SiN/Ag/SiN新型光谱选择性透过涂层的设计与制备

光谱选择性透过涂层在节能窗上能有效反射红外光,通过减少室内外的热传递而降低能耗。本文分别测量SiN膜和Ag膜的透射光谱和光学常数,利用TFCale软件对SiN/Ag/SiN选择性透过涂层的各层厚度进行优化设计并利用磁控溅射进行制备。使用紫外-可见-近红外分光光度计（UV/VIS/NIR）、扫描电子显微镜（SEM）和俄歇电子能谱（AES）测试与表征涂层的选择透过特性、微观形貌与成分分布。结果表明,实际制备的涂层厚度及光学性能与理论设计值具有良好的一致性。当SiN/Ag/SiN涂层的各层厚度分别为30/15/35 nm时,其可见光和近红外波段的透射率分别为73.1%和17.2%,体现出明显的选择透过性。观察Ag膜的生长模式,发现15 nm的Ag膜仍处于岛状粒子生长阶段,上层的SiN层粒子会在沉积过程中进入Ag岛之间的缝隙。探究不同类型涂层的光学性能,发现金属Ag薄膜对选择透过涂层的红外透过率有显著影响,且外层的SiN薄膜是保证涂层可见光透过率的关键因素。     

热等静压(HIP)对CVDZnS光学性能的影响

对化学气相沉积(CVD)ZnS经热等静压(HIP)处理前后在光学透过率等方面的改变进行了比较分析。针对温度、原生样品厚度等因素对样品性能的影响做了详细阐述。实验表明，热等静压对原生CVDZnS光学性能有促进作用，随处理温度的升高，透过率在1010～1050℃之间出现峰值；原生样品厚度的影响不容忽视，导热均匀的薄样品晶粒均匀且尺寸较大，光学及力学性能要好于厚样品。     

硬质合金基体上金刚石膜粘附性能的影响因素探讨

采用压痕试验法的临界开裂（或剥落）载荷PCr和抗裂性参数dP/dX两指标系统,评定了硬质合金基体经不同预处理工艺和沉积工艺参数全盛的金刚石膜的粘附性能。探讨了粘附性能指标与基体表面钴相含量、表面粗糙度、主要沉积工艺参数（如甲烷浓度、沉积气压、沉积功率）、膜中残余应力之间的内在关系。适当的基体表面预处理、合适的甲烷浓度、较低的沉积气压、较高的沉积功率、适中的残余应力均有利于改善硬质合金基体上金刚石膜的粘附性能。     

厚度对室温沉积ZnO:Al薄膜光电特性的影响

利用直流磁控溅射法, 在室温玻璃衬底上制备了具有良好附着性的多晶ZnO∶ Al(ZAO)薄膜. 比较了室温下获得的薄膜与衬底加热条件下所得薄膜的结晶程度, 研究了厚度对室温条件下制备的ZAO薄膜表面形貌、电学性能及紫外-可见-近红外光区透光性的影响. 结果表明, 室温条件下制备的ZAO薄膜也具有(002)面择优取向, 随着膜厚的增加薄膜晶粒化程度提高, 载流子浓度和迁移率增大, 电阻率下降, 薄膜在紫外光区的吸收边发生红移, 在可见光区的平均透过率降低, 在近红外光区的透过率随厚度的增加而减小. 厚度为1200 nm的ZAO薄膜具有最佳光电综合性能, 其电阻率为7.315×10~(-4) Ω·cm, 方块电阻为6.1 Ω/□, 可见光区平均透过率达到82%, 波长为550 nm处的透过率为87%.     

