共查询到19条相似文献,搜索用时 62 毫秒
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有机膦酸对碳钢缓蚀性能及机理研究 总被引:1,自引:0,他引:1
采用失重法评定了氨基三亚甲基膦酸(ATMP)、羟基乙叉二膦酸(HEDP)、乙二胺四亚甲基膦酸(EDTMP)、二乙烯三胺五甲叉膦酸(DTPMP)、羟基膦酰基乙酸(HPAA)及2-磷酸丁烷-1,2,4-三羧酸(PBTC)在酸性条件下对碳钢的缓蚀性能,并结合电化学极化曲线研究了有机膦酸的缓蚀机理。结果表明:DTPMP、HEDP、ATMP、PBTC及HPAA为阳极型缓蚀剂,其缓蚀效率由大到小为:DTPMP〉EDTMP〉HEDP〉ATMP〉PBTC〉HPAA。 相似文献
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以2-羟基-4-甲氧基苯乙酮与3-硝基苯胺为原料,在一定条件下,通过加成-脱水反应制备2-羟基-4-甲氧基苯乙酮席夫碱,探讨了合成反应的影响因素,利用元素分析、红外光谱确定其结构,产品的收率为84%。 相似文献
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《Journal of Adhesion Science and Technology》2012,26(2):135-152
AbstractA newly Schiff base, 4-amino-N-benzylidene-benzamide (4-BAB) protection ability was synthesised from a condensation reaction of 4-aminobenzamide (4-AB) and benzaldehyde (BA). Adsorption and corrosion inhibition effect of this compound on mild steel (MS) in 1.0?M HCl solution were studied. The data obtained from measurments of this compound were compared with that of 4-AB and BA using many electrochemical, microscopic and hydrogen gas evolution techniques to clarify superiority of the Schiff base. Some thermodynamic parameters were calculated from experimental results and discussed. The value of ΔGads showed that adsorption of 4-BAB on MS from acidic solution obeys the Langmuir adsorption isotherm model. Surface SEM images of the MS specimens which were exposed to 1.0?M HCl solution in the absence and presence of the inhibitors showed that a homogeneous and protective inhibitor film forms on the metal surface, which hinder corrosive attack. It was concluded that synthesising the Schiff base improves protection ability with respect to related amine and aldehyde and the inhibitive action is in the order of 4-BAB > 4-AB?>?BA.
- Highlights
4-Amino-N-benzylidene-benzamide (4-BAB) is synthesized by condensation reaction between 4-aminobenzamide (4-AB) and benzaldehyde (BA)
The inhibitor efficiencies calculated from all the applied methods are in agreement and are found to be in the order: 4-BAB >4-AB?>?BA
The adsorption process of inhibitors on mild steel surface obeys the Langmuir adsorption isotherm
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利用静态失重法、Tafel极化曲线研究了油酸咪唑啉类缓蚀剂在不同酸介质中对不锈钢的缓蚀性能,并尝试了油酸咪唑啉缓蚀剂与KI的复配实验。结果表明,油酸咪唑啉类缓蚀剂在10%盐酸中和10%硫酸中对不锈钢有很好的缓蚀作用。在10%盐酸介质中,只需加入0.3%的油酸咪唑啉缓蚀剂,不锈钢材质的缓蚀率就能达到98%;在10%硫酸介质中,缓蚀率在油酸咪唑啉缓蚀剂添加量为0.5%时最大,达到94%。与KI的复配结果表明,咪唑啉与KI之间有一定的缓蚀协同效应,复合使用可以达到降低成本和保持高缓蚀率的作用。 相似文献
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Taleb Ibrahim Elron Gomes Ime B. Obot Mustafa Khamis Mohamed Abou Zour 《Journal of Adhesion Science and Technology》2016,30(23):2523-2543
The Calotropis procera leaves extract (CPLE) was investigated as a corrosion inhibitor for mild steel in a CO2-saturated 3.5 wt% NaCl solution using various electrochemical techniques. The results show that the CPLE is an effective inhibitor with inhibition efficiency of 80% using 50 ppm. Polarization studies show that the CPLE acts as a mixed inhibitor, and the adsorption of CPLE follows Langmuir adsorption isotherm. Molecular dynamics simulations reveal that the presence of N, O in the CPLE as well as π-electron systems coupled with high adsorption energies of interaction of the CPLE with steel are responsible for corrosion inhibition performance. 相似文献
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The Citrus aurantifolia leaves extract was tested for corrosion inhibition on the mild steel in a 0.5?M sulfuric acid solution using weight loss, Tafel and EIS. The state of mixed adsorption with the potentiodynamic polarization effect is shown. Citrus aurantifolia showed the strongest corrosion inhibition of 96.46% at a concentration of 250?mg/L. SEM and AFM are used to verify the formation of a protective layer on the surface of mild steel. The adsorption phenomenon was verified using UV-Vis. spectroscopic technique, whereas FT-IR confirmed the presence of several functional groups containing heteroatoms. Adsorption of the inhibitory molecules on the mild steel surface followed the Langmuir adsorption isotherm. All obtained results ensure that C. aurantifolia leaves extract can form an effective blocking layer and control the corrosion process. 相似文献
