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Effect of additives on mechanical properties of oxidation-resistant carbon/carbon composite fabricated by rapid CVD method 总被引:1,自引:0,他引:1
The optimum composition of additives was obtained by the orthogonal design test method for oxidation-resistant carbon/carbon composites (C/C) fabricated by the rapid CVD method. The effect of additives on mechanical properties was examined. The additives used in this test included silicon carbide, silicon nitride, and metal borides. Additives doped into the matrix of C/C increase not only the initial oxidation temperature from 400 to 657°C (64%), but also its flexural strength from 121 to 254 MPa (110%), and flexural modulus from 25 to 45 GPa (96%). The increase of mechanical properties is considered to be due to the formation of a metallic carbon–boron compound in the microstructure. 相似文献
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The electronic properties of as-prepared and purified DWNT films were tested using the four-probe method. The resistivity of the purified DWNT films is about 1 mΩ cm at room temperature and has a positive dρ/dT above 55 K, which shows a good metallic property. The electrical resistivities of the purified DWNT films are quite similar to those of the SWNT bundles and acid-treated SWNTs. Our results are correspondent with the early theoretical calculation on the band structure of DWNTs. 相似文献
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The effect of heat treatment on microstructure of a plain-weave carbon fabric reinforced carbon-carbon composite with phenolformaldehyde-derived carbon matrix was investigated by X-ray diffraction. The diffraction patterns were analysed by the least-square fitting program Carbonxs. After heat treatment from 1000 to 2800 °C the interplanar distance of (002) planes decreased from 3.488 to 3.420 Å and the lattice parameter in basal plane increased from 2.440 to 2.464 Å, respectively. Simultaneously, the coherent block size in the basal plane directions increased from 18 to 54 Å, which was accompanied by an increase of the fraction of organised carbon atoms from 0.50 to 0.85. The 002 diffraction profile of the composite was much narrower than the sum of peaks of the matrix and fabric alone. This can probably be caused by a better crystallographic ordering (or by a partial graphitisation) of the matrix in the composite. On the other hand, the composite Young’s modulus slightly decreased with the treatment temperature increasing from 2200 to 2800 °C in spite of the established strong improvement of fibre crystallinity and, therefore, fibre modulus. The mechanisms diminishing the modulus of composite (e.g. partial matrix graphitisation at the fibre/matrix interface and decreasing fibre/matrix contact area) probably prevailed over the increasing contribution of the fibre modulus. 相似文献
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Effect of carbonization rate on the properties of a PAN/phenolic-based carbon/carbon composite 总被引:1,自引:0,他引:1
The effect of carbonization rate in a wide range (1, 100 and 1000 °C/min) on the properties of a PAN/phenolic-based carbon/carbon (C/C) composite was studied. The results indicated that the composite processed at a higher carbonization rate had a higher porosity level, more large pores and a more graphitic structure than that processed at a lower carbonization rate. After second graphitization the bending properties of composites carbonized at 1 °C/min and 1000 °C/min were comparable. The composite carbonized at 1000 °C/min had the highest fracture energy. The composite carbonized at 100 °C/min showed the worst mechanical performance among three. The large increase in carbonization rate can be beneficial to the industry from an economic point of view. 相似文献
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Yijun Li Kunlin Wang Jinquan Wei Zhiyi Gu Zhicheng Wang Jianbin Luo Dehai Wu 《Carbon》2005,43(1):31-35
The mechanical properties of well-aligned double-walled carbon nanotube (DWNT) strands with diameters of 3-20 μm and lengths of ∼10 mm were measured using a stress-strain puller. The average tensile strength and Young’s modulus of the tested strands are 1.2 GPa and 16 GPa, respectively. Deformation and fracture processes of these samples are discussed. The tensile strength and Young’s modulus of an individual DWNT bundle were estimated, with values comparable to those of SWNT bundles. The superior mechanical strengths of our as-prepared DWNT strands are expected to give them potential as a high-strength material and a reinforcement in composites. 相似文献
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Compressive behavior of three-dimensionally reinforced carbon/carbon composite (3D-C/C) was examined from room temperature to elevated temperatures up to about 3000 K. Three-dimensionally reinforced C/C was found to have an inclination to induce kinks at the ends of specimens due to extremely low shear strength. In order to avoid this type of premature fracture and to conduct high-temperature tests, discussion was made on specimen geometry and testing procedure, and the combination of a dumbbell-shape specimen and test configuration without a supporting jig were found to be suitable for the present study. Using this set-up, the compressive strength of a 3D-C/C was evaluated as a function of temperature up to about 3000 K. The compressive strength of the 3D-C/C monotonically increased with the increase in temperature up to 2300 K, but decreased above this temperature. The strength enhancement was suggested to be caused by improvement in the fiber/matrix interfacial bonding, and the degradation over 2300 K was by softening of the matrix at high temperatures. 相似文献
