.2O_1.9 content was 10 wt.%. The average coefficient of thermal expansion at 30-1000 °C in air increased with Ce_0.8Sm_0.2O_1.9 content, ranging from 11.12 × 10⁻⁶ to 12.46 × 10⁻⁶ K⁻¹. The oxygen permeation measurement illustrated a negligible oxygen ionic conduction, indicating it is still an electronically conducting ceramic. Therefore, this material system will be a very promising interconnect for solid oxide fuel cells.     

Compressive behavior of C/SiC composite sandwich structure with stitched lattice core

C/SiC composite sandwich structure with stitched lattice core was fabricated by a technique that involved polymer impregnation and interweaving. The mechanical behaviors of C/SiC composite sandwich structure were investigated at room temperature. The out-of-plane compressive strength was 20.97 MPa while modulus was 1473.55 MPa. The microstructural evolution on compression fracture surfaces of the stitching yarns was investigated by scanning electron microscopy, and the damage pattern of fibers on compression fracture surface was presented and discussed. Under an in-plane compression loading, the C/SiC composite sandwich structure displayed a linear-elastic behavior until failure. The peak strength and average modulus are 165.61 MPa and 19.74 GPa, respectively. The failure of the specimen was dominated by the fracture of the facesheet.     

Fabrication of titania/hydroxyapatite composite granules for photo-catalyst

The titania/hydroxyapatite composite granular photo-catalyst with novel microstructure was fabricated by the process based on the liquid immiscibility effect and followed by precalcination and hydrothermal treatment from commercially available powders of α-Tri-calcium phosphate and TiO₂. XRD, SEM, BET, optical microscopy and UV-vis spectrophotometer were applied to characterize the prepared photo-catalyst. Microstructure analysis indicated that the granule was weaved by rod-shaped hydroxyapatite crystals whose surface was covered by nano-sized TiO₂. In the composite granules, the active surface of anatase was retained effectively. With the hybridization of TiO₂ and HAp, a 16-nm blue-shift of absorption edge could be observed and the crystallinity of anatase could be enhanced by precalcination. The granules with the rod-shaped hydroxyapatite crystals performing as scaffold work as three-dimensional high porous, size-controllable small reactor. The phase and microstructure transformation of the granule before and after hydrothermal treatment was investigated and its decomposition ability was evaluated by using Methylene blue as a target pollutant compound.     

Localized mechanical property assessment of SiC/SiC composite materials

SiC fiber-reinforced SiC matrix composites (SiC/SiC) are under consideration as a structural material for a range of nuclear applications. While these materials have been studied for decades, recently new small scale materials testing techniques have emerged which can be used to characterize SiC/SiC materials from a new perspective. In this work cross section nanoindentation was performed on SiC/SiC composites revealing that both the hardness and Young’s modulus was substantially lower in the fiber compared to the matrix despite both being SiC. Using scanning electron microscopy it was observed that the grain growth of the matrix during formation was radially out from the fiber with a changing grain structure as a function of radius from the fiber center. Focused ion beam machining was used to manufacture micro-cantilever samples and evaluate the fracture toughness and fracture strength in the matrix as a function of grain orientation in the matrix. Additionally microstructural characterization techniques like Raman spectroscopy, X-ray diffraction, and microtomography were used to evaluate differences in the matrix and fibers of the composite.     

Synthesis of Pt/PEI-MWCNT composite materials on polyethyleneimine-functionalized MWNTs as supports

Composite materials with highly dispersed platinum (Pt) nanoparticles on multiwalled carbon nanotubes (MWCNTs), functionalized with polyethyleneimine (PEI) by a noncovalent method were prepared. The PEI-functionalization provided high density homogeneous functional groups on the MWCNTs’ sidewalls for binding Pt nanoparticles. Cationic PEI leads to homogeneous dispersion in solutions such as water and organic solvents. The effects of a reducing agent on the Pt nanoparticles that form on the surfaces of the MWCNT were studied by varying the molar ratio of NaOH to H₂PtCl₆. These composite materials were characterized with transmission electron micrograph (TEM), X-ray diffractometer (XRD) and X-ray photoelectron spectroscopy (XPS). The Pt/PEI-MWCNT catalyst exhibits excellent electrocatalytic activity and compared with Pt/PVP-MWCNT catalysts obtained with polyvinylpyrrolidone (PVP). Finally, the cyclic voltammogram of methanol electrooxidation for Pt/PEI-MWCNT shows better tolerance to CO and methanol oxidation to CO₂ than of Pt/PVP-MWCNT.     

Effect of carbon nanofibers on the infiltration and thermal conductivity of carbon/carbon composites

Preforms containing 0, 5, 10, 15 and 20 wt.% carbon nanofibers (CNFs) were fabricated by spreading layers of carbon cloth, and infiltrated using the electrified preform heating chemical vapor infiltration method (ECVI) under atmospheric pressure. Initial thermal gradients were determined. Resistivity and density evolutions with infiltration time have been recorded. Scanning electron microscopy, polarized light micrograph and X-ray diffraction technique were used to analyze the experiment results. The results showed that the infiltration rate increased with the rising of CNF content, and after 120 h of infiltration, the density was the highest when the CNF content was 5 wt.%, but the composite could not be densified efficiently as the CNF content ranged from 10 wt.% to 20 wt.%. CNF-reinforced C/C composites have enhanced thermal conductivity, the values at 5 wt.% were increased by nearly 5.5-24.1% in the X-Y direction and 153.8-251.3% in the Z direction compared to those with no CNFs. When the additive content was increased to 20 wt.%, due to the holes and cavities in the CNF web and between carbon cloth and matrix, the thermal conductivities in the X-Y and Z directions decreased from their maximum values at 5 wt.%.     