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The effect of some mercapto functional azole compounds on the corrosion of mild steel in 1 M hydrochloric acid solution was studied by polarization and electrochemical impedance spectroscopy (EIS). Polarization studies showed depression of cathodic and anodic polarization curves in the presence of mercapto functional azole compounds, indicating mixed type corrosion inhibition of the compounds. Double layer capacitance and charge transfer resistance values were derived from EIS results. Changes in impedance parameters are indicative of adsorption of these compounds on the metal surface. Surface analysis SEM/EDX showing presence of sulfur on the surface confirmed the adsorption of the azole compounds on the mild steel surface as showed by electrochemical methods. Both compounds contain a pyridine-like nitrogen atom and a sulfur atom in their molecular structure, while they differ in only one heteroatom: oxygen in the oxazole ring and pyrrole-like nitrogen in the imidazole ring. The results of the electrochemical techniques revealed that changing the pyrrole like nitrogen atom to oxygen atom in the azole ring results in a decrease of corrosion inhibition performance in hydrochloric acid solution, which could be related to more negative charge on pyrrole-like nitrogen atom in comparison to oxygen atom as depicted by quantum chemical calculations. 相似文献
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2-(N,N-dimethylamino) benzylidene imino-4-(4-methyl phenyl)-1,3-thiazole (DIMPT), 2-benzylidene imino-4-(4-methyl phenyl)-1,3-thiazole (BIMPT), 2-salicylidene imino-4-(4-methyl phenyl)-1,3-thiazole (SIMPT) and 2-cinnamylidene imino-4-(4-methyl phenyl)-1,3-thiazole (CIMPT) were synthesized in the laboratory and their influence on the inhibition of corrosion of mild steel in 20 formic acid and 20 acetic acid was investigated by weight loss and potentiodynamic polarization techniques. The inhibition efficiency of these compounds was found to vary with their nature and concentration, temperature, immersion time and acid concentration. The values of activation energy and free energy of adsorption of the thiazoles were calculated to investigate the mechanism of corrosion inhibition. The adsorption of all the thiazoles on mild steel surface was found to obey Langmuir adsorption isotherm. The potentiodynamic polarization result revealed that the compounds studied are mixed type inhibitors. Electrochemical impedance spectroscopy was used to investigate the mechanism of corrosion inhibition. 相似文献
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Mahendra Yadav Rajesh Ranjan Sinha Tarun Kanti Sarkar Nidhi Tiwari 《Journal of Adhesion Science and Technology》2013,27(16):1690-1713
Synthesized compounds, namely methyl 5-(4-Chlorobenzoyloxy)-1-phenyl-1H-pyrazole-3-carboxylate (MCPPC) and 5-(4-methoxyphenyl)-3-(4-methylphenyl)4,5-dihydro-1H-pyrazol-1-yl-(pyridin-4-yl)methanone (MMDPPM) were investigated as corrosion inhibitor for mild steel (MS) in 15% HCl solution using weight loss measurement, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) methods. Inhibition efficiency was found concentration-dependent and increased by increasing the concentration of MCPPC and MMDPPM. Both of inhibitors were efficient even at a very low concentration of 25 ppm. The inhibitors MCPPC and MMDPPM showed inhibition efficiency of 67.1 and 76.8%, respectively, at 25 ppm, whereas it was 92.0 and 95.9%, respectively, at 250 ppm concentration at 303 K. The potentiodynamic polarization curves showed that MCPPC and MMDPPM act as mixed-type inhibitor in 15% HCl solution. The Nyquist plots showed that charge transfer resistance increased and double-layer capacitance decreased on increasing the concentration of studied inhibitors due to adsorption of inhibitor molecules on MS surface. The adsorption of each inhibitor on MS surface obeys Langmuir adsorption isotherm. On the basis of thermodynamic adsorption parameters, mixed-type adsorption (physisorption and chemisorption) for the studied inhibitors on MS surface was suggested. Scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and atomic force microscopy (AFM) analyses confirmed the existence of a protective film of the inhibitor on MS surface. The density functional theory was employed for theoretical calculations, and the obtained results were found to be consistent with the experimental findings. 相似文献