SiC纤维增强TB8复合材料工艺对组织影响规律

通过箔-纤维-箔法制备了SiC纤维增强TB8复合材料，采用光学电子显微镜（OM）、扫描电镜（SEM）和电子探针（EPMA）对复合材料的微观组织进行表征与分析，研究了真空热压复合时压力、温度和时间等工艺参数对SiC纤维增强TB8复合材料微观组织的影响规律。结果表明：压力显著地影响着复合材料基体与基体以及纤维与基体的结合，而温度对纤维基体界面反应情况影响较大。通过热压工艺的优化，可以有效控制界面反应层厚度，获得组织优良的SiCf/ TB8复合材料。     

钛合金表面多弧离子镀TiAlN薄膜微观组织结构及性能研究

采用多弧离子镀技术在TC11钛合金基体上沉积了TiAlN涂层。金相截面组织观察和扫描电镜表面形貌照片显示,制备出的膜层连续、光滑、孑L隙率低、组织致密;X射线衍射分析表明,膜层的相结构中大致含有以下组成相：（Ti,A1）N、Ti2A1N、Ti。用EDS能谱分析对膜层中的元素含量进行了测定,发现Al元素出现了成分负偏析。性能测试表明,TiAlN膜具有较高的硬度和膜／基结合力。     

包壳用锆合金表面Cr涂层的高温耐蚀性能

为了提高包壳用锆合金的耐高温腐蚀性能,采用等离子增强物理气相复合沉积（PPC）技术在Zr-4合金试样表面制备了厚度为15μm的Cr涂层,并对其性能进行了表征。通过在（420±3）℃,（10.3±0.7）MPa高温高压蒸汽中进行100 d腐蚀试验,对比了Zr-4基体和Cr涂层试样在高温蒸汽中腐蚀100 d后的耐蚀性能,利用X射线衍射（XRD）分析了涂层的物相,利用扫描电镜（SEM）分析了试样腐蚀后的氧化层厚度及断面形貌,利用能谱（EDS）线扫描分析了腐蚀后试样断面的元素成分,利用金相显微镜（OM）检测试样内部氢化物分布并采用气体分析法测量氢含量。结果表明：采用PPC技术制备的Cr涂层均匀致密,无裂纹、孔洞等缺陷;经高温高压蒸汽腐蚀后,试样表面Cr涂层氧化加重,随着腐蚀时间的延长,基体表面氧化膜厚度逐渐增加,而Cr涂层会发生减薄现象,但剩余涂层连续致密,且基体未出现氧化腐蚀现象,说明Cr涂层具有良好的耐蚀性能;涂层试样比基体具有更低的腐蚀增重率,说明Cr涂层能对基体起到保护作用;Cr涂层部分涂覆的试样涂层与基体过渡区基体侧出现氧化层,但氧化层厚度均匀一致,说明Cr涂层并未加速基体的腐蚀;与...     

膜结构对钛／铌快速扩散行为的影响

膜结构对钛／铌快速扩散行为的影响日本国家金属研究所研究了膜结构时铌膜／钛基体和钛膜／铌基体的快速扩散行为影响。这种钛基体上的铌膜和铌基体上的钛膜是用电子束沉积而获得的。将沉积样品在真空中加热，并用俄歇电子光谱对通过膜的基体元素的扩散行为进行了研究，还...     

晶体硅太阳电池减反射膜的研究

为了提高晶体硅太阳能电池的光电转换效率,以及获得较佳的减反射膜的膜厚和折射率,根据计算得出的在波长为600 nm的太阳光下减反射膜的膜厚和折射率的最佳理论值,设计了三组等离子体增强化学气相沉积工艺(1#,2#和3#工艺),来制备不同膜厚和折射率的SiNx∶H(氮化硅)减反射膜.实验结果显示:1#工艺对应的膜厚为83 n...     

