Investigation of mechanical properties of advanced Al–Zn–Mg–Cu alloy

Abstract

The mechanical properties of the rapidly solidified 7000 series powder alloy CW 67 were investigated for various extrusion and heat treatment conditions. The principal aim of the work was to ascertain the optimum processing route for peak aged (T6) material. The highest proof stress in the T6 condition was found to be 572 MN m^?2 for material extruded at 325°C and aged for 13·5 h at 120°C after solutionising. The ductility of this material was found to be 13·5%. The fracture toughness was measured in two orientations and found to be approximately 21 MN m^?3/2 in the short transverse direction and 44 MN m^?3/2 in the longitudinal direction. Degassing and hot compaction was found to improve the fracture toughness of the material substantially.

MST/1504     

A high strength and ductility Mg–Zn–Al–Cu–Mn magnesium alloy

A high strength Mg–8.0Zn–1.0Al–0.5Cu–0.5Mn (wt.%) magnesium alloy with outstanding ductility was developed using a common casting technique and heat treatment. The microstructure of the as-cast alloy is composed of α-Mg, MgZn, MgZnCu and Al–Mn phases. After the solution treatment and subsequent two-step aging treatment, the yield strength (YS), ultimate tensile strength (UTS) and elongation of the alloy at peak hardness reach 228 MPa, 328 MPa and 16.0% at room temperature, respectively. The comprehensive mechanical properties of the alloy are superior to almost all other high performance casting Mg alloys.     

Microstructure and tensile properties of squeeze cast Al–Zn–Mg–Cu alloy

Abstract

It is well known that wrought aluminium alloys have tensile properties superior to those of the cast products. Wrought grade alloys cannot usually be produced by conventional casting processes to attain the same level of tensile properties. However, progress in casting methods in recent years has made it possible to produce wrought alloys by means of squeeze casting techniques. In the present study an Al–Zn–Mg–Cu alloy has been produced by squeeze casting. Tensile properties close to those of wrought products have been achieved by controlling the microstructure, pressure, and other processing parameters.     

Microstructure and mechanical properties of Al–Si–Mg–Cu–Ti alloy with trace amounts of scandium

The effect of Sc on the microstructure and mechanical properties of Al–Si–Mg–Cu–Ti alloy was investigated. Results obtained in this research indicate that, with increasing Sc content, the microstructure of the investigated alloys exhibits finer equiaxed dendrites with rounded edges and the morphology of the eutectic Si shows a complete transition from a coarse needle-like structure to a fine fibrous structure upon modification of eutectic Si. Subsequent T6 heat treatment had further induced the precipitation of nano-scaled secondary Al₃(Sc, Ti) phase, as well as spheroidisation of eutectic Si. Combined with T6 heat treatment, the ultimate tensile strength, yield strength, percentage elongation and hardness were achieved in 0.20?wt-% Sc-modified alloy.     

Thermomechanical processing of Cu–Ni–Si–Cr–Mg alloy

Abstract

The relationships between the structure and properties of a Cu–Ni–Si–Cr–Mg alloy are discussed. Possible methods of improving the properties and operating characteristics of semiproducts manufactured from this type of alloy were investigated. It was found that these properties, in particular their stability, depend mainly on the structure of the material, which in turn depends on the thermomechanical treatment. Examples and possible applications are presented.

MST/1436     

Influence of second phases on mechanical properties of spray-deposited Al–Zn–Mg–Cu alloy

Al–10.66Zn–2.48Mg–1.41Cu–0.17Zr–0.17Sc (wt.%) alloy prepared by spray deposition was processed with different hot deformation followed by heat treatment. The mechanical properties and microstructure evolution were investigated. The results indicate that uniform ultimate tensile strength of 774 MPa, yield strength of 734 MPa and elongation of 13.7% are obtained with two-step hot deformation, which increase by 2.7%, 3.82% and 95% compared with one-step hot deformation. Microstructural observations show that increase of elongation is mainly ascribed to high volume fraction of smaller precipitates and reduction of stress concentration areas as a result of disappearance of the coarse second phases. The fractured tensile specimens with two-step hot deformation exhibit dimple fractographic features. Improvement of strength is attributed to the precipitation strengthening and dispersed strengthening.     

