共查询到20条相似文献,搜索用时 93 毫秒
1.
2.
3.
全氟碘烷合成技术进展与应用前景 总被引:4,自引:0,他引:4
秦伟程 《精细化工原料及中间体》2005,(4):21-24
全氟碘烷是一类重要的有机氟中间体,是生产含氟表面活性剂、含氟织物整理剂和其他含氟精细化学品的主要原料,含氟表面活性剂和织物整理作为各自领域的精英产品倍受国内外关注,具有极好的市场空间和发展前景,因此全氟碘烷化合物作为基础原料具有良好开发前景。 相似文献
4.
5.
6.
含氟中间体的生产与开发 总被引:6,自引:0,他引:6
梁诚 《精细与专用化学品》2005,13(21):5-9
介绍了2,4-二氯氟苯、2,4-二氟硝基苯、2,4-二氟苯胺、3,5-二氟苯胺、邻氟苯酚、对三氟甲基苯胺、2,3,5,6-四氟苄醇、六氟丙酮、三氟乙酸、全氟碘烷等21种含氟中间体的用途、生产方法和生产厂家。我国含氟中间体的主要生产厂家有阜新特种化学品股份有限公司、江苏暨阳集团、江苏东方化工集团、台州市第二化工厂、浙江鹰鹏化工有限公司等。 相似文献
7.
全氟碘烷合成技术进展与应用前景 总被引:1,自引:0,他引:1
全氟碘烷是一类重要的有机氟中间体.是生产含氟表面活性剂,含氟织物整理剂和其他含氟精细化学品的主要原料.含氟表面活性剂和织物整理剂作为各自领域的精英产品倍受国内外关注.具有极好的市场空间和发展…… 相似文献
8.
《精细与专用化学品》2008,16(20):33-34
一种氧化还原引发制备全氟烷基碘的调聚方法 本发明涉及一种通式为Rf(CF2CF2)nI的全氟烷基碘的调聚方法,以含氟烯烃为主链物,RfI为调聚剂. 相似文献
9.
含氟表面活性剂具有高表面活性、高耐热稳定性及高化学稳定性以及既憎水又憎油的独特性能,目前已广泛应用于化工、机械、纺织、造纸、涂料、玻璃、陶瓷等许多行业。全氟烷基碘化物(CnF2n+1I,n=1~12)易与乙烯发生加成反应,生成全氟烷基碘乙烯加成物——1,1,2,2-四氢全氟烷基碘.该加成物中碘原子不再与全氟烷基相连,受到全氟烷基的诱导作用减弱,因此1.1,2,2-四氢全氟烷基碘上的碘易发生取代反应,可以转变成相应的醇、硫醇和磺酰氯等各种含氟中间体,故1,1,2,2-四氢全氟烷基碘是制备含氟表面活性剂的重要中间体。在此基础上,可开展大量含氟表面活性剂的研制。其合成路线主要有:(1)在水或水与另一极性溶剂为共溶剂的体系中,以能产生二氧化硫阴离子基的物质为引发剂,以金属的碱或盐为吸酸剂。经全氟碘代烷对乙烯的自由基加成反应而制得。该法反应时间较短.但对设备要求高.反应过程较为复杂。(2)使用金属铜催化剂,在50-200℃.0.01-3MPa下得到目标产物。该法对设备要求高,还需进行催化剂的制备。(3)利用钌/活性炭、铂/活性炭、银/氧化铝等贵金属作为催化剂的方法。该法贵金属价格高,制造成本高。(4)利用偶氮二异丁腈、过氧化苯甲酰等过氧化物作为催化剂的方法。该法工艺简单,引发剂用量少,反应液无需处理可直接进行下一步反应。
本工艺采用了第四条路线.以全氟烷基碘、乙烯为原料,过氧化物为引发剂。经过加成反应一步制得1,1,2,2-四氢全氟烷基碘。 相似文献
10.
11.
Shan Li Yafen Yuan Jiangtao Zhu Haibo Xie Zixian Chen Yongming Wu 《Advanced Synthesis \u0026amp; Catalysis》2010,352(10):1582-1586
2‐Fluoromethylated quinolines were synthesized through the reaction of N‐aryl‐fluorinated imidoyl iodides with terminal alkynes in good yields by the catalysis of copper(I) iodide (CuI) alone. 相似文献
12.
13.
14.