制备MoO2粉末的方法、由MoO2粉末制备的产品、MoO2薄膜的沉积以及使用这种材料的方法

本发明涉及在旋转或舟形炉中，通过使用氢作为还原剂，还原钼酸铵或三氧化钼得到的高纯MoO2粉末。将通过压制／烧结、热压和／或HIP进行的粉末固结用来制备圆盘、厚块或板，该圆盘、厚块或板用作溅射靶。使用适宜的溅射方法或其他物理方式将该MoO2圆盘、厚块或板形式溅射在基底上，从而提供具有期望膜厚的薄膜。就透射率、导电率、功函数、均匀性以及表面糙度而言，该薄膜具有与氧化铟锡（ITO）和掺锌ITO可比或优于其的性能如电的、光的、表面粗糙度以及均匀性。可将该MoO2和含该MoO2的薄膜用在有机发光二极管（OLED）、液晶显示器（LCD）、等离子体显示板（PDP）、场致发射显示器（FED）、薄膜太阳能电池、低电阻率欧姆接触以及其他电子和半导体器件中。     

China's Major Non-ferrous Metals Imports & Exports

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Zinc Production by Province in 2014

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80% of Chinese Firms Purchasing Overseas Mines Ended up in the Red

<正>Minmetals Resources acquired the world’s largest copper mine under construction for USD5.85 billion.One after another,listed companies Jien Nickle,China Molybdenum and Chihong Zinc and Germanium raised money to get involved in overseas mining projects…SOEs and private enterprises are engaged in a frenzy of overseas mine purchasing.A reporter with Economic     

Copper Processing Profit Dropped Sharply,Copper Consumption Will Face Impact in the Second Half of the Year

正Judging from China’s copper consumption field,the biggest consumption unit is electric power,which accounts for 47%of total consumption;it is followed by light industry sector,including household electrical appliance,machinery,durable goods and hardware etc,which accounts for 22%of total consumption;followed by transportation field,     

Central Geological Prospecting Fund Newly Added 16.47 Million Tonnes of Bauxite in 2013

正In 2013,the Central Geological Prospecting Fund(CGPF)Project newly discovered 15 ore fields,including 3 large above ore fields,and 5medium sized ore fields.The reporter learned from the recently published"Annual Report of Central Geological Prospecting Fund Project(2013)"that,from 2006 to 2013 the CGPF     

Manufacturers of Copper Tube for Central Air Conditioner Use Face Mounting Pressure in the Final Quarter of the Year

正This year,the investment growth rate of real estate industry continued to slow down,sold area of commercial housing also dropped significantly,which brought huge pressure to the domestic air conditioning manufactures.In the first half of the year,by relying on high growth in national financial expenditure,along with investment in public infrastructure     

Xinjiang Ranks No.1 in Production of Primary Aluminum in China

正Kang Yi,Honorary Chairman of China Nonferrous Metals Industry Association,said recently at the Forum on Development of the Non-ferrous Metals Industry in Central and Western China held in Zhengzhou that,as more and more electrolytic aluminum factories in Xinjiang came into operation,the electrolytic aluminum output of Xinjiang had reached2,275,000 tons in the first 7 months this year,     

Shenhuo Coal Industry and Electricity Power Completed800,000 t/a Aluminum Project in Xinjiang

正"Xinjiang project has been completed according to schedule,but total completion and total start of production are two different concepts,after completion it still needs a gradual process of reaching production target."On the morning of November 3,Shenhuo Coal Industry and Electricity Power told investors the above statement on the investor interaction platform.     

Guangdong Metal Transaction Center has Become the Second Largest Precious Metal Transaction Platform Nationwide

正The reporter learned from Guangdong Province Precious Metal Transaction Center that in 2013the Center maintained healthy development momentum,and had become the second largest precious metal transaction platform in China in terms of market size;currently Guangdong is quickening steps of financial innovation for the Center,aiming to build a transaction center with international core competitiveness.     

Seven Rare Earth Projects Involving Close to 3 Billion Yuan Investment Landed In the HighTech Zone

正On May 22,Baotou Rare Earth Industry Cooperation Consultation MeetingProject Agreement-signing Ceremony was held in Ningbo,nearly 40 enterprises from Ningbo,Guangdong,Hunan,and Shanxi participated in project consultation.After multi-lateral communication,agreements were signed for a total of 7 rare earth projects successfully.