Effect of Zn addition on two-step aging behaviour of Al–Mg–Si–Cu alloy

This study investigates the effect of Zn addition two-step behaviour in an Al–Mg–Si–Cu alloy. During pre-aging at 100°C for 3?h, the Zn can partition into clusters because of the strong Zn–Mg interaction, prompting the formation of clusters. During subsequent artificial aging at 180°C for up to 240?min (peak hardness condition), the Zn does not significantly partition into clusters or precipitates, and the majority of Zn remains in the Al matrix. However, the presence of Zn in the matrix stimulates the transformation from clusters to GP zones to β′′ phases. The enhanced formation of GP zones and β′′ phases correlates well with the remarkable age-hardening response.     

Mechanism of grain refinement of an Al–Zn–Mg–Cu alloy prepared by low-frequency electromagnetic casting

Low-frequency electromagnetic casting (LFEC) process had been developed and is being used for the past several years with the application of an induction coil placed outside the conventional direct chill (DC) casting mould. It has been demonstrated that the LFEC process has a significant grain refining effect on aluminium alloys. In the present study, temperature measurement and direct quenching from liquid and/or semi-solid were carried out to study the temperature field during casting process and to understand the mechanism of the grain-refining effect of the LFEC process. The experimental results showed that in contrast to the conventional DC casting process, the liquid melt from the launder, during the LFEC process, is cooled with very high cooling rate directly to 3–6 °C below the liquidus, and the temperature field of the entire melt in the mould, and the hot top is quite uniform, which results in the enhanced heterogeneous nucleation and improved survival rate of the nuclei. This is believed to be the main reason why the LFEC process can significantly refine the grain size of aluminium alloys.     

Microstructural evolution of Al–Zn–Mg–Cu alloy during homogenization

In this study, the microstructural evolution of an as-cast Al–Zn–Mg–Cu alloy (AA7085) during various homogenization schemes is investigated. It is found that in a single-stage homogenization scheme, some of the primary eutectic gets transformed into the Al₂CuMg phase at 400 °C, and the primary eutectic and Al₂Cu phase gradually dissolve into the alloy matrix at 450 °C. The Al₃Zr particles are mainly precipitated at the center of the grain because Zr is peritectic. However, the homogeneous distribution of the Al₃Zr particles improves and the fraction of Al₃Zr particles increases in two-stage homogenization scheme. At the first low-temperature (e.g., 400 °C) stage, the Al₃Zr particles are homogeneously precipitated at the center of the grain by homogeneous nucleation and may be heterogeneously nucleated on the residual second-phase particles at the grain boundary regions. At the second elevated-temperature (e.g., 470 °C) stage, the Al₃Zr nuclei become larger. A suitable two-stage homogenization scheme for the present 7085-type Al alloy is 400 °C/12 h + 470 °C/12 h.     

Hot deformation behavior of spray-deposited Al–Zn–Mg–Cu alloy

The flow behavior of spray-deposited Al–10.21Zn–2.76Mg–1.45Cu–0.16Zr (wt.%) alloy has been systematically investigated by thermal compression tests with temperature and strain rate ranging from 613 K to 733 K and 0.001–1 s⁻¹, respectively. Microstructural observations revealed that the average grain size of spray-deposited alloy was below 25 μm due to the high cooling rate. Both relatively high temperature and low strain rate could promote the formation of dynamic recrystallization (DRX). The stress level of the alloy decreased with increasing deformation temperature and decreasing strain rate, which could be characterized by a Zener–Hollomon parameter in the hyperbolic-sine equation. Furthermore, the strain-dependent constitutive equation could lead to a good agreement between the calculated and measured flow stresses in the elevated temperature range for spray-deposited alloy. The deformation activation energy for spray-deposited alloy was relatively lower than that of the as-cast alloy owing to ultrafine grains and high supersaturated solid solubility.     

High-pressure homogenization treatment of Al–Zn–Mg–Cu aluminum alloy

Absract The microstructures and aging hardening response of Al–12Zn–3.5Mg–3.0Cu–0.14Zr aluminum alloy after a high-pressure homogenization treatment at 750 °C for 45 min under 5 GPa were investigated. The results showed that the constituent phases dissolved completely and formed α-Al single-phase solid solution comparable to that formed after ambient-pressure homogenization at 450 °C/96 h + 460 °C/128 h. The complete dissolution of the constituent phases increased the solubility of the alloying elements, as well with the over-burning temperature and aging hardness.     

