The Infrared Hall Effect in YBCO: Temperature and Frequency Dependence of Hall Scattering

We measure the Hall angle, _H , in YBCO films in the far- and mid-infrared to determine the temperature and frequency dependence of the Hall scattering. Using novel modulation techniques we measure both the Faraday rotation and ellipticity induced by these films in high magnetic fields to deduce the complex conductivity tensor. We observe a strong temperature dependence of the mid-infrared Hall conductivity in sharp contrast to the weak dependence of the longitudinal conductivity. By fitting the frequency dependent normal state Hall angle to a Lorentzian _H () = _H /( _H – i) we find the Hall frequency, _H , is nearly independent of temperature. The Hall scattering rate, _H , is consistent with _H T ² up to 200 K and is remarkably independent of IR frequency suggesting non-Fermi liquid behavior.     

The Interplay of Electronic and Nuclear Magnetism in PtFe x at Milli-, Micro-, and Nanokelvin Temperatures

We have measured ac susceptibility, nuclear magnetic resonance, and nuclear heat capacity of two PtFe _x samples with concentrations of magnetic impurities x = 11 ppm and 41 ppm at magnetic fields (0 ± 0.05) mTB248 mT. The susceptibility data have been measured at temperatures of 0.3 KT100 mK, no hint for nuclear magnetic ordering could be detected to a temperature of 0.3 K. The nuclear heat capacity data taken at 1.4 KT10 mK show enhanced values which scale with x at low polarization. This effect is described by a model assuming an internal magnetic field caused by the impurities. No indication for nuclear magnetic ordering could be detected to 1.4 K. The nuclear magnetic resonance experiments have been performed on these samples at 0.8 KT0.5 mK and 2.5 mTB22.8 mT as well as on three other samples with x = 5, 10, 31 ppm in a different setup at 40 KT0.5 mK and at 5.4 mTB200 mT. Spin-lattice and effective spin-spin relaxation times ₁and ₂ ^* of ¹⁹⁵ Pt strongly depend on x and on the external magnetic field. No temperature dependence of ₁and ₂ ^* could be detected and the NMR data, too, give no hint for nuclear magnetic ordering to 0.8 K.     

Angular variation of coercivity of interacting fine acicular skeleton particles

For fine, acicular skeleton particles of -Fe prepared from -FeOOH, the effect of interparticle interaction on the angular variation ofH _c was numerically investigated using a direct expansion scheme of the chain-of-spheres fanning model to an interacting chain system forming an orthorhombic type of regular space lattice. The model theory reveals that only magnetostatic lateral interchain interaction can affect the angular variation ofH _c. The results have been used to explain the experimentally observed effects of particle morphology and packing fraction on the angular variation ofH _c in systems made from fine acicular particles prepared for audio/video magnetic recording media. It is suggested that a local aggregate of the so-called multiple type, is unavoidably generated in the system.     

Intensity of critical opalescence of helium-4

We present measurements of the critical opalescence of helium-4. The results are analyzed by the Einstein and Ornstein-Zernike theory and the power laws. We obtain ==1.17±0.02, ==0.62±0.1,/=4.5±0.3,P _c =1706.008 mm Hg, andT _c =5,189.863 mK (T ₅₈ ). The critical behavior of helium-4 is almost the same as that of classical fluids and the influence of the quantum nature of helium-4 is not as evident as has been claimed.     

Some observations on the deformation characteristics of bulk polycrystalline zirconium hydrides

The deformation behaviour of bulk polycrystalline zirconium hydrides in the composition range ZrH_1.27 to ZrH_1.66 has been investigated by compressive loading at temperatures between room temperature and 500° C. Single-phase -zirconium hydride is brittle below 100° C. Analyses of slip traces on specimens deformed at temperatures between 100 and 250° C have shown that the glide planes are {111} types. The deformation characteristics of and ( + ) alloys at temperatures between 100 and 500° C are consistent with the hydrogen vacancies in the -phase providing significant lattice friction to the movement of dislocations in the zirconium lattice of the hydride structure. The room temperature fracture stress of ( + ) alloys increases with the volume fraction of the -phase and this can be related to the resistance offered by platelets to the propagation of cleavage cracks in the matrix. In a ( + + ) alloy the resistance to crack propagation at room temperature is further increased by the soft -zirconium phase.     

A gradient method of defining smooth solutions to inverse boundary-value problems in thermal conduction

An iterative algorithm is described for solving boundary-value inverse problems in thermal conduction by steepest descent, which utilizes information on the smoothness of the solution.Notation A, B linear operators - u element of solution space U - f exact reference data - f reference data uncertainty - value of reference data uncertainty - A^–1 inverse operator - u^(k)() k-th derivative of function u - _m length of observation interval - _i(t) polynomials of degree i–1 - A^*, B^*, L^* operators conjugate to the operators A, B, L - Jg discrepancy functional gradient - _n descent step along the discrepancy antigradient for the n-th iteration - K( –) kernel of integral equation - q() heat flux - T() measured temperature inside body Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 2, pp. 259–263, August, 1980.     

