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低温煤焦油的综合利用 总被引:2,自引:0,他引:2
随着国内煤低温干馏的发展,低温煤焦油的产能也随之不断增加.为综合高效利用低温煤焦油,解决其燃烧过程中的环境问题,对低温煤焦油性质和组成、加工工艺及两种主要工艺路线(燃料型和燃料-化工型)的经济性进行了研究.结果表明:低温煤焦油加工应选择先提酚类,而后加氢的燃料-化工型路线.该路线有效地利用了低温煤焦油中的高附加值组分,工艺合理,投资回收期短,是产业化前景较为广阔的路线. 相似文献
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本文综合评述了当前发展煤基精细化工的若干技术论点,并就煤基精细化工的加工技术进行了初步的探讨。文章以煤的焦化生产中得到的煤焦油和粗苯这两大化工原料资源为重点,论述了发展煤基精细化工必须对煤焦油和粗苯资源进行集中加工、合理利用;对精细化工发展要统一规划,突出重点;要加快技术进步,实现产品的升级换代,要努力开发新品种,调整产品品种结构;要提高产品加工深度,生产精细化工中间体及产品和加强应用研究与技术服务。同时介绍了部分粗苯和煤焦油组分的深度加工工艺与最终产品及其用途。 相似文献
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煤焦油、苯的加工利用 总被引:3,自引:0,他引:3
概述了国外煤焦油加工企业的典型发展模式及特点。详细介绍了中国煤焦油加工行业的发展状况:产业集中度低、深加工水平不高是其发展中存在的主要问题;集中化、大型化、深加工、节能高效化、清洁化和品种多样化是其今后发展方向,指出发展煤焦油加工要合理引导、布局煤焦油加工企业,合理确定工艺路线和产品结构,提高焦油沥青产量。并就宝钢化工煤焦油加工的现状进行介绍。 相似文献
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焦化粗苯和煤焦油的加工 总被引:1,自引:0,他引:1
世界粗苯和煤焦油加工能力基本稳定,但加工利用潜力较大,重点转向精细化工利用。文章介绍了莫夫莱苯萃取精馏工艺、定向结晶生产精萘工艺、新工艺炭黑、酚类抗氧剂和煤沥青碳纤维等新技术的进展动态。 相似文献
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苯乙烯是重要的石油化工原料。本文介绍了国内外苯乙烯生产的发展概况,合成乙苯,苯乙烯所用的催化剂种类,并就苯乙烯生产及催化剂的发展趋势提出了自己的观点。 相似文献
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Synthesis and characterization of homopolymers and copolymers of various acrylates and acrylonitrile
Various homopolymers and copolymers of methyl acrylate, ethyl acrylate, butyl acrylate, and acrylonitrile in different feed ratios were synthesized. These were characterized by IR, 13C-NMR, DSC, DTA, and TGA. Spectroscopic characterization helped in differentiating copolymers of different mol ratios. Thermal analysis revealed different degradation patterns for homopolymers and copolymers. The temperature and energy changes associated with various phase transitions were dependent on the chemical composition of homo- and copolymers, as expected. © 1993 John Wiley & Sons, Inc. 相似文献
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The variation of the Au 4f binding energy of Au clusters with the cluster size has been established by measuring the binding energies of clusters whose size distributions were independently determined by HREM and STM. The binding energy increases significantly when the cluster size is less than 2 nm. Au-Cu bimetallic clusters of the composition Cu3Au have been deposited for the first time on carbon substrates. The shifts in the core level binding energies of the bimetallic clusters show the effect of alloying in the case of large clusters, but show effects of both alloying and cluster size in the case of the small clusters. The interaction of CO with Cu3Au clusters is stronger than with a bulk Cu metal. The interaction of CO with small Cu clusters also seems to be stronger than with bulk Cu or with large Cu clusters. 相似文献
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《国际聚合物材料杂志》2012,61(1-4):113-122
Abstract Kinetics and mechanisms of oxidation of 6 acetals by molecular oxygen and ozone in liquid phase have been studied. Reaction with molecular oxygen (70°C, 15–16 hr) leads to the formation monoethers of the corresponding glycols with 68–90% selectivity. Salts of metals and complexes with crown-ethers have increased the reaction rate significally. Ozone have reacted with acetals with formation similar products. The mechanisms of intermediate stages have been proposed. 相似文献
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G. R. Hamed 《The Journal of Adhesion》1983,16(1):31-39
A substantially greater detachment energy is required to strip a polyethylene tereph-thalate (Mylar) film from a styrene-butadiene-styrene (SBS) triblock copolymer compared to that for peeling from a random styrene-butadiene (SBR) copolymer. This is true even though the intrinsic interaction between the Mylar and each elastomer is expected to be similar because of their virtually identical chemical composition. It is proposed that this difference in peel strength (between the SBS and SBR) is a consequence of the much higher dissipative capacity of the former elastomer. Another manifestation of this is the higher cohesive tear strength of the SBS compared to the SBR. Extents of energy dissipation within each elastomer during detachment of the Mylar adherend are consistent with the hypothesis that the average maximum stress experience before detachment is some similar fraction of each elastomer's tensile strength. 相似文献
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责任是人应主动承担的角色义务和对其因过失所造成后果应承担的责罚.有两层涵义:一是义务;二是后果.责任心是个体自觉做好分内事务和履行道德义务的心理倾向,是个性心理品质成分中自我特征维度上的重要内容.责任心具有两个方面的涵义:一是角色分内职责;二是角色道德义务.责任心是一种通过责任认知、责任个性和责任适应的动态形式表现出来的静态品质,责任心是责任心过程结构与责任心关系结构相互制约、相互影响的统一体. 相似文献
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Polypentafluorostyrene (PPFS), polymethylacrylate (PMA), and poly(pentafluorostyrene-co-methylacrylate), poly(PFS-co-MA) were prepared and the wetting characteristics of polymer blends of PPFS and PMA were compared with that of poly(PFS-co-MA) via contact angle measurements. The critical surface tension of polypentafluorostyrene was found to be 22.6 dyne/cm, which is comparable to the value reported for polytrifluoroethylene (22 dyne/cm). The critical surface tension of poly(PFS-co-MA) is not linearly related to its composition. The polymer blends of PPFS and PMA exhibit significant surface enrichment of the fluoropolymer. The harmonic-mean method1 was employed to determine surface tensions of these polymers and many known polymers. It is found that the method produces useful surface tension data provided the contact angle values are derived from testing liquids of dissimilar polarity. 相似文献