激光诱导荧光及其应用

阐述了荧光产生的机理、荧光测量的几种方法，概括了荧光在几个方面的应用。     

丙烯醛的激光诱导荧光研究

报道了丙烯醛在359～365 nm 的激光诱导荧光激发谱,对所得的光谱进行了标识。实验发现丙烯醛分子在上述波长范围以外荧光中断。主要原因可能是:在长波端由于三重态和单重态的系间窜越造成非辐射跃迁,而在短波端则由于是(?)态受到预离解的(?)态微扰。实验得到丙烯醛 A 态的势垒高度为 E_T=1900 cm~(-1)。     

ⅡB族同核准分子Hg2226.2nm漫射带研究

本文报导在高纯Ｈｇ蒸气石英放电管中首次观测到峰值位于２２６．２ｎｍ左右属于Ｈｇ２准分子ＧＯ＾＋ｕ→ＸＯ＾＋ｇ束缚→自由跃迁的漫射带辐射，实验测量了漫射带强度随放电电流、气体温度和密度的变化关系，获得漫射带最大信号输出的工作参量。     

激光诱导荧光光谱法研究NaK分子d~3∏态布居的机制

用Ar~+激光器514.5nm激光线激发NaK分子,在590—710nm范围获得d~3∏→a~3∑~+跃迁三重态荧光谱。实验结果表明:D~1∏态与d~3∏态间相互微扰以及D~1∏态到d~3∏态的碰撞诱导转移是引起d~3∏→a~3∑~+跃迁增强的最主要原因。     

激光诱导荧光技术在农药残留物探测中的应用

介绍了一种由3 倍频Nd∶YAG激光器、光谱仪、ICCD 以及计算机构成的激光荧光光谱检测系统及其测量原理和方法,实际测量了5 种农药的荧光谱,该系统具有简便、快捷、准确、灵敏度高等优点,适合用于未来的农药残留物检测。     

激光诱导荧光检测技术

激光诱导荧光(LIE)检测作为目前灵敏度最高的检测技术之一,在生物、化学、医学等领域应用广泛,其本身的技术发展也十分迅速.综述了近年来LIF检测系统、荧光探针、荧光分析技术和应用领域的进展,重点介绍了LIF激光光源、光纤光路LIF系统、多通道LIF系统以及LIF成像的最新进展和应用前景.     

紫外激光诱导胃癌组织自体荧光的研究

本文测量了紫外激光（３０８ｎｍ）激发诱导正常组织和胃癌组织３１５ｎｍ－６００ｎｍ波段的自体荧光，发现胃癌组织在此荧光光谱不同于正常组织的荧光光谱。根据两者４的区别，可以把胃癌组织从正常组织中区分出来，这为诊断胃癌提供了一个新的思路。     

掺铬镁橄榄石的LIF光谱研究

本文用LIF方法研究了铬镁橄榄石(Cr∶Mg_2SiO_4)的室温电子辐射谱。该辐射谱有两个辐射带(S带和L带),其中S带来自Cr~(3+)离子的辐射,而L带则对应于Cr~(4+)的辐射。     

Revisit of the band gaps of rutile SnO2 and TiO2: a first-principles study

From the recent experimentally observed conduction band offset and previously reported band gaps,one may deduce that the valence band offset between rutile SnO2 and TiO2 is around 1 eV,with TiO2 having a higher valence band maximum.This implication sharply contradicts the fact that the two compounds have the same rutile structure and the Γ3^+ VBM state is mostly an oxygen p state with a small amount of cation d character,thus one would expect that SnO2 and TiO2 should have small valence band offset.If the valence band offset between SnO2 and TiO2 is indeed small,one may question the correctness of the previously reported band gaps of SnO2 and TiO2.In this paper,using first-principles calculations with different levels of computational methods and functionals within the density functional theory,we reinvestigate the long-standing band gap problem for SnO2.Our analysis suggests that the fundamental band gap of SnO2 should be similar to that of TiO2,i.e.,around 3.0 eV.This value is significantly smaller than the previously reported value of about 3.6 eV,which can be attributed as the optical band gap of this material.Similar to what has been found in In2O3,the discrepancy between the fundamental and optical gaps of SnO2 can be ascribed to the inversion symmetry of its crystal structure and the resultant dipole-forbidden transitions between its band edges.Our results are consistent with most of the optical and electrical measurements of the band gaps and band offset between SnO2 and TiO2,thus provide new understanding of the band structure and optical properties of SnO2.Experimental tests of our predictions are called for.     