C/C复合材料飞机刹车盘的结构与性能

采用企业、行业及国家相关标准的试验方法，对超码复合材料公司，英国Dunlop公司，法国CarbonIn-dusty公司，美国B．F．Goodrich、ALS公司等生产的9种C／C复合材料飞机刹车盘的物理、力学、热学、摩擦磨损的性能特征，以及中南大学生产的C／C复合材料刹车盘的有关性能，进行了对比分析。结果表明，选择适宜的炭纤维预制体结构，控制热解炭基体微观结构为光学粗糙层结构，合理的热处理温度是获得高性能炭刹车盘材料的关键。我国拥有自主知识产权研发的大型民机炭刹车盘在高摩擦特性方面获得了重大突破，已用于波音757—200型飞机，实现了国内C／C复合材料具有里程碑意义的第四个重大突破。     

Ablation behavior and mechanism of SiC/Zr–Si–C multilayer coating for PIP-C/SiC composites under oxyacetylene torch flame

To improve the ablation resistance of PIP-C/SiC composites, SiC/Zr–Si–C multilayer coating was prepared by chemical vapor deposition (CVD) using methyltrichlorosilane (MTS) and hydrogen as the precursors and molten salt reaction using KCl–NaCl, sponge Zr and K₂ZrF₆, then the ablation capability of the coated composites was tested under oxyacetylene torch flame. The linear and mass ablation rates were much lower than those of uncoated samples. The linear and mass ablation rates of the three coating coated samples reached 0.0452 mm/s and 0.031 g/s, decreased by 27.3% and 27.1%, respectively. Moreover, the linear and mass ablation rates of the five coating coated samples reached 0.0255 mm/s and 0.0274 g/s, decreased by 59.0% and 35.5%. The gases released during ablation could take away a lot of heat, which was also helpful to the protection of the composites.     

Finite difference solution of steady state creep deformations in a short fiber composite in presence of fiber/matrix debonding

A finite difference technique is developed to predict the second stage creep displacement rates and stress analysis of a short fiber metal matrix composite subjecting to a constant axial load through a micromechanical approach. The technique is capable to take into account the presence of interfacial debonding as one of the main factors affecting the creep performance of short fiber composites. The exponential law is adopted to describe the matrix creep behavior. Also, a model for prediction of interfacial debonding at fiber/matrix interface is developed using a stress based method. The obtained results could greatly help to better understand the flow pattern of matrix material and the load transfer mechanism between fiber and matrix with and without the presence of interfacial debond. The predicted strain rate by the proposed approach exhibits good agreement with the experimental results.     

Invariant temperature and field strain functions for Nb3Sn composite superconductors

The observed strain dependence of Nb₃Sn over an extended range of applied strain requires revision of the functions used previously to represent that strain dependence. The concept and various definitions of the strain function for the upper critical field and the critical temperature are reviewed. An invariant strain function for the critical temperature is derived from the strain energy potential of the general invariant strain analysis. The invariant strain function is applied to a study of uniaxial longitudinal applied strain on wire and tape conductors. Uniaxial forms of the general strain function are derived, and parameter values of the strain function are determined from a fit of the uniaxial forms to published uniaxial strain data for the critical temperature. The concept of precompression is examined in the context of the strain function. The invariant strain function, as an analytic function, is compared with numerical calculations of the general invariant strain analysis for longitudinal and transverse applied strain. The correspondence between the strain dependence of the critical temperature and the upper critical field is discussed, and a form of the invariant strain function for the upper critical field is presented.     

Characterisation and photocatalytic activity of structure-controlled spherical granules of an anatase/hydroxyapatite composite

Materials that can purify the environments are desirable. Anatase (TiO₂) has received attention because it is stable and can decompose organic substances because of its photocatalytic activity. To make use of anatase effectively, we deposited nano-sized anatase particles on porous hydroxyapatite (HA) ceramics composed of rod-shaped particles. Spherical porous HA granules composed of rod-shaped HA particles were prepared using a hydrothermal process. The granules were soaked in a solution containing a water-soluble titanium complex and then hydrothermally treated. Nano-sized anatase particles were deposited on each rod-shaped HA particle. The anatase/HA granules composed of rod-shaped HA particles showed higher photocatalytic activity than those composed of globular HA particles. The granules are expected to be useful as an environment-purifying material with high manageability and photocatalytic activity.     

In situ NiTi/Nb(Ti) composite

This paper reports on the creation of a series of in situ NiTi/Nb(Ti) composites with controllable transformation temperatures based on the pseudo-binary hypereutectic transformation of NiTi–Nb system. The composite constituent morphology was controlled by forging and rolling. It is found that the thickness of the NiTi lamella in the composite reached micron level after the hot-forging and cold-rolling. The NiTi/Nb(Ti) composite exhibited high damping capacity as well as high yield strength.