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Electrical properties of polyethylene and carbon black particle blends prepared by gelation/crystallization from solution 总被引:1,自引:0,他引:1
Composite materials based on low molecular weight polyethylene (LMWPE), ultra-high molecular weight polyethylene (UHMWPE) and carbon black (CB) particles were prepared by gelation/crystallization from solution. The positive temperature coefficient (PTC) intensity for the 90/10 (LMWPE/UHMWPE) composition exceeded five orders of magnitude for the specimens heat-treated at a suitable temperature, which was almost equal to that observed with LMWPE-CB blends prepared by a kneading method. In comparison with LMWPE-CB blends, much promoted reproducibility of PTC effect and inhibition of the negative temperature coefficient (NTC) effect were achieved. 相似文献
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The effects of needle-punched felt structure, including mass ratio of non-woven cloth to short-cut fiber web, PAN-based carbon fiber types of non-woven cloth and thickness of unit (one layer of non-woven cloth and short-cut web was named as a unit), on the flexural properties of C/C composites from pressure gradient CVI are discussed. Results show that flexural strength and modulus increase when mass ratio of non-woven cloth to short-cut fiber web changes from 7:3 to 6:4 and that PAN-based carbon fiber types of non-woven cloth strongly influence the flexural properties. The strength of C/C composites is not linear with the strength of non-woven cloth carbon fiber because of the important interface between carbon fiber and matrix carbon. It is suitable to choose T300 or T700 as reinforcing carbon fiber for C/C composites in the present study. An optimum unit number per cm of the needle-punched felts for higher flexural properties exists. 相似文献
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Different fluorination methods were applied to modify the surface properties of carbon fibers. The relationship between the degree of fluorination and the physicochemical properties of carbon fibers was studied using a combination of mechanical tests, elemental analysis (EA), X-ray photoelectron spectrometry (XPS), and X-ray diffraction (XRD). EA and XPS analyses of fluorinated carbon fibers showed that treatment with mixtures of F2/O2 introduced a much higher fluorine concentration than that with F2 only. However, XRD analysis showed that there was no increase in the interlayer distance, due to the mild fluorination condition applied. Consequently, the oxyfluorination was one of the more effective methods to increase surface polarity of carbon fibers, which probably played an important role in improving the tensile properties of the fibers in the epoxy resin system. 相似文献
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Yangqiao Liu 《Carbon》2005,43(1):47-52
Novel carbon nanotube-NiFe2O4 composite materials have been prepared for the first time by in situ chemical precipitation of metal hydroxides in ethanol in the presence of carbon nanotubes (CNTs) and followed by hydrothermal processing. The obtained composite powders were characterized using XRD, TEM and EDS. The effect of surface oxidation treatment of CNTs on their properties was investigated by FTIR, zeta potential and hydrodynamic radius distribution characterization. Electrical conductivity measurements show that surface oxidation treatment of CNTs can improve the electrical conductivity of the composites more pronouncedly than pristine CNTs do. With 10 wt.% addition of surface treated CNTs, the electrical conductivity is increased by 5 orders of magnitude. The surface oxidized CNTs are crucial for this significant increase in electrical conductivity, which provides strong adhesion between the nanotubes and the matrix to give a homogeneous carbon nanotube-NiFe2O4 composite. 相似文献
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Spring-shaped carbon microcoils (CMCs) were embedded in epoxy resins to form CMC/epoxy resin composites. The mechanical properties of the composites were examined and compared with those of conventional straight carbon fiber (CF) /epoxy resin composites. CMCs were found to be more effective than CFs as a reinforcing material for the epoxy resin having a low Young’s modulus (0.54 MPa). SEM images of the fractured cross-sections of the composite revealed that CMCs were not pulled out from the resin matrix but fractured with the matrix. This could be ascribed to the unique conformations of CMCs. 相似文献
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The thermal shock behavior of a three-dimensional carbon fiber reinforced SiC matrix fabricated by chemical vapor infiltration (CVI) technique was studied using the air quenched method. Damage to composites was assessed by a destructive technique of measuring mechanical properties using three-point flexure and SEM characterization. C/SiC composites displayed good resistance to thermal shock, and retained 83% of the original strength after quenching from 1300 to 300°C 100 times. The critical ΔT of C/SiC in combustion environment was 700°C. The critical number of thermal shocks for the C/SiC composite was about 50 times. When the number of thermal shocks was less than 50 times, the residual flexural strength of C/SiC composites decreased with the increase of thermal shock times. When the number of thermal shocks of C/SiC was greater than 50, the strength of C/SiC did not further decrease because the crack density was saturated. 相似文献
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Preparation and characterization of porous carbon beads and their application in dispersing small metal crystallites 总被引:2,自引:0,他引:2