含氟烯烃是一类重要精细化学品,最近几年其制备得到了广泛研究。本文主要介绍了以含氟烷烃为原料经气相催化脱氟化氢制备含氟烯烃的方法。简述了气相催化脱氟化氢法所涉及的反应机理。综述了此法采用的催化剂,主要包括活性炭基催化剂、铬基催化剂和铝基催化剂。活性炭基催化剂制备简单,成本低,但不易再生;铬基催化剂性能优异,但其使用存在引发环境问题的可能;目前铝基催化剂是此法研究的重点,但如何维持较高的活性和选择性,抑制催化剂失活是亟待解决的问题,通过添加合适的助剂有望解决这一问题。 相似文献
15.
16.
17.
含氟聚氨酯树脂涂料的制备及应用 总被引:9,自引:0,他引:9
本文介绍了可溶性的带痉基含氟烯烃的合成及含氟聚氨酯涂料的制备,含氟聚氨酯涂料具有优异的耐候性,保色性及耐热,耐腐蚀,耐化学性,可用于建筑,储罐,船舶和飞机等领域。 相似文献
18.
Fluorinated acrylate latex was prepared by copolymerizing fluorinated monomer, butyl acrylate, and methyl methacrylate, which was initiated by potassium persulfate in the water. The resultant fluorinated latex and its film were characterized with contact angle determinator, dynamic light scattering detector, and differential scanning calorimetry, respectively. Influence of type of fluorinated monomers on colloidal and polymer properties of fluorinated acrylate latex was studied. Results show that the coagulation rate, particle size, contact angle, glass transition temperature, and chemical resistance are increased with the increase of the number of fluorine atom in the fluorinated monomer. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
19.
BACKGROUND: The aim of the present work was to prepare novel fluoroalkyl end‐capped oligomer/zinc oxide nanocomposites by the use of fluoroalkyl end‐capped oligomers as key intermediates. In addition, it was intended to clarify the unique properties of these fluorinated nanocomposites. RESULTS: A variety of fluoroalkyl end‐capped oligomer/zinc oxide nanocomposites were prepared by the interaction of the corresponding oligomers with zinc oxide particles, which were obtained by the reaction of zinc acetate dihydrate with sodium hydroxide in ethanol solution at room temperature. In contrast, fluoroalkyl end‐capped 2‐methacryolyoxyethanesulfonic acid oligomer was found to afford the corresponding fluorinated amorphous zinc oxide composites under similar conditions. CONCLUSION: These fluorinated zinc oxide composites thus obtained are nanometer size‐controlled very fine particles, and they exhibit a good dispersibility and stability in water and traditional organic media. These fluorinated nanocomposites were also applied for the surface modification of poly(methyl methacrylate) (PMMA) films, which gave not only a good surface‐active property imparted by fluorine but also unique characteristics related to the presence of zinc oxide nanoparticles on the modified PMMA film surface. Copyright © 2008 Society of Chemical Industry 相似文献
20.
Probing the Outstanding Local Hydrophobicity Increases in Peptide Sequences Induced by Incorporation of Trifluoromethylated Amino Acids
下载免费PDF全文
![点击此处可从《Chembiochem : a European journal of chemical biology》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Charlène Gadais Dr. Emmanuelle Devillers Dr. Vincent Gasparik Dr. Evelyne Chelain Dr. Julien Pytkowicz Prof. Dr. Thierry Brigaud 《Chembiochem : a European journal of chemical biology》2018,19(10):1026-1030
In order to achieve accurate determination of the local hydrophobicity increases in peptide sequences produced by incorporation of trifluoromethylated amino acids (TfmAAs), the chromatographic hydrophobicity indexes (?0) of three series of tripeptides containing three unnatural trifluoromethylated amino acids have been measured and compared with those of their non‐fluorinated analogues. The hydrophobic contribution of each fluorinated amino acid was quantified by varying the position and the protection of (R)‐ and (S)‐α‐trifluoromethylalanine (TfmAla), (R)‐trifluoromethylcysteine (TfmCys), and (S)‐trifluoromethionine (TFM) in a short peptide sequence. As a general trend, strong increases in hydrophobicity were precisely measured, even exceeding the high hydrophobic contribution of the natural amino acid isoleucine. This study validates the incorporation of trifluoromethylated amino acids into peptide sequences as a rational strategy for the fine‐tuning of hydrophobic peptide–protein interactions. 相似文献