应用激光诱发荧光诊断不同物质导致的白鼠肝纤维化

本文应用激光诱导荧光的方法,对不同物质诱发白鼠的肝纤维化的肝组织进行了荧光光谱分析,发现经过注射不同物质的白鼠的肝组织与正常白鼠的肝组织的荧光光谱有明显不同,这一结果对于研究肝纤维化的起因和对肝纤维化进行早期诊断有重要参考价值。     

~(52)Cr原子束激光生荧光稳频技术

通过分析52Cr原子光刻对激光系统的技术要求,详细介绍了一种基于原子束激光感生荧光(LIF)光 谱技术的稳频方法。     

Determination of the optimum material parameters for intermediate band solar cells using diffusion model

In this study, the optimum material parameters capable of providing high efficiencies close to the detailed balance limit are determined for intermediate band solar cells. A diffusion model, including the overlap effect between absorption coefficients, is used during the calculations for the first time. It is obtained that to achieve high efficiencies close to the detailed balance limit; the effective density of state value, N_CV, should be higher than 10¹⁷ cm⁻³ and the carrier mobility should be larger than 200 cm²/Vs, where the light concentration should not be higher than nearly 1000 sun. Besides, it is found out that the optimum intermediate band level and the base width depend on the mobility and effective density of state values. So they need to be optimized according to the material parameters. The effect of overlap between absorption coefficients on the performance of intermediate band solar cells is also investigated. Copyright © 2012 John Wiley & Sons, Ltd.     

工作条件对TEA序列带CO2激光器输出的影响

选择主放电电容器容量、电压、混合气配气比和预电离条件等对ＴＥＡＣＯ２序列带激光输出随注入能量变化的特性进行了研究。采取有效的能量注入,获得了好的输出结果。     

K波段宽带螺旋天线设计

从理论上分析了螺旋天线的设计原理,利用阿基米德螺旋天线实现了一款K波段的高频宽带螺旋天线,使高频天线拥有更轻的质量,更低的剖面及更好的圆极化性。最后通过仿真软件CST设计了一款带宽覆盖18.0~26.5GHz的阿基米德螺旋天线,涵盖了整个K波段。结果表明,该天线在整个频段电压驻波比<2,能很好的满足天线收发要求。     

二维正方复式晶格的完全光子带隙

为产生光子晶体完全光子带隙,在二维正方晶格的介质柱中心构造一个空气柱孔缺陷,应用平面波展开的方法研究了光波在其中的传播规律,发现在特定的结构参数条件下,该结构产生了完全光子带隙,从而找到了在简单晶格结构条件下实现完全光子带隙的方法。     

Nd2O3掺杂K0.5Na0.5NbO3无铅压电陶瓷压电性能的研究

采用传统固相反应法制备了K<,0.5>Na<,0.5>NbO<,3-x>Nd<,2>O<,3>(简称KNN-<,x>Nd)系列无铅压电陶瓷,研究了不同Nd<,2>O<,3>含量(x=0,0.05,0.15,0.25,0.35,0.50,0.60,1.00)样品的物相组成、显微结构及压电性能.结果表明:A位的Nd<'3+...     

宽带CARS技术用于气体温度的测量

本文报道了用宽带CARS技术测量高温空气的温度及其实时的升降过程。结果明显地优于有滞后效应的常规热电偶测试方法。