共查询到18条相似文献,搜索用时 189 毫秒
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SiC-ZrO2(3Y)-Al2O3纳米复相陶瓷的力学性能和显微结构 总被引:10,自引:0,他引:10
本文介绍用非均相沉淀方法制备的纳米SiC-ZrO2(3Y)-Al2O3复合粉体经放电等离子超快速烧得到晶内型的纳米复相陶瓷,超快速烧结的升温速率为600℃/min,在烧结温度不保温,迅即在3min内冷却至600℃以下。 相似文献
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包覆型ZrO2(3Y)粉体研制 总被引:13,自引:3,他引:10
用微波法制备单分散、纳米水合二氧化锆,利用异相成核工艺在水合二氧化锆粒子表面均匀包覆一层Y(OH)3,制备出包覆型ZrO2(3Y)粉体先驱体.最后对煅烧ZrO2(3Y)粉体进行相结构分析,发现在室温下包覆型ZrO2(3Y)粉体中无m-ZrO2存在.结果表明;利用包覆的方法能将Y2O3均匀地加入到ZrO2中,提高ZrO2(3Y)粉体中亚稳定t-ZrO2的含量. 相似文献
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纳米ZrO2/(1-n)SiO2-nAl2O3介孔复合作的制备与光致发光 总被引:1,自引:0,他引:1
采用溶胶-凝胶法和超临界干燥技术制备了(1-n)SiO2-nAl2O3(n=0、0.01、0.1)混合气凝胶体系,并以此作为载体,成功地将纳米ZrO2粒子组装到(1-n)SiO2-nAl2O3介孔体系中,而形成纳米ZrO2/(1-n)SiO2-nAl2O3介孔复合材料。光致发光光谱研究表明,室温下以316nm(3.92eV)波长激发时,纳米ZrO2粒子540nm(2.30eV)荧光峰,在介孔复合体 相似文献
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Preparation and Properties of Sintering Additives Coated Si3N4 from Heterogeneous Nucleation Processing 总被引:1,自引:0,他引:1
The sintering additives such as Al2O3 and /or Y2O3 were coated on the surfaces of Si3N4 particles via heterogeneous nucleation processing using a buffered pH solution as the precipitation reagent .They nucleated and grew only on the surfaces of Si3N4 and did not form sol particles in solution by TEM observation .The isoelectric point(IEP) of coated Si3N4 was different from that of as-received Si3N4.The IEP of Al(OH)3-coated Si3N4 occurred at pH8.4, which is close to that of alumina .When Al(OH)3-coated Si3N4 particles were coated with Y(OH)3,the IEP of coated Si3N4 powder shifted from pH8.4 to pH9.2 ,similar to that of yttria.In addition ,the rheological data showed that Al2O3 and /or Y2O3 coated Si3N4 suspension is nearly Newtonian and that added Si3N4 suspension shows a shear rate thinning behavior. 相似文献
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Properties of Al2O3-coated nano-SiC have been compared with those of as-received SiC.The isoelectric point(IEP) of SiC changed from pH3.4 to pH7.3 after coating with the alumina precursor,which is close to that of alumina.Because both surfaces of coated SiC and Al2O3 possess higher positive charge at pH=4.5-5.0 ,they are uniformly dispersed in the two-phase aqueous suspensions.Then a mixed powder containing nano-SiC dispersed homogeneously into the Al2O3 matrix was achieved from flocculating the two-phase suspension.Finally,Al2O3/SiC nanocomposited were obtained by coating nano-SiC with Al2O3 ,in which the majority of SiC particles were located within the Al2O3 grains.The observation by transmission electron microscopy(TEM) and the analysis by the X-ray photoelectron spectroscopy(XPS) showed that cracks propagated towards the intragranular SiC rather than along prain boundaries. 相似文献
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Aluminum oxide (Al2O3) matrix have been reinforced by the multi-walled carbon nanotubes (MWCNTs) to overcome the inherent brittleness of Al2O3 matrix. In order to increase mechanical properties of MWCNTs-Al2O3 composites, MWCNTs need to be well dispersed and individually incorporated in Al2O3 matrix. In this work, aluminum hydroxide (Al(OH)3) used as a Al2O3 precursor and MWCNTs were mixed in an aqueous solution for the homogeneous mixing of hetero-particles, as functions of the content of MWCNTs and the potential hydrogen (pH) of Al(OH)3 suspension. Firstly, MWCNTs were purified and modified by an acid reagent, inducing that the dispersibility of MWCNTs is increased in an aqueous solution by carboxylic group given on the surface of MWCNTs. The modified MWCNTs were added in the Al(OH)3 suspension, and then the mixture was filtered at room temperature. The filtered powders were formed using an uniaxial pressing and then densified by a pressureless heat treatment. As the pH is decreased the Al(OH)3 particles are well dispersed in an aqueous solution, due to the increment of repulsive force between particles with a same surface charge. MWCNTs are individually incorporated into Al2O3 matrix up to 1 vol.% MWCNTs, whereas MWCNTs are aggregated at the composite with 3 vol.% MWCNTs. Therefore, control of the pH and the MWCNTs content are key factors to be considered for the fabrication of MWCNTs-Al2O3 composites with high functional properties. 相似文献
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为了改善Y2O3粉体的分散性,提高其烧结活性,试验以三乙醇胺和氨水为凝胶剂,利用溶胶-凝胶方法合成了纳米级Y2O3粉体,采用差热/热重、X射线衍射、透射电镜研究了前驱体的组成、前驱体在不同的煅烧温度下的物相变化以及煅烧粉体的分散性.结果表明,前驱体的组成为Y2(OH)5.14(NO3)0.86H2O,在500℃保温2h可直接生成立方相的Y2O3,煅烧至1000℃保温2h得到了结晶度高、分散性好、平均粒径为50nm、近球形的YO纳米粉体;三乙醇胺的加入有利于提高YO粉体的分散性. 相似文献