Precipitation in Cu–Ni–Si–Zn alloy for lead frame

The aging of Cu–Ni–Si–Zn alloy for lead frame is investigated. The results showed that the peak of hardening effect occurs after aging for about 1 h and the electrical conductivity increases continuously with aging times. The hardness of the alloy reached a peak at 430–460 °C for 2 h and electrical conductivity reached a peak at 500–550 °C and continuously decreased afterwards. The cold rolling prior to the aging treatment was used to increase the precipitation rate. The precipitates responsible for the age-hardening effect are disc-shaped δ-Ni₂Si, which has an orthorhombic structure.     

Effect of processing variables on structure and tensile properties of investment cast Al–Si–Mg casting alloy

Abstract

A research programme was conducted to study the effects of grain refinement, eutectic silicon modification, filtering, pouring and shell preheat temperatures, and heat treatment on the structure and tensile properties of an investment cast Al–Si–Mg alloy, LM25 (BS 1490 : 1988). The principal findings of the research were that: an increase in shell preheat temperature adversely affects the structure and, hence, the tensile properties; grain refinement was enhanced as the titanium content was increased to about 0·28% but the tensile properties were not affected; a modified eutectic silicon structure was achieved with strontium additions in the range 0·01–0·02%, with the optimum addition, based on tensile properties, being 0·01%; and, as would be expected, heat treatment improved the tensile properties. On the basis of the interrelationships between process variables, structural changes, and tensile properties observed, an optimum processing route was identified. The optimum tensile properties were obtained in fully heat treated specimens that had been both grain refined and modified and produced in moulds poured at ambient temperature.     

Non-isothermal aging of a high-Zn-containing Al–Zn–Mg–Cu alloy: microstructure and mechanical properties

The non-isothermal aging behaviour of a newly developed Al–Zn–Mg–Cu alloy containing 17?wt-% Zn was investigated. Hardness and shear punch tests demonstrated that during non-isothermal aging, the mechanical properties of the alloy first increased and then decreased. The best properties were obtained in a sample which was non-isothermally aged upto 250°C with heating rate of 20°C?min^?1, due to the presence of η′/η (MgZn₂) phases. This was confirmed by differential scanning calorimetery. After homogenisation, residual eutectic phases remained at triple junctions or in a spherical form. During aging, these phases transformed into rodlike S (Al₂CuMg)-phase at 400°C, with sizes ranging from 50 to 250?nm. The precipitation sequence in this high-Zn alloy was similar to that for conventional Al–Zn–Mg–Cu alloys.     

Effect of cooling aging on microstructure and mechanical properties of an Al–Zn–Mg–Cu alloy

In the present work, Al–Zn–Mg–Cu alloy was aged by non-isothermal cooling aging treatment (CAT). At high initial aging temperature (IAT), the hardness was decreased with the decreased cooling rate. However, when IAT was lower than 180 °C, the hardness was increased with the decreased cooling rate. Conductivity was increased with the decreased cooling rate regardless of IAT. The tensile strength, yield strength and conductivity of Al alloy after (200–100 °C, 80 °C/h) CAT were increased 2.9%, 8.1% and 8.3% than that after T6 treatment, respectively. With an increase of IAT and decrease of cooling rate, the fine GP zone and η′ phase were transformed to be larger η′ and η precipitates. Moreover, continuous η phase at grain boundary was also grown to be individual large precipitates. Cooling aging time was decreased about 90% than that for T6 treatment, indicating cooling aging could improve the mechanical properties, corrosion resistance and production efficiency with less energy consumption.     

Effects of Cu content on microstructure and mechanical properties of Al–14.5Si–0.5Mg alloy

This study elucidates how Cu content affects the microstructure and mechanical properties of Al–14.5Si–0.5Mg alloy, by adding 4.65 wt.% and 0.52 wt.% Cu. Different Fe-bearing phases were found in the two alloys. The acicular β-Al₅FeSi was found only in the high-Cu alloy. In the low-Cu alloy, Al₈Mg₃FeSi₆ was the Fe-bearing phase. Tensile testing indicated that the low-Cu alloy containing Al₈Mg₃FeSi₆ had higher UTS and elongation than the high-Cu alloy containing the acicular β-Al₅FeSi. It is believed that the presence of the acicular β-Al₅FeSi in the high-Cu alloy increased the number of crack initiators and brittleness of the alloy. Increasing Cu content in the Al–14.5Si–0.5Mg alloy also promoted solution hardening and precipitation hardening under as-quenched and aging conditions, respectively. The hardness of the high-Cu alloy therefore exceeded that of low-Cu alloy.     