Standard Gibbs' energies of formation of BaCuO2, Y2Cu2O5 and Y2BaCuO5

The Gibbs' energies of formation of BaCuO₂, Y₂Cu₂O₅ and Y₂BaCuO₅ from component oxides have been measured using solid state galvanic cells incorporating CaF₂ as the solid electrolyte under pure oxygen at a pressure of 1.01×10⁵ Pa BaO + CuO BaCuO₂ G _f,ox ^o (± 0.3) (kJ mol^–1)=–63.4–0.0525T(K) Y₂O₃ + 2CuO Y₂Cu₂O₂ G _f,ox ^o (± 0.3) (kJ mol^–1)=18.47–0.0219T(K) Y₂O₃ + BaO + CuO Y₂BaCuO₅ G _f,ox ^o (± 0.7) (kJ mol^–1)=–72.5–0.0793T(K) Because the superconducting compound YBa₂Cu₃O_7– coexists with any two of the phases CuO, BaCuO₂ and Y₂BaCuO₅, the data on BaCuO₂ and Y₂BaCuO₅ obtained in this study provide the basis for the evaluation of the Gibbs' energy of formation of the 1-2-3 compound at high temperatures.     

Transient heat conduction in hollow spheres with a moving inner boundary

The finite integral transform method is used to obtain the solution of unsteady heat conduction problems for a hollow sphere with a moving internal boundary and various boundary conditions at the outer surface. For the solution of the problems of interest integral transform formulas are presented with kernels (16), (20), and (24) and the corresponding inversion formulas (18), (22), (26), (29) and characteristic equations (17), (21), (25), (28), (31), (33).Nomenclature a, thermal diffusivity and conductivity - t temperature of phase transformation - density - heat transfer coefficient - Q total quantity of heat passing through inner boundary - F latent heat of phase transformation - Fo(1,)=a/R ₁ ² , Fo(i,)=/r _i ² , Fo(i, _i)=a _i/r _i ² Fourier numbers - Bi₂=R₂/ Biot number     

Instability of the Critical State in NdBa2Cu3O7−δ Single Crystals

Instabilities of the critical state are observed in various NdBa ₂ Cu ₃ O _7– single crystals by means of direct magneto-optic (MO) imaging while warming up flux states containing vortices of opposite polarity. Using the same samples as in the MO investigations, we observe for the first time characteristic steps in the integral magnetization measured by means of a SQUID system, which allows a constant temperature sweep. The integral measurement technique enables the study of the instability phenomenon (turbulence) in a much wider range of temperatures and fields than the MO investigations, and also in the orientations H _a c and H _a c. As a result, we find turbulence not only in a narrow window of temperatures (65 T 80 K), but also in a window of applied negative fields ranging between 30 and 80 mT.     

Transport property and battery discharge characteristic studies on 1−x(0.75Agl∶0.25AgCl)∶ xAl2O3 composite electrolyte system

Various experimental studies on a new fast Ag⁺ ion-conducting composite electrolyte system: (1–x) (0.75Agl0.25AgCl)xAl₂O₃ are reported. Undried Al₂O₃ particles of size <10 m were used. The conventional matrix material Agl has been replaced by a new mixed 0.75Agl0.25AgCl quenched and/or annealed host compound. Conductivity enhancements 10 from the annealed host and 3 times from the quenched host obtained for the composition 0.7(0.75Agl0.25AgCl)0.3Al₂O₃, can be explained on the basis of the space charge interface mechanism. Direct measurements of ionic mobility as function of temperature together with the conductivity were carried out for the best composition. Subsequently, the mobile ion concentration n values were calculated from and a data. The value of heat of ion transport q* obtained from the plot of thermoelectric power versus 1/T supports Rice and Roth's free ion theory for superionic conductors. Using the best composition as an electrolyte various solid state batteries were fabricated and studied at room temperature with different cathode preparations and load conditions.     

Influence lines for bending under a ring load of a free shell,a shell embedded in a soft medium and a shell containing a soft core

Summary Theoretical expressions for stresses and displacements have been derived for bending under a ring load of a free shell, a shell embedded in a soft medium, and a shell containing a soft core. Numerical work has been done for typical cases with anElliot 803 Digital Computer and influence lines are drawn therefrom.