Porous carbon beads were prepared by the pyrolysis of poly(vinylidene chloride) beads that were synthesized by suspension polymerization. After prolysis treatment at 180–300 °C under argon stream, the polymeric beads were further carbonized at 1000 °C for 3 h under argon stream to acquire porous carbon beads, of which the specific surface area was about 1000 m2/g, and pore size was mainly in the width range of 0.8–1.2 nm. The carbon structure and surface chemical composition characterized by X-ray diffraction and X-ray photoelectron spectroscopy, depended on the preparation temperature and the relations between them were examined. The characterization of the carbon beads by scanning electron microscopy, atomic force microscopy presented the morphological structure of the carbon beads surface and a global view of pores. The dispersion of nickel crystallites on the carbon beads surface was characterized by electron microprobe analysis. This study reveals that uniform surface morphological structure leads to the fine dispersion of metal crystallites. 相似文献
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The Li0.35Zn0.3Fe2.35O4 micro-belts were prepared by cotton template for the first time. The nickel-coated carbon fibers were obtained by the electroless plating method. The formation mechanism of the ferrite micro-belt was studied. The microwave absorption properties of the two layers absorbers containing Li0.35Zn0.3Fe2.35O4 micro-belts and nickel-coated carbon fibers composites were investigated in the frequency range of 30–6000 MHz. The absorbers of the Li0.35Zn0.3Fe2.35O4 micro-belts/nickel-coated carbon fibers composites have much better microwave absorption properties than the nickel-coated carbon fibers absorbers, and the microwave absorption properties of the composites are influenced by the content of the absorber. 相似文献
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Sharp indentation tests on carbon fiber and carbon matrix composites (C/C composite) were carried out over a wide load range from 0 to 2 N on three different cross sections: normal, parallel and inclined to the fiber axis. For comparison purposes, a variety of carbons including HOPG, glassy C, and pyrocarbon films was also examined. Both the fibers and the matrices displayed first a purely elastic response and second crack-induced damage. A purely elastic behavior was also observed with most of the varieties of carbon considered. Young’s modulus was extracted from the indentation curves either at maximum or at various forces, using the Sneddon equation of elastic response on loading (elastic indentation) or a classical equation based on elastic recovery on unloading (elastoplastic indentation). Results are discussed with respect to features of structure and heterogeneity of material in the stressed volume. 相似文献
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In this study, the oxyfluorination of PAN-based carbon fibers was undertaken at room temperature using fluorine-oxygen mixtures, and the influence of oxyfluorination on properties such as wettability, surface polarity, surface free energy, conductivity and tensile strength was investigated. As the oxyfluorination time increased at a total pressure of 5 kPa, both the fluorine/carbon and oxygen/carbon ratios increased. The contribution of semicovalent C-F bond to F1s spectra is considerably decreased with increasing total pressure from 5 to 80 kPa, and at the same time, the contribution of covalent C-F bond is increased. As the total pressure of fluorine-oxygen mixtures increased, the contact angle of water significantly decreased and again increased to a similar value to that of as-received carbon fiber. A short oxyfluorination of carbon fibers considerably increased the wettability, that is, hydrophilicity.The electrical conductivity of oxyfluorinated carbon fiber is larger than that of the as-received fiber. This is because the surface region of carbon fiber is fluorinated. An increase in the tensile strength of about 18% after oxyfluorination is observed. The increase in tensile strength of oxyfluorinated carbon fibers can be understood as being due to a decrease in the diameter of the fiber. 相似文献
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High dispersion and electrocatalytic properties of platinum on well-aligned carbon nanotube arrays 总被引:1,自引:0,他引:1
Platinum (Pt) electrocatalyst was electrochemically dispersed on well-aligned carbon nanotube (CNT) arrays by a potential-step method. The structure and elemental composition of the resulting Pt/CNT electrode were characterized by scanning electron microscopy, transmission electron microscopy and energy dispersive X-ray spectroscopy. The electrocatalytic properties of the Pt/CNT electrode for oxygen reduction reaction have been investigated by linear sweep voltammetry. Compared with a Pt/graphite electrode, higher electrocatalytic activity of the Pt/CNT electrode can be observed. This may be attributed to the high dispersion of platinum catalysts and the particular properties of CNT supports. The results imply that the Pt/CNT has good potential applications in proton exchange membrane fuel cells. 相似文献
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Three-dimensional (3D) spring-like carbon nano-coils were obtained in high purity (nearly 100%) and high yield (20%) by the catalytic pyrolysis of acetylene at 750-790 °C using an Fe-based catalyst; 54Fe-38Cr-4Mn-4Mo or 71Fe-18Cr-8Ni-3Mo (SUS513). The morphologies and microstructure were examined in detail, and the growth mechanism is also discussed. The diameter of carbon fiber, from which the carbon nano-coils was formed, was 50-200 nm, the coil diameter 100-1000 nm, and the coil pitch 10-500 nm. The nano-coils were generally grown by a mono-directional growth mode, and laces with various morphologies were very commonly observed on the surface. It was observed that the spring-like carbon nano-coils are actually composed of two fused nano-coils. 相似文献