Evolution of nickel-rich phases in Al–Si–Cu–Ni–Mg piston alloys with different Cu additions

Evolution of nickel-rich phases (Ni-phases) in Al–Si–Cu–Ni–Mg piston alloys is investigated. The qualitative results show that, with the increasing of Cu content, Ni-phases translate from Al₃Ni (ε-phase) or Al₃CuNi (δ-phase) to Al₇Cu₄Ni (γ-phase), and their morphologies change from short-strip to reticular and then annular or semi-annular shape. Moreover, the quantitative calculations by Thermo-Calc software are in accordance with that of experiments’. The evolutions have a great effect on the mechanical properties. The tensile strength at room temperature decreases from 263.8 MPa to 229.6 MPa, and then increases to 278.9 MPa. Otherwise, the elevated temperature tensile strength increases about 19.7%. But the coefficient of linear expansion decreases constantly.     

Microstructure and mechanical properties of variable-plane-rolled Mg–3Al–1Zn alloy

A flawless bulk AZ31 magnesium alloy with extensive mechanical twins was produced by variable-plane rolling, in which the sample was rotated 90° around its longitudinal axis between passes. The unique orientation relationship between the parent grains and the twin grains favours twinning during variable-plane rolling, which leads to the formation of extensive twins. Tensile testing revealed an excellent balance of mechanical properties, with a yield strength of 280 MPa and 15.5% elongation to failure. The significant strengthening originates from the effective blockage of glide dislocations by numerous conventional grain boundaries and twin boundaries. A weak double-peak (slightly off-basal) texture is formed during variable-plane rolling, which helps in achieving the desired level of ductility.     

Heating aging behavior of Al–8.35Zn–2.5Mg–2.25Cu alloy

In the present work, the influence of heating aging treatment (HAT) on the microstructure and mechanical properties of Al–Zn–Mg–Cu alloy was investigated. When the final aging temperature (FAT) was lower than 180 °C, the hardness increased with the decreasing of heating rate, however, in the case of the FAT was higher than 180 °C, the variation of hardness was opposite. The electrical conductivity of Al–Zn–Mg–Cu alloy increased with the decrease of heating rate regardless of FAT. The tensile strength, yield strength and conductivity of the Al alloy after (100–180 °C, 20 °C/h) HAT increased by 1.6%, 4.5% and 14.1% than that after T6 treatment, respectively. The precipitates sequence of HAT was coincident with that of isothermal aging, which is SSS → GP zone → η′ → η. With the increase of FAT and the decrease of heating rate, the fine precipitates became larger and the continuous η phase at grain boundary grew to be individual large precipitates. The HAT time was decreased about 80% than that for T6 treatment, indicating HAT could improve the mechanical properties, corrosion resistance and production efficiency with less energy consumption.     

Microstructure and mechanical properties of a new Al–Zn–Mg–Cu alloy joints welded by laser beam

A new type of Al–Zn–Mg–Cu alloy sheets with T6 temper were welded by laser beam welding (LBW). Microstructure characteristics and mechanical properties of the joints were evaluated. Results show that grains in the heat affected zone (HAZ) exhibit an elongated shape which is almost same as the base metal (BM). A non-dendritic equiaxed grain zone (EQZ) appears along the fusion line in the fusion zone (FZ), and grains here do not appear to nucleate epitaxially from the HAZ substrate. The FZ is mainly made up of dendritic equiaxed grains whose boundaries are decorated with continuous particles, identified as the T (AlZnMgCu) phase. Obvious softening occurs in FZ and HAZ, which mainly due to the changes of nanometric precipitates. The precipitates in BM are mainly η′, while plenty of GPI zones exist in FZ and HAZ adjacent to FZ, in the HAZ farther away from FZ, η phase appears. The minimum microhardness of the joint is always obtained in FZ at different times after welding. The ultimate tensile strength of the joint is 471.1 MPa which is 69.7% of that of the BM. Samples of the tensile tests always fracture at the FZ.