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Einflußlinien für die Biegung einer freien Schale, einer Schale in einer weichen Bettung und einer Schale mit weichem Kern

Zusammenfassung Für die Biegung einer freien Schale, einer weich gebetteten Schale und einer Schale mit weichem Kern unter einer Ringlast werden Ausdrücke für die Spannungen und Verschiebungen hergeleitet. Die Ergebnisse wurden für einige typische Fälle mit einem DigitalrechnerElliot 803 numerisch ausgewertet. Die sich ergebenden Einflußlinien wurden graphisch dargestellt.

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Nomenclature A (),B () Functions of - a, t Mean radius and thickness of the shell - E _S , _S Young's modulus andPoisson's ratio of the shell - G _c , _c Shear modulus andPoisson's ratio of the casting or core - I ₀ (r),I ₁ (r) ModifiedBessel functions of the first kind and order zero and one respectively - K ₀ (r),K ₁ (r) ModifiedBessel functions of the second kind and order zero and one respectively - p Ring load, lb/in - U, W Displacement components in the casing or core in thez andr direction - u, w Displacement components of a middle surface point in the shell - _r , _rz Radial and shearing stress components - Independent variable of infinite integrals - k [3(1–S ²)a ²/t ²]^1/4 With 13 Figures     

High-frequency dielectric properties of Mg-Al-Si,Ca-Al-Si and Y-Al-Si oxynitride glasses

Recently developed coaxial line techniques [1] have been used to determine, at room temperature, the values of the real () and imaginary (') parts of the dielectric constants for some Mg-Al-Si, Ca-Al-Si and Y-Al-Si oxynitride glasses over the frequency range 500 MHz to 5 GHz. The frequency dependencies of and ' are consistent with the universal law of dielectric response in that (-_t8)^(n–1) and '^(n–1) for all glass compositions; the high experimental value of the exponent (n=1.0±0.1) suggests the limiting form of lattice loss [2] situation. In this frequency range, as previously reported [3] at longer wavelengths, the addition of nitrogen increases the dielectric constant, (); in both the oxide and oxynitride glasses is also influenced by the cation, being increased with cation type in the order magnesium, yttrium, calcium as at lower frequencies.     

Spin hydrodynamic equations with external disturbances and suitable Green's functions for superfluid3He-B. New onsager relations

The spin hydrodynamic equations for superfluid³He-B have been obtained for the case of external, time-dependent fields. On the basis of a microscopic approach, expressions are found for additional terms in equations containing these fields. Considering the linear response of the system to the switching on of external fields, formulas are found for suitable Green's functions (magnetization-magnetization, rotation-rotation, magnetization-rotation, rotation-magnetization). The rotation-rotation Green's function has the 1/q ² singularity characteristic of superfluid systems. Connections between Green's functions lead to relations among kinetic coefficients v, ₁, and ₂. It is also shown that there is a conserved quantityQ ^(B) = div v _s ^(B) that describes sources or magnetic type charges (monopoles) of the superfluid velocity v _s ^(B) . Comparison with the phenomenological approach suggests thatQ ^(B) is proportional to a pseudoscalar giving the projection of the spin density onto the vector describing the axis of rotation.     

Hole pockets in the doped 2D Hubbard model

The electronic momentum distributionn(k) of the two dimensional Hubbard model is studied for different values of the couplingU/t, electronic density n, and temperature, using quantum Monte Carlo techniques. A detailed analysis of the data on 8 × 8 clusters shows that features consistent with hole pockets at momentak = (±/2,±/2) appear as the system is doped away from half-filling. Our results are consistent with recent experimental data for the cuprates discussed by Aebi et al. (Phys. Rev. Lett. 72, 5757 (1994)). In the range of couplings studied, the depth of the pockets is maximum at n 0.9,and it increases with decreasing temperature. The apparent absence of hole pockets in previous numerical studies of this model is explained.     

Experimental Investigation of the Reflectivity of Refractory Dielectric Materials in the Vacuum Ultraviolet Spectral Region

The paper deals with the results of experimental investigation of spectrally averaged group reflectivities R() in a vacuum ultraviolet (h 10 to 70 eV) spectral range of commercial samples of high-temperature dielectric materials (-Al₂O₃, SiO₂, BNC) under conditions of a prethreshold (prior to the beginning of developed surface evaporation) power density of probing radiation.     

Measurements of the dynamic input impedance of a dc SQUID

The impedance of a circuit coupled magnetically via a mutual inductanceM _i to a dc SQUID of geometric inductanceL is modified by the dynamic input impedance of the SQUID, which can be characterized by the flux-to-current transfer functionJ J/;J is the current circulating in the SQUID loop and is the flux applied to the loop. At the same time, the SQUID is modified by the presence of the input circuit: in the lumped circuit approximation, one expects its inductance to be reduced toL ^r=(1– _e ² )L, where _e is an effective coupling coefficient. Calculations of J using an analog simulator are described and presented in the form of a dynamic inductance and a dynamic resistance versus bias currentI and . Experimental measurements of and were made on a planar, thin-film SQUID tightly coupled to a spiral input coil that was connected in series with a capacitorC _i to form a resonant circuit. Thus,J was determined from the change in the resonant freqency and quality factor of this circuit as a function ofI and . At low bias currents (low Josephson frequencies) the measured values of were in reasonable agreement with values simulated for the reduced SQUID, while at higher bias currents (higher Josephson frequencies) the measured values were in better agreement with values simulated for the unscreened SQUID. Similar conclusions were reached in the comparison of the experimental and simulated values of the flux-to-voltage transfer functionV . The reduction in the screening at the higher Josephson frequencies is believed to result from the parasitic capacitanceC _p between the SQUID and the input coil. In contrast to the behavior of the input inductance, the change in the input resistance R _i could not be explained in terms of the dynamic impedance of the SQUID reflected into the input circuit. Instead, R _i was dominated by capacitive feedback between the output of the SQUID and the input circuit viaC _p . The experimental values of R _i were satisfactorily explained by a simplified model that predicts R _i –M _iV ^r (C _p /C _i ).     

Recovery of a creep-deformed Type 316 stainless steel

The recovery of the dislocation structures produced in a Type 316 steel during creep has been examined by annealing over a range of temperatures and times, both in the presence and in the absence of stress. The influence of dislocation recovery on subsequent reloading behaviour has also been examined.Initial dislocation recovery occurs rapidly but the rate of recovery subsequently decreases as precipitate effects become more important. Dislocation recovery in the early, rapid stage appears to be controlled by vacancy diffusion between the dislocation links. The application of stress during recovery leads to an enhancement of the recovery rate in agreement with the network coarsening model whilst the incremental strains observed on reloading after recovery correlate well with the changes in dislocation structure produced during the recovery periods.List of symbols and appropriate values l dislocation link length - D _s self diffusion coefficient - b Burgers vector (2.5×10^–1 m) - C _j equilibrium jog concentration - dislocation link tension - k Boltzman's constant (1.38×10^–23 J atom^–1 K^–1) - T absolute temperature - t recovery time - M mobility term - Z frictional term associated with particles - _d dislocation density determined from micrographs - N _d number of dislocation intersections on test line - p length of test line - S foil thickness - ¯l mean dislocation link length - _c mean intragranular particle (carbide) spacing - r ₀ mean intragranular particle radius at timet=0 - r _t mean intragranular particle radius at timet - D solute diffusion coefficient - B solubility of M₂₃C₆ in austenite - particle-matrix interface energy - atomic volume (10^–29m³) - change in dislocation density during recovery period - incremental strain associated with reloading after recovery period - K constant - dislocation density - ₀ dislocation density at timet=0 - _t dislocation density at timet - ₀ friction stress associated with particles - constant (1) - shear modulus - angle between dislocation segments as dislocation breaks through a particle - A 1 cos (/2) - E constant - creep rate - F Taylor factor - L mean slip distance of dislocations - rate of dislocation recovery - stress - _y yield stress - J strength coefficient - _p plastic strain     

Ionic and electronic conductivity in some simple lithium salts

The electrical conductivity () and thermoelectric power (S) of Li₃VO₄, Li₃PO₄ and Li₃BO₃ solidified melts are presented in the temperature range from 415 K to the melting point of each solid. The ionic ( _i,) and electronic ( _e) contributions to have been separated over the entire temperature range with the help of a time-dependence study of the d.c. electrical conductivity. Superionic phases in all three solids have been observed below their melting points in which the conductivity is almost purely ionic. The value of the phase transition temperature below which the solid transforms from superionic to normal phase has been obtained. It has been shown that in the normal phase, these solids are mixed conductors. Data for the temperature variations of both _i, and _e are also presented and discussed.     

Phase transformations in permanent-mould-cast aluminium bronze

The phases obtained in aluminium bronze (Cu-10Al-4Fe) cast into a permanent mould were investigated. The parameters examined were the pre-heating temperature of the mould and the graphite coating thickness. The phases and ₂ were detected as well as the metastable phases and . The intermetallics of the system Fe-Al were obtained in various stoichiometric compositions. The different cooling rates of the casting resulted in two mechanisms of transformation to grains out of the unstable phase, one being nucleation and growth producing needle-shaped grains, the other exhibiting a massive transformation to spherical grains. These two mechanisms determine the changes in the size of the a grains as result of changes in the cooling rate